| Common Name: | ONE SHOT (R-422C) |
| Manufacturer: | ICOR INTERNATIONAL |
| SDS Revision Date: | 7/1/2007 |
| SDS Format: | No Format Specified |
| Item Number(s): | 6PPV0 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ICOR INTERNATIONAL
"MAKING YOUR LIFE EASIER(TM)"
MATERIAL SAFETY DATA SHEET
ONE SHOT(R*) (C) (R-422C)
| 1 CHEMICAL PRODUCT/COMPANY IDENTIFICATION |  |
PRODUCT NAME: ONE SHOT(R*) (C) (R-422C)
PRODUCT USE: REFRIGERANT
CHEMICAL NAMES:
BLEND OF PENTAFLUOROETHANE, TETRAFLUROETHANE AND ISOBUTANE
MANUFACTURER:
ICOR INTERNATIONAL, INC.
10640 E. 59TH ST.
INDIANAPOLIS, IN 46236
IN CASE OF EMERGENCY CALL (24 HOURS/DAY, 7 DAYS/WEEK):
CHEMTREC: 1-800-424-9300
PRODUCT INFORMATION CALL (MONDAY-FRIDAY, 8:00 AM-4:30 PM):
ICOR: 1-800-497-6805
| 2 COMPOSITION/INFORMATION ON IDENTIFICATION | |
MATERIAL CAS NUMBER TYPICAL WT. %
*1,1,1,2,2-PENTAFLUOROETHANE (HFC-125) 354-33-6 82.0%
*1,1,1,2-TETRAFLUROETHANE (HFC-134A) 811-97-2 15.0%
ISOBUTANE (HC-600A) 75-28-5 3.0%
*REGULATED AS A TOXIC CHEMICAL UNDER SECTION 313 OF TITLE III OF THE
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372.
| 3 HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
OVEREXPOSURE MAY CAUSE DIZZINESS AND LOSS OF CONCENTRATION. AT HIGHER
LEVELS, CENTRAL NERVOUS SYSTEM DEPRESSION AND CARDIAC ARRHYTHMIA MAY
RESULT. VAPORS DISPLACE AIR AND MAY CAUSE ASPHYXIATION IN CONFINED SPACES.
VOLATILE LIQUID WITH FAINT SWEETISH ODOR.
POTENTIAL HEALTH EFFECTS:
EYE: LIQUID MAY CAUSE FROSTBITE. MIST MAY IRRITATE.
SKIN:
IRRITATION CAN RESULT FROM A DEFATTING ACTION ON TISSUE. LIQUID CONTACT MAY
CAUSE FROSTBITE.
INGESTION:
UNLIKELY ROUTE OF EXPOSURE. SHOULD IT RESULT, DISCOMFORT IN THE
GASTROINTESTINAL TRACT WOULD OCCUR.
INHALATION:
OVEREXPOSURE MAY CAUSE DIZZINESS AND LOSS OF CONCENTRATION. AT HIGHER
LEVELS, CENTRAL NERVOUS SYSTEM DEPRESSION AND CARDIAC ARRHYTHMIA MAY
RESULT.
CHRONIC (CANCER) INFORMATION:
NONE OF THE COMPONENTS ARE DESIGNATED AS CARCINOGENS BY IARC, NTP, OSHA,
OR ACGIH.
TERATOLOGY (BIRTH DEFECT) INFORMATION: NOT EXPECTED TO BE TERATOGENIC.
REPRODUCTIVE INFORMATION: NO HAZARD EXPECTED.
| 4 FIRST AID MEASURES | |
INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION,
ADMINISTER OXYGEN AND CALL A PHYSICIAN.
DO NOT GIVE EPINEPHRINE OR SIMILAR DRUGS.
SKIN CONTACT:
WARM THE AREA GRADUALLY BY FLUSHING WITH PLENTY OF WATER. GET MEDICAL
ATTENTION IF THERE IS EVIDENCE OF TISSUE DAMAGE.
EYE CONTACT:
IRRIGATE EYES WITH RUNNING WATER FOR AT LEAST 15 MINUTES. GET MEDICAL
ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION.
| 5 FIRE FIGHTING MEASURES | |
FLAMMABLE PROPERTIES:
FLASH POINT: NO FLASH POINT
FLAMMABLE LIMITS IN AIR (% BY VOLUME):
AUTOIGNITION: >550 DEG. C
FLAMMABLE LIMITS IN AIR (% BY VOLUME):
LEL: NONE (PER ASTM E681)
UEL: NONE (PER ASTM E681)
FIRE AND EXPLOSION HAZARDS:
CYLINDERS MAY RUPTURE UNDER ELEVATED TEMPERATURES AND/OR FIRE CONDITIONS.
IN CONCENTRATIONS ABOVE THE RECOMMENDED EXPOSURE LIMIT, OPEN FLAME WILL
VARY IN SIZE AND COLOR. ELIMINATE THE FLAME OR IGNITION SOURCE AND
VENTILATE TO DISPERSE THE REFRIGERANT VAPORS.
ONE SHOT(R*) (C) IS NOT FLAMMABLE AT ATMOSPHERIC PRESSURE AND TEMPERATURES
BELOW 100 DEG. C (212 DEG. F). ONE SHOT(R*) (C) SHOULD NOT EXIST WITH
AIR/EXCESS OXYGEN AT ELEVATED PRESSURES AND HIGH TEMPERATURES. ONE SHOT(R*)
(C) CAN BECOME COMBUSTIBLE WITH COMBINATIONS OF ELEVATED TEMPERATURES,
PRESSURES, AND OXYGEN, AND AN IGNITION SOURCE.
FOR EXAMPLE:
DO NOT MIX ONE SHOT(R*) (C) WITH AIR UNDER PRESSURE FOR LEAK DETECTION
PURPOSES.
EXTINGUISHING MEDIA: THE CHOICE OF MEDIA DEPENDS ON SURROUNDING MATERIALS.
FIRE FIGHTING INSTRUCTIONS:
KEEP PERSONNEL REMOVED AND UPWIND OF FIRE. WEAR SELF CONTAINED BREATHING
APPARATUS. WEAR FULL PROTECTIVE EQUIPMENT. COOL TANK/CONTAINER WITH WATER
SPRAY. HEAT MAY RUPTURE CONTAINERS. FIGHT FIRE FROM DISTANCE. CONTAIN AND
NEUTRALIZE RUN OFF PRIOR TO DISPOSAL.
| 6 ACCIDENTAL RELEASE MEASURES | |
SAFEGUARDS (PERSONNEL):
NOTE:
REVIEW FIRE FIGHTING MEASURES AND HANDLING SECTIONS BEFORE PROCEEDING WITH
CLEAN-UP. USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN UP.
ACCIDENTAL RELEASE MEASURES:
REMOVE OR EXTINGUISH COMBUSTION SOURCES. EVACUATE ENCLOSED SPACES UNTIL GAS
IS DISPERSED. STOP THE RELEASE IF POSSIBLE. VENTILATE AREA INCLUDING LOW OR
ENCLOSED SPACES. EXHAUST OUTDOORS. CONTAIN SPILL AND COLLECT REMAINDER
USING ABSORBENT MATERIAL AND PLACE IN DRUM APPROVED FOR WASTE DISPOSAL OR
RECOVERY.
| 7 HANDLING AND STORAGE | |
HANDLING (PERSONNEL):
AVOID BREATHING VAPORS. AVOID CONTACT WITH SKIN OR EYES. USE INSULATED OR
LINED BUTYL GLOVES, FACE SHIELD OR GOGGLES, AND IMPERVIOUS CLOTHING. DO NOT
SMOKE.
HANDLING (PHYSICAL ASPECTS):
INSURE ADEQUATE VENTILATION TO KEEP EXPOSURE BELOW RECOMMENDED LIMITS. AVOID
CONTACT WITH CHLORINE OR OTHER OXIDIZING. SEE FIRE AND EXPLOSION DATA
SECTION.
STORAGE:
DO NOT STORE CYLINDERS IN DIRECT SUN OR EXPOSE TO HEAT ABOVE 125 DEG. F
(52 DEG. C).
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
AVOID CONTACT WITH SKIN OR EYES. AVOID BREATHING VAPORS. USE WITH
SUFFICIENT VENTILATION TO KEEP EXPOSURE BELOW RECOMMENDED EXPOSURE LIMIT.
UTILIZE MECHANICAL VENTILATION IN CASE OF LOW OR ENCLOSED SPACES, OR
RELEASE OF LARGE QUANTITY.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: GOGGLES OR FACE SHIELD.
RESPIRATORS: USE IF EXPOSURE LEVEL IS ABOVE PEL.
PROTECTIVE CLOTHING: IMPERVIOUS.
HYGIENE MEASURES: DO NOT DRINK, EAT, OR SMOKE IN WORK PLACE.
EXPOSURE GUIDELINES:
LONG TERM EXPOSURE LIMIT**: 1000 PPM (8 HR. TWA REFERENCE PERIOD)
INDIVIDUAL COMPONENT APPLICABLE EXPOSURE LIMITS:
PENTAFLUOROETHANE (HFC-125):
AEL* (ICOR): 1000 PPM - 8 & 12 HR. TWA
WEEL (AIHA): 1000 PPM - 4900 MG/M3*, 8 HR. TWA
PEL (OSHA): NONE ESTABLISHED
TLV (ACGIH): NONE ESTABLISHED
1,1,1,2-TETRAFLOUROETHANE (HFC-134A):
AEL* (ICOR): 1000 PPM - 8 & 12 HR. TWA
WELL (AIHA): 1000 PPM - 4900 MG/M3, 8 HR. TWA
PEL (OSHA): NONE ESTABLISHED
TLV (ACGIH): NONE ESTABLISHED
ISOBUTANE (HC-600A):
TLV: NONE ESTABLISHED
DFG MAK:
1000 PPM
2350 MG/M3 PEAK LIMITATION CATEGORY
TWA (NIOSH):
800 PPM
1900 MG/M3 RECOMMENDED TWA 10 HRS.
** AS BLENDED (ICOR ACCEPTABLE EXPOSURE LIMIT)
* ICOR REVIEWS INDUSTRY STANDARDS AND RECOMMENDATIONS IN CONSIDERATION OF
ACCEPTABLE EXPOSURE LIMITATIONS. WHERE REGULATED EXPOSURE LIMITS ARE LOWER
THAN ICOR'S RECOMMENDED AEL, THOSE LIMITS SHALL SUPERSEDE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL DATA:
PHYSICAL STATE: GAS AT AMBIENT TEMPERATURE
COLOR: COLORLESS
ODOR: SLIGHTLY ETHEREAL
DENSITY:
LIQUID @ 1 ATM.: 89.20 LB/FT3
VAPOR @ 1 ATM.: .3912 LB/FT3
SOLUBILITY IN WATER: NOT DETERMINED
BOILING POINT:
DEW @ 1 ATM.: -45.1 DEG. F
BUBBLE @ 1 ATM.: -50.7 DEG. F
VAPOR PRESSURE:
@ 70 DEG. F: 155.6 PSIA
@ 130 DEG. F: 360.1 PSIA
FREEZING POINT: NOT DETERMINED
pH: NEUTRAL
MOLECULAR WEIGHT: 113.49 G/MOL
% VOLATILES: 100
| 10 STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
MATERIAL IS STABLE. HOWEVER, AVOID HIGH TEMPERATURES AND OPEN FLAMES.
DECOMPOSITION:
DECOMPOSITIONS ARE HAZARDOUS. HIGH TEMPERATURES OR FLAMES WILL CAUSE
DECOMPOSITION BY PRODUCTS FORMING HALOGENS, HALOGEN ACIDS AND POSSIBLE
CARBONYL HALIDES.
POLYMERIZATION: WILL NOT OCCUR
OTHER HAZARDS:
CYLINDERS OF USED PRODUCT MAY CONTAIN OIL AS WELL AS REFRIGERANT. A LEAK OR
VENTING DURING A FIRE WILL PRODUCE A CLOUD OF OIL MIST THAT IS FLAMMABLE.
| 11 TOXICOLOGICAL INFORMATION | |
IMMEDIATE (ACUTE) EFFECTS:
HFC-134A:
LC50:
4 HR. (RAT): >500,000 PPM
CARDIAC SENSITIVITY THRESHOLD: 80,000 PPM
NOEL: 50,000 PPM
AS BLENDED: UNTESTED
HFC-125:
LC50:
4 HR. (RAT): >800,000 PPM
CARDIAC SENSITIVITY THRESHOLD: 75,000 PPM
HC-600A:
LC50:
2 HR. (MOUSE): 520,000 PPM
| 12 ECOLOGICAL INFORMATION | |
DEGRADABILITY (BOD):
ONE SHOT(R*) (C) IS A GAS AT ROOM TEMPERATURE. IT IS UNLIKELY TO REMAIN IN
WATER.
OCTANOL WATER PARTITION COEFFICIENT: AS BLENDED N/A
COMPONENTS:
R-134A - LOG POW: 1.06
R-125 - LOG POW: 1.48
R-600A - LOG POW: 2.8
| 13 DISPOSAL CONSIDERATIONS | |
DISPOSAL MUST COMPLY WITH FEDERAL, STATE, AND LOCAL REGULATIONS. ONE
SHOT(R*) (C) IS SUBJECT TO CLEAN AIR ACT REGULATIONS SECTION 608 IN 40 CFR
PART 82 CONCERNING REFRIGERANT RECYCLING.
RCRA: NOT A HAZARDOUS WASTE
ALTERATION TO THE PRODUCT SUCH AS MIXING WITH OTHER MATERIAL MAY CHANGE THE
CHARACTERISTICS OF THE MATERIAL AND ALTER THE RCRA CLASSIFICATION AND THE
PROPER DISPOSAL METHOD.
| 14 TRANSPORTATION INFORMATION | |
DOT/IMO/IATA:
PROPER SHIPPING NAME:
LIQUEFIED GAS N.O.S. (PENTAFLUOROETHANE, TETRAFLUOROETHANE)
HAZARD CLASS: 2.2
UN NUMBER: 3163
LABELING: 2-NON FLAMMABLE GAS
CARGO AIRCRAFT:
PACKING INSTRUCTIONS:
200 QUANTITY: 150 KG
PASSENGER AIRCRAFT:
PACKING INSTRUCTIONS:
200 QUANTITY: 75 KG
| 15 REGULATORY INFORMATION | |
TOXIC SUBSTANCE CONTROL ACT (TSCA):
COMPONENTS: LISTED ON INVENTORY
SARA TITLE III/CERCLA:
COMPONENTS:
REPORTABLE QUANTITIES (RQS): NO COMPONENTS LISTED
THRESHOLD PLANNING QUANTITIES (TPQS): NO COMPONENTS LISTED
SECTION 311 HAZARD CLASS: IMMEDIATE PRESSURE
SECTION 313 TOXIC CHEMICALS: NO COMPONENTS LISTED
ADDITIONAL REGULATORY INFORMATION: U.S. CLEAN AIR ACT - 40 CFR PART 82
WHMIS CLASSIFICATION (CANADA):
THIS PRODUCT HAS BEEN EVALUATED WITH THE HAZARD CRITERIA OF THE CPR, AND
THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR.
FOREIGN INVENTORY STATUS:
COMPONENTS:
EU-EINECS:
#2065578 - HFC-125
#223770 - HFC-134A
#2008572 - HC-600A
CEPA STATUS: COMPONENTS LISTED ON DSL
| 16 OTHER INFORMATION | |
OTHER INFORMATION:
HMIS CLASSIFICATION:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
NFPA CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
REACTIVITY 0
OSHA REGULATIONS FOR COMPRESSED GASES: 29 CFR 1910.11
DOT CLASSIFICATION PER 49 CFR 172.101
ANSI/ASHRAE: STANDARD 34 SAFETY DESIGNATION - A1
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS MSDS PERTAINS ONLY TO THE SPECIFIC
MATERIAL DESIGNATED HEREIN AND DOES NOT RELATE TO USE IN COMBINATION WITH
OTHER MATERIALS. THIS INFORMATION IS OFFERED IN GOOD FAITH. NO WARRANTY,
EITHER EXPRESSED OR IMPLIED, AS TO SUITABILITY TO APPLICATION IS HEREBY
MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE
BELIEVED TO BE RELIABLE. EACH USER SHOULD REVIEW THESE RECOMMENDATIONS IN
THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER THEY ARE
APPROPRIATE. THESE RECOMMENDATIONS ARE NOT INTENDED TO SUPERSEDE STATE OR
LOCAL SAFETY CODES AND PROCEDURES. THE INFORMATION CONTAINED HEREIN IS
SUBJECT TO REVISION WITHOUT NOTIFICATION AS ADDITIONAL KNOWLEDGE AND
EXPERIENCE IS GAINED.
FORM: MSDS-422C
7/07/1M