| Common Name: | SP 857 BLAST'EM WASP & HORNET KILLER |
| Manufacturer: | SHERWIN-WILLIAMS |
| SDS Revision Date: | 6/27/2010 |
| SDS Format: | No Format Specified |
| Item Number(s): | 6KDR2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
S00857
01 00
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NUMBER: S00857
PRODUCT NAME: SP 857 BLAST'EM* WASP & HORNET KILLER
HMIS CODES:
HEALTH 2
FLAMMABILITY 2
REACTIVITY 0
MANUFACTURER'S NAME:
THE SHERWIN-WILLIAMS COMPANY
CONSUMER GROUP - INDUSTRIAL
CLEVELAND, OH 44115
EMERGENCY TELEPHONE NO.: (216) 566-2917
INFORMATION TELEPHONE NO.: (800) 251-2486
DATE OF PREPARATION: 27-JUN-10
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
% BY WT CAS NO. INGREDIENT UNITS VAPOR
PRESSURE
92 64742-47-8 HEAVY ALIPHATIC SOLVENT 0.2 MM
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
5 67-63-0 2-PROPANOL 33 MM
ACGIH TLV: 400 PPM
ACGIH TLV: 500 PPM STEL
OSHA PEL: 400 PPM
OSHA PEL: 500 PPM STEL
0.5 51-03-6 PIPERONYL BUTOXIDE
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
0.3 52645-53-1 PERMETHRIN
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
3 124-38-9 CARBON DIOXIDE 760 MM
ACGIH TLV: 5000 PPM
OSHA PEL: 5000 PPM
| SECTION 3 - HAZARDS IDENTIFICATION | |
ROUTES OF EXPOSURE:
INHALATION OF VAPOR OR SPRAY MIST.
EYE OR SKIN CONTACT WITH THE PRODUCT, VAPOR OR SPRAY MIST.
EFFECTS OF OVEREXPOSURE:
EYES: IRRITATION.
SKIN: PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION.
INHALATION:
IRRITATION OF THE UPPER RESPIRATORY SYSTEM.
MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN
UNCONSCIOUSNESS AND POSSIBLY DEATH.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS.
REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE
SKIN EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
PROLONGED OR FREQUENT REPEATED SKIN CONTACT MAY CAUSE ALLERGIC REACTIONS
IN SOME INDIVIDUALS.
CANCER INFORMATION:
FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11.
| SECTION 4 - FIRST AID MEASURES | |
EYES:
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL
ATTENTION.
SKIN:
WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
INHALATION:
IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET.
INGESTION:
DO NOT INDUCE VOMITING.
GET MEDICAL ATTENTION IMMEDIATELY.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT: 53 DEG. F PMCC
LEL: 0.7
UEL: 12.7
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.
DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY
CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN
MEDICAL ATTENTION.
SPECIAL FIRE FIGHTING PROCEDURES:
FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS
SHOULD BE USED.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO
EXTREME HEAT.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA.
REMOVE WITH INERT ABSORBENT.
| SECTION 7 - HANDLING AND STORAGE | |
THIS PRODUCT IS TOXIC TO FISH. DO NOT ALLOW PRODUCT TO ENTER GROUNDWATER,
STREAMS, LAKES OR PONDS. DO NOT CONTAMINATE WATER BY CLEANING OF EQUIPMENT
OR DISPOSAL OF WASTES.
STORAGE CATEGORY: NOT AVAILABLE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
KEEP AWAY FROM HEAT AND OPEN FLAME.
CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING PROCEDURES.
CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE, OR EXPOSE TO
TEMPERATURE ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER,
AND OTHER HEAT SOURCES COULD CAUSE CONTAINER TO BURST. DO NOT TAKE
INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRECAUTIONS TO BE TAKEN IN USE:
USE ONLY WITH ADEQUATE VENTILATION.
AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR AND SPRAY MIST.
WASH HANDS AFTER USING.
DO NOT USE IN COMMERCIAL FOOD/FEED HANDLING ESTABLISHMENTS, RESTAURANTS
OR OTHER SITES WHERE FOOD/FEED IS COMMERCIALLY PREPARED OR PROCESSED. DO
NOT USE IN FEDERALLY INSPECTED MEAT AND POULTRY PLANTS.
DO NOT ALLOW CHILDREN OR PETS TO CONTACT TREATED SURFACES UNTIL SPRAY HAS
DRIED. DO NOT SPRAY AIR IN ROOMS OR USE ON PLANTS. AVOID SPRAYING
VEGETATION DIRECTLY. APPLY AS A SURFACE SPRAY ONLY. DO NOT SPRAY TO
CONTACT FOOD, FEEDSTUFFS OR WATER SUPPLIES. THOROUGHLY WASH DISHES AND
FOOD-HANDLING UTENSILS CONTAMINATED WITH THIS PRODUCT. REMOVE PETS AND
COVER FISH BOWLS BEFORE SPRAYING.
DO NOT CONTAMINATE WATER, FOOD OR FEED BY STORAGE OR DISPOSAL. DO NOT
STORE NEAR HEAT OR OPEN FLAME. STORE IN COOL AREA AWAY FROM CHILDREN.
IT IS A VIOLATION OF FEDERAL LAW TO USE THIS PRODUCT IN A MANNER
INCONSISTENT WITH ITS LABELING. READ ENTIRE LABEL.
VENTILATION:
LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO
MATERIALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION:
IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY
VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR
APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS IN SECTION 2.
PROTECTIVE GLOVES: WEAR CHEMICAL-RESISTANT GLOVES TO PREVENT SKIN CONTACT.
EYE PROTECTION: WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
OTHER PRECAUTIONS:
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
CAN BE HARMFUL OR FATAL.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
PRODUCT WEIGHT:
6.6 LB/GAL
780 G/L
SPECIFIC GRAVITY: 0.79
BOILING POINT:
<0 - 500 F
<-18 - 260 C
MELTING POINT: NOT AVAILABLE
VOLATILE VOLUME: 99%
EVAPORATION RATE: FASTER THAN ETHER
VAPOR DENSITY: HEAVIER THAN AIR
SOLUBILITY IN WATER: N.A.
VOLATILE ORGANIC COMPOUNDS (VOC THEORETICAL):
VOLATILE WEIGHT 96.65% LESS WATER AND FEDERALLY EXEMPT SOLVENTS
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBILITY: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
CHRONIC HEALTH HAZARDS:
NO INGREDIENT IN THIS PRODUCT IS AN IARC, NTP OR OSHA LISTED CARCINOGEN.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
TOXICOLOGY DATA:
CAS NO. INGREDIENT NAME
64742-47-8 HEAVY ALIPHATIC SOLVENT
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
67-63-0 2-PROPANOL
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 5045 MG/KG
51-03-6 PIPERONYL BUTOXIDE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
52645-53-1 PERMETHRIN
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 410 MG/KG
124-38-9 CARBON DIOXIDE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
| SECTION 12 - ECOLOGICAL INFORMATION | |
ENVIRONMENTAL HAZARDS:
THIS PRODUCT IS TOXIC TO FISH AND AQUATIC INVERTEBRATES. DO NOT APPLY
DIRECTLY TO WATER.
ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
WASTE FROM THIS PRODUCT IS NOT HAZARDOUS AS DEFINED UNDER THE RESOURCE
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261.
DO NOT INCINERATE. DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE WITH
FEDERAL, STATE/PROVINCIAL, AND LOCAL REGULATIONS REGARDING POLLUTION.
| SECTION 14 - TRANSPORT INFORMATION | |
US GROUND (DOT):
MAY BE CLASSED AS CONSUMER COMMODITY, ORM-D
UN1950, AEROSOLS, 2.2, LIMITED QUANTITY, (ERG#126)
CANADA (TDG):
MAY BE CLASSED AS CONSUMER COMMODITY, ORM-D
UN1950, AEROSOLS, CLASS 2.2, LIMITED QUANTITY, (ERG#126)
IMO:
MAY BE SHIPPED AS LIMITED QUANTITY
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EMS F-D, S-U, ADR (D)
| SECTION 15 - REGULATORY INFORMATION | |
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION:
NO INGREDIENTS IN THIS PRODUCT ARE SUBJECT TO SARA 313 (40 CFR 372.65C)
SUPPLIER NOTIFICATION.
TSCA CERTIFICATION:
ALL CHEMICALS IN THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON
THE TSCA INVENTORY.
| SECTION 16 - OTHER INFORMATION | |
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS
ALL OF THE INFORMATION REQUIRED BY THE CPR.
THE ABOVE INFORMATION PERTAINS TO THIS PRODUCT AS CURRENTLY FORMULATED,
AND IS BASED ON THE INFORMATION AVAILABLE AT THIS TIME. ADDITION OF
REDUCERS OR OTHER ADDITIVES TO THIS PRODUCT MAY SUBSTANTIALLY ALTER THE
COMPOSITION AND HAZARDS OF THE PRODUCT. SINCE CONDITIONS OF USE ARE
OUTSIDE OUR CONTROL, WE MAKE NO WARRANTIES, EXPRESS OR IMPLIED, AND ASSUME
NO LIABILITY IN CONNECTION WITH ANY USE OF THIS INFORMATION.