| Common Name: | KABOOM SCRUB FREE |
| Manufacturer: | CHURCH & DWIGHT |
| SDS Revision Date: | 2/7/2008 |
| SDS Format: | No Format Specified |
| Item Number(s): | 13F103 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
ARM & HAMMER(R*) THE STANDARD OF PURITY(R*)
KABOOM SCRUB FREE
REVISION NUMBER: 1
REVISION DATE: FEBRUARY 07, 2008
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND |  |
THE COMPANY/UNDERTAKING
PRODUCT CODE: MSDS-154
PRODUCT NAME: KABOOM SCRUB FREE
SYNONYMS: CONTINUOUS TOILET BOWL CLEANER.
MANUFACTURER, IMPORTER, SUPPLIER:
CHURCH & DWIGHT CO., INC.
469 NORTH HARRISON STREET
PRINCETON, NJ, 08543
EMERGENCY TELEPHONE NUMBER:
PRODUCT INFORMATION: +1-800-781-7529
CHEMTREC: +1-800-424-9300
MEDICAL EMERGENCY: 1-888-234-1828
| 2. HAZARDOUS INFORMATION | |
EMERGENCY OVERVIEW:
THE PRODUCT MAY CAUSE BURNS OF EYES AND MUCOUS MEMBRANES
MAY BE HARMFUL BY INHALATION
BASED UPON AVAILABLE TOXICITY INFORMATION FOR THIS, AND CLOSELY RELATED
MATERIALS, IT IS ANTICIPATED THAT THIS MATERIAL WILL BE HARMFUL IF
SWALLOWED AND DIRECT SKIN AND EYE CONTACT CAN RESULT IN SEVERE SKIN AND EYE
IRRITATION AND/OR CHEMICAL BURNS WITH POTENTIAL IRREVERSIBLE DAMAGE.
INHALATION OF DUST CAN BE SEVERLY IRRITATING TO THE LUNGS WITH POTENTIAL
SYSTEMIC ABSORBTION AND TISSUE DAMAGE. REPEATED SKIN EXPOSURE MAY INDUCE
SENSITIZATION.
EYE CONTACT:
MAY CAUSE SEVERE EYE IRRITATION.
CORROSIVE TO THE EYES AND MAY CAUSE SEVERE DAMAGE INCLUDING BLINDNESS
RISK OF SERIOUS DAMAGE TO EYES
SKIN CONTACT: CAUSES SKIN BURNS
INHALATION: MAY BE HARMFUL BY INHALATION
INGESTION:
INGESTION CAUSES BURNS OF THE UPPER DIGESTIVE AND RESPIRATORY TRACTS
CAN BURN MOUTH, THROAT, AND STOMACH
HARMFUL IF SWALLOWED
GENERAL ADVICE: SEE FIRST AID SECTION
PROPERTIES AFFECTING HEALTH: NO EFFECTS INDICATED
PRINCIPLE ROUTES OF EXPOSURE:
EYE
INHALATION
SKIN
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CAS CHEMICAL NAME % WEIGHT OSHA* ACGIH* ACGIH*
126-06-7 3-BROMO-1-CHLORO-5,5-DIMETHYL- 20 - 40% N/A N/A N/A
2,4-IMIDAZOLIDINEDIONE
16079-88-2 2,4-IMIDAZOLIDINEDIONE, 20 - 40% N/A N/A N/A
1-BROMO-3-CHLORO-5,5-DIMETHYL-
118-52-5 1,3-DICHLORO-5,5-DIMETHYL 20 - 40% 0.2 0.4 0.2
HYDANTOIN MG/M3 MG/M3 MG/M3
TWA STEL TWA
89415-87-2 2,4-IMIDAZOLIDINEDIONE, 5 - 15% N/A N/A N/A
1,3-DICHLORO-5-ETHYL-5-METHYL-
* OSHA - FINAL PELS - TIME WEIGHTED AVERAGES (TWAS)
* ACGIH - OCCUPATIONAL EXPOSURE LIMITS - STELS
* ACGIH - OCCUPATIONAL EXPOSURE LIMITS - TWAS
| 4. FIRST AID MEASURES | |
GENERAL ADVICE: SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE
SKIN CONTACT:
IMMEDIATE MEDICAL ATTENTION IS REQUIRED
WASH SKIN WITH PLENTY OF WATER FOR 15 MINUTES, REMOVING ALL CONTAMINATED
CLOTHES AND SHOES.
EYE CONTACT:
IMMEDIATE MEDICAL ATTENTION IS REQUIRED
IN CASE OF EYE CONTACT, REMOVE CONTACT LENS AND RINSE IMMEDIATELY WITH
PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT LEAST 15 MINUTES
KEEP EYE WIDE OPEN WHILE RINSING
IF PHYSICIAN IS NOT AVAILABLE, FLUSH FOR ADDITIONAL 15 MINUTES AND
TRANSPORT VICTIM TO MEDICAL CARE.
INHALATION:
IMMEDIATE MEDICAL ATTENTION IS REQUIRED
IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION
IF BREATHING IS DIFFICULT, GIVE OXYGEN
MOVE TO FRESH AIR
INGESTION:
IF SWALLOWED, IMMEDIATELY GIVE 3-4 GLASSES OF WATER.
DO NOT INDUCE VOMITING
IF VOMITING OCCURS, GIVE FLUIDS AGAIN.
IMMEDIATE MEDICAL ATTENTION IS REQUIRED
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON
HAVE PHYSICIAN DETERMINE IF CONDITION ALLOWS INDUCTION OF VOMITING OR
EVACUATION OF STOMACH.
AGGRAVATED MEDICAL CONDITIONS: NO EFFECTS INDICATED
| 5. FIRE-FIGHTING MEASURES | |
FLASH POINT: >200 F (COC)
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY
ALCOHOL-RESISTANT FOAM
DRY CHEMICAL
EXTINGUISHING MEDIA WHICH MUST NOT BE USED FOR SAFETY REASONS:
UNKNOWN
SPECIFIC HAZARDS:
TO MINIMIZE NOXIOUS GAS GENERATION, FLOOD BURNING MATERIAL WITH LARGE
QUANTITIES OF WATER.
COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
MUST WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE
CLOTHING
SPECIAL EXPOSURE HAZARDS ARISING FROM THE SUBSTANCE OR PREPARATION ITSELF,
ITS COMBUSTION PRODUCTS, OR RELEASED GASES:
MATERIAL IS A STRONG OXIDIZER AND CORROSIVE. MAY IGNITE COMBUSTIBLE
MATERIALS AND PRODUCE NOXIUOS GASES. PRODUCTS OF COMBUSTION ARE TOXIC.
THIS PRODUCT IS CLASSIFIED AS A ST-1 DUST EXPLOSIVE HAZARD. AIRBORNE DUSTS
OF THIS MATERIAL, IN AN ENCLOSED SPACE AND IN THE PRESENCE OF AN IGNITION
SOURCE MAY CONSTITUTE AN EXPLOSION HAZARD.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
SPECIFIC METHODS:
COOL CONTAINERS / TANKS WITH WATER SPRAY
FIRE RESIDUES AND CONTAMINATED FIRE EXTINGUISHING WATER MUST BE DISPOSED OF
IN ACCORDANCE WITH LOCAL REGULATIONS
NFPA (NATIONAL FIRE PROTECTION ASSOCIATION): UNKNOWN
HMIS (HAZARDOUS MATERIAL INFORMATION SYSTEM):
HEALTH 3
FIRE 4
REACTIVITY 1
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
DANGER!
OXIDIZING MATERIAL.
DO NOT BREATH DUST, DO NOT GET IN EYES OR ON SKIN, DO NOT SWALLOW.
EVACUATE PERSONNEL TO SAFE AREAS
ENSURE ADEQUATE VENTILATION
KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK
USE PERSONAL PROTECTIVE EQUIPMENT
ENVIRONMENTAL PRECAUTIONS:
MATERIAL IS TOXIC TO FISH.
DO NOT DISCHARGE INTO LAKES, STREAM, PONDS OR PUBLIC WATER UNLESS IN
ACCORDANCE WITH AN NPDES PERMIT.
METHODS FOR CLEANING UP:
TAKE UP MECHANICALLY, AVOIDING GENERATION OF DUST, AND COLLECT IN SUITABLE
CONTAINER FOR DISPOSAL
DO NOT BREATH DUST, DO NOT GET IN EYES OR ON SKIN, DO NOT SWALLOW.
WEAR PERSONAL PROTECTIVE EQUIPMENT
FOR LARGE SPILS OR IN CONTACT WITH WATER, SELF-CONTAINED BREATHING
APPARATUS IS PREFFERED.
DANGER!
OXIDIZING MATERIAL
POSSIBLE DUST EXPLOSION HAZARD.
NEUTRALIZE ANY RESIDUE WITH DILUTE ALKALINE SODIUM BISULFITE OR THIOSULFATE
SOLUTION.
ABSORB WITH SAND OR VERMICULITE AND PLACE IN COMPATIBLE CONTAINER FOR
DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING
DO NOT BREATH DUST, DO NOT GET IN EYES OR ON SKIN, DO NOT SWALLOW.
ENSURE ADEQUATE VENTILATION
SAFE HANDLING ADVICE:
AVOID CONTACT WITH SKIN AND EYES AND CLOTHING
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE NIOSH RESPIRATORY
EQUIPMENT
AVOID CONTACT WITH EYES. WASH HANDS IMMEDIATELY AFTER CONTACT TO AVOID
HAND-EYE TRANSFER.
DO NOT BREATH DUST, DO NOT GET IN EYES OR ON SKIN, DO NOT SWALLOW.
FINE DUST DISPERSED IN AIR MAY IGNITE
STORAGE:
TECHNICAL MEASURES/PRECAUTIONS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE
KEEP IN PROPERLY LABELLED CONTAINERS
STORE AWAY FROM ORGANIC MATERIAL. PRODUCT IS A STRONG OXIZER AND
CORROSIVE.
KEEP AWAY FROM DIRECT SUNLIGHT
KEEP AWAY FROM HEAT
EMPTY CONTAINERS MAY CONTAIN RESIDUE AND CAN BE DANGEROUS.
INCOMPATIBLE PRODUCTS: OXIDIZABLE MATERIALS
SPECIFIC USE(S): TOILET CLEANER
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING MEASURES:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS
PERSONAL PROTECTIVE EQUIPMENT:
HAND PROTECTION: RUBBER OR NEOPRENE GLOVES
EYE PROTECTION:
TIGHTLY FITTING SAFETY GOGGLES IN TIGHT AREAS OR WHERE EXPOSURE TO EYES IS
LIKELY.
AVOID CONTACT WITH EYES
RESPIRATORY PROTECTION:
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE NIOSH RESPIRATORY
EQUIPMENT
SKIN AND BODY PROTECTION:
USE CHEMICAL PROTECTIVE CLOTHING FOR PROLONGED OR REPEATED CONTACT.
LONG SLEEVED CLOTHING - GLOVES - BOOTS - APRON
HYGIENE MEASURES:
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS
WHEN USING, DO NOT EAT, DRINK OR SMOKE
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE
REGULAR CLEANING OF EQUIPMENT, WORK AREA AND CLOTHING
AVOID CONTACT WITH SKIN, EYES AND CLOTHING
FOR ENVIRONMENTAL PROTECTION REMOVE AND WASH ALL CONTAMINATED PROTECTIVE
EQUIPMENT BEFORE RE-USE
WEAR SUITABLE GLOVES AND EYE/FACE PROTECTION
ENVIRONMENTAL EXPOSURE CONTROLS:
DO NOT BREATH DUST, DO NOT GET IN EYES OR ON SKIN, DO NOT SWALLOW.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
GENERAL INFORMATION:
FORM: GRANULAR. PELLETS.
APPEARANCE: SOLID.
COLOR: WHITE.
ODOR: CHLORINE LIKE CHEMICAL.
IMPORTANT HEALTH SAFETY AND ENVIRONMENTAL INFORMATION:
pH: UNKNOWN
BOILING POINT/RANGE: N/A
VAPOR PRESSURE: N/E.
DENSITY: N/E
VAPOR DENSITY (AIR = 1): N/E.
WATER SOLUBILITY: 5 G/L @ 25C.
SPECIFIC GRAVITY: N/E.
VISCOSITY: N/A
VAPOR PRESSURE: N/A
MELTING POINT/RANGE: 106 TO 148
EVAPORATION RATE (BUTYL ACETATE=1): <1
PERCENT VOLATILE (BY VOLUME): <0.5
| 10. STABILITY AND REACTIVITY | |
STABILITY:
STABLE UNDER NORMAL CONDITIONS
DECOMPOSES AT 181C
CONDITIONS TO AVOID: NONE KNOWN
MATERIALS TO AVOID:
INCOMPATIBLE WITH STRONG ACIDS AND BASES
HIGH TEMPERATURES
READILY OXIDIZED MATERIALS
MOISTURE
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION MAY PRODUCE TOXIC VAPORS/FUMES OF CHLORINE, BROMINE,
ORGANIC MATERIALS AND OXIDES OF CARBON AND NITROGEN.
POLYMERIZATION: WILL NOT OCCUR
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
COMPONENT INFORMATION:
PRODUCT INFORMATION:
LD50/ORAL/RAT: 468 - 477 MG/KG
LOCAL EFFECTS:
SKIN IRRITATION: CORROSIVE
EYE IRRITATION: SEVERE IRRITANT AND CORROSIVE
SENSITIZATION: SKIN SENSITIZER.
SPECIFIC EFFECTS:
SEVERELY IRRITATING TO THE LUNG UPON INHALATION WITH POTENTIAL SYSTEMIC
ABSORPTION AND TISSUE DAMAGE.
CARCINOGENIC EFFECTS: NOT DETERMINED.
MUTAGENIC EFFECTS: NOT DETERMINED.
REPRODUCTIVE TOXICITY: NOT DETERMINED.
TARGET ORGAN EFFECTS: NOT DETERMINED.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY EFFECTS:
COMPONENT INFORMATION:
CAS CHEMICAL NAME % WEIGHT EFFSD*
126-06-7 3-BROMO-1-CHLORO-5,5-DIMETHYL- 20 - 40% 96 HR LC50 RAINBOW
2,4-IMIDAZOLIDINEDIONE TROUT: 0.87 MG/L
96 HR LC50 FATHEAD
MINNOW (JUVENILE):
0.28 MG/L
96 HR LC50 BLUEGILL:
0.56 MG/L
16079-88-2 2,4-IMIDAZOLIDINEDIONE, 20 - 40% N/A
1-BROMO-3-CHLORO-5,5-DIMETHYL-
118-52-5 1,3-DICHLORO-5,5-DIMETHYL 20 - 40% N/A
HYDANTOIN
89415-87-2 2,4-IMIDAZOLIDINEDIONE, 5 - 15% N/A
1,3-DICHLORO-5-ETHYL-5-METHYL-
* EFFSD - ECOTOXICITY - FRESHWATER FISH SPECIES DATA
PRODUCT INFORMATION:
AQUATIC TOXICITY:
LC50:
(RAINBOW TROUT) - 96 HOURS: 0.5 MG/L
(BLUEGILL SUNFISH) - 96 HOURS: 1.2 MG/L
(DAPHNIA MAGNA) - 48 HOURS: 0.4 MG/L
(MYSID SHRIMP) - 96 HOURS: 0.93 MG/L
(SHEEPSHEAD MINNOW) - 96 HOURS: 1.4 MG/L AS Br2
EC50:
(EASTERN OYSTERS) - 96 HOURS: 0.84 MG/L
(ALGAE-SELENASTRUM) - 72 HOURS: 0.12 MG/L
OTHER INFORMATION:
| 13. DISPOSAL CONSIDERATIONS | |
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
INCINERATION IS THE PREFERRED METHOD. RELATIVELY SMALL QUANTITIES OF
PRODUCT CAN BE NUETRALIZED (SEE SECTION 6) AND, IF IN ACCORDANCE WITH LOCAL
LAWS AND OPERATORS, DISCHARGED INTO SEWAGE TREATMENT SYSTEMS AND PLANTS.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL.
FURTHER INFORMATION:
| 14. TRANSPORT INFORMATION | |
DOT: OXIDIZER
UN-NO: 1479
PROPER SHIPPING NAME: OXIDIZING SOLID N.O.S.
PACKING GROUP: II
DESCRIPTION: CORROSIVEMARINE POLLUTANT
HAZARD CLASS: 5.1
IMDG: OXIDIZING SOLID, CORROSIVE, N.O.S. (UN#-3085)
ADR: OXIDIZER
UN-NO: 1479
PROPER SHIPPING NAME: OXIDIZING SOLID N.O.S.
PACKING GROUP: II
SUBSIDIARY RISK: 5.1
DESCRIPTION: CORROSIVEMARINE POLLUTANT
ICAO: OXIDIZER
UN-NO: 1479
PROPER SHIPPING NAME: OXIDIZING SOLID N.O.S.
PACKING GROUP: II
SUBSIDIARY RISK: 5.1
DESCRIPTION: CORROSIVE MARINE POLLUTANT
IATA: OXIDIZER
UN-NO: 1479
PROPER SHIPPING NAME: OXIDIZING SOLID N.O.S.
PACKING GROUP: II
SUBSIDIARY RISK: 5.1
DESCRIPTION: CORROSIVE MARINE POLLUTANT
| 15. REGULATORY INFORMATION | |
U.S. INVENTORIES:
CAS CHEMICAL NAME % WEIGHT TSCA* SARA
TITLE III,
SECTIONS
311/312
126-06-7 3-BROMO-1-CHLORO-5,5-DIMETHYL- 20 - 40% PRESENT A,F
2,4-IMIDAZOLIDINEDIONE
16079-88-2 2,4-IMIDAZOLIDINEDIONE, 20 - 40% P; S A,F
1-BROMO-3-CHLORO-5,5-DIMETHYL-
118-52-5 1,3-DICHLORO-5,5-DIMETHYL 20 - 40% PRESENT A,F
HYDANTOIN
89415-87-2 2,4-IMIDAZOLIDINEDIONE, 5 - 15% P A,F
1,3-DICHLORO-5-ETHYL-5-METHYL-
CHEMICAL NAME NJRTK* WHMIS* WHMIS* PRTK*
3-BROMO-1-CHLORO-5,5-DIMETHYL- N/A N/A N/A N/A
2,4-IMIDAZOLIDINEDIONE
2,4-IMIDAZOLIDINEDIONE, N/A N/A N/A N/A
1-BROMO-3-CHLORO-5,5-DIMETHYL-
1,3-DICHLORO-5,5-DIMETHYL SN 0650 D2B 1% PRESENT
HYDANTOIN (ENGLISH
ITEM 544,
FRENCH
ITEM 663)
2,4-IMIDAZOLIDINEDIONE, N/A N/A N/A N/A
1,3-DICHLORO-5-ETHYL-5-METHYL-
* TSCA - UNITED STATES - SECTION 8 (B) INVENTORY (TSCA)
* NJRTK - NEW JERSEY - DEPARTMENT OF HEALTH RTK LIST
* WHMIS - CANADA - WHMIS - CLASSIFICATIONS OF SUBSTANCES
* WHMIS - CANADA - WHMIS - INGREDIENT DISCLOSURE
* PRTK - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
INTERNATIONAL INVENTORIES:
CAS CHEMICAL NAME % WEIGHT DSL - CANADA* WHMIS*
126-06-7 3-BROMO-1-CHLORO-5,5-DIMETHYL- 20 - 40% PRESENT N/A
2,4-IMIDAZOLIDINEDIONE
16079-88-2 2,4-IMIDAZOLIDINEDIONE, 20 - 40% PRESENT N/A
1-BROMO-3-CHLORO-5,5-DIMETHYL-
118-52-5 1,3-DICHLORO-5,5-DIMETHYL 20 - 40% PRESENT D2B
HYDANTOIN
89415-87-2 2,4-IMIDAZOLIDINEDIONE, 5 - 15% PRESENT N/A
1,3-DICHLORO-5-ETHYL-5-METHYL-
* DSL - CANADA - DOMESTIC SUBSTANCES LIST (DSL)
* WHMIS - CANADA - WHMIS - CLASSIFICATIONS OF SUBSTANCES
| 16. OTHER INFORMATION | |
LITERARY REFERENCE: HOUSEHOLD CLEANING PRODUCT.
PREPARED BY:
R&D TECHNICAL REGULATORY AFFAIRS: 1-609-279-7705.
OTHER:
THE INFORMATION PROVIDED HAS BEEN ADAPTED FROM THE MANUFACTURER SUPPLIED
MSDS. THE INFORMATION ABOVE IS BELIEVED TO BE ACCURATE AND REPRESENTS THE
BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF
MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO
SUCH INFORMATION, WE ASSUME NO LIABILITY RESULTING FROM USE OF MSDS
INFORMATION.
N/E: NOT ESTABLISHED