| Common Name: | TITEBOND SOLVENT FREE CONSTRUCTION ADHESIVE |
| Manufacturer: | SINGER SAFETY |
| SDS Revision Date: | 1/3/1996 |
| SDS Format: | No Format Specified |
| Item Number(s): | 9GF53 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
MSDS NAME: TITEBOND SOLVENT FREE CONSTRUCTION ADHESIVE
MSDS: 4056
MSDS NUMBER: 7471
VERSION NUMBER: 0001
MSDS DATE: 010396
| SECTION I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: TITEBOND SOLVENT FREE CONSTRUCTION ADHESIVE
CAS NUMBER: NONE
HAZARD RATING:
HEALTH 1
FIRE 0
REACTIVITY 0
SINGER SAFETY COMPANY
2300 WEST LOGAN BOULEVARD
CHICAGO, IL 60647
PRODUCT CLASS: SOLVENT FREE ADHESIVE
PRODUCT CODE: 3435
DIVISION: CONSTRUCTION ADHESIVE & SEALANTS
| SECTION II - COMPOSITION, INFORMATION ON INGREDIENTS | |
HAZARDOUS INGREDIENTS CAS NUMBER %
VINYL ACETATE 108-05-4 0.24
OSHA PELS & ACGIH TLVS ARE LISTED IN SECTION VIII WHERE APPLICABLE. ALL
COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSA INVENTORY EXCEPT AS
EXEMPTED.
| SECTION III - HAZARD IDENTIFICATION | |
NOTE: NOT APPLICABLE
EMERGENCY OVERVIEW:
LIGHT BROWN COLORED MASTIC. NON-FLAMMABLE. SLIPPERY IN THE WET STATE.
ROUTES OF ENTRY:
INHALATION: YES
INGESTION: NO
SKIN: NO
EYE: YES
INHALATION: NO HAZARD IN NORMAL INDUSTRIAL USE.
INGESTION: NO HAZARD EXPECTED BASED ON THE PRODUCT FORMULA.
SKIN: PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE IRRITATION.
EYE: MILDLY IRRITATING TO EYES.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
NONE EXPECTED IN NORMAL INDUSTRIAL USE.
CARCINOGENICITY:
IARC: YES, 2B (VINYL ACETATE). SEE SECTION II.
NTP: NO
OSHA: NO
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAS DETERMINED VINYL
ACETATE TO BE CARCINOGENIC IN EXPERIMENTAL ANIMALS AT A RELATIVELY HIGH
DOSE, BY ROUTE(S) OF ADMINISTRATION, AT SITE(S), OF HISTOLOGIC TYPE(S),
OR BY MECHANISM(S) THAT ARE NOT CONSIDERED RELEVANT TO WORKER
EXPOSURE. AVAILABLE EPIDEMIOLOGIC STUDIES DO NOT CONFIRM AN INCREASED
RISK OF CANCER IN EXPOSED HUMANS. AVAILABLE EVIDENCE SUGGESTS THAT THE
AGENT IS NOT LIKELY TO CAUSE CANCER IN HUMANS EXCEPT UNDER UNCOMMON OR
UNLIKELY ROUTES OR LEVELS OF EXPOSURE. SEE SECTION II FOR VINYL ACETATE
CONTENT.
REPRODUCTIVE TOXICITY: NONE ANTICIPATED BASED ON PRODUCT FORMULA.
TARGET ORGANS: EYES AND SKIN.
| SECTION IV - FIRST AID MEASURES | |
INHALATION: REMOVE PATIENT TO FRESH AIR.
INGESTION:
CALL POISON CONTROL CENTER IMMEDIATELY. FOLLOW THEIR SPECIFIC
INSTRUCTIONS. DO NOT INDUCE VOMITING. ASPIRATION INTO LUNGS MAY CAUSE
CHEMICAL PNEUMONITIS.
SKIN:
WASH WITH SOAP AND WATER. CONTACT A PHYSICIAN IF IRRITATION DEVELOPS OR
PERSISTS.
EYE:
HOLD EYELIDS APART AND FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. SEEK MEDICAL ATTENTION.
| SECTION V - FIRE-FIGHTING MEASURES | |
FLAMMABILITY CLASS (OSHA): IIIB
FLASH RANGE: NOT APPLICABLE
EXPLOSIVE RANGE: NOT APPLICABLE
EXTINGUISHING MEDIA: WATER IF PRODUCT HAS DRIED.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON AND MONOMER MAY BE RELEASED DURING COMBUSTION.
FIRE FIGHTING PROCEDURES:
WEAR A NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS.
| SECTION VI - ACCIDENTAL RELEASE MEASURES | |
CONTAINMENT TECHNIQUES: USE SUITABLE ABSORBENT TO DIKE THE SPILL.
CLEAN-UP:
IF POSSIBLE PUMP LIQUID INTO AN APPROVED CONTAINER OR SPREAD ABSORBENT
OVER SPILL AND SHOVEL (USE NON-SPARKING EQUIPMENT) PRODUCT / ABSORBENT
MIXTURE INTO AN APPROVED CONTAINER. IF PRODUCT HAS DRIED. SCRAPE UP
AND PLACE IN AN APPROVED CONTAINER.
EMERGENCY MEASURES: NONE REQUIRED.
| SECTION VII - HANDLING AND STORAGE | |
HANDLING:
DO NOT GET MATERIAL IN EYES.
WASH HANDS BEFORE EATING.
AVOID PROLONGED OR REPEATED CONTACT WITH THE SKIN.
STORAGE: KEEP FROM FREEZING.
PRECAUTIONARY STATEMENT: KEEP OUT OF THE REACH OF CHILDREN.
| SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL
VINYL ACETATE 10.00 PPM N/EST 15.00 PPM N/EST N/EST
ENGINEERING CONTROLS:
USE LOCAL EXHAUST AS NEEDED TO MAINTAIN OCCUPATIONAL EXPOSURE LIMITS.
MAINTAIN STANDARD PLANT VENTILATION.
OTHER:
FACILITIES STORING OR UTILIZING ANY CHEMICAL SHOULD BE EQUIPPED WITH AN
EYEWASH FACILITY AND A SAFETY SHOWER.
RESPIRATORY PROTECTION:
WHERE EXPOSURE LIMITS ARE EXCEEDED SELECT A NIOSH/MSHA APPROVED
RESPIRATOR WITH APPROPRIATE PROTECTION FACTOR AND CARTRIDGE FOR THE
SPECIFIC CONTAINMENTS. FOLLOW REQUIREMENTS FOR RESPIRATORY PROTECTION IN
OSHA 1910.134.
EYE PROTECTION:
WEAR SPLASHPROOF SAFETY EYE PROTECTION IF SPLASHING OR MISTING OF PRODUCT
MAY OCCUR.
SKIN PROTECTION:
WHERE REPEATED OR PROLONGED CONTACT CAN OCCUR, WEAR IMPERVIOUS GLOVES.
| SECTION IX - PHYSICAL & CHEMICAL PROPERTIES | |
FORM: MASTIC
APPEARANCE/COLOR: LIGHT BROWN
ODOR: MILD
SOLUBILITY (IN WATER): MISCIBLE
pH VALUE: 5.
BOILING RANGE: 212. DEG. F
EVAPORATION RATE: FASTER THAN n-BUTYL ACETATE
% VOLATILE: 33.%
SPECIFIC GRAVITY: 1.45469
VOC (CALIFORNIA RULE 1160): 5.1 G/L
| SECTION X - STABILITY & REACTIVITY | |
STABILITY: THIS PRODUCT IS STABLE
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION WILL NOT OCCUR
CONDITIONS TO AVOID: NONE.
INCOMPATIBILITY: STRONG ACIDS AND BASES.
HAZARDOUS DECOMPOSITION PRODUCTS: NOT APPLICABLE
| SECTION XI - TOXICOLOGICAL INFORMATION | |
TWO YEAR ANIMAL TESTS (INHALATION) AT 50, 200 AND 600 PPM OF VINYL
ACETATE MONOMER HAVE SHOWN THAT SOME ANIMALS IN THE 600 PPM GROUP
DEVELOPED TUMORS. THERE IS NO EVIDENCE OF HUMAN CARCINOGENICITY.
| SECTION XII - ECOLOGICAL INFORMATION | |
THIS FORMULATION HAS NOT BEEN TESTED FOR ENVIRONMENTAL EFFECTS.
| SECTION XIII - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL:
DISPOSAL OF THIS PRODUCT MUST COMPLY WITH ALL APPLICABLE FEDERAL, STATE
AND LOCAL REGULATIONS.
CONTAINER DISPOSAL:
DISPOSAL OF THIS CONTAINER SHOULD COMPLY WITH ALL APPLICABLE FEDERAL,
STATE AND LOCAL REGULATIONS.
| SECTION XIV - TRANSPORT INFORMATION | |
UN NUMBER: NONE
UN PACK GROUP: N/A
UN CLASS: NONE
ICAO / IATA CLASS: NON-HAZARDOUS (* SEE NOTE)
IMDG CLASS: NON-HAZARDOUS
SHIPPING NAME: NOT APPLICABLE
SHIPPING NAME: BOXES ADHESIVES NOI
* PACKAGING IS NOT APPROVED FOR SHIPPING BY AIR. PLEASE CONTACT FRANKLIN
INTERNATIONAL FOR FURTHER INFORMATION.
| SECTION XV - REGULATORY INFORMATION | |
SARA TITLE III SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT TO KNOW ACT OF 1986 AND OF 40 CFR 372:
CAS NUMBER CHEMICAL NAME WT
108-05-4 VINYL ACETATE 0.24
PENNSYLVANIA:
SPECIAL HAZARDOUS COMPONENT REQUIRED TO BE LISTED AT .01% OR MORE:
FORMALDEHYDE; FORMALDEHYDE 50-00-0
HAZARDOUS COMPONENTS REQUIRED TO BE LISTED AT 1% OR MORE:
CRYSTALLINE SILICA, QUARTS 14808-60-7
KAOLIN CLAY; KAOLIN 1332-58-7
PROPYLENE GLYCOL; 1,2-PROPANEDIOL 57-55-6
NON-HAZARDOUS COMPONENTS REQUIRED TO BE LISTED AT 3% OR MORE:
POLYVINYL ACETATE EMULISON 26337-27-9
DIPROPYLENE GLYCOL DIBENZOATE 27138-31-4
WATER 7732-18-5