| Common Name: | RTV GASKET MAKER & SEALER, S00010 CLEAR, S00020 WHITE, S00030 BLUE, S00040 BLACK |
| Manufacturer: | SHERWIN-WILLIAMS |
| SDS Revision Date: | 8/7/2006 |
| SDS Format: | No Format Specified |
| Item Number(s): | 6KDT3, 6KDU4, 6KDV4, 6KDW1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
S00010-RTV/ISD
2006
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFICATION:
RTV GASKET MAKER & SEALER
S00010 CLEAR
S00020 WHITE
S00030 BLUE
S00040 BLACK
S00050 RED HI-TEMP
HMIS CODES:
HEALTH 2*
FLAMMABILITY 1
REACTIVITY 0
MANUFACTURER'S NAME:
THE SHERWIN-WILLIAMS COMPANY
CONSUMER GROUP - INDUSTRIAL
CLEVELAND, OH 44115
EMERGENCY TELEPHONE NO.: (216) 566-2917
INFORMATION TELEPHONE NO.: (800) 251-2486
DATE OF PREPARATION: 7-AUG-06
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
% BY WT CAS NO. INGREDIENT UNITS VAPOR PRESSURE
2 74-98-6 PROPANE 760 MM
ACGIH TLV: 2500 PPM
OSHA PEL: 1000 PPM
2 106-97-8 BUTANE 760 MM
ACGIH TLV: 800 PPM
OSHA PEL: 800 PPM
2 17689-77-9 ETHYL TRIACETOXYSILANE
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
2 4253-34-3 METHYL TRIACETOXYSILANE
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
8-10 7631-86-9 AMORPHOUS SILICA
ACGIH TLV: 10 MG/M3 AS DUST
OSHA PEL: 6 MG/M3 AS DUST
<5 13463-67-7 TITANIUM DIOXIDE
(IN S00020 WHITE ONLY) ACGIH TLV: 10 MG/M3 AS DUST
OSHA PEL: 10 MG/M3 TOTAL DUST
OSHA PEL: 5 MG/M3 RESPIRABLE
FRACTION
<5 1333-86-4 CARBON BLACK
(IN S00040 BLACK ONLY) ACGIH TLV: 3.5 MG/M3
OSHA PEL: 3.5 MG/M3
NOTE:
THESE PRODUCTS MAY EVOLVE SMALL QUANTITIES OF ACETIC ACID DURING CURING.
EXPOSURE LIMITS FOR ACETIC ACID ARE:
<1 64-19-7 ACETIC ACID
ACGIH TLV: 10 PPM
ACGIH TLV: 15 PPM STEL
OSHA PEL: 10 PPM
| SECTION 3 - HAZARDS IDENTIFICATION | |
ROUTES OF EXPOSURE:
INHALATION OF VAPOR OR SPRAY MIST.
EYE OR SKIN CONTACT WITH THE PRODUCT OR VAPOR.
EFFECTS OF OVEREXPOSURE:
EYES: IRRITATION.
SKIN: PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION.
INHALATION: IRRITATION OF THE UPPER RESPIRATORY SYSTEM.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS.
REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN
EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE KNOWN.
CANCER INFORMATION:
FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11.
| SECTION 4 - FIRST AID MEASURES | |
EYES:
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES.
GET MEDICAL ATTENTION.
SKIN:
WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
IF IRRITATION PERSISTS OR OCCURS LATER, GET MEDICAL ATTENTION.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
INHALATION:
IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM AND QUIET.
INGESTION:
DO NOT INDUCE VOMITING.
GET MEDICAL ATTENTION IMMEDIATELY.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT:
>200 DEG. F FOR RTV
-20 DEG. F FOR PROPELLANT
LEL: N.AP.
UEL: N.AP.
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.
DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE
A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL
ATTENTION.
SPECIAL FIRE FIGHTING PROCEDURES:
FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS
SHOULD BE USED.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE
BUILD-UP AND POSSIBLE AUTO IGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME
HEAT.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
REMOVE WITH INERT ABSORBENT.
| SECTION 7 - HANDLING AND STORAGE | |
STORAGE CATEGORY: NOT AVAILABLE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.
DURING USE AND UNTIL ALL VAPORS ARE GONE:
KEEP AREA VENTILATED - DO NOT SMOKE - EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS - TURN OFF STOVES, ELECTRIC TOOLS AND APPLIANCES, AND ANY OTHER
SOURCES OF IGNITION.
CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING PROCEDURES.
CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE, OR EXPOSE TO
TEMPERATURE ABOVE 120 DEG. F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT
WATER, AND OTHER HEAT SOURCES COULD CAUSE CONTAINER TO BURST. DO NOT TAKE
INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRECAUTIONS TO BE TAKEN IN USE:
USE ONLY WITH ADEQUATE VENTILATION.
AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR AND SPRAY MIST.
WASH HANDS AFTER USING.
THESE PRODUCTS MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES
(LISTED "AS DUST" IN SECTION 2) WHICH MAY BE PRESENT AT HAZARDOUS LEVELS
ONLY DURING SANDING OR ABRADING OF THE DRIED FILM. IF NO SPECIFIC DUSTS
ARE LISTED IN SECTION 2, THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE
ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION),
OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION).
VENTILATION:
LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO
MATERIALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION:
NONE REQUIRED FOR TYPICAL USE IN WELL-VENTILATED AREA. IF PERSONAL EXPOSURE
CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, OR IF
IRRITATION OCCURS, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE
RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS IN
SECTION 2.
WHEN SANDING OR ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR
APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT,
UNDERLYING COATING, OR THE ABRASIVE.
PROTECTIVE GLOVES:
TO PREVENT SKIN CONTACT, WEAR CHEMICAL-RESISTANT GLOVES RECOMMENDED BY GLOVE
SUPPLIER FOR PROTECTION AGAINST MATERIALS IN SECTION 2.
EYE PROTECTION: WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
OTHER PRECAUTIONS:
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
CAN BE HARMFUL OR FATAL.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
PRODUCT WEIGHT:
8.3 LB/GAL
990 G/L
SPECIFIC GRAVITY: 1.0
BOILING POINT:
<0 - 34 F
<-18 - 1 C
MELTING POINT: NOT AVAILABLE
VOLATILE VOLUME: 7%
EVAPORATION RATE: FASTER THAN ETHER
VAPOR DENSITY: HEAVIER THAN AIR
SOLUBILITY IN WATER: N.A.
VOLATILE ORGANIC COMPOUNDS (VOC THEORETICAL):
VOLATILE WEIGHT: 4% LESS WATER AND FEDERALLY EXEMPT SOLVENTS
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBILITY: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, ACETIC ACID
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
CHRONIC HEALTH HAZARDS:
NO INGREDIENT IN THIS PRODUCT IS AN IARC, NTP OR OSHA LISTED CARCINOGEN.
RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG./M3 DEVELOPED LUNG CANCER,
HOWEVER, SUCH EXPOSURE LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE.
TOXICOLOGY DATA:
CAS NO. INGREDIENT NAME
74-98-6 PROPANE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
106-97-8 BUTANE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
17689-77-9 ETHYL TRIACETOXYSILANE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
4253-34-3 METHYL TRIACETOXYSILANE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
7631-86-9 AMORPHOUS SILICA
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
64-19-7 ACETIC ACID
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 3310 MG/KG
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
WASTE FROM THESE PRODUCTS MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261. CURED RTV IS NOT HAZARDOUS.
SPENT CONTAINERS CONTAIN PROPELLANT WHICH MEETS THE IGNITABILITY
CHARACTERISTIC OF HAZARDOUS WASTE.
DO NOT INCINERATE. DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE WITH
FEDERAL, STATE/PROVINCIAL, AND LOCAL REGULATIONS REGARDING POLLUTION.
| SECTION 14 - TRANSPORT INFORMATION | |
NO DATA AVAILABLE.
| SECTION 15 - REGULATORY INFORMATION | |
SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C):
NO INGREDIENT IN THESE PRODUCTS IS SUBJECT TO SARA 313 (40 CFR 372.65C)
SUPPLIER NOTIFICATION.
CALIFORNIA PROPOSITION 65:
WARNING:
THESE PRODUCTS CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
TSCA CERTIFICATION:
ALL CHEMICALS IN THESE PRODUCTS ARE LISTED, OR ARE EXEMPT FROM LISTING, ON
THE TSCA INVENTORY.
| SECTION 16 - OTHER INFORMATION | |
THESE PRODUCTS HAVE BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS
ALL OF THE INFORMATION REQUIRED BY THE CPR.
THE ABOVE INFORMATION PERTAINS TO THESE PRODUCTS AS CURRENTLY FORMULATED,
AND IS BASED ON THE INFORMATION AVAILABLE AT THIS TIME. ADDITION OF REDUCERS
OR OTHER ADDITIVES TO THESE PRODUCTS MAY SUBSTANTIALLY ALTER THE COMPOSITION
AND HAZARDS OF THE PRODUCT. SINCE CONDITIONS OF USE ARE OUTSIDE OUR CONTROL,
WE MAKE NO WARRANTIES, EXPRESS OR IMPLIED, AND ASSUME NO LIABILITY IN
CONNECTION WITH ANY USE OF THIS INFORMATION.