| Common Name: | RAID FLYING INSECT KILLER FORMULA 7 |
| Manufacturer: | S.C. JOHNSON |
| SDS Revision Date: | 10/15/2010 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4HK57, 8AEJ7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SC JOHNSON
A FAMILY COMPANY
MATERIAL SAFETY DATA SHEET
ACCORDING TO ANSI Z400.1 - 2004 AND 29 CFR 1910.1200
RAID(R*) FLYING INSECT KILLER FORMULA 7
VERSION: 3.0
PRINT DATE: 02/01/2011
REVISION DATE: 10/15/2010
MSDS NUMBER: 350000010286
SITE_FORM NUMBER: 30000000000000008805.003
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT INFORMATION:
TRADE NAME: RAID(R*) FLYING INSECT KILLER FORMULA 7
USE OF THE SUBSTANCE/MIXTURE: INSECTICIDE
COMPANY:
S.C. JOHNSON & SON, INC.
1525 HOWE STREET
RACINE, WI 53403-2236
EMERGENCY TELEPHONE NUMBER:
24 HOUR TRANSPORT & MEDICAL EMERGENCY PHONE: (866) 231-5406
24 HOUR INTERNATIONAL EMERGENCY PHONE: (952) 852-4647
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
APPEARANCE / ODOR: OPAQUE / AEROSOL / CHARACTERISTIC
IMMEDIATE CONCERNS:
CAUTION
CAUSES SKIN IRRITATION.
AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
KEEP AWAY FROM HEAT, SPARKS AND FLAME.
CONTENTS UNDER PRESSURE.
DO NOT PUNCTURE OR INCINERATE.
DO NOT STORE AT TEMPERATURES ABOVE 120 DEG. F (50 DEG C), AS CONTAINER MAY
BURST.
POTENTIAL HEALTH EFFECTS:
EXPOSURE ROUTES: EYE, SKIN, INHALATION, INGESTION.
EYES:
MAY CAUSE: MILD EYE IRRITATION
SKIN:
MAY CAUSE TRANSIENT TINGLING AND REDDENING OF THE SKIN.
CAUSES MODERATE SKIN IRRITATION.
INHALATION: MAY CAUSE NOSE, THROAT, AND LUNG IRRITATION.
INGESTION:
MAY CAUSE IRRITATION TO MOUTH, THROAT AND STOMACH.
MAY CAUSE ABDOMINAL DISCOMFORT.
AGGRAVATED MEDICAL CONDITION:
PERSONS WITH PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO
IRRITATING EFFECTS.
INDIVIDUALS WITH CHRONIC RESPIRATORY DISORDERS SUCH AS ASTHMA, CHRONIC
BRONCHITIS, EMPHYSEMA, ETC. MAY BE MORE SUSCEPTIBLE TO IRRITATING EFFECTS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS CHEMICALS PRESENT AT OR ABOVE REPORTABLE LEVELS AS DEFINED BY
OSHA 29 CFR 1910.1200 OR THE CANADIAN CONTROLLED PRODUCTS REGULATIONS ARE
LISTED IN THIS TABLE:
CHEMICAL NAME CAS-NO. WEIGHT PERCENT
BUTANE 106-97-8 5.00 - 10.00
DISTILLATES (PETROLEUM), 64742-47-8 5.00 - 10.00
HYDROTREATED LIGHT
PROPANE 74-98-6 5.00 - 10.00
ISOBUTANE 75-28-5 5.00 - 10.00
TETRAMETHRIN 7696-12-0 0.10 - 1.00
PERMETHRIN 52645-53-1 0.10 - 1.00
ALLETHRIN 584-79-2 0.01 - 0.10
FOR ADDITIONAL INFORMATION ON PRODUCT INGREDIENTS, SEE
WWW.WHATSINSIDESCJOHNSON.COM.
| 4. FIRST AID MEASURES | |
EYE CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS
AND PERSISTS.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
INHALATION:
REMOVE TO FRESH AIR. IF BREATHING IS AFFECTED, GET MEDICAL ATTENTION.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL
PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIFIC HAZARDS DURING FIRE FIGHTING:
AEROSOL PRODUCT - CONTAINERS MAY ROCKET OR EXPLODE IN HEAT OF FIRE.
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
FURTHER INFORMATION:
FIGHT FIRE FROM MAXIMUM DISTANCE OR PROTECTED AREA. COOL AND USE CAUTION
WHEN APPROACHING OR HANDLING FIRE-EXPOSED CONTAINERS. WEAR FULL PROTECTIVE
CLOTHING AND POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS. IN CASE
OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
FLASH POINT:
<-7 DEG. C
<19.4 DEG. F
METHOD: TAG CLOSED CUP (TCC)
NOTE: PROPELLANT
LOWER EXPLOSION LIMIT:
NOTE: NO DATA AVAILABLE
UPPER EXPLOSION LIMIT:
NOTE: NO DATA AVAILABLE
NFPA CLASSIFICATION: NFPA LEVEL 1 AEROSOL
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
REMOVE ALL SOURCES OF IGNITION.
WEAR PERSONAL PROTECTIVE EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
OUTSIDE OF NORMAL USE, AVOID RELEASE TO THE ENVIRONMENT.
METHODS FOR CLEANING UP:
IF DAMAGE OCCURS TO AEROSOL CAN:
CONTAIN SPILLAGE, SOAK UP WITH NON-COMBUSTIBLE ABSORBENT MATERIAL,
(E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND TRANSFER TO
A CONTAINER FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS
(SEE SECTION 13). USE ONLY NON-SPARKING EQUIPMENT. CLEAN RESIDUE FROM
SPILL SITE.
| 7. HANDLING AND STORAGE | |
HANDLING:
ADVICE ON SAFE HANDLING:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
DO NOT PUNCTURE OR INCINERATE.
DO NOT ENTER PLACES WHERE USED OR STORED UNTIL ADEQUATELY VENTILATED.
AVOID BREATHING VAPORS, MIST OR GAS.
FOR PERSONAL PROTECTION SEE SECTION 8.
DO NOT SPRAY TOWARD FACE.
DO NOT USE IN AREAS WITHOUT ADEQUATE VENTILATION.
USE ONLY AS DIRECTED.
KEEP OUT OF REACH OF CHILDREN AND PETS.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
KEEP AWAY FROM HEAT AND SOURCES OF IGNITION.
STORAGE:
REQUIREMENTS FOR STORAGE AREAS AND CONTAINERS:
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS.
DO NOT STORE AT TEMPERATURES ABOVE 120 DEG. F (50 DEG C), AS CONTAINER MAY
BURST.
KEEP IN A DRY, COOL AND WELL-VENTILATED PLACE.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
COMPONENTS CAS-NO. MG/M3 PPM NON- BASIS
STANDARD
UNITS
| BUTANE 106-97-8 1,000 PPM ACGIH
TWA
| BUTANE 106-97-8 1,000 PPM ACGIH
TWA
| BUTANE 106-97-8 1,000 PPM ACGIH
TWA
DISTILLATES 64742-47-8 1,200 MG/M3 152 PPM SUPPLIER
(PETROLEUM),
HYDROTREATED
LIGHT
PROPANE 74-98-6 1,800 MG/M3 1,000 PPM OSHA
TWA
| PROPANE 74-98-6 1,000 PPM ACGIH
TWA
| ISOBUTANE 75-28-5 1,000 PPM ACGIH
TWA
| ISOBUTANE 75-28-5 1,000 PPM ACGIH
TWA
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
INDUSTRIAL SETTING:
USE ONLY WITH ADEQUATE VENTILATION.
DO NOT SPRAY IN ENCLOSED AREAS.
HOUSEHOLD SETTING: NO SPECIAL REQUIREMENTS.
HAND PROTECTION:
IF PROLONGED OR REPEATED CONTACT IS POSSIBLE: WEAR SUITABLE GLOVES.
EYE PROTECTION:
INDUSTRIAL SETTING: NO SPECIAL REQUIREMENTS.
HOUSEHOLD SETTING: NO SPECIAL REQUIREMENTS.
SKIN AND BODY PROTECTION: NO SPECIAL REQUIREMENTS.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
WASH THOROUGHLY AFTER HANDLING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
FORM: AEROSOL
COLOR: OPAQUE
ODOR: CHARACTERISTIC
pH: 5.5 - 8.0
BOILING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
FLASH POINT:
<-7 DEG. C
<19.4 DEG. F
METHOD: TAG CLOSED CUP (TCC) PROPELLANT
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
DENSITY: 0.86 G/CM3
WATER SOLUBILITY: NEGLIGIBLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS (CALIFORNIA AIR RESOURCE BOARD - CARB) TOTAL
VOC (WT. %): 19% - DOES NOT INCLUDE ANY APPLICABLE REGULATORY EXEMPTIONS
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS.
MATERIALS TO AVOID: STRONG OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES AND VAPORS.
HAZARDOUS REACTIONS: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE ORAL TOXICITY:
LD50 ESTIMATED: 5,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 ESTIMATED: >2.2 MG/L
ACUTE DERMAL TOXICITY:
LD50 ESTIMATED: >5,000 MG/KG
CHRONIC EFFECTS:
CARCINOGENICITY: NO DATA AVAILABLE
MUTAGENICITY: NO DATA AVAILABLE
REPRODUCTIVE EFFECTS: NO DATA AVAILABLE
TERATOGENICITY: NO DATA AVAILABLE
SENSITISATION: NO DATA AVAILABLE
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY EFFECTS: HARMFUL TO AQUATIC ORGANISMS.
| 13. DISPOSAL CONSIDERATIONS | |
PESTICIDAL WASTE:
OBSERVE ALL APPLICABLE FEDERAL, PROVINCIAL AND STATE REGULATIONS AND
LOCAL/MUNICIPAL ORDINANCES REGARDING DISPOSAL.
CONSUMER MAY DISCARD EMPTY CONTAINER IN TRASH, OR RECYCLE WHERE FACILITIES
EXIST.
RCRA WASTE CLASS: D001 (IGNITABLE WASTE)
SCJ PRODUCT CATEGORY:
AF: AEROSOL FLAMMABLE
| 14. TRANSPORT INFORMATION | |
LAND TRANSPORT:
U.S. DOT AND CANADIAN TDG SURFACE TRANSPORTATION:
PROPER SHIPPING NAME: UN 1950 AEROSOLS, FLAMMABLE, 2.1
CLASS: 2.1
UN NUMBER: 1950
PACKAGING GROUP: NONE.
NOTE:
SC JOHNSON SHIPS THIS PRODUCT AS CONSUMER COMMODITY ORM-D
(NON-BULK PACKAGES)
SEA TRANSPORT:
IMDG:
PROPER SHIPPING NAME: UN 1950 AEROSOLS, FLAMMABLE, 2.1
CLASS: 2
UN NUMBER: 1950
PACKAGING GROUP: NONE.
EMS: F-D, S-U
NOTE:
LIMITED QUANTITIES DEROGATION MAY BE APPLICABLE TO THIS PRODUCT, PLEASE
CHECK TRANSPORT DOCUMENTS.
AIR TRANSPORT:
ICAO/IATA:
PROPER SHIPPING NAME: UN 1950 AEROSOLS, FLAMMABLE, 2.1
CLASS: 2.1
UN/ID NO.: UN 1950
PACKAGING GROUP: NONE.
NOTE:
SC JOHNSON TYPICALLY DOES NOT SHIP PRODUCTS VIA AIR, THEREFORE IT HAS NOT
BEEN DETERMINED IF THE PRODUCT CONTAINER MEETS CURRENT IATA/ICAO PACKAGE
CRITERIA. REFER TO IATA/ICAO DANGEROUS GOODS REGULATIONS FOR DETAILED
INSTRUCTIONS WHEN SHIPPING THIS ITEM BY AIR.
| 15. REGULATORY INFORMATION | |
NOTIFICATION STATUS:
ALL INGREDIENTS OF THIS PRODUCT ARE LISTED OR ARE EXCLUDED FROM LISTING ON
THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY.
CALIFORNIA PROP. 65:
THIS PRODUCT IS NOT SUBJECT TO THE REPORTING REQUIREMENTS UNDER
CALIFORNIA'S PROPOSITION 65.
REGISTRATION # / AGENCY: 4822-513/US/EPA
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 1
FLAMMABILITY 4
REACTIVITY 0
NFPA RATINGS:
HEALTH 1
FIRE 4
REACTIVITY 0
SPECIAL
FURTHER INFORMATION:
THIS DOCUMENT HAS BEEN PREPARED USING DATA FROM SOURCES CONSIDERED TO BE
TECHNICALLY RELIABLE. IT DOES NOT CONSTITUTE A WARRANTY, EXPRESSED OR
IMPLIED, AS TO THE ACCURACY OF THE INFORMATION CONTAINED HEREIN. ACTUAL
CONDITIONS OF USE ARE BEYOND THE SELLER'S CONTROL. USER IS RESPONSIBLE TO
EVALUATE ALL AVAILABLE INFORMATION WHEN USING PRODUCT FOR ANY PARTICULAR
USE AND TO COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL AND LOCAL LAWS AND
REGULATIONS.
PREPARED BY:
SC JOHNSON GLOBAL SAFETY ASSESSMENT & REGULATORY AFFAIRS (GSARA)