| Common Name: | SAFE MARK BLACK |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 2/5/2010 |
| SDS Format: | No Format Specified |
| Item Number(s): | 6RRF2, 6RRF3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
HMIS(R*):
HEALTH 2
FLAMMABILITY 3
REACTIVITY 0
PERSONAL PROTECTION B
| SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
IDENTITY: SAFE MARK BLACK
ITEM NO.: 40907, 82907
OTHER NAMES:
FORMULA: A981M
NOTE:
BLANK SPACES ARE NOT PERMITTED. IF ANY ITEM IS NOT APPLICABLE, OR NO
INFORMATION IS AVAILABLE, THE SPACE MUST BE MARKED TO INDICATE THAT.
COMPANY NAME: W.W. GRAINGER, INC.
ADDRESS (NUMBER, STREET, CITY, STATE, AND ZIP CODE):
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045
EMERGENCY TELEPHONE NUMBER: 1-800-228-5635
TELEPHONE NUMBER FOR INFORMATION: 1-847-565-5400
PRODUCT CLASS: SOLVENT BASED MARKER.
DATE PREPARED: 2/05/10
SIGNATURE OF PREPARER (OPTIONAL): REGULATORY DEPT.
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENTS CAS NO. %(OPT.)
(SPECIFIC CHEMICAL
IDENTITY, COMMON NAME(S)
METHYL ISOBUTYL KETONE 108-10-1 65 - 75
CYCLOHEXANONE 108-94-1 15 - 25
HAZARDOUS COMPONENTS OSHA PEL ACGIH-TLV OTHER LIMITS
(SPECIFIC CHEMICAL RECOMMENDED
IDENTITY, COMMON NAME(S)
METHYL ISOBUTYL KETONE TWA: 100 PPM TWA: 50 PPM NO DATA
CYCLOHEXANONE TWA: 25 PPM TWA: 25 PPM NO DATA
*NUISANCE DUST AS FREE DUST ONLY, NOT AS BOUND IN PAINT OR INK.
| SECTION 3 HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
BLACK THIN VISCOSITY LIQUID WITH MILD KETONIC SOLVENT ODOR.
WARNING!
FLAMMABLE LIQUID AND VAPOR. KEEP AWAY FROM HEAT SPARKS AND FLAMES. MAY
CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. IF SWALLOWED DO NOT
INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
POTENTIAL HEALTH EFFECTS:
EYES: LIQUID IS MODERATELY IRRITATING TO THE EYES.
SKIN: LIQUID IS MILDLY IRRITATING TO THE SKIN.
INGESTION: INGESTION OF LIQUID MAY CAUSE VOMITING.
INHALATION:
HIGH CONCENTRATION OF VAPORS MAY PRODUCE IRRITATION OF THE RESPIRATORY
TRACT, HEADACHE, DIZZINESS, AND NAUSEA.
CHRONIC HEALTH EFFECTS:
PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN SENSITIZATION OR DERMATITIS.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE
TO SOLVENTS WITH IRREVERSIBLE BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL
MISUSE BY DELIBERATELY CONCENTRATING OR INHALING THIS PRODUCT MAY BE
HARMFUL OR FATAL.
| SECTION 4 FIRST AID MEASURES | |
EYES:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL ATTENTION IMMEDIATELY.
INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN:
FLUSH SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
INGESTION:
IF LARGE QUANTITIES OF THIS MATERIAL ARE SWALLOWED, GET IMMEDIATE MEDICAL
ATTENTION. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.
| SECTION 5 FIRE FIGHTING MEASURES | |
FLASH POINT (METHOD USED): 73 DEG. F (TAG CLOSED CUP)
FLAMMABLE LIMITS:
LEL: 1.2
UEL: 8
EXTINGUISHING MEDIA:
USE WATER FOG, FOAM, DRY CHEMICAL OR CO2. USE WATER SPRAY TO COOL
FIRE-EXPOSED CONTAINERS AND TO PROTECT PERSONNEL.
SPECIAL FIRE FIGHTING PROCEDURES:
KEEP CONTAINERS COOL AND VAPORS DOWN WITH WATER SPRAY. PREVENT SPILL FROM
ENTERING DRAINS, SEWERS, STREAMS OR OTHER BODIES OF WATER. IF RUN-OFF
OCCURS, NOTIFY PROPER AUTHORITIES. DO NOT ENTER CONFINED FIRE SPACE
WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES
AND RUBBER BOOTS); INCLUDING A POSITIVE PRESSURE NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG GROUND, OR BE MOVED BY
VENTILATION AND BE IGNITED BY IGNITION SOURCE.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
SMALL SPILL:
ABSORB LIQUID WITH NON-COMBUSTIBLE FLOOR ABSORBENT AND PLACE IN
NON-LEAKING CONTAINER; SEAL PROPERLY AND DISPOSE OF PROPERLY IN COMPLIANCE
WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
LARGE SPILL:
EVACUATE AREA OF UNPROTECTED PERSONNEL. ELIMINATE ALL IGNITION SOURCES.
STOP SPILL AT SOURCE IF SAFE TO DO SO. HANDLING EQUIPMENT MUST BE GROUNDED
TO PREVENT SPARKING. PREVENT SPILL FROM ENTERING DRAINS, SEWERS, STREAMS
OR OTHER BODIES OF WATER. IF RUN-OFF OCCURS, NOTIFY PROPER AUTHORITIES.
PUMP OR VACUUM TRANSFER SPILLED PRODUCT TO CLEAN CONTAINERS FOR RECOVERY.
ABSORB UNRECOVERABLE PRODUCT. TRANSFER CONTAMINATED ABSORBENT, SOIL AND
OTHER MATERIALS TO CONTAINERS FOR DISPOSAL. DISPOSE OF PROPERLY IN
COMPLIANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
| SECTION 7 HANDLING AND STORAGE | |
HANDLING:
EMPTY CONTAINERS RETAIN RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE
DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR
EXPOSE SUCH CONTAINERS TO HEAT, SPARKS, FLAMES, STATIC ELECTRICITY, OR
OTHER SOURCES OF IGNITION. MANY HOT ORGANIC CHEMICAL VAPORS OR MISTS ARE
SUSCEPTIBLE TO SUDDEN SPONTANEOUS COMBUSTION WHEN MIXED WITH AIR. IGNITION
MAY OCCUR AT TEMPERATURES BELOW THOSE PUBLISHED IN THE LITERATURE AS
"AUTOIGNITION" OR IGNITION TEMPERATURES. IGNITION TEMPERATURES DECREASE
WITH INCREASING VAPOR VOLUME AND VAPOR VOLUME AND VAPOR/AIR CONTACT TIME,
AND ARE INFLUENCED BY PRESSURE CHANGES. IGNITION OF ORGANIC CHEMICAL
VAPORS MAY OCCUR AT TYPICAL ELEVATED-TEMPERATURE PROCESS CONDITIONS,
ESPECIALLY IN PROCESSES OPERATING UNDER VACUUM IF SUBJECTED TO SUDDEN
INGRESS OF AIR, OR OUTSIDE PROCESS EQUIPMENT OPERATING UNDER ELEVATED
PRESSURE IF SUDDEN ESCAPE OF VAPORS OR MISTS TO THE ATMOSPHERE OCCURS.
ANY PROPOSED USE OF THIS PRODUCT IN ELEVATED-TEMPERATURE PROCESSES SHOULD
BE THOROUGHLY EVALUATED TO ASSURE THAT SAFE OPERATING CONDITIONS ARE
ESTABLISHED AND MAINTAINED.
STORAGE:
KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAMES. KEEP OUT OF REACH OF
CHILDREN. KEEP CONTAINER TIGHTLY SEALED WHEN NOT IN USE. STORE IN COOL,
WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS. INFORMATION ON
THIS MATERIAL SAFETY DATA SHEETS REFERS TO INK USED IN PENS AND MARKERS;
HOWEVER, IT APPLIES TO THESE INKS IN BULK. THE INKS ARE CONTAINED IN
CAPILLARY OR VALVE RESERVOIRS AND WILL NOT SPILL OR LEAK UNDER NORMAL
CONDITIONS.
| SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
RESPIRATORY PROTECTION (SPECIFY TYPE):
NOT USUALLY NECESSARY. USE WITH ADEQUATE VENTILATION. USE NIOSH/MSHA
APPROVED RESPIRATOR IF PELS OR TLVS ARE EXCEEDED.
ENGINEERING CONTROLS:
LOCAL EXHAUST: NOT USUALLY NEEDED
MECHANICAL (GENERAL): YES
SPECIAL: NONE
OTHER: NONE
PROTECTIVE GLOVES:
CHEMICAL RESISTANT GLOVES IF SKIN CONTACT IS POSSIBLE
(CONSULT YOUR SAFETY EQUIPMENT SUPPLIER).
EYE PROTECTION:
NOT NORMALLY REQUIRED IF USED AS INTENDED. WEAR CHEMICAL SPLASH GOGGLES
IN COMPLIANCE WITH OSHA REGULATION IF SPLASHING IS POSSIBLE.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
NOT USUALLY NECESSARY. FOR BULK MATERIAL, IF DIRECT CONTACT IS POSSIBLE,
WEAR APRON, BOOTS, FACE SHIELD, ETC. AS NEEDED.
WORK/HYGIENIC PRACTICES:
FOLLOW LABEL INSTRUCTIONS. WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, SMOKING, USING RESTROOMS, ETC.
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT: 243 DEG. F
SPECIFIC GRAVITY (H2O = 1) @70 DEG. F: <1
VAPOR PRESSURE (MM-Hg @ 70 DEG. F): NO DATA
MELTING POINT: NO DATA
VAPOR DENSITY (AIR = 1): GREATER THAN ONE (1)
EVAPORATION RATE (BUTYL ACETATE = 1): 1.6
SOLUBILITY IN WATER: MODERATE
pH: NO DATA
APPEARANCE AND ODOR:
BLACK THIN VISCOSITY LIQUID WITH MILD KETONIC SOLVENT ODOR.
VOC: THIS PRODUCT CONTAINS 766 GRAMS PER LITER OR 87.8% BY WEIGHT VOC'S.
| SECTION 10 STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
UNSTABLE ( )
STABLE (X)
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBILITY (MATERIALS TO AVOID):
STRONG OXIDIZING AND REDUCING AGENTS, STRONG ALKALIES AND STRONG ACIDS.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE, SMOKE, SOOT AND VARIOUS ORGANIC OXIDATION
BY-PRODUCTS.
HAZARDOUS POLYMERIZATION:
MAY OCCUR ( )
WILL NOT OCCUR (X)
CONDITIONS TO AVOID: NO DATA
| SECTION 11 TOXICOLOGICAL INFORMATION | |
PLEASE REFER TO SECTION 3 FOR AVAILABLE INFORMATION ON POTENTIAL HEALTH
EFFECTS
| SECTION 12 ECOLOGICAL INFORMATION | |
NO SPECIFIC ECOLOGICAL DATA ARE AVAILABLE FOR THIS PRODUCT. PLEASE REFER
TO SECTION 6 FOR INFORMATION REGARDING ACCIDENTAL RELEASES AND SECTION
15 FOR REGULATORY REPORTING INFORMATION.
| SECTION 13 DISPOSAL CONSIDERATIONS | |
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
| SECTION 14 TRANSPORT INFORMATION | |
(NOT MEANT TO BE ALL INCLUSIVE)
DOMESTIC HIGHWAY (CONTAINERS <1 QUART ARE ORM-D):
PROPER SHIPPING NAME: PAINT
HAZARD CLASS/SUBSIDIARY HAZARD: 3
UN/NA NO.: UN1263
PACKING GROUP: II
LABEL REQUIRED: FLAMMABLE LIQUID (3)
DOMESTIC AIR SHIPMENTS (PENS):
PROPER SHIPPING NAME: CONSUMER COMMODITY
HAZARD CLASS/SUBSIDIARY HAZARD: 9
UN/NA NO.: I.D. 8000
PACKING GROUP: NONE
LABEL REQUIRED: CLASS 9
| SECTION 15 REGULATORY INFORMATION | |
(NOT MEANT TO BE ALL INCLUSIVE - SELECTED REGULATIONS REPRESENTED)
U.S. FEDERAL REGULATIONS:
CARCINOGENICITY:
NTP?: NO
IARC MONOGRAPHS?: NO
OSHA REGULATIONS?: NO
OSHA:
HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200).
SECTION 313:
THIS PRODUCT CONTAINS METHYL ISO BUTYL KETONE (108-10-1) WHICH IS LISTED
AND MAY REQUIRE REPORTING UNDER SARA TITLE III SEC. 313 IF USED OVER THE
THRESHOLD REPORTING QUANTITY. THIS INFORMATION MUST BE INCLUDED IN ALL
MSDSS THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL.
INTERNATIONAL REGULATIONS:
CANADIAN WHMIS: NOT WHMIS CONTROLLED (PENS)
BULK: CLASS B2, D2A
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT KNOWN TO CONTAIN ANY MATERIAL LISTED UNDER CALIFORNIA'S
PROPOSITION 65.
| SECTION 16 OTHER INFORMATION | |
MSDS STATUS:
REVISED SECTION(S):
WARNING!
THE USE OF THIS PRODUCT IS BEYOND THE CONTROL OF THE MANUFACTURER AND
DISTRIBUTOR; THEREFORE, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE AS TO
THE EFFECTS OF SUCH OR THE RESULTS TO BE OBTAINED IF NOT USED IN
ACCORDANCE WITH DIRECTIONS OR ESTABLISHED SAFE PRACTICE. THE USER MUST
ASSUME ALL RESPONSIBILITY, INCLUDING INJURY OR DAMAGE, RESULTING FROM ITS
MISUSE AS SUCH, OR IN COMBINATION WITH OTHER MATERIALS. THE MANUFACTURER
AND DISTRIBUTOR WARRANT ONLY THAT THIS PRODUCT MEETS THE SPECIFICATIONS
FOR SUCH PRODUCT. THIS WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES,
EXPRESS OR IMPLIED, AS TO DESCRIPTION, QUALITY, MERCHANTABILITY, FITNESS
FOR ANY PARTICULAR PURPOSE, PRODUCTIVENESS, OR ANY OTHER MATTER OF THIS
PRODUCT. THE MANUFACTURER AND DISTRIBUTOR SHALL BE IN NO WAY RESPONSIBLE
FOR THE IMPROPER USE OF THIS PRODUCT. THE SOLE AND EXCLUSIVE REMEDY
AGAINST THE MANUFACTURER AND DISTRIBUTOR FOR BREACH OF WARRANTY SHALL BE
REIMBURSEMENT OF THE PURCHASE PRICE OF THE PRODUCT IN THE EVENT THAT A
DEFECTIVE CONDITION OF THE PRODUCT SHALL BE FOUND TO EXIST. NO OTHER
REMEDY (INCLUDING BUT NOT LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES
FOR INJURY TO PERSON OR PROPERTY OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL
LOSS SHALL BE AVAILABLE.