| Common Name: | ROHPER QT 4PK ADDITV ALKYD ACCELERATOR, 239503 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 4/3/2009 |
| SDS Format: | No Format Specified |
| Item Number(s): | 2RNK8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
24 HOUR ASSISTANCE:
1-847-367-7700
RUST-OLEUM CORP.
WWW.RUSTOLEUM.COM
| SECTION 1 - CHEMICAL PRODUCT / COMPANY INFORMATION |  |
PRODUCT NAME: ROHPER QT 4PK ADDITV ALKYD ACCELERATOR
IDENTIFICATION NUMBER: 239503
PRODUCT USE/CLASS: ADDITIVE/ALKYD ACCELERATOR
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
REVISION DATE: 04/03/2009
| SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NUMBER WEIGHT ACGIH ACGIH OSHA OSHA
% LESS TLV-TWA TLV-STEL PEL- PEL
THAN TWA CEILING
HEXANE, 28182-81-2 60.0 N.E. N.E. N.E. N.E.
1,6-DIISOCYANATO-,
HOMOPOLYMER
ISOPHORONE 53880-05-0 25.0
DIISOCYANATE
HOMOPOLYMER
n-BUTYL 123-86-4 15.0 150 PPM 200 PPM 150 N.E.
ACETATE PPM
SOLVENT 64742-95-6 5.0 25 PPM N.E. N.E. N.E.
NAPTHA, LIGHT
AROMATIC
1,2,4- 95-63-6 5.0 25 PPM N.E. N.E. N.E.
TRIMETHYLBENZENE
ISOPHORONE 4098-71-9 1.0 0.05 0.18 N.E. N.E.
DIISOCYANATE MG/M3 MG/M3
| SECTION 3 - HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
INDIVIDUALS WITH LUNG OR BREATHING PROBLEMS OR PRIOR REACTION TO
ISOCYANATES MUST NOT BE EXPOSED TO VAPOR OR SPRAY MIST. HARMFUL IF
INHALED. MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS,
HEADACHE OR NAUSEA. HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION.
VAPORS IRRITATING TO EYES AND RESPIRATORY TRACT. MAY CAUSE ALLERGIC
SKIN REACTION. MAY CAUSE ALLERGIC RESPIRATORY REACTION. COMBUSTIBLE
LIQUID AND VAPOR.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES EYE IRRITATION.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
MAY CAUSE SKIN IRRITATION. MAY CAUSE SKIN SENSITIZATION, AN ALLERGIC
REACTION, WHICH BECOMES EVIDENT ON RE-EXPOSURE TO THIS MATERIAL.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND
LUNGS. MAY CAUSE HEADACHES AND DIZZINESS. MAY CAUSE ALLERGIC RESPIRATORY
REACTION. HARMFUL IF INHALED. AVOID BREATHING VAPORS OR MISTS.
EFFECTS OF OVEREXPOSURE - INGESTION:
ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND CAUSE DAMAGE.
SUBSTANCE MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
OVEREXPOSURE MAY CAUSE LUNG DAMAGE. REPORTS HAVE ASSOCIATED REPEATED AND
PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE.
DANGER!
VAPOR AND SPRAY MIST HARMFUL. OVEREXPOSURE MAY CAUSE LUNG DAMAGE. MAY
CAUSE ALLERGIC SKIN AND RESPIRATORY REACTION, EFFECTS MAY BE PERMANENT.
MAY AFFECT THE BRAIN AND NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR
NAUSEA. CAUSES EYE, SKIN, NOSE AND THROAT IRRITATION.
PRIMARY ROUTE(S) OF ENTRY:
SKIN CONTACT, SKIN ABSORPTION, INHALATION, INGESTION, EYE CONTACT
| SECTION 4 - FIRST AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES
HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION.
FIRST AID - SKIN CONTACT:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS
OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL
CAN ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT: 105 F (SETAFLASH)
LOWER EXPLOSIVE LIMIT: 1.2%
UPPER EXPLOSIVE LIMIT: 7.5%
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: KEEP CONTAINERS TIGHTLY CLOSED.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP
AND POSSIBLE AUTOIGNITION OR EXPLOSION. EVACUATE AREA AND FIGHT FIRE
FROM A SAFE DISTANCE.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE
MATERIALS SUCH AS SAWDUST. DISPOSE OF ACCORDING TO LOCAL, STATE
(PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED
CONTAINERS.
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING:
FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS EMPTIED
BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING VAPOR OR MIST.
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. AVOID CONTACT
WITH EYES.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. KEEP AWAY FROM HEAT, SPARKS, FLAME AND SOURCES OF
IGNITION. KEEP CONTAINER CLOSED WHEN NOT IN USE.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR
OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED
EXPOSURE LIMITS.
PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A
POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR
AN UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR IN ANY OTHER
CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING RANGE: 0 - 330 F
VAPOR DENSITY: HEAVIER THAN AIR
ODOR: N.A.
ODOR THRESHOLD: N.D.
APPEARANCE: LIQUID
EVAPORATION RATE: SLOWER THAN ETHER
SOLUBILITY IN H2O: SLIGHT
FREEZE POINT: N.D.
SPECIFIC GRAVITY: 1.094
VAPOR PRESSURE: N.D.
pH: N.E.
PHYSICAL STATE: LIQUID
(SEE SECTION 16 FOR ABBREVIATION LEGEND)
| SECTION 10 - STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID: AVOID ALL POSSIBLE SOURCES OF IGNITION.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
PRODUCT LD50: N.D.
PRODUCT LC50: N.D.
CHEMICAL NAME LD50 LC50
HEXANE, 1,6-DIISOCYANATO-, 10000 MG/KG RAT 137-1150 MG/M3RT/4H
HOMOPOLYMER
ISOPHORONE DIISOCYANATE
HOMOPOLYMER
n-BUTYL ACETATE 13100 MG/KG (RAT, ORAL) 2000 PPM (RAT,
INHALATION, 4 HR)
SOLVENT NAPTHA, LIGHT 4700 MG/KG (RAT, ORAL) 3670 MG/KG
AROMATIC (RAT, INHALATION)
1,2,4-TRIMETHYLBENZENE N.E. 18000 MG/M3
(RAT, 4HR)
ISOPHORONE DIISOCYANATE
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| SECTION 13 - DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER STORM DRAINS OR SEWER SYSTEMS.
| SECTION 14 - TRANSPORTATION INFORMATION | |
DOT PROPER SHIPPING NAME: PAINT RELATED MATERIAL
DOT TECHNICAL NAME:
DOT HAZARD CLASS: 3
DOT UN/NA NUMBER: UN1263
PACKING GROUP: III
HAZARD SUBCLASS:
RESP. GUIDE PAGE: 128
| SECTION 15 - REGULATORY INFORMATION | |
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES"
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
IMMEDIATE HEALTH HAZARD
CHRONIC HEALTH HAZARD
FIRE HAZARD
SARA SECTION 313:
LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT
ARE SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF
THE SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART
372:
CHEMICAL NAME CAS NUMBER
1,2,4-TRIMETHYLBENZENE 95-63-6
ISOPHORONE DIISOCYANATE 4098-71-9
TOXIC SUBSTANCES CONTROL ACT:
LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT
ARE SUBJECT TO THE REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM
THE UNITED STATES:
U.S. STATE REGULATIONS: AS FOLLOWS
NEW JERSEY RIGHT-TO-KNOW:
THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE
COMPONENTS IN THIS PRODUCT.
NONE
PENNSYLVANIA RIGHT-TO-KNOW:
THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT
GREATER THAN 3%.
NONE
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS NO CHEMICALS KNOWN BY THE STATE OF CALIFORNIA TO
CAUSE CANCER
THIS PRODUCT CONTAINS NO CHEMICALS KNOWN BY THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM
INTERNATIONAL REGULATIONS: AS FOLLOWS
CANADIAN WHMIS:
THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
CANADIAN WHMIS CLASS:
B3
D2B
| SECTION 16 - OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 3*
FLAMMABILITY 2
REACTIVITY 1
PERSONAL PROTECTION X
REASON FOR REVISION: REGULATORY UPDATE
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
THE INFORMATION CONTAINED ON THIS MSDS HAS BEEN CHECKED AND SHOULD BE
ACCURATE. HOWEVER, IT IS THE RESPONSIBILITY OF THE USER TO COMPLY WITH
ALL FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS.