| Common Name: | CARBON DIOXIDE (COMPRESSED) |
| Manufacturer: | ISI NORTH AMERICA |
| SDS Revision Date: | 6/1/2010 |
| SDS Format: | No Format Specified |
| Item Number(s): | 11N755, 11N756, 11N757, 11N758, 11N759, 11N760, 11N781, 11W064, 12L912, 12L913, 12L916, 12L918, 12L922, 2FLK3, 3NFR7, 3URV3, 3URV8, 3URW4, 41088815, 46G121, 46G122, 46G123, 5UYA8, 5UYA9, 5UYC0, 5UYC1, 5UYD4, 5UYD5, 5UYD6, 5UYD7, 5UYD8, 5UYD9, 9YHV1, 9YK18, 9YKN0, 9YKN1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ISI COMPONENTS MATERIAL SAFETY DATA SHEET
PRODUCT: CARBON DIOXIDE CYLINDERS
DATE: JUNE 2010
| 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: CARBON DIOXIDE (COMPRESSED)
TRADE NAME: CARBON DIOXIDE
CHEMICAL NAME: CARBON DIOXIDE
SYNONYMS: CARBONIC ANHYDRIDE, CARBONIC ACID GAS
FORMULA: CO2
CHEMICAL FAMILY: ACID ANHYDRIDES
TELEPHONE:
EMERGENCIES: 1-800-424-9300*
ROUTINE: 1-973-227-2426*
COMPANY NAME:
ISI NORTH AMERICA, INC.
175 ROUTE 46 WEST
FAIRFIELD, NJ 07004
* CALL EMERGENCY NUMBERS 24 HOURS A DAY ONLY FOR SPILLS, LEAKS, FIRE,
EXPOSURE, OR ACCIDENTS INVOLVING THIS PRODUCT. FOR ROUTINE INFORMATION,
CONTACT ISI COMPONENTS OR CALL THE NUMBER ABOVE.
| 2. COMPOSITION/INFORMATION ON INGREDIENTS | |
| CARBON DIOXIDE IS SUPPLIED IN CYLINDERS AS A LIQUID UNDER ITS OWN VAPOR
| PRESSURE, WHICH VARIES DEPENDING ON THE TEMPERATURE. IT IS NON-TOXIC,
| NON-FLAMMABLE AND HEAVIER THAN AIR. CYLINDERS RANGE IN SIZE FROM 10 ML.
| TO 350 ML.
INGREDIENT CAS NUMBER CONCENTRATION OSHA PEL ACGIH TLV-TWA
CARBON DIOXIDE 124-38-9 >99% 5,000 PPM* 5,000 PPM**
* THE SYMBOL > MEANS "GREATER THAN"; THE SYMBOL < "LESS THAN."
** SEE FOLLOWING SECTION.
| 3. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
CAUTION!
HIGH-PRESSURE LIQUID AND GAS.
CAN CAUSE RAPID SUFFOCATION.
CAN INCREASE RESPIRATION AND HEART RATE.
MAY CAUSE NERVOUS SYSTEM DAMAGE.
MAY CAUSE FROSTBITE.
MAY CAUSE DIZZINESS AND DROWSINESS.
SELF-CONTAINED BREATHING APPARATUS MAY BE REQUIRED BY RESCUE WORKERS.
ODOR: NONE TO SLIGHTLY PUNGENT
| THRESHOLD LIMIT VALUE:
| TLV-TWA, 5,000 PPM (ACGIH, 1998).
| TLV-TWA, 15 MIN STEL, 30,000 PPM.
EFFECTS OF A SINGLE (ACUTE) OVEREXPOSURE:
INHALATION:
CARBON DIOXIDE GAS IS AN ASPHYXIANT WITH EFFECTS DUE TO LACK OF OXYGEN.
IT IS ALSO PHYSIOLOGICALLY ACTIVE, AFFECTING CIRCULATION AND BREATHING.
MODERATE CONCENTRATIONS MAY CAUSE HEADACHE, DROWSINESS, DIZZINESS, STINGING
OF THE NOSE AND THROAT, EXCITATION, RAPID BREATHING AND HEART RATE, EXCESS
SALIVATION, VOMITING, AND UNCONSCIOUSNESS. LACK OF OXYGEN CAN KILL.
SKIN CONTACT:
NO HARM EXPECTED FROM VAPOR. COLD GAS, OR LIQUID OR SOLID CARBON DIOXIDE
MAY CAUSE SEVERE FROSTBITE.
SWALLOWING:
AN UNLIKELY ROUTE OF EXPOSURE. THIS PRODUCT IS A GAS AT NORMAL TEMPERATURE
AND PRESSURE.
EYE CONTACT:
NO HARM EXPECTED FROM VAPOR. COLD GAS, OR LIQUID OR SOLID CARBON DIOXIDE
MAY CAUSE SEVERE FROSTBITE.
EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: NO HARM EXPECTED
OTHER EFFECTS OF OVEREXPOSURE:
DAMAGE TO RETINAL OR GANGLION CELLS AND CENTRAL NERVOUS SYSTEM MAY OCCUR.
MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE:
THE TOXICOLOGY AND THE PHYSICAL AND CHEMICAL PROPERTIES OF CARBON DIOXIDE
SUGGEST THAT OVEREXPOSURE IS UNLIKELY TO AGGRAVATE EXISTING MEDICAL
CONDITIONS.
SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD
EVALUATION:
A SINGLE STUDY HAS SHOWN AN INCREASE IN HEART DEFECTS IN RATS EXPOSED TO
6% CARBON DIOXIDE IN AIR FOR 24 HOURS AT DIFFERENT TIMES DURING GESTATION.
THERE IS NO EVIDENCE THAT CARBON DIOXIDE IS TERATOGENIC IN HUMANS.
CARCINOGENICITY: CARBON DIOXIDE IS NOT LISTED BY NTP, OSHA, OR IARC.
| 4. FIRST AID MEASURES | |
INHALATION:
IMMEDIATELY REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, QUALIFIED PERSONNEL MAY GIVE
OXYGEN. CALL A PHYSICIAN.
SKIN CONTACT:
FOR EXPOSURE TO COLD VAPOR OR SOLID, IMMEDIATELY WARM FROSTBITE AREA WITH
WARM WATER NOT TO EXCEED 105 DEG. F (41 DEG. C). IN CASE OF MASSIVE
EXPOSURE, REMOVE CONTAMINATED CLOTHING WHILE SHOWERING WITH WARM WATER.
CALL A PHYSICIAN.
SWALLOWING:
AN UNLIKELY ROUTE OF EXPOSURE. THIS PRODUCT IS A GAS AT NORMAL TEMPERATURE
AND PRESSURE.
EYE CONTACT:
FOR EXPOSURE TO COLD VAPOR OR SOLID, IMMEDIATELY FLUSH EYES THOROUGHLY
WITH WARM WATER FOR AT LEAST 15 MINUTES. HOLD THE EYELIDS OPEN AND AWAY
FROM THE EYEBALLS TO ENSURE THAT ALL SURFACES ARE FLUSHED THOROUGHLY. SEE
A PHYSICIAN, PREFERABLY AN OPHTHALMOLOGIST, IMMEDIATELY.
NOTES TO PHYSICIAN:
THERE IS NO SPECIFIC ANTIDOTE. TREATMENT OF OVEREXPOSURE SHOULD BE DIRECTED
AT THE CONTROL OF SYMPTOMS AND THE CLINICAL CONDITION OF THE PATIENT.
| 5. FIRE FIGHTING MEASURES | |
FLASH POINT (TEST METHOD): NOT APPLICABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
FLAMMABLE LIMITS IN AIR, % BY VOLUME:
LOWER: NOT APPLICABLE
UPPER: NOT APPLICABLE
EXTINGUISHING MEDIA:
CARBON DIOXIDE CANNOT CATCH FIRE. USE MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
SPECIAL FIRE FIGHTING PROCEDURES:
CAUTION!
HIGH-PRESSURE GAS LIQUID AND GAS.
EVACUATE ALL PERSONNEL FROM DANGER AREA. IMMEDIATELY DELUGE CYLINDERS WITH
WATER FROM MAXIMUM DISTANCE UNTIL COOL, THEN MOVE THEM AWAY FROM FIRE AREA
IF WITHOUT RISK. SELF-CONTAINED BREATHING APPARATUS MAY BE REQUIRED BY
RESCUE WORKERS. ON-SITE FIRE BRIGADES MUST COMPLY WITH OSHA
29 CFR 1910.156.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
HEAT OF FIRE CAN BUILD PRESSURE IN CYLINDER AND CAUSE IT TO RUPTURE.
RECOMMENDED STORAGE TEMPERATURE: -30 DEGREES C TO +65 DEGREES C.
HAZARDOUS COMBUSTION PRODUCTS: NONE KNOWN
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CAUTION!
HIGH-PRESSURE LIQUID AND GAS.
CARBON DIOXIDE IS AN ASPHYXIANT. LACK OF OXYGEN CAN KILL. EVACUATE ALL
PERSONNEL FROM DANGER AREA. USE SELF-CONTAINED BREATHING APPARATUS WHERE
NEEDED. SHUT OFF LEAK IF YOU CAN DO SO WITHOUT RISK. VENTILATE AREA OR MOVE
CYLINDER TO A WELL-VENTILATED AREA. TEST FOR SUFFICIENT OXYGEN, ESPECIALLY
IN CONFINED SPACES, BEFORE ALLOWING REENTRY.
WASTE DISPOSAL METHOD:
PREVENT WASTE FROM CONTAMINATING THE SURROUNDING ENVIRONMENT. KEEP
PERSONNEL AWAY. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER, OR
LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH
FEDERAL, STATE, AND LOCAL REGULATIONS. IF NECESSARY, CALL YOUR LOCAL
SUPPLIER FOR ASSISTANCE.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS TO BE TAKEN IN STORAGE:
STORE AND USE WITH ADEQUATE VENTILATION. IF APPLICABLE, SECURE CYLINDERS
UPRIGHT TO KEEP THEM FROM FALLING OR BEING KNOCKED OVER.
PRECAUTIONS TO BE TAKEN IN HANDLING:
PROTECT CYLINDERS FROM DAMAGE, REFER TO SECTION 16.
FOR ADDITIONAL INFORMATION ON STORAGE AND HANDLING, REFER TO COMPRESSED GAS
ASSOCIATION (CGA) PAMPHLET P-1, SAFE HANDLING OF COMPRESSED GASES IN
CONTAINERS, AVAILABLE FROM THE CGA.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
VENTILATION/ENGINEERING CONTROLS:
LOCAL EXHAUST:
USE A LOCAL EXHAUST SYSTEM, IF NECESSARY, TO CONTROL THE CONCENTRATION OF
CARBON DIOXIDE IN THE WORKER'S BREATHING ZONE.
MECHANICAL (GENERAL):
UNDER CERTAIN CONDITIONS, GENERAL EXHAUST VENTILATION MAY BE ACCEPTABLE TO
KEEP CARBON DIOXIDE BELOW THE EXPOSURE LIMIT.
SPECIAL: NONE
OTHER: NONE
RESPIRATORY PROTECTION:
NONE REQUIRED UNDER NORMAL USE. AN AIR-SUPPLIED RESPIRATOR MUST BE USED IN
CONFINED SPACES. RESPIRATORY PROTECTION MUST CONFORM TO OSHA RULES AS
SPECIFIED IN 29 CFR 1910.134.
| SKIN PROTECTION: WEAR INSULATED NEOPRENE GLOVES FOR CYLINDER HANDLING
| EYE PROTECTION: SELECT IN ACCORDANCE WITH OSHA 29 CFR 1910.133.
| OTHER PROTECTIVE EQUIPMENT:
| METATARSAL SHOES FOR CYLINDER HANDLING. SELECT IN ACCORDANCE WITH OSHA
| 29 CFR 1910.132 AND 1910.133.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
MOLECULAR WEIGHT: 44.01
SPECIFIC GRAVITY (AIR = 1) AT 70 DEG. F (21.1 DEG. C) AND 1 ATM: 1.522
GAS DENSITY AT 70 DEG. F (21.1 DEG. C) AND 1 ATM:
0.1444 LB/FT3 (1.833 KG/M3)
| LIQUID DENSITY (SATURATED) AT 70 DEG. F (21.1 DEG. C) AND 1 ATM:
| 47.6 LB/FT3 (762 KG/M3)
VAPOR PRESSURE AT 70 DEG. F (21.1 DEG. C): 838 PSIG (5778 KPA)
SOLUBILITY IN WATER, VOL/VOL AT 68 DEG. F (20 DEG. C) AND 1 ATM: 0.90
PERCENT VOLATILES BY VOLUME: 100
EVAPORATION RATE (BUTYL ACETATE = 1): HIGH
pH: 3.7 (FOR CARBONIC ACID)
SUBLIMATION POINT AT 1 ATM: -109.3 DEG. F (-78.5 DEG. C)
APPEARANCE, ODOR, AND STATE:
COLORLESS, ODORLESS, SLIGHTLY ACID GAS. IT IS FELT BY SOME TO HAVE A
SLIGHT, PUNGENT ODOR AND BITING TASTE.
| 10. STABILITY AND REACTIVITY | |
STABILITY:
( ) UNSTABLE
(X) STABLE
INCOMPATIBILITY (MATERIALS TO AVOID):
ALKALI METALS, ALKALINE EARTH METALS, METAL ACETYLIDES, CHROMIUM, TITANIUM
ABOVE 1022 DEG. F (550 DEG. C), URANIUM ABOVE 1382 DEG. F (750 DEG. C),
MAGNESIUM ABOVE 1427 DEG. F (775 DEG. C)
| HAZARDOUS DECOMPOSITION PRODUCTS:
| ELECTRICAL DISCHARGES AND HIGH TEMPERATURES DECOMPOSE CARBON DIOXIDE INTO
| CARBON MONOXIDE AND OXYGEN.
HAZARDOUS POLYMERIZATION:
( ) MAY OCCUR
(X) WILL NOT OCCUR
CONDITIONS TO AVOID: NONE KNOWN.
| 11. TOXICOLOGICAL INFORMATION | |
|
CARBON DIOXIDE IS AN ASPHYXIANT. IT INITIALLY STIMULATES RESPIRATION AND
THEN CAUSES RESPIRATORY DEPRESSION. HIGH CONCENTRATIONS RESULT IN
NARCOSIS. SYMPTOMS IN HUMANS ARE AS FOLLOWS:
EFFECT CONCENTRATION
BREATHING RATE INCREASES SLIGHTLY. 1%
BREATHING RATE INCREASES TO 50% ABOVE NORMAL LEVEL. 2%
PROLONGED EXPOSURE CAN CAUSE HEADACHE, TIREDNESS.
BREATHING INCREASES TO TWICE NORMAL RATE AND BECOMES 3%
LABORED. WEAK NARCOTIC EFFECT. IMPAIRED HEARING,
HEADACHE, INCREASED BLOOD PRESSURE AND PULSE RATE.
BREATHING INCREASES TO APPROXIMATELY FOUR TIMES NORMAL 4 - 5%
RATE, SYMPTOMS OF INTOXICATION BECOME EVIDENT, AND SLIGHT
CHOKING MAY BE FELT.
CHARACTERISTIC SHARP ODOR NOTICEABLE. VERY LABORED 5 - 10%
BREATHING, HEADACHE, VISUAL IMPAIRMENT, AND RINGING IN
THE EARS. JUDGMENT MAY BE IMPAIRED, FOLLOWED WITHIN
MINUTES BY LOSS OF CONSCIOUSNESS.
UNCONSCIOUSNESS OCCURS MORE RAPIDLY ABOVE 10% LEVEL. 50 - 100%
PROLONGED EXPOSURE TO HIGH CONCENTRATIONS MAY EVENTUALLY
RESULT IN DEATH FROM ASPHYXIATION.
| 12. ECOLOGICAL INFORMATION | |
NO ADVERSE ECOLOGICAL EFFECTS EXPECTED. CARBON DIOXIDE DOES NOT CONTAIN
ANY CLASS I OR CLASS II OZONE-DEPLETING CHEMICALS. CARBON DIOXIDE IS NOT
LISTED AS A MARINE POLLUTANT BY DOT.
| 13. DISPOSAL CONSIDERATIONS | |
EMPTY CYLINDERS PRIOR TO DISPOSAL. CYLINDER SHELLS ARE 100% RECYCLABLE
STEEL.
| 14. TRANSPORT INFORMATION | |
DOT/IMO SHIPPING NAME: CARBON DIOXIDE
HAZARD CLASS: 2.2
IDENTIFICATION NUMBER: UN 1013
PRODUCT RQ: NOT APPLICABLE
SHIPPING LABEL(S): NONFLAMMABLE GAS
PLACARD (WHEN REQUIRED): NONFLAMMABLE GAS
SPECIAL SHIPPING INFORMATION:
CYLINDERS SHOULD BE TRANSPORTED IN A SECURE POSITION, IN A WELL-VENTILATED
VEHICLE. CYLINDERS TRANSPORTED IN AN ENCLOSED, NONVENTILATED COMPARTMENT
OF A VEHICLE CAN PRESENT SERIOUS SAFETY HAZARDS.
SHIPMENT OF COMPRESSED GAS CYLINDERS THAT HAVE BEEN FILLED WITHOUT THE
OWNER'S CONSENT IS A VIOLATION OF FEDERAL LAW (49 CFR 173.301(B)).
| 15. REGULATORY INFORMATION | |
THE FOLLOWING SELECTED REGULATORY REQUIREMENTS MAY APPLY TO THIS PRODUCT.
NOT ALL SUCH REQUIREMENTS ARE IDENTIFIED. USERS OF THIS PRODUCT ARE SOLELY
RESPONSIBLE FOR COMPLIANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
REGULATIONS.
U.S. FEDERAL REGULATIONS:
EPA (ENVIRONMENTAL PROTECTION AGENCY):
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT OF
1980 (40 CFR PARTS 117 AND 302):
REPORTABLE QUANTITY (RQ): NONE
SARA:
SUPERFUND AMENDMENT AND REAUTHORIZATION ACT:
SECTIONS 302/304:
REQUIRE EMERGENCY PLANNING BASED ON THRESHOLD PLANNING QUANTITY (TPQ) AND
RELEASE REPORTING BASED ON REPORTABLE QUANTITIES (RQ) OF EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR PART 355):
THRESHOLD PLANNING QUANTITY (TPQ): NONE
EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): NONE
SECTIONS 311/312:
REQUIRE SUBMISSION OF MSDSS AND REPORTING OF CHEMICAL INVENTORIES WITH
IDENTIFICATION OF EPA HAZARD CATEGORIES.
THE HAZARD CATEGORIES FOR THIS PRODUCT ARE AS FOLLOWS:
IMMEDIATE: YES
DELAYED: NO
PRESSURE: YES
REACTIVITY: NO
FIRE: NO
SECTION 313:
REQUIRES SUBMISSION OF ANNUAL REPORTS OF RELEASE OF TOXIC CHEMICALS THAT
APPEAR IN 40 CFR PART 372.
CARBON DIOXIDE DOES NOT REQUIRE REPORTING UNDER SECTION 313.
40 CFR 68:
RISK MANAGEMENT PROGRAM FOR CHEMICAL ACCIDENTAL RELEASE PREVENTION:
REQUIRES DEVELOPMENT AND IMPLEMENTATION OF RISK MANAGEMENT PROGRAMS AT
FACILITIES THAT MANUFACTURE, USE, STORE, OR OTHERWISE HANDLE REGULATED
SUBSTANCES IN QUANTITIES THAT EXCEED SPECIFIED THRESHOLDS.
CARBON DIOXIDE IS NOT LISTED AS A REGULATED SUBSTANCE.
TSCA:
TOXIC SUBSTANCES CONTROL ACT:
CARBON DIOXIDE IS LISTED ON THE TSCA INVENTORY.
OSHA:
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION:
29 CFR 1910.119:
PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICALS:
REQUIRES FACILITIES TO DEVELOP A PROCESS SAFETY MANAGEMENT PROGRAM BASED
ON THRESHOLD QUANTITIES (TQ) OF HIGHLY HAZARDOUS CHEMICALS.
CARBON DIOXIDE IS NOT LISTED IN APPENDIX A AS A HIGHLY HAZARDOUS CHEMICAL.
STATE REGULATIONS:
| CALIFORNIA:
| CARBON DIOXIDE IS NOT LISTED BY CALIFORNIA UNDER THE SAFE DRINKING WATER
| AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65).).
| WARNING:
| THE COMBUSTION OF THIS GAS PRODUCES CARBON MONOXIDE-A CHEMICAL KNOWN TO
| THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE
| HARM. (CALIFORNIA HEALTH AND SAFETY CODE SUBSECTION 25249.5.)
PENNSYLVANIA:
CARBON DIOXIDE IS SUBJECT TO THE PENNSYLVANIA WORKER AND COMMUNITY
RIGHT-TO-KNOW ACT (35 P.S. SECTIONS 7301-7320).
| 16. OTHER INFORMATION | |
| HAZARD RATING SYSTEMS:
| NFPA RATINGS:
| HEALTH 1
| FLAMMABILITY 0
| REACTIVITY 0
| SPECIAL SA (CGA RECOMMENDS THIS TO DESIGNATE SIMPLE ASPHYXIANT)
| HMIS RATINGS:
| HEALTH 0
| FLAMMABILITY 0
| REACTIVITY 0