| Common Name: | KRYLON INDOOR/OUTDOOR PRIMER, ALL-PURPOSE GRAY PRIMER |
| Manufacturer: | SHERWIN-WILLIAMS |
| SDS Revision Date: | 11/28/2010 |
| SDS Format: | No Format Specified |
| Item Number(s): | 1AVT8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
51318
05 00
DATE OF PREPARATION: NOV 28, 2010
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NUMBER: 51318
PRODUCT NAME: KRYLON(R*) INDOOR/OUTDOOR PRIMER, ALL-PURPOSE GRAY PRIMER
MANUFACTURER'S NAME:
THE SHERWIN-WILLIAMS COMPANY
KRYLON PRODUCTS GROUP
CLEVELAND, OH 44115
TELEPHONE NUMBERS AND WEBSITES:
PRODUCT INFORMATION: (800) 832-2541
REGULATORY INFORMATION:
(216) 566-2902
WWW.PAINTDOCS.COM
MEDICAL EMERGENCY: (216) 566-2917
TRANSPORTATION EMERGENCY*: (800) 424-9300
*FOR CHEMICAL EMERGENCY ONLY (SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT)
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
% BY CAS NUMBER INGREDIENT UNITS VAPOR
WEIGHT PRESSURE
17 74-98-6 PROPANE 760 MM
ACGIH TLV: 2500 PPM
OSHA PEL: 1000 PPM
8 106-97-8 BUTANE 760 MM
ACGIH TLV: 800 PPM
OSHA PEL: 800 PPM
3 142-82-5 HEPTANE 50 MM
ACGIH TLV: 400 PPM
ACGIH TLV: 500 PPM STEL
OSHA PEL: 400 PPM
OSHA PEL: 500 PPM STEL
6 64742-89-8 V. M. & P. NAPHTHA 12 MM
ACGIH TLV: 300 PPM
OSHA PEL: 300 PPM
OSHA PEL: 400 PPM STEL
10 108-88-3 TOLUENE 22 MM
ACGIH TLV: 20 PPM
OSHA PEL: 100 PPM (SKIN)
OSHA PEL: 150 PPM (SKIN) STEL
0.1 100-41-4 ETHYLBENZENE 7.1 MM
ACGIH TLV: 100 PPM
ACGIH TLV: 125 PPM STEL
OSHA PEL: 100 PPM
OSHA PEL: 125 PPM STEL
1 64742-95-6 LIGHT AROMATIC HYDROCARBONS 3.8 MM
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
2 95-63-6 1,2,4-TRIMETHYLBENZENE 2.03 MM
ACGIH TLV: 25 PPM
OSHA PEL: 25 PPM
30 67-64-1 ACETONE 180 MM
ACGIH TLV: 500 PPM
ACGIH TLV: 750 PPM STEL
OSHA PEL: 1000 PPM
10 14807-96-6 TALC
ACGIH TLV: 2 MG/M3 AS RESP. DUST
OSHA PEL: 2 MG/M3 AS RESP. DUST
2 13463-67-7 TITANIUM DIOXIDE
ACGIH TLV: 10 MG/M3 AS DUST
OSHA PEL: 10 MG/M3 TOTAL DUST
OSHA PEL: 5 MG/M3 RESPIRABLE
FRACTION
0.1 1333-86-4 CARBON BLACK
ACGIH TLV: 3.5 MG/M3
OSHA PEL: 3.5 MG/M3
% BY WEIGHT INGREDIENT
0.90 BARIUM (AS Ba; TOTAL)
| SECTION 3 - HAZARDS IDENTIFICATION | |
ROUTES OF EXPOSURE:
INHALATION OF VAPOR OR SPRAY MIST.
EYE OR SKIN CONTACT WITH THE PRODUCT, VAPOR OR SPRAY MIST.
EFFECTS OF OVEREXPOSURE:
EYES: IRRITATION.
SKIN: PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION.
INHALATION: IRRITATION OF THE UPPER RESPIRATORY SYSTEM.
MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN
UNCONSCIOUSNESS AND POSSIBLY DEATH.
PROLONGED OVEREXPOSURE TO HAZARDOUS INGREDIENTS IN SECTION 2 MAY CAUSE
ADVERSE CHRONIC EFFECTS TO THE FOLLOWING ORGANS OR SYSTEMS:
THE LIVER
THE URINARY SYSTEM
THE CARDIOVASCULAR SYSTEM
THE REPRODUCTIVE SYSTEM
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS. REDNESS AND ITCHING OR
BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE GENERALLY RECOGNIZED.
CANCER INFORMATION:
FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11.
HMIS CODES:
HEALTH 2*
FLAMMABILITY 3
REACTIVITY 0
| SECTION 4 - FIRST AID MEASURES | |
EYES:
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL
ATTENTION.
SKIN:
WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
INHALATION:
IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND
QUIET.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT: PROPELLANT <0 DEG. F
LEL: 0.7
UEL: 12.8
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.
DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY
CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT.
OBTAIN MEDICAL ATTENTION.
SPECIAL FIRE FIGHTING PROCEDURES:
FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS
SHOULD BE USED.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED
TO EXTREME HEAT.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA.
REMOVE WITH INERT ABSORBENT.
| SECTION 7 - HANDLING AND STORAGE | |
STORAGE CATEGORY: NOT AVAILABLE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. VAPORS WILL ACCUMULATE
READILY AND MAY IGNITE EXPLOSIVELY.
DURING USE AND UNTIL ALL VAPORS ARE GONE:
KEEP AREA VENTILATED - DO NOT SMOKE - EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS - TURN OFF STOVES, ELECTRIC TOOLS AND APPLIANCES, AND ANY
OTHER SOURCES OF IGNITION.
CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING PROCEDURES.
CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE, OR EXPOSE TO
TEMPERATURE ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER,
AND OTHER HEAT SOURCES COULD CAUSE CONTAINER TO BURST. DO NOT TAKE
INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRECAUTIONS TO BE TAKEN IN USE:
USE ONLY WITH ADEQUATE VENTILATION.
AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR AND SPRAY MIST.
WASH HANDS AFTER USING.
THIS COATING MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES
(LISTED "AS DUST" IN SECTION 2) WHICH MAY BE PRESENT AT HAZARDOUS LEVELS
ONLY DURING SANDING OR ABRADING OF THE DRIED FILM. IF NO SPECIFIC DUSTS
ARE LISTED IN SECTION 2, THE APPLICABLE LIMITS FOR NUISANCE DUSTS
ARE ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION),
OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION).
VENTILATION:
LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE
TO MATERIALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION:
IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY
VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR
APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS IN SECTION 2.
WHEN SANDING, WIREBRUSHING, ABRADING, BURNING OR WELDING THE DRIED FILM,
WEAR A PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION
AGAINST NON-VOLATILE MATERIALS IN SECTION 2.
PROTECTIVE GLOVES:
NONE REQUIRED FOR NORMAL APPLICATION OF AEROSOL PRODUCTS WHERE MINIMAL
SKIN CONTACT IS EXPECTED. FOR LONG OR REPEATED CONTACT, WEAR CHEMICAL
RESISTANT GLOVES.
EYE PROTECTION: WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
OTHER PRECAUTIONS:
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
CAN BE HARMFUL OR FATAL.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
PRODUCT WEIGHT:
6.60 LB/GAL
790 G/L
SPECIFIC GRAVITY: 0.79
BOILING POINT:
<0 - 360 DEG. F
<-18 - 182 DEG. C
MELTING POINT: NOT AVAILABLE
VOLATILE VOLUME: 90%
EVAPORATION RATE: FASTER THAN ETHER
VAPOR DENSITY: HEAVIER THAN AIR
SOLUBILITY IN WATER: N.A.
pH: 7.0
VOLATILE ORGANIC COMPOUNDS (VOC THEORETICAL - AS PACKAGED):
VOLATILE WEIGHT 48.60% LESS WATER AND FEDERALLY EXEMPT SOLVENTS
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBILITY: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF METALS IN SECTION 2
HAZARDOUS POLYMERIZATION: WLL NOT OCCUR
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
CHRONIC HEALTH HAZARDS:
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
ETHYLBENZENE IS CLASSIFIED BY IARC AS POSSIBLY CARCINOGENIC TO HUMANS
(2B) BASED ON INADEQUATE EVIDENCE IN HUMANS AND SUFFICIENT EVIDENCE
IN LABORATORY ANIMALS. LIFETIME INHALATION EXPOSURE OF RATS AND MICE
TO HIGH ETHYLBENZENE CONCENTRATIONS RESULTED IN INCREASES IN CERTAIN
TYPES OF CANCER, INCLUDING KIDNEY TUMORS IN RATS AND LUNG AND LIVER
TUMORS IN MICE. THESE EFFECTS WERE NOT OBSERVED IN ANIMALS EXPOSED TO
LOWER CONCENTRATIONS. THERE IS NO EVIDENCE THAT ETHYLBENZENE CAUSES
CANCER IN HUMANS.
IARC'S MONOGRAPH NO. 93 REPORTS THERE IS SUFFICIENT EVIDENCE OF
CARCINOGENICITY IN EXPERIMENTAL RATS EXPOSED TO TITANIUM DIOXIDE BUT
INADEQUATE EVIDENCE FOR CARCINOGENICITY IN HUMANS AND HAS ASSIGNED A
GROUP 2B RATING. IN ADDITION, THE IARC SUMMARY CONCLUDES, "NO SIGNIFICANT
EXPOSURE TO TITANIUM DIOXIDE IS THOUGHT TO OCCUR DURING THE USE OF
PRODUCTS IN WHICH TITANIUM IS BOUND TO OTHER MATERIALS, SUCH AS PAINT."
CARBON BLACK IS CLASSIFIED BY IARC AS POSSIBLY CARCINOGENIC TO HUMANS
(GROUP 2B) BASED ON EXPERIMENTAL ANIMAL DATA, HOWEVER, THERE IS
INSUFFICIENT EVIDENCE IN HUMANS FOR ITS CARCINOGENICITY.
TOXICOLOGY DATA:
CAS NO. INGREDIENT NAME
74-98-6 PROPANE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
106-97-8 BUTANE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
142-82-5 HEPTANE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
64742-89-8 V. M. & P. NAPHTHA
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
108-88-3 TOLUENE
LC50 RAT 4HR: 4000 PPM
LD50 RAT: 5000 MG/KG
100-41-4 ETHYLBENZENE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 3500 MG/KG
64742-95-6 LIGHT AROMATIC HYDROCARBONS
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
95-63-6 1,2,4-TRIMETHYLBENZENE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
67-64-1 ACETONE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 5800 MG/KG
14807-96-6 TALC
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
13463-67-7 TITANIUM DIOXIDE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
1333-86-4 CARBON BLACK
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261.
WASTE MUST BE TESTED FOR IGNITABILITY AND EXTRACTABILITY TO DETERMINE
THE APPLICABLE EPA HAZARDOUS WASTE NUMBERS.
DO NOT INCINERATE. DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE
WITH FEDERAL, STATE/PROVINCIAL, AND LOCAL REGULATIONS REGARDING POLLUTION.
| SECTION 14 - TRANSPORT INFORMATION | |
US GROUND (DOT):
MAY BE CLASSED AS CONSUMER COMMODITY, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
CANADA (TDG):
MAY BE CLASSED AS CONSUMER COMMODITY, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO:
MAY BE SHIPPED AS LIMITED QUANTITY
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EMS F-D, S-U, ADR (D)
| SECTION 15 - REGULATORY INFORMATION | |
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION:
CAS NO. CHEMICAL/COMPOUND % BY WT % ELEMENT
108-88-3 TOLUENE 10
100-41-4 ETHYLBENZENE 0.1
95-63-6 1,2,4-TRIMETHYLBENZENE 2
BARIUM COMPOUND 2 0.8
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
TSCA CERTIFICATION:
ALL CHEMICALS IN THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING,
ON THE TSCA INVENTORY.
| SECTION 16 - OTHER INFORMATION | |
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS
CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
THE ABOVE INFORMATION PERTAINS TO THIS PRODUCT AS CURRENTLY FORMULATED,
AND IS BASED ON THE INFORMATION AVAILABLE AT THIS TIME. ADDITION OF
REDUCERS OR OTHER ADDITIVES TO THIS PRODUCT MAY SUBSTANTIALLY ALTER
THE COMPOSITION AND HAZARDS OF THE PRODUCT. SINCE CONDITIONS OF USE
ARE OUTSIDE OUR CONTROL, WE MAKE NO WARRANTIES, EXPRESS OR IMPLIED,
AND ASSUME NO LIABILITY IN CONNECTION WITH ANY USE OF THIS INFORMATION.