| Common Name: | LITHIUM-ION RECHARGEABLE BATTERIES |
| Manufacturer: | SHENZHEN XTE TECHNOLOGY CHINA |
| SDS Revision Date: | 1/1/2007 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4NUP9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
MATERIAL SAFETY DATA SHEET
DOCUMENT NO.: XTE-A601
XTNY
SHENZHEN XTE TECHNOLOGY CO., LTD
(FORM ACCORDING TO EEC DIRECTIVE 93/112/EC)
NAME: LITHIUM-ION RECHARGEABLE BATTERIES
| 1 - IDENTIFICATION (OF THE PRODUCT AND THE SUPPLIER) |  |
1.1 PRODUCT: RECHARGEABLE BATTERY
TRADE NAME AND MODEL: ALUMINUM RIND LITHIUM-ION BATTERY
MODELS:
XT052030
XT033450A
XT043048AT
XT053436A
XT053040A
XT053450A
XT063048AH
XT063450AR
XT083448A
XT033450AT
XT033448A
XT043048A
XT053455A
XT053048A
XT053450AL
XT063048AB
XT063450ARH
XT103450AR
XT033450AL
XT033048A
XT434260A
XT052246A
XT053048AH
XT063048A
XT063448A
XT073048A
XT103450ARL
XT033450AB
XT043048AL
XT043450AL
XT052248A
XT053048AS
XT063048AL
XT063465A
XT402535
XT043450A
ELECTROCHEMICAL SYSTEM:
ELECTRODES:
NEGATIVE ELECTRODE: CARBON
POSITIVE ELECTRODE: LITHIUM COBALTITE (LiCoO2)
ELECTROLYTE:
SOLUTION OF LITHIUM HEXAFLUOROPHOSPHATE (LiPF6) IN A MIXTURE OF ORGANIC
SOLVENTS
NOMINAL VOLTAGE: 3.7 VOLTS
EQUIVALENT NAME: LITHIATED COBALT OXIDE.
ETHYLENE CARBONATE (EC) + DIMETHYL CARBONATE (DMC) + DIETHYL CARBONATE
DEC).
1.2 SUPPLIER:
NAME: XTE TECHNOLOGY CO., LTD
ADDRESS:
MINGZHI INDUSTRY PARK
MINGZHI, LONGHUA TOWN
BAOAN DISTRICT SHENZHEN
CHINA
PHONE: +86-755-29611112
FAX: +86-755-81755155
| 2 - COMPOSITION | |
(TYPICAL WEIGHT PERCENTAGES OF BASIC MATERIAL)
METALS %
STEEL 2-5
COPPER 6-9
ALUMINUM 14-33
LITHIUM METAL 0
NICKEL 0-2
OTHERS %
LITHIUM COBALTITE 23-33
Li 2.3
CARBON 12-17
ORGANIC SOLVENTS 12-15
SALTS 8-12
POLYPROPYLENE
POLYETHYLENE 0-2
POLYVINYLIDENE FLUORIDE(PVDF) 1-4
| 3 - HAZARDS IDENTIFICATION | |
3.1 PHYSICAL:
THE LITHIUM-ION RECHARGEABLE BATTERIES DESCRIBED IN THIS MATERIAL SAFETY
DATA SHEET ARE SEALED UNITS WHICH ARE NOT HAZARDOUS WHEN USED ACCORDING TO
THE RECOMMENDATIONS OF THE MANUFACTURER.
UNDER NORMAL CONDITIONS OF USE, THE SOLID ELECTRODE MATERIALS AND LIQUID
ELECTROLYTE THEY CONTAIN ARE NON-REACTIVE PROVIDED THE BATTERY INTEGRITY IS
MAINTAINED AND SEALS REMAIN INTACT. RISK OF EXPOSURE ONLY IN CASE OF ABUSE
(MECHANICAL, THERMAL, ELECTRICAL) WHICH LEADS TO THE ACTIVATION OF THE
SAFETY VALVE AND/OR THE RUPTURE OF THE BATTERY CONTAINER. ELECTROLYTE
LEAKAGE, ELECTRODE MATERIALS REACTION WITH MOISTURE/WATER OR BATTERY
VENT/EXPLOSION/FIRE MAY FOLLOW, DEPENDING UPON THE CIRCUMSTANCES.
XT BATTERIES ARE FITTED WITH A SAFETY VENT FOR PROTECTION IN CASE OF
EXCESSIVE INTERNAL PRESSURE AND/OR TEMPERATURE.
3.2 CHEMICAL:
CLASSIFICATION OF DANGEROUS SUBSTANCES CONTAINED INTO THE PRODUCT AS PER
DIRECTIVE 67/548/EEC
SUBSTANCE CHEMICAL SYMBOL MELTING POINT BOILING POINT
CAS NO
12190-79-3 LiCOO2 >1000 DEG. C N/A
EC: 96-49-1 ORGANIC SOLVENTS EC: 38 DEG. C EC: 243 DEG. C
DMC: 616-38-6 (DC-DMC DEC) DMC: 4 DEG. C DMC: 90 DEG. C
DEC: 105-58-8 DEC: -43 DEG. C DEC: 127 DEG. C
21324-40-3 LiPF6 N/A N/A
(DECOMPOSES AT
160 DEG. C)
SUBSTANCE CLASSIFICATION
CAS NO EXPOSURE INDICATION SPECIAL SAFETY
LIMIT OF DANGER RISK(1) ADVICES(2)
12190-79-3 0.1 MG/M3 R22 S2 S22
OSHA R43 S24 S26
S36
S37 S43
S45
EC: 96-49-1 NONE FLAMMABLE R21 S2 S24
ESTABLISHED R22 S26 S36
DMC: 616-38-6 OSHA R41 S37 S45
R42/43
DEC: 105-58-8
21324-40-3 NONE IRRITANT R14 S2 S8 S22
ESTABLISHED CORROSIVE R21 S24 S26
OSHA R22 S36
R41 S37 S45
R43
1 - NATURE OF SPECIAL RISKS:
R 14: REACTS WITH WATER.
R 21: HARMFUL IN CONTACT WITH SKIN.
R 22: HARMFUL IF SWALLOWED.
R 41: RISK OF SERIOUS DAMAGE TO THE EYE.
R 42/43: MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT.
R 43: MAY CAUSE SENSITIZATION BY SKIN CONTACT.
2 - SAFETY ADVICES:
S 2: KEEP OUT OF REACH FROM CHILDREN.
S 8: KEEP AWAY FROM MOISTURE.
S 22: DO NOT BREATHE DUST.
S 24: AVOID CONTACT WITH SKIN.
S 26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ATTENTION.
S 36: WEAR SUITABLE PROTECTIVE CLOTHING.
S 37: WEAR SUITABLE GLOVES.
S 45: IN CASE OF INCIDENT, SEEK MEDICAL ATTENTION.
| 4 - FIRST AID MEASURES | |
IN CASE OF BATTERY RUPTURE OR EXPLOSION, EVACUATE PERSONNEL FROM
CONTAMINATED AREA AND PROVIDE MAXIMUM VENTILATION TO CLEAR OUT FUMES/GASES.
IN ALL CASE, SEEK MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH PLENTY OF WATER (EYELIDS HELD OPEN) FOR AT LEAST 15 MINUTES.
SKIN CONTACT:
REMOVE ALL CONTAMINATED CLOTHING AND FLUSH AFFECTED AREAS WITH PLENTY OF
WATER AND SOAP FOR AT LEAST 15 MINUTES.
DO NOT APPLY GREASES OR OINTMENTS.
INGESTION:
DILUTE BY GIVING PLENTY OF WATER AND GET IMMEDIATE MEDICAL ATTENTION.
ASSURE THAT THE VICTIM DOES NOT ASPIRATE VOMITED MATERIAL BY USE OF
POSITIONAL DRAINAGE.
ASSURE THAT MUCUS DOES NOT OBSTRUCT THE AIRWAY.
DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
INHALATION:
REMOVE TO FRESH AIR AND VENTILATE THE CONTAMINATED AREA.
GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.
| 5 - FIRE-FIGHTING MEASURES | |
FIRE AND EXPLOSION HAZARD:
THE BATTERIES CAN LEAK AND/OR SPOUT VAPORIZED OR DECOMPOSED AND COMBUSTIBLE
ELECTROLYTE FUMES IN CASE OF EXPOSURE ABOVE 90 DEG. C RESULTING FROM
INAPPROPRIATE USE OR FROM THE ENVIRONMENT.
POSSIBLE FORMATION OF HYDROGEN FLUORIDE (HF) AND PHOSPHOROUS OXIDES DURING
FIRE.
LIPF6 SALT CONTAINED IN THE ELECTROLYTE RELEASES HYDROGEN FLUORIDE (HF) IN
CONTACT WITH WATER.
EXTINGUISHING MEDIA:
SUITABLE: CO2, DRY CHEMICAL OR FOAM EXTINGUISHERS
NOT TO BE USED: TYPE D EXTINGUISHERS
SPECIAL EXPOSURE HAZARDS:
FOLLOWING CELL OVERHEATING DUE TO EXTERNAL SOURCE OR DUE TO UNPROPER USE,
ELECTROLYTE LEAKAGE OR BATTERY CONTAINER RUPTURE MAY OCCUR AND RELEASE
INNER COMPONENT/MATERIAL IN THE ENVIRONMENT.
EYE CONTACT:
THE ELECTROLYTE SOLUTION CONTAINED IN THE BATTERY IS IRRITANT TO OCULAR
TISSUES.
SKIN CONTACT:
THE ELECTROLYTE SOLUTION CONTAINED IN THE BATTERY CAUSES SKIN IRRITATION.
INGESTION:
THE INGESTION OF ELECTROLYTE SOLUTION CAUSES TISSUE DAMAGE TO THROAT AND
GASTRO/RESPIRATORY TRACT.
INHALATION:
CONTENTS OF A LEAKING OR RUPTURED BATTERY CAN CAUSE RESPIRATORY TRACT,
MUCUS, MEMBRANE IRRITATION AND EDEMA.
SPECIAL PROTECTIVE EQUIPMENT:
USE SELF-CONTAINED BREATHING APPARATUS TO AVOID BREATHING IRRITANT FUMES.
WEAR PROTECTIVE CLOTHING AND EQUIPMENT TO PREVENT BODY CONTACT WITH
ELECTROLYTE SOLUTION.
| 6 - ACCIDENTAL RELEASE MEASURES | |
THE MATERIAL CONTAINED WITHIN THE BATTERIES WOULD ONLY BE EXPELLED UNDER
ABUSIVE CONDITIONS. USING SHOVEL OR BROOM, COVER BATTERY OR SPILLED
SUBSTANCES WITH DRY SAND OR VERMICULITE, PLACE IN APPROVED CONTAINER (AFTER
COOLING IF NECESSARY) AND DISPOSE IN ACCORDANCE WITH LOCAL REGULATIONS.
| 7 - HANDLING AND STORAGE | |
THE BATTERIES SHOULD NOT BE OPENED, DESTROYED NOR INCINERATE SINCE THEY
MAY LEAK OR RUPTURE AND RELEASE IN THE ENVIRONMENT THE INGREDIENTS THEY
CONTAIN.
HANDLING:
DO NOT CRUSH, PIERCE, SHORT (+) AND (-) BATTERY TERMINALS WITH CONDUCTIVE
(I.E. METAL) GOODS. DO NOT DIRECTLY HEAT OR SOLDER. DO NOT THROW INTO FIRE.
DO NOT MIX BATTERIES OF DIFFERENT TYPES AND BRANDS. DO NOT MIX NEW AND USED
BATTERIES. KEEP BATTERIES IN NON-CONDUCTIVE (I.E. PLASTIC) TRAYS.
STORAGE:
STORE IN A COOL (PREFERABLY BELOW 30 DEG. C) AND VENTILATED AREA AWAY FROM
MOISTURE, SOURCES OF HEAT, OPEN FLAMES, FOOD AND DRINK. KEEP ADEQUATE
CLEARANCE BETWEEN WALLS AND BATTERIES. TEMPERATURE ABOVE 90 DEG. C MAY
RESULT IN BATTERY LEAKAGE AND RUPTURE. SINCE SHORT CIRCUIT CAN CAUSE BURN,
LEAKAGE AND RUPTURE HAZARD, KEEP BATTERIES IN ORIGINAL PACKAGING UNTIL USE
AND DO NOT JUMBLE THEM.
OTHER:
FOLLOW MANUFACTURER RECOMMENDATIONS REGARDING MAXIMUM RECOMMENDED CURRENTS
AND OPERATING TEMPERATURE RANGE. APPLYING PRESSURE ON DEFORMING THE BATTERY
MAY LEAD TO DISASSEMBLY FOLLOWED BY EYE, SKIN AND THROAT IRRITATION.
| 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
RESPIRATORY PROTECTION:
NOT NECESSARY UNDER NORMAL USE. IN CASE OF BATTERY RUPTURE, USE
SELF-CONTAINED FULL-FACE RESPIRATORY EQUIPMENT.
HAND PROTECTION:
NOT NECESSARY UNDER NORMAL USE. USE VITON RUBBER GLOVES IF HANDLING A
LEAKING OR RUPTURED BATTERY.
EYE PROTECTION:
NOT NECESSARY UNDER NORMAL USE. WEAR SAFETY GOGGLES OR GLASSES WITH SIDE
SHIELDS IF HANDLING A LEAKING OR RUPTURED BATTERY.
SKIN PROTECTION:
NOT NECESSARY UNDER NORMAL USE. USE RUBBER APRON AND PROTECTIVE WORKING IN
CASE OF HANDLING OF A RUPTURED BATTERY.
| 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 APPEARANCE:
(PHYSICAL SHAPE AND COLOR AS SUPPLIED) METAL SQUARES, HERMETICALLY SEALED
AND FITTED WITH AN EXTERNAL PLASTIC BOX.
9.2 TEMPERATURE RANGE:
CONTINUOUS OCCASIONAL
IN STORAGE +30 DEG. C MAX -20/+60 DEG. C
DURING DISCHARGE -20/+60 DEG. C -20/+60 DEG. C
DURING CHARGE 0/+50 DEG. C 0/+50 DEG. C
9.3 SPECIFIC ENERGY: APPROX. 135 WH/KG
NOTE:
WH: NOMINAL VOLTAGE X RATED AH AS DEFINED IN IEC STANDARD NO 285.
KG: AVERAGE BATTERY WEIGHT
9.4 SPECIFIC PULSE POWER: APPROX. 300 WH/KG
9.5 MECHANICAL RESISTANCE: AS DEFINED IN RELEVANT IEC STANDARD
9.6 OTHER:
| 10 - STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
HEAT ABOVE 90 DEG. C OR INCINERATE.
DEFORM, MUTILATE, CRUSH, PIERCE, DISASSEMBLE.
SHORT CIRCUIT.
PROLONGED EXPOSURE TO HUMID CONDITIONS.
MATERIALS TO AVOID: N/A.
HAZARDOUS DECOMPOSITION PRODUCTS:
CORROSIVE/IRRITANT HYDROGEN FLUORIDE (HF) IS PRODUCED IN CASE OF REACTION
OF LITHIUM HEXAFLUOROPHOSPHATE (LiPF6) WITH WATER.
COMBUSTIBLE VAPORS AND FORMATION OF HYDROGEN FLUORIDE (HF) AND PHOSPHOROUS
OXIDES DURING FIRE.
| 11 - TOXOLOGICAL INFORMATION | |
XT LITHIUM-ION RECHARGEABLE BATTERIES DO NOT CONTAIN TOXIC MATERIALS.
| 12 - ECOLOGICAL INFORMATION | |
WHEN PROPERLY USED OR DISPOSED, XT LITHIUM-ION RECHARGEABLE BATTERIES DO
NOT PRESENT ENVIRONMENTAL HAZARD.
| 13 - DISPOSAL CONSIDERATIONS | |
DISPOSE IN ACCORDANCE WITH APPLICABLE REGULATIONS WHICH VARY FROM COUNTRY
TO COUNTRY.
(IN MORE COUNTRIES, THE THRASHING OF USED BATTERIES IS FORBIDDEN AND
THE END-USERS ARE INVITED TO DISPOSE THEM PROPERLY, EVENTUALLY THROUGH
NOT-FOR-PROFIT ORGANIZATIONS, MANDATED BY LOCAL GOVERNMENTS OR ORGANIZED
ON A VOLUNTARY BASIS BY PROFESSIONALS).
LITHIUM-ION BATTERIES SHOULD HAVE THEIR TERMINALS INSULATED AND BE
PREFERABLY WRAPPED IN PLASTIC BAGS PRIOR TO DISPOSAL.
13.1 INCINERATION:
INCINERATION SHOULD NEVER BE PERFORMED BY BATTERY USERS BUT EVENTUALLY BY
TRAINED PROFESSIONALS IN AUTHORIZED FACILITIES WITH PROPER GAS AND FUMES
TREATMENT.
13.2 LANDFILLING: LEACHABILITY REGULATIONS (MG/L)
COMPONENT LEACHABILITY EC LIMIT EPA OTHER*
IRON 100 5
NICKEL 500 2 0.5
13.3 RECYCLING:
SEND TO AUTHORIZED RECYCLING FACILITIES, EVENTUALLY THROUGH LICENSED WASTE
CARRIER.
| 14 - TRANSPORT INFORMATION | |
14.1 UNITED NATIONS:
UN NO: 3090
CLASSIFICATION: 9
PACKAGING:
ICAO: 903 FOR AIR TRANSPORT
IMDG: 903 FOR SEA TRANSPORT
14.2 INTERNATIONAL CONVENTIONS:
AIR:
IATA: YES
SEA:
IMDG: YES
LAND:
ADR (ROAD): YES
RID (RAIL): YES
14.3 OTHER:
IN THE USA: CODE OF FEDERAL REGULATIONS (49 CFR CH. 1 SUBSECTION 173-185)
| 15 - REGULATION INFORMATION | |
THE TRANSPORT OF RECHARGEABLE LITHIUM-ION BATTERIES IS REGULATED BY
VARIOUS BODIES (IATA, IMO, ADR, US-DOT) THAT FOLLOW THE UNITED NATIONS
"RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS GOODS, MODEL REGULATIONS,
13TH REVISED EDITION - 2007 - REF. ST/SG/AC. 10/1 REV. 13". DEPENDING ON
THEIR LITHIUM METAL EQUIVALENT WEIGHT CONTENT, DESIGN, AND ABILITY TO PASS
SAFETY TESTS DEFINED BY THE UN IN THE "RECOMMENDATIONS ON THE TRANSPORT
OF DANGEROUS GOOD - MANUAL OF TESTS AND CRITERIA - 3RD REVISED EDITION -
2007 - REF. ST/SG/AC. 10/11 REV. 3 AMENDMENT 1 (LITHIUM BATTERIES)", THE
LITHIUM-ION CELLS AND THE BATTERY PACKS MAY OR MAY NOT BE ASSIGNED TO THE
UN NO 3090 CLASS-9, THAT IS RESTRICTED FOR TRANSPORT.
INDIVIDUAL LITHIUM-ION CELLS AND BATTERY PACKS WITH RESPECTIVELY LESS
THAN 1.5 AND 8 GRAMS OF EQUIVALENT LITHIUM METAL CONTENT THAT PASS THE
UN-DEFINED SAFETY TESTS, ARE NOT RESTRICTED FOR TRANSPORT (1.0 AH OF
DECLARED NOMINAL CAPACITY = 0.3 GRAM OF LI EQUIVALENT WEIGHT CONTENT).
THESE LITHIUM SATISFY THE SPECIAL PROVISION A45 UNDER ICAO TECHNICAL
INSTRUCTION FOR THE SAFE TRANSPORT OF DANGEROUS GOODS BY AIR (TI) CAN
BE TRANSPORTED AS NON-RESTRICTED AIR CARGO.
| 16 - OTHER INFORMATION / DISCLAIMER | |
THIS INFORMATION HAS BEEN COMPILED FROM SOURCES CONSIDERED TO BE DEPENDABLE
AND IS, TO THE BEST OF OUR KNOWLEDGE AND BELIEF, ACCURATE AND RELIABLE AS
OF THE DATE COMPILED. HOWEVER, NO REPRESENTATION, WARRANTY (EITHER
EXPRESSED OR IMPLIED) OR GUARANTEE IS MADE TO THE ACCURACY, RELIABILITY
OR COMPLETENESS OF THE INFORMATION CONTAINED HEREIN.
THIS INFORMATION RELATES TO THE SPECIFIC MATERIALS DESIGNATED AND MAY NOT
BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR
IN ANY PROCESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY HIMSELF AS TO
THE SUITABILITY AND COMPLETENESS OF THIS INFORMATION FOR HIS PARTICULAR
USE.
XT DOES NOT ACCEPT LIABILITY FOR ANY LOSS OR DAMAGE THAT MAY OCCUR, WHETHER
DIRECT, INDIRECT, INCIDENTAL OR CONSEQUENTIAL, FROM THE USE OF THIS
INFORMATION. XT DOES NOT OFFER WARRANTY AGAINST PATENT INFRINGEMENT.
ADDITIONAL INFORMATION IS AVAILABLE BY CALLING THE TELEPHONE NUMBER ABOVE
DESIGNATED PURPOSE.
REVISION: 1
DATE: 01/2007
SIGN: CHENGLI WANG