| Common Name: | PVTLBL SSPR 6PK TG ENAMEL FLAT WHITE |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 1/12/2010 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4WGD2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
24 HOUR ASSISTANCE: 800-228-5635
| SECTION 1 - CHEMICAL PRODUCT / COMPANY INFORMATION |  |
PRODUCT NAME: PVTLBL SSPR 6PK TG ENAMEL FLAT WHITE
IDENTIFICATION NUMBER: 251844
PRODUCT USE/CLASS: TOUGH GUY AEROSOLS 4WGD2
SUPPLIER:
W.W. GRAINGER
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045-5201
USA
MANUFACTURER:
W.W. GRAINGER
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045-5201
USA
PREPARER: REGULATORY DEPARTMENT
REVISION DATE: 01/12/2010
| SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL CAS WEIGHT ACGIH ACGIH OSHA OSHA
NAME NUMBER % LESS TLV-TWA TLV-STEL PEL-TWA PEL
THAN CEILING
LIQUEFIED 68476-86-8 35.0 N.E. N.E. N.E. N.E.
PETROLEUM
GAS
ACETONE 67-64-1 25.0 500 PPM 750 PPM 1000 PPM N.E.
TITANIUM 13463-67-7 10.0 10 MG/M3 N.E. 15 MG/M3 N.E.
DIOXIDE (TOTAL
DUST)
MINERAL 64742-88-7 10.0 100 PPM N.E. 100 PPM N.E.
SPIRITS
MAGNESIUM 14807-96-6 5.0 2 MG/M3 N.E. 0.1 MG/M3 N.E.
SILICATE (RESPIRABLE)
NAPHTHA 8032-32-4 5.0 N.E. N.E. N.E. N.E.
XYLENE 1330-20-7 5.0 100 PPM 150 PPM 100 PPM N.E.
TOLUENE 108-88-3 5.0 20 PPM N.E. 200 PPM 300 PPM
ETHYL- 100-41-4 5.0 100 PPM 125 PPM 100 PPM N.E.
BENZENE
CALCINED 1332-58-7 5.0 2 MG/M3 N.E. 5 MG/M3 N.E.
ALUMINUM (RESPIRABLE)
SILICATE
| SECTION 3 - HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
CONTENTS UNDER PRESSURE. HARMFUL IF INHALED. MAY AFFECT THE BRAIN OR
NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. VAPORS MAY CAUSE
FLASH FIRE OR EXPLOSION. HARMFUL IF SWALLOWED. EXTREMELY FLAMMABLE
LIQUID AND VAPOR.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES EYE IRRITATION.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION. SUBSTANCE MAY
CAUSE SLIGHT SKIN IRRITATION.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND
LUNGS. AVOID BREATHING VAPORS OR MISTS. HIGH GAS, VAPOR, MIST OR DUST
CONCENTRATIONS MAY BE HARMFUL IF INHALED. HARMFUL IF INHALED.
EFFECTS OF OVEREXPOSURE - INGESTION:
ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND CAUSE DAMAGE.
SUBSTANCE MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
CONTAINS TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP 2B-
"POSSIBLY CARCINOGENIC TO HUMANS" BY IARC. SIGNIFICANT EXPOSURE IS NOT
ANTICIPATED DURING BRUSH APPLICATION OR DRYING. RISK OF OVEREXPOSURE
DEPENDS ON DURATION AND LEVEL OF EXPOSURE TO DUST FROM REPEATED SANDING
OF SURFACES OR SPRAY MIST AND THE ACTUAL CONCENTRATION OF TITANIUM
DIOXIDE IN THE FORMULA.
IARC LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B). MAY
CAUSE CENTRAL NERVOUS SYSTEM DISORDER (E.G., NARCOSIS INVOLVING A LOSS
OF COORDINATION, WEAKNESS, FATIGUE, MENTAL CONFUSION, AND BLURRED VISION)
AND/OR DAMAGE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
OVEREXPOSURE TO XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH
LIVER ABNORMALITIES, KIDNEY, LUNG, SPLEEN, EYE AND BLOOD DAMAGE AS WELL
AS REPRODUCTIVE DISORDERS. EFFECTS IN HUMANS, DUE TO CHRONIC OVEREXPOSURE,
HAVE INCLUDED LIVER, CARDIAC ABNORMALITIES AND NERVOUS SYSTEM DAMAGE.
PRIMARY ROUTE(S) OF ENTRY:
SKIN CONTACT, SKIN ABSORPTION, INHALATION, INGESTION, EYE CONTACT
| SECTION 4 - FIRST AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES
HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF
EYES OR KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS
OR PERSISTS.
FIRST AID - INHALATION:
IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN
FRESH AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL ASSISTANCE
IMMEDIATELY.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL
CAN ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT: -156 F (SETAFLASH)
LOWER EXPLOSIVE LIMIT: 0.7%
UPPER EXPLOSIVE LIMIT: 12.8%
EXTINGUISHING MEDIA:
FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
WATER SPRAY MAY BE INEFFECTIVE. CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK.
FLASH POINT IS LESS THAN 20 DEG. F. - EXTREMELY FLAMMABLE LIQUID AND
VAPOR!
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. PERFORATION OF THE PRESSURIZED CONTAINER MAY
CAUSE BURSTING OF THE CAN.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE
MATERIALS SUCH AS SAWDUST. DISPOSE OF ACCORDING TO LOCAL, STATE
(PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND REMOVE WITH INERT
ABSORBENT AND NON-SPARKING TOOLS.
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN
AFTER CONTAINER IS EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID
BREATHING VAPOR OR MIST. USE ONLY IN A WELL-VENTILATED AREA. WASH HANDS
BEFORE EATING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. DO NOT STORE ABOVE 120 DEG. F. STORE LARGE
QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS I
FLAMMABLE LIQUIDS. CONTENTS UNDER PRESSURE. DO NOT EXPOSE TO HEAT OR
STORE ABOVE 120 DEG. F.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION,
OR OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW
RECOMMENDED EXPOSURE LIMITS. USE EXPLOSION-PROOF VENTILATION EQUIPMENT.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED
EXPOSURE LIMITS.
PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A
POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR
AN UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR IN ANY OTHER
CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING RANGE: -34 - 400 F
VAPOR DENSITY: HEAVIER THAN AIR
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
APPEARANCE: AEROSOLIZED MIST
EVAPORATION RATE: FASTER THAN ETHER
SOLUBILITY IN H2O: SLIGHT
FREEZE POINT: N.D.
SPECIFIC GRAVITY: 0.784
VAPOR PRESSURE: N.D.
pH: N.A.
PHYSICAL STATE: LIQUID
(SEE SECTION 16 FOR ABBREVIATION LEGEND)
| SECTION 10 - STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 120 DEG. F. AVOID ALL POSSIBLE SOURCES OF
IGNITION.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
PRODUCT LD50: N.D.
PRODUCT LC50: N.D.
CHEMICAL NAME LD50 LC50
LIQUEFIED PETROLEUM GAS N.E. N.E.
ACETONE 5800 MG/KG (RAT) 50100 MG/M3 (RAT, 8HR)
TITANIUM DIOXIDE >7500 MG/KG (RAT, ORAL) N.E.
MINERAL SPIRITS >8 MG/KG (RAT, ORAL) >1400 PPM
(RAT, INHALATION, 4HR)
MAGNESIUM SILICATE N.E. TCLO:
11 MG/M3 (INHALATION)
NAPHTHA >5000 MG/KG (RAT, ORAL) N.E.
XYLENE 4300 MG/KG (RAT, ORAL) 5000 PPM
(RAT, INHALATION, 4HR)
TOLUENE 636 MG/KG (RAT, ORAL) >26700 PPM
(RAT, INHALATION, 1HR)
ETHYLBENZENE 3500 MG/KG (RAT, ORAL) N.E.
CALCINED ALUMINUM 5000 MG/KG (RAT, ORAL) N.E.
SILICATE
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| SECTION 13 - DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER STORM DRAINS OR SEWER SYSTEMS.
| SECTION 14 - TRANSPORTATION INFORMATION | |
DOT PROPER SHIPPING NAME: CONSUMER COMMODITY
DOT TECHNICAL NAME: N.A.
DOT HAZARD CLASS: ORM-D
DOT UN/NA NUMBER: N.A.
PACKING GROUP: N.A.
HAZARD SUBCLASS: N.A.
RESP. GUIDE PAGE: N.A.
| SECTION 15 - REGULATORY INFORMATION | |
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES"
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
IMMEDIATE HEALTH HAZARD
CHRONIC HEALTH HAZARD
FIRE HAZARD
PRESSURIZED GAS HAZARD
SARA SECTION 313:
LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT
ARE SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF
THE SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986 AND
40 CFR PART 372:
CHEMICAL NAME CAS NUMBER
XYLENE 1330-20-7
TOLUENE 108-88-3
ETHYLBENZENE 100-41-4
TOXIC SUBSTANCES CONTROL ACT:
LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT
THAT ARE SUBJECT TO THE REPORTING REQUIREMENTS OF TSCA 12(B) IF
EXPORTED FROM THE UNITED STATES:
U.S. STATE REGULATIONS: AS FOLLOWS
NEW JERSEY RIGHT-TO-KNOW:
THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE
COMPONENTS IN THIS PRODUCT.
CHEMICAL NAME CAS NUMBER
MODIFIED ALKYD PROPRIETARY
PENNSYLVANIA RIGHT-TO-KNOW:
THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT
GREATER THAN 3%.
CHEMICAL NAME CAS NUMBER
MODIFIED ALKYD PROPRIETARY
CALCIUM CARBONATE 1317-65-3
CALIFORNIA PROPOSITION 65:
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN BY THE STATE OF CALIFORNIA TO
CAUSE CANCER.
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INTERNATIONAL REGULATIONS: AS FOLLOWS
CANADIAN WHMIS:
THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
CANADIAN WHMIS CLASS:
AB5
D2A
D2B
| SECTION 16 - OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 4
REACTIVITY 0
PERSONAL PROTECTION X
REASON FOR REVISION: REGULATORY UPDATE
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
THE INFORMATION CONTAINED ON THIS MSDS HAS BEEN CHECKED AND SHOULD BE
ACCURATE. HOWEVER, IT IS THE RESPONSIBILITY OF THE USER TO COMPLY WITH
ALL FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS.