| Common Name: | LITHIUM MANGANESE DIOXIDE COIN BATTERIES |
| Manufacturer: | DURACELL |
| SDS Revision Date: | 7/1/2008 |
| SDS Format: | No Format Specified |
| Item Number(s): | 16A668, 25TT45, 2HYJ1, 2HYK2, 2HYK3, 2HYK4, 2HYK5, 2HYK6, 2HYK7, 3MPA5, 3MPA6, 3MPA7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
DURACELL(R*)
SAFETY DATA SHEET
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND OF THE COMPANY/UNDERTAKING
PRODUCT NAME: DURACELL LITHIUM MANGANESE DIOXIDE COIN BATTERIES
PRODUCT IDENTIFICATION: LITHIUM MANGANESE DIOXIDE COIN CELLS -
DURACELL DESIGNATIONS:
BATTERY NAME/SIZE DURACELL DESIGNATION VOLTAGE IEC DESIGNATION
DURACELL 1220 1220 3 CR1220
DURACELL 1616 1616 3 CR1616
DURACELL 1620 1620 3 CR1620
DURACELL 2016 2016 3 CR2016
DURACELL 2025 2025 3 CR2025
DURACELL 2032 2032 3 CR2032
DURACELL 2430 2430 3 CR2430
DURACELL 2450 2450 3 CR2450
PRODUCT USE: ENERGY SOURCE
SDS DATE OF PREPARATION: JULY 1, 2008
COMPANY IDENTIFICATION:
EU OFFICE:
PROCTER & GAMBLE UK.
THE HEIGHTS, BROOKLANDS
WEYBRIDGE, SURREY
KT13 0XP UK
TELEPHONE: +44-1-93-289-6000
SWITZERLAND OFFICE:
PROCTER & GAMBLE
SWITZERLAND SARL
ROUTE DE SAINT-GEORGES 47
1213 PETIT-LANCY, 1, GENEVA,
TELEPHONE: +41-58-004-6111
US OFFICE:
DURACELL, A DIVISION OF P&G
BERKSHIRE CORPORATE PARK
BETHEL, CT 06801 USA
TELEPHONE: 203-796-4000
EMERGENCY PHONE NUMBER:
CHEMTREC 24-HOUR EMERGENCY RESPONSE HOTLINE:
703-527-3887 (UNITED STATES OF AMERICA)
| SECTION 2: HAZARDS IDENTIFICATION | |
PHYSICAL APPEARANCE: SMALL CYLINDRICAL BATTERIES.
CAUTION:
BATTERY CAN EXPLODE OR LEAK IF HEATED, DISASSEMBLED, SHORTED, RECHARGED,
EXPOSED TO FIRE OR HIGH TEMPERATURE OR INSERTED INCORRECTLY. KEEP IN
ORIGINAL PACKAGE UNTIL READY TO USE. DO NOT CARRY BATTERIES LOOSE IN YOUR
POCKET OR PURSE. KEEP BATTERIES AWAY FROM CHILDREN. IF SWALLOWED, CONSULT
A PHYSICIAN AT ONCE. FOR INFORMATION ON TREATMENT, CALL THE NATIONAL
BUTTON BATTERY INGESTION HOTLINE, COLLECT TO THE UNITED STATES OF AMERICA,
DAY OR NIGHT AT (202) 625-3333. UNDER CERTAIN MISUSE CONDITIONS AND BY
ABUSIVELY OPENING THE BATTERY, EXPOSED LITHIUM CAN REACT WITH WATER OR
MOISTURE IN THE AIR CAUSING POTENTIAL THERMAL BURNS OR FIRE.
EU CLASSIFICATION OF PREPARATION:
NOT CLASSIFIED AS A DANGEROUS PREPARATION.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NUMBER EINECS AMOUNT CLASSIFICATION
NUMBER
MANGANESE DIOXIDE 1313-13-9 215-202-6 65-75% Xn, R20/22
PROPYLENE CARBONATE 108-32-7 203-572-1 10-15% Xi, R36
LITHIUM 7439-93-2 231-102-5 5-10% C, F, R14/15, R34
GRAPHITE, SYNTHETIC 7440-44-0 231-153-3 5-10% NONE
1,2-DIMETHOXYETHANE 110-71-4 203-794-9 1-10% F, REPR CAT 2,
Xn, R11, R19,
R20, R60, R61
LITHIUM PERCHLORATE 7791-03-9 232-237-2 <1.5% O, Xi, R8,
R36/37/38
| SECTION 4: FIRST AID MEASURES | |
GENERAL ADVICE:
THE CHEMICALS AND METALS IN THIS PRODUCT ARE CONTAINED IN A SEALED CAN.
EXPOSURE TO THE CONTENTS WILL NOT OCCUR UNLESS THE BATTERY LEAKS, IS
EXPOSED TO HIGH TEMPERATURES OR IS MECHANICALLY, PHYSICALLY, OR
ELECTRICALLY ABUSED.
EYE CONTACT:
IF BATTERY IS LEAKING AND MATERIAL CONTACTS THE EYE, FLUSH THOROUGHLY WITH
COPIOUS AMOUNTS OF RUNNING WATER FOR 30 MINUTES. SEEK IMMEDIATE MEDICAL
ADVICE.
SKIN CONTACT:
IF BATTERY IS LEAKING AND MATERIAL CONTACTS THE SKIN, REMOVE ANY
CONTAMINATED CLOTHING AND FLUSH EXPOSED SKIN WITH COPIOUS AMOUNTS OF
RUNNING WATER FOR AT LEAST 15 MINUTES. IF IRRITATION, INJURY OR PAIN
PERSISTS, SEEK MEDICAL ADVICE.
INHALED:
IF BATTERY IS LEAKING, CONTENTS MAY BE IRRITATING TO RESPIRATORY PASSAGES.
MOVE TO FRESH AIR. IF IRRITATION PERSISTS, SEEK MEDICAL ADVICE.
SWALLOWED:
IF BATTERY IS SWALLOWED SEEK IMMEDIATE MEDICAL ADVICE. BATTERIES LODGED IN
THE ESOPHAGUS SHOULD BE REMOVED IMMEDIATELY SINCE LEAKAGE, CAUSTIC BURNS
AND PERFORATION CAN OCCUR AS SOON AS TWO HOURS AFTER INGESTION. IF MOUTH
AREA IRRITATION OR BURNING HAS OCCURRED, RINSE THE MOUTH AND SURROUNDING
AREA WITH TEPID WATER FOR AT LEAST 15 MINUTES. DO NOT GIVE IPECAC.
NOTE TO PHYSICIAN:
PUBLISHED REPORTS RECOMMEND REMOVAL FROM THE ESOPHAGUS BE DONE
ENDOSCOPICALLY (UNDER DIRECT VISUALIZATION). BATTERIES BEYOND THE
ESOPHAGUS NEED NOT BE RETRIEVED UNLESS THERE ARE SIGNS OF INJURY TO THE GI
TRACT OR A LARGE DIAMETER BATTERY FAILS TO PASS THE PYLORUS. IF
ASYMPTOMATIC, FOLLOW-UP X-RAYS ARE NECESSARY ONLY TO CONFIRM THE PASSAGE
OF LARGER BATTERIES. CONFIRMATION BY STOOL INSPECTION IS PREFERABLE UNDER
MOST CIRCUMSTANCES. FOR INFORMATION ON TREATMENT, TELEPHONE
(202) 625-3333, COLLECT TO THE UNITED STATES OF AMERICA, DAY OR NIGHT.
POTENTIAL LEAKAGE OF LESS THAN 50 MILLIGRAMS OF DIMETHOXYETHANE AND
PROPYLENE CARBONATE. DIMETHOXYETHANE RAPIDLY EVAPORATES. DO NOT GIVE
IPECAC.
| SECTION 5: FIRE FIGHTING MEASURES | |
FIRE AND EXPLOSION HAZARDS:
BATTERIES MAY BURST AND RELEASE HAZARDOUS DECOMPOSITION PRODUCTS WHEN
EXPOSED TO A FIRE SITUATION.
EXTINGUISHING MEDIA:
USE ANY EXTINGUISHING MEDIA THAT IS APPROPRIATE FOR THE SURROUNDING FIRE.
SPECIAL FIRE FIGHTING PROCEDURES:
FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE CLOTHING. FIGHT FIRE FROM A DISTANCE OR
PROTECTED AREA. COOL FIRE EXPOSED BATTERIES TO PREVENT RUPTURE. USE
CAUTION WHEN HANDLING FIRE-EXPOSED CONTAINERS (BATTERIES MAY EXPLODE IN
HEAT OF FIRE).
HAZARDOUS COMBUSTION PRODUCTS:
THERMAL DEGRADATION MAY PRODUCE HAZARDOUS FUMES OF LITHIUM AND MANGANESE;
OXIDES OF CARBON AND OTHER TOXIC BY-PRODUCTS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
NOTIFY SAFETY PERSONNEL OF LARGE SPILLS. IRRITATING VAPORS AND FLAMMABLE
MAY BE RELEASED FROM LEAKING OR RUPTURED BATTERIES. ELIMINATE ALL IGNITION
SOURCES. EVACUATE THE AREA AND ALLOW THE VAPORS TO DISSIPATE. CLEAN-UP
PERSONNEL SHOULD WEAR APPROPRIATE PROTECTIVE CLOTHING TO AVOID EYE AND
SKIN CONTACT AND INHALATION OF VAPORS OR FUMES. INCREASE VENTILATION.
CAREFULLY COLLECT BATTERIES AND PLACE IN AN APPROPRIATE CONTAINER FOR
DISPOSAL. REMOVE SPILLED LIQUID WITH ABSORBENT AND CONTAIN FOR DISPOSAL.
| SECTION 7: HANDLING AND STORAGE | |
AVOID MECHANICAL OR ELECTRICAL ABUSE. DO NOT SHORT CIRCUIT OR INSTALL
INCORRECTLY. BATTERIES MAY EXPLODE, PYROLIZE OR VENT IF DISASSEMBLED,
CRUSHED, RECHARGED OR EXPOSED TO HIGH TEMPERATURES. INSTALL BATTERIES IN
ACCORDANCE WITH EQUIPMENT INSTRUCTIONS. REPLACE ALL BATTERIES IN EQUIPMENT
AT THE SAME TIME. DO NOT CARRY BATTERIES LOOSE IN A POCKET OR BAG.
STORAGE: STORE BATTERIES IN A DRY PLACE AT NORMAL ROOM TEMPERATURE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
THE FOLLOWING OCCUPATIONAL EXPOSURE LIMITS ARE PROVIDED FOR INFORMATIONAL
PURPOSES. NO EXPOSURE TO THE BATTERY COMPONENTS SHOULD OCCUR DURING NORMAL
CONSUMER USE. REFER TO SPECIFIC COUNTRY REGULATIONS FOR ADDITIONAL
EXPOSURE LIMIT INFORMATION.
CHEMICAL NAME EXPOSURE LIMITS
MANGANESE DIOXIDE 0,5 MG/M3 TWA UK WEL
0,5 MG/M3 TWA (INHALABLE) DFG MAK
0,2 MG/M VL BELGIUM
0,2 MG/M3 TWA DENMARK LV
PROPYLENE CARBONATE NONE ESTABLISHED
LITHIUM NONE ESTABLISHED
GRAPHITE 4 MG/M3 TWA UK WEL (RESPIRABLE DUST)
10 MG/M3 TWA UK WEL (INHALABLE DUST)
1,5 MG/M3 TWA DFG MAK (RESPIRABLE DUST)
4 MG/M3 TWA DFG MAK (INHALABLE DUST)
2 MG/M3 VL BELGIUM (RESPIRABLE DUST)
1,2-DIMETHOXYETHANE NONE ESTABLISHED
LITHIUM PERCHLORATE NONE ESTABLISHED
VENTILATION: NO SPECIAL VENTILATION IS NEEDED FOR NORMAL USE.
RESPIRATORY PROTECTION: NONE REQUIRED FOR NORMAL USE.
SKIN PROTECTION:
NONE REQUIRED FOR NORMAL USE. USE BUTYL RUBBER GLOVES WHEN HANDLING
LEAKING BATTERIES.
EYE PROTECTION:
NONE REQUIRED FOR NORMAL USE. WEAR SAFETY GOGGLES WHEN HANDLING LEAKING
BATTERIES.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE AND ODOR: COIN CELLS.
WATER SOLUBILITY: INSOLUBLE
FLASH POINT: 29 DEG. F (-2 DEG. C) (1,2-DIMETHOXYETHANE)
| SECTION 10: STABILITY AND REACTIVITY | |
STABILITY: THIS PRODUCT IS STABLE.
INCOMPATIBILITY/CONDITIONS TO AVOID:
CONTENTS ARE INCOMPATIBLE WITH STRONG OXIDIZING AGENTS. DO NOT HEAT,
CRUSH, DISASSEMBLE, SHORT CIRCUIT OR RECHARGE.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION MAY PRODUCE HAZARDOUS FUMES OF LITHIUM AND
MANGANESE; OXIDES OF CARBON AND OTHER TOXIC BY-PRODUCTS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
| SECTION 11: TOXICOLOGICAL INFORMATION | |
POTENTIAL HEALTH EFFECTS:
THE CHEMICALS AND METALS IN THIS PRODUCT ARE CONTAINED IN A SEALED CAN.
EXPOSURE TO THE CONTENTS WILL NOT OCCUR UNLESS THE BATTERY LEAKS, IS
EXPOSED TO HIGH TEMPERATURES OR IS MECHANICALLY, PHYSICALLY, OR
ELECTRICALLY ABUSED.
EYE CONTACT: CONTACT WITH BATTERY CONTENTS MAY CAUSE IRRITATION.
SKIN CONTACT: CONTACT WITH BATTERY CONTENTS MAY CAUSE IRRITATION.
INHALATION:
INHALATION OF VAPORS OR FUMES RELEASED DUE TO HEAT OR A LARGE NUMBER OF
LEAKING BATTERIES MAY CAUSE RESPIRATORY AND EYE IRRITATION.
INGESTION:
SEEK IMMEDIATE MEDICAL ADVICE. BATTERIES LODGED IN THE ESOPHAGUS SHOULD BE
REMOVED IMMEDIATELY SINCE LEAKAGE, CAUSTIC BURNS AND PERFORATION CAN OCCUR
AS SOON AS TWO HOURS AFTER INGESTION. IRRITATION TO THE INTERNAL/EXTERNAL
MOUTH AREAS, MAY OCCUR FOLLOWING EXPOSURE TO A LEAKING BATTERY.
ACUTE TOXICITY DATA:
MANGANESE DIOXIDE:
LD50 ORAL RAT: >3478 MG/KG
PROPYLENE CARBONATE:
LD50 ORAL RAT: 29100 (MICRO)L/KG
LD50 DERMAL RABBIT: >20 ML/KG
LC50 INHALATION RAT: >5 G/M3
1,2-DIMETHOXYETHANE:
LDLO ORAL RAT: 1000 MG/KG
LCLO INHALATION RAT: 63 G/M3/6 HR
CHRONIC EFFECTS:
THE CHEMICALS IN THIS PRODUCT ARE CONTAINED IN A SEALED CAN AND EXPOSURE
DOES NOT OCCUR DURING NORMAL HANDLING AND USE. NO CHRONIC EFFECTS WOULD BE
EXPECTED FROM HANDLING A LEAKING BATTERY.
TARGET ORGANS: SKIN, EYES AND RESPIRATORY SYSTEM.
CARCINOGENICITY:
NONE OF THE COMPONENTS OF THIS PRODUCT ARE LISTED AS CARCINOGENS BY THE EU
DIRECTIVE ON THE CLASSIFICATION AND LABELING OF SUBSTANCES.
| SECTION 12: ECOLOGICAL INFORMATION | |
NO ECOTOXICITY DATA IS AVAILABLE. THIS PRODUCT IS NOT EXPECTED TO PRESENT
AN ENVIRONMENTAL HAZARD.
| SECTION 13: DISPOSAL INFORMATION | |
DISPOSAL SHOULD BE IN ACCORDANCE WITH NATIONAL AND LOCAL REGULATIONS. DO
NOT INCINERATE FOR DISPOSAL EXCEPT FOR IN A CONTOLLED INCINERATOR.
DURACELL MANGANESE DIOXIDE LITHIUM COIN CELL BATTERIES ARE LABELED IN
COMPLIANCE WITH THE EU BATTERY DIRECTIVE 2006/66.
| SECTION 14: TRANSPORT INFORMATION | |
THE TRANSPORTATION OF LITHIUM BATTERIES IS REGULATED AS UN3090 BY ICAO,
IATA, IMO AND US DOT. HOWEVER, DURACELL LITHIUM MANGANESE DIOXIDE
BATTERIES CELLS AND BATTERIES ARE NOT SUBJECT TO THE OTHER PROVISIONS OF
THE REGULATIONS AS LONG AS THEY ARE PACKAGED AND MARKED IN ACCORDANCE WITH
THE REGULATIONS. (THE LITHIUM CONTENT OF CELLS CONTAINED IN THIS DOCUMENT
IS LESS THAN 1 GRAM.)
DURACELL CERTIFIES THAT ALL OF ITS LITHIUM BATTERIES MEET THE REQUIREMENTS
OF THE UN MANUAL OF TESTS AND CRITERIA, PART III SUBSECTION 38.3. IF YOU
ASSEMBLE THESE BATTERIES INTO LARGER BATTERY PACKS, IT IS RECOMMENDED THAT
YOU PERFORM THE UN TESTS TO ENSURE THE REQUIREMENTS ARE MET PRIOR TO
SHIPMENT. CELLS AND BATTERIES ARE TO BE SEPARATED SO AS TO PREVENT SHORT
CIRCUITS AND PACKED IN STRONG PACKAGING, EXCEPT WHEN INSTALLED IN
EQUIPMENT. EXCEPT WHEN INSTALLED IN EQUIPMENT, EACH PACKAGE CONTAINING
MORE THAN 24 CELLS OR 12 BATTERIES MUST BE MARKED INDICATING THAT IT
CONTAINS LITHIUM BATTERIES AND THAT SPECIAL PROCEDURES SHOULD BE FOLLOWING
IN THE EVENT THAT THE PACKAGING IS DAMAGED. IN ADDITION, EACH SHIPMENT
MUST BE ACCOMPANIED BY APPROPRIATE DOCUMENTATION AND THE PACKAGE MUST BE
CAPABLE OF WITHSTANDING THE DROP TEST REQUIREMENTS.
SHIPPING PACKAGES CONTAINING NON-RECHARGEABLE LITHIUM BATTERIES MUST BE
LABELED, REGARDLESS OF SIZE OR NUMBER OF BATTERIES, WITH THE FOLLOWING
STATEMENT:
"PRIMARY LITHIUM BATTERIES - FORBIDDEN FOR TRANSPORT ABOARD PASSENGER
AIRCRAFT." THE LABELING REQUIREMENT COVERS SHIPMENTS VIA HIGHWAY, RAIL,
VESSEL OR CARGO-ONLY AIRCRAFT AND COVERS ALL SHIPMENTS INSIDE, INTO OR
OUT OF THE US. THE LABEL MUST BE IN CONTRASTING COLOR AND THE LETTERS
MUST BE 12 MM (0.5 IN) IN HEIGHT FOR PACKAGES WEIGHING MORE THAN 30 KG
(66 LBS) AND 6 MM (0.24 IN) IN HEIGHT FOR PACKAGES LESS THAN 30 KG
(66 LBS).
EXCEPT FOR PERSONAL USE, THE SHIPMENT OF LITHIUM BATTERIES ABOARD
PASSENGER AIRCRAFT IS NO LONGER ALLOWED. AIRLINE PASSENGERS MAY CONTINUE
TO HAVE NON-RECHARGEABLE LITHIUM BATTERIES FOR THEIR EQUIPMENT AND A
REASONABLE AMOUNT OF SPARE NON-RECHARGEABLE LITHIUM BATTERIES FOR THEIR
EQUIPMENT IN THEIR CARRY-ON LUGGAGE - NOT IN THEIR CHECKED BAGGAGE. FOR
MORE INFORMATION, AIR TRAVELERS SHOULD CONSULT THE US DEPARTMENT OF
TRANSPORTATION (DOT) SAFETY TRAVEL WEB SITE AT HTTP://SAFETRAVEL.DOT.GOV
| SECTION 15: REGULATORY INFORMATION | |
EU CLASSIFICATION OF PREPARATION:
NOT CLASSIFIED AS A DANGEROUS PREPARATION.
REACH:
THESE PRODUCTS ARE MANUFACTURED ARTICLES AND NOT SUBJECT TO REACH
REGISTRATION REQUIREMENTS.
EU LABELING: NONE REQUIRED
LABELING IS NOT REQUIRED BECAUSE BATTERIES ARE CLASSIFIED AS ARTICLES
UNDER THE BOTH REACH AND THE DANGEROUS PREPARATIONS DIRECTIVE AND AS SUCH
ARE EXEMPT FROM THE REQUIREMENT FOR LABELING.
| SECTION 16: OTHER INFORMATION | |
P&G HAZARD RATING:
HEALTH 0
FIRE 0
REACTIVITY 0
EU CLASSES AND RISK PHRASES FOR REFERENCE (SEE SECTIONS 2 AND 3):
C: CORROSIVE
F: FLAMMABLE
O: OXIDIZING
REPR CAT 2: TOXIC TO REPRODUCTION CATEGORY 2
Xi: IRRITANT
Xn: HARMFUL
R8: CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE.
R11: VERY FLAMMABLE
R14/15: REACTS VIOLENTLY WITH WATER, LIBERATING EXTREMELY FLAMMABLE GASES
R19: MAY FORM EXPLOSIVE PEROXIDES
R20: HARMFUL BY INHALATION
R20/22: HARMFUL BY INHALATION AND IF SWALLOWED.
R34: CAUSES BURNS
R36: IRRITATING TO EYES
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
R60: MAY IMPAIR FERTILITY.
R61: MAY CAUSE HARM TO THE UNBORN CHILD.
DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND
HEALTH.
DISCLAIMER:
THIS SDS IS INTENDED TO PROVIDE A BRIEF SUMMARY OF OUR KNOWLEDGE AND
GUIDANCE REGARDING THE USE OF THIS MATERIAL. THE INFORMATION CONTAINED
HERE HAS BEEN COMPILED FROM SOURCES CONSIDERED BY PROCTER & GAMBLE TO BE
DEPENDABLE AND IS ACCURATE TO THE BEST OF THE COMPANY'S KNOWLEDGE. IT IS
NOT MEANT TO BE AN ALL-INCLUSIVE DOCUMENT ON WORLDWIDE HAZARD
COMMUNICATION REGULATIONS.
THIS INFORMATION IS OFFERED IN GOOD FAITH. EACH USER OF THIS MATERIAL
NEEDS TO EVALUATE THE CONDITIONS OF USE AND DESIGN THE APPROPRIATE
PROTECTIVE MECHANISMS TO PREVENT EMPLOYEE EXPOSURES, PROPERTY DAMAGE OR
RELEASE TO THE ENVIRONMENT. PROCTER & GAMBLE ASSUMED NO RESPONSIBILITY FOR
INJURY TO THE RECIPIENT OR THIRD PERSONS, OR FOR ANY DAMAGE TO ANY
PROPERTY RESULTING FROM MISUSE OF THE PRODUCT.
GMEL # 2033.6-EU