| Common Name: | ICE MACHINE SANITIZER |
| Manufacturer: | MANITOWOC ICE |
| SDS Revision Date: | 1/29/2009 |
| SDS Format: | No Format Specified |
| Item Number(s): | 10L485 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
ICE MACHINE SANITIZER
MSDS ID: MI0896
REVISED: 01-29-2009
REPLACES: 08-01-2008
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: ICE MACHINE SANITIZER
MSDS ID: MI0896
SYNONYMS: N.A.
CAS NUMBER: MIXTURE
CHEMICAL FAMILY: SANITIZER/DISINFECTANT
FORMULA:
EPA REG. NO.: 10324-81-58001
DISTRIBUTED BY:
MANITOWOC ICE, INC.
2110 SOUTH 26TH ST.
MANITOWOC, WI 54220
(920) 682-0161
WWW.MANITOWOCICE.COM
EMERGENCY RESPONSE NUMBERS:
24 HOUR EMERGENCY #: (920) 682-0161
CHEMTREC EMERGENCY #: (800) 424-9300
MANUFACTURED BY: HYDRITE CHEMICAL CO.
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER!
CORROSIVE. CORROSIVE TO THE EYES, SKIN, RESPIRATORY TRACT, AND
GASTROINTESTINAL TRACT. HARMFUL IF SWALLOWED. HARMFUL IF INHALED. MAY BE
FATAL IF ABSORBED THROUGH THE SKIN.
PHYSICAL STATE: LIQUID.
COLOR: CLEAR. COLORLESS.
ODOR: NO ODOR.
POTENTIAL HEALTH EFFECTS:
ROUTES OF EXPOSURE: EYES. SKIN. INHALATION. INGESTION. ABSORPTION.
TARGET ORGANS: EYES. SKIN. RESPIRATORY SYSTEM. CENTRAL NERVOUS SYSTEM.
EYE CONTACT: CORROSIVE-CAUSES SEVERE IRRITATION AND BURNS.
MAY CAUSE: PERMANENT EYE DAMAGE. BLINDNESS.
SKIN CONTACT: CORROSIVE-CAUSES SEVERE IRRITATION AND BURNS.
BRIEF CONTACT MAY CAUSE:
IRRITATION. DEFATTING. EXPOSURES NOT PROMPTLY WASHED OFF MAY LEAD TO TOXIC
EFFECTS SIMILAR TO INGESTION.
SKIN ABSORPTION: MAY BE FATAL IF ABSORBED THROUGH THE SKIN.
INHALATION:
MAY BE CORROSIVE TO THE RESPIRATORY TRACT. SEVERE IRRITATION AND BURNS
MAY RESULT.
VAPORS OR MISTS MAY IRRITATE: THROAT. RESPIRATORY TRACT.
HIGH VAPOR CONCENTRATIONS MAY CAUSE: CENTRAL NERVOUS SYSTEM EFFECTS.
SYMPTOMS MAY INCLUDE: HEADACHE. DIZZINESS. DROWSINESS.
INGESTION: CORROSIVE-CAUSES SEVERE IRRITATION AND BURNS.
MAY CAUSE: GASTROINTESTINAL IRRITATION. NAUSEA. VOMITING. DIARRHEA.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE TO PRODUCT: NONE KNOWN.
OTHER:
INGESTION OF ETHANOL BY PREGNANT WOMEN CAN CAUSE REPRODUCTIVE TOXICITY TO
THE FETUS.
CANCER INFORMATION:
THIS PRODUCT DOES NOT CONTAIN 0.1% OR MORE OF THE KNOWN OR POTENTIAL
CARCINOGENS LISTED IN NTP, IARC, OR OSHA.
POTENTIAL ENVIRONMENTAL EFFECTS: SEE SECTION 12.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS NUMBER OSHA HAZARD % BY WT.
ALKYL(50%C14,40%C12,10%C16) 68424-85-1 YES 3.0%
DIMETHYL BENZYL AMMONIUM
CHLORIDE
OCTYL DECYL DIMETHYL AMMONIUM 32426-11-2 YES 2.25%
CHLORIDE
ETHYL ALCOHOL 64-17-5 YES 0 - 2%
DIDECYL DIMETHYL AMMONIUM 7173-51-5 YES 1.125%
CHLORIDE
DIOCTYL DIMETHYL AMMONIUM 5538-94-3 YES 1.125%
CHLORIDE
| 4. FIRST-AID MEASURES | |
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE
HOLDING EYELIDS OPEN. TILT HEAD TO AVOID CONTAMINATING UNAFFECTED EYE. GET
IMMEDIATE MEDICAL ATTENTION. REMOVE CONTACT LENSES AFTER THE FIRST 5
MINUTES AND CONTINUE FLUSHING.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE
REMOVING CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION
IMMEDIATELY. DO NOT REUSE CLOTHING AND SHOES UNTIL CLEANED. WASH WITH
SOAP AND WATER.
INHALATION:
REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. GET
MEDICAL ATTENTION IMMEDIATELY. KEEP WARM AND QUIET.
INGESTION:
IF SWALLOWED, CALL A PHYSICIAN IMMEDIATELY. DO NOT INDUCE VOMITING UNLESS
DIRECTED TO DO SO BY A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS
TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS. HAVE PERSON SIP A GLASS OF
WATER IF ABLE TO SWALLOW.
NOTE TO PHYSICIANS:
PROBABLE MUCOSAL DAMAGE MAY CONTRAINDICATE THE USE OF GASTRIC LAVAGE.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOR FIRES IN AREA USE APPROPRIATE MEDIA.
FOR EXAMPLE: WATER SPRAY. DRY CHEMICAL. CARBON DIOXIDE. ALCOHOL FOAM.
FIRE FIGHTING METHODS:
EVACUATE AREA OF UNPROTECTED PERSONNEL. WEAR PROTECTIVE CLOTHING INCLUDING
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. REMAIN UPWIND OF FIRE
TO AVOID HAZARDOUS VAPORS AND DECOMPOSITION PRODUCTS. USE WATER SPRAY TO
COOL FIRE-EXPOSED CONTAINERS. RUN-OFF FROM FIRE CONTROL MAY CAUSE
POLLUTION.
FIRE AND EXPLOSION HAZARDS:
NONE KNOWN. CONTACT WITH STRONG OXIDIZING AGENTS MAY CAUSE FIRE.
HAZARDOUS COMBUSTION PRODUCTS: IRRITATING AND/OR TOXIC GASES.
| 6. ACCIDENTAL RELEASE MEASURES | |
SPILL CLEAN-UP PROCEDURES:
CORROSIVE MATERIAL. EVACUATE UNPROTECTED PERSONNEL FROM AREA. MAINTAIN
ADEQUATE VENTILATION. FOLLOW PERSONAL PROTECTIVE EQUIPMENT RECOMMENDATIONS
FOUND IN SECTION 8. NEVER EXCEED ANY OCCUPATIONAL EXPOSURE LIMIT. CONTAIN
SPILL, PLACE INTO DRUMS FOR PROPER DISPOSAL. FLUSH REMAINING AREA WITH
WATER TO REMOVE TRACE RESIDUE AND DISPOSE OF PROPERLY. AVOID DIRECT
DISCHARGE TO SEWERS AND SURFACE WATERS. NOTIFY AUTHORITIES IF ENTRY
OCCURS.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. USE WITH ADEQUATE
VENTILATION. DO NOT SWALLOW. AVOID BREATHING VAPORS, MISTS, OR DUST. DO
NOT EAT, DRINK, OR SMOKE IN WORK AREA. WASH THOROUGHLY AFTER HANDLING.
STORAGE:
CORROSIVE MATERIAL. STORE IN A COOL, WELL VENTILATED AREA, OUT OF DIRECT
SUNLIGHT. STORE IN A DRY LOCATION AWAY FROM HEAT. KEEP AWAY FROM
INCOMPATIBLE MATERIALS. KEEP CONTAINERS TIGHTLY CLOSED. DO NOT STORE IN
UNLABELED OR MISLABELED CONTAINERS. DO NOT STORE NEAR HEAT OR OPEN FLAMES.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
COMPONENT OSHA OSHA ACGIH ACGIH
PEL STEL/C TWA STEL/C
ALKYL(50%C14,40%C12,10%C16) NOT NOT NOT NOT ESTAB.
DIMETHYL BENZYL AMMONIUM ESTAB. ESTAB. ESTAB.
CHLORIDE
OCTYL DECYL DIMETHYL NOT NOT NOT NOT ESTAB.
AMMONIUM CHLORIDE ESTAB. ESTAB. ESTAB.
ETHYL ALCOHOL 1000 NOT 1000 PPM NOT ESTAB.
PPM ESTAB.
DIDECYL DIMETHYL AMMONIUM NOT NOT NOT NOT ESTAB.
CHLORIDE ESTAB. ESTAB. ESTAB.
DIOCTYL DIMETHYL AMMONIUM NOT NOT NOT NOT ESTAB.
CHLORIDE ESTAB. ESTAB. ESTAB.
ENGINEERING CONTROLS:
GENERAL ROOM VENTILATION AND LOCAL EXHAUST ARE REQUIRED. MAINTAIN ADEQUATE
VENTILATION. DO NOT USE IN CLOSED OR CONFINED SPACES. AVOID CREATING DUST
OR MIST. KEEP LEVELS BELOW EXPOSURE LIMITS. TO DETERMINE EXPOSURE LEVELS,
MONITORING SHOULD BE PERFORMED REGULARLY.
EYE/FACE PROTECTION:
WEAR CHEMICAL SAFETY GOGGLES WHILE HANDLING THIS PRODUCT. WEAR ADDITIONAL
EYE PROTECTION SUCH AS A FACE SHIELD WHEN THE POSSIBILITY EXISTS FOR EYE
CONTACT WITH SPLASHING OR SPRAYING LIQUID, OR AIRBORNE MATERIAL.
SKIN PROTECTION:
PREVENT CONTACT WITH THIS PRODUCT. WEAR GLOVES AND PROTECTIVE CLOTHING
DEPENDING ON CONDITION OF USE.
PROTECTIVE GLOVES: IMPERVIOUS. RUBBER. NEOPRENE.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION MAY BE REQUIRED TO AVOID OVEREXPOSURE WHEN HANDLING
THIS PRODUCT.
IF EXPOSURE LIMITS ARE EXCEEDED, WEAR:
NIOSH-APPROVED AIR-PURIFYING RESPIRATOR WITH:
ORGANIC VAPOR CARTRIDGE. NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS. DO NOT EXCEED LIMITS ESTABLISHED BY THE RESPIRATOR
MANUFACTURER. ALL RESPIRATORY PROTECTION PROGRAMS MUST COMPLY WITH OSHA
29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS AND MUST BE FOLLOWED WHENEVER
WORKPLACE CONDITIONS REQUIRE A RESPIRATOR'S USE.
OTHER PROTECTIVE EQUIPMENT:
EYE-WASH STATION. SAFETY SHOWER. IMPERVIOUS CLOTHING. PROTECTIVE CLOTHING.
GENERAL HYGIENE CONDITIONS:
WASH WITH SOAP AND WATER BEFORE MEAL TIMES AND AT THE END OF EACH WORK
SHIFT. GOOD MANUFACTURING PRACTICES REQUIRE GROSS AMOUNTS OF ANY CHEMICAL
BE REMOVED FROM SKIN AS SOON AS PRACTICAL, ESPECIALLY BEFORE EATING OR
SMOKING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID.
COLOR: CLEAR. COLORLESS.
ODOR: NO ODOR.
BOILING POINT (DEG. F): N.D.
FREEZING POINT (DEG. F): N.D.
MELTING POINT (DEG. F): N.D.
VAPOR PRESSURE (MMHg): N.D.
VAPOR DENSITY (AIR=1): N.D.
SOLUBILITY IN WATER: COMPLETE
pH: 8.0 (AS IS)
SPECIFIC GRAVITY: 0.990 @ 25C
% VOLATILE (WT%): APPROX. 93
EVAPORATION RATE (nBuAc = 1): N.D.
VOC (WT%): 0.75-1.5
VOC (LBS/GAL): 0.06-0.12
VISCOSITY: N.D.
FLASH POINT: NONE WHEN HEATED TO 100 DEG. C
FLASH POINT METHOD: COC.
LOWER EXPLOSION LIMIT: N.A.
UPPER EXPLOSION LIMIT: N.A.
AUTOIGNITION TEMPERATURE: NO DATA
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID:
AVOID ELEVATED TEMPERATURES. AVOID MIXING WITH OTHER CLEANING PRODUCTS.
MIX ONLY WITH WATER.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS. REDUCING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. HYDROGEN CHLORIDE.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR UNDER NORMAL CONDITIONS.
CONTACT WITH STRONG OXIDIZING AGENTS MAY CAUSE FIRE.
| 11. TOXICOLOGICAL INFORMATION | |
LD50 ORAL: >2000 MG/KG IN MALE AND FEMALE RATS.
LD50 SKIN: >200 THRU 2000 MK/KG IN MALE AND FEMALE RATS.
PRIMARY SKIN: CORROSIVE.
PRIMARY EYE: CORROSIVE.
LC50 INHALATION: NO DATA
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.
CHEMICAL FATE INFORMATION: PRODUCT IS BIODEGRADABLE.
| 13. DISPOSAL CONSIDERATIONS | |
HAZARDOUS WASTE NUMBER:
DISPOSAL METHOD:
DISPOSE OF IN A PERMITTED HAZARDOUS WASTE MANAGEMENT FACILITY FOLLOWING
ALL LOCAL, STATE AND FEDERAL REGULATIONS. CHEMICAL ADDITIONS TO,
PROCESSING OF, OR OTHERWISE ALTERING THIS MATERIAL MAY MAKE THIS WASTE
MANAGEMENT INFORMATION INCOMPLETE, INACCURATE, OR OTHERWISE INAPPROPRIATE.
FURTHERMORE, STATE AND LOCAL WASTE DISPOSAL REQUIREMENTS MAY BE MORE
RESTRICTIVE OR OTHERWISE DIFFERENT FROM FEDERAL LAWS AND REGULATIONS.
SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. DO NOT PRESSURIZE, CUT, WELD, SOLDER,
DRILL, GRIND OR EXPOSE EMPTY CONTAINERS TO HEAT, FLAME, SPARKS OR OTHER
SOURCES OF IGNITION.
| 14. TRANSPORTATION INFORMATION | |
DOT (DEPARTMENT OF TRANSPORTATION):
PROPER SHIPPING NAME:
DISINFECTANTS, LIQUID, CORROSIVE N.O.S. (QUATERNARY AMMONIUM COMPOUND)
HAZARD CLASS: 8
IDENTIFICATION NUMBER: UN1903
PACKING GROUP: III
LABEL REQUIRED: CORROSIVE
NOTE:
THE LISTED TRANSPORTATION CLASSIFICATION DOES NOT ADDRESS REGULATORY
VARIATIONS DUE TO CHANGES IN PACKAGE SIZE, MODE OF SHIPMENT OR OTHER
REGULATORY DESCRIPTORS. IN THE UNITED STATES, IT MAY BE POSSIBLE TO
RECLASSIFY THIS MATERIAL AS A CONSUMER COMMODITY ORM-D BASED ON 49 CFR
173.154 (B)(C).
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA INVENTORY STATUS:
THIS PRODUCT OR ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA
INVENTORY OF CHEMICAL SUBSTANCES.
SARA TITLE III SECTION 311/312 CATEGORY:
IMMEDIATE (ACUTE) HEALTH HAZARD (Y)
DELAYED (CHRONIC) HEALTH HAZARD (N)
FIRE HAZARD (N)
SUDDEN RELEASE OF PRESSURE HAZARD (N)
REACTIVE HAZARD (N)
SARA SECTION 302/304/313/HAP:
COMPONENT CERCLA RQ SARA RQ SARA TPQ SARA 313 U.S. HAP
ALKYL(50%C14,40%C12, N.A. N.A. N.A. NO NO
10%C16) DIMETHYL
BENZYL AMMONIUM
CHLORIDE
OCTYL DECYL DIMETHYL N.A. N.A. N.A. NO NO
AMMONIUM CHLORIDE
ETHYL ALCOHOL N.A. N.A. N.A. NO NO
DIDECYL DIMETHYL N.A. N.A. N.A. NO NO
AMMONIUM CHLORIDE
DIOCTYL DIMETHYL N.A. N.A. N.A. NO NO
AMMONIUM CHLORIDE
U.S. STATE REGULATIONS:
CALIFORNIA - THE FOLLOWING COMPONENTS ARE LISTED UNDER PROPOSITION 65:
BENZYL CHLORIDE (TRACE IMPURITY <2 PPM)
ETHANOL (0.75 - 1.5%)
WISCONSIN - THE FOLLOWING COMPONENTS ARE LISTED AS A WISCONSIN HAP: NONE.
| 16. ADDITIONAL INFORMATION | |
HYDRITE RATING SYSTEM:
HEALTH 3
FLAMMABILITY 0
REACTIVITY 0
* = CHRONIC HEALTH HAZARD
NFPA RATING SYSTEM:
HEALTH 3
FLAMMABILITY 0
REACTIVITY 0
SPECIAL HAZARD NONE
MSDS ABBREVIATIONS:
N.A. = NOT APPLICABLE
N.D. = NOT DETERMINED
HAP = HAZARDOUS AIR POLLUTANT
VOC = VOLATILE ORGANIC COMPOUND
C = CEILING LIMIT
N.E./NOT ESTAB. = NOT ESTABLISHED
MSDS PREPARED BY: JAK
REASON FOR REVISION: CHANGES MADE THROUGHOUT THE MSDS.
THE DATA IN THIS MATERIAL SAFETY DATA SHEET RELATES TO THE SPECIFIC
MATERIAL DESIGNATED AND DOES NOT RELATE TO ITS USE IN COMBINATION WITH ANY
OTHER MATERIAL OR PROCESS. THE DATA CONTAINED IS BELIEVED TO BE CORRECT.
HOWEVER, SINCE CONDITIONS OF USE ARE OUTSIDE OUR CONTROL IT SHOULD NOT BE
TAKEN AS WARRANTY OR REPRESENTATION FOR WHICH HYDRITE CHEMICAL CO. ASSUMES
LEGAL RESPONSIBILITY. THIS INFORMATION IS PROVIDED SOLELY FOR YOUR
CONSIDERATION, INVESTIGATION, AND VERIFICATION.