| Common Name: | TOUGH GUY HYDROGEN PEROXIDE GP CLEANER |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 7/5/2011 |
| SDS Format: | No Format Specified |
| Item Number(s): | 12M180 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
GRAINGER(R*) FOR THE ONES WHO GET IT DONE
MANUFACTURED FOR:
W.W. GRAINGER, INC.
100 GRAINGER PKWY.
LAKE FOREST, IL 60045-5201
1-847-535-1000
WWW.GRAINGER.COM
| SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: TOUGH GUY HYDROGEN PEROXIDE GP CLEANER
PRODUCT USE: HARD SURFACE CLEANER
PRODUCT CODE: 12M180
DATE OF ISSUE: 07/05/11
SUPERSEDES:
EMERGENCY TELEPHONE NUMBERS:
FOR MSDS INFORMATION:
TECHNICAL SERVICES: 1-847-535-5400
FOR MEDICAL EMERGENCY: (800) 983-4582 TOLL FREE
FOR TRANSPORTATION EMERGENCY:
CHEMTREC: (800) 424-9300 - ALL CALLS RECORDED
IN THE DISTRICT OF COLUMBIA: (202) 483-7616
PREPARED BY:
COMPLIANCE SERVICES
1420 SEABOARD INDUSTRIAL BLVD.
ATLANTA, GA 30318
| SECTION 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING!
CAUSES EYE AND SKIN IRRITATION. MAY BE HARMFUL IF SWALLOWED.
NOTE:
MSDS DATA PERTAINS TO THE PRODUCT AS DELIVERED IN THE ORIGINAL SHIPPING
CONTAINER(S). RISK OF ADVERSE EFFECTS ARE LESSENED BY FOLLOWING ALL
PRESCRIBED SAFETY PRECAUTIONS, INCLUDING THE USE OF PROPER PERSONAL
PROTECTIVE EQUIPMENT.
ACUTE EFFECTS:
ROUTES OF ENTRY: DERMAL CONTACT. EYE CONTACT. INHALATION.
EYES:
CAUSES EYE IRRITATION. INFLAMMATION OF THE EYE IS CHARACTERIZED BY REDNESS,
WATERING AND ITCHING.
SKIN:
CAUSES SKIN IRRITATION. SKIN INFLAMMATION IS CHARACTERIZED BY ITCHING,
SCALING, OR REDDENING.
INHALATION:
AVOID BREATHING VAPORS, SPRAY OR MISTS. OVER-EXPOSURE BY INHALATION MAY
CAUSE RESPIRATORY IRRITATION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED. CAN CAUSE GASTROINTESTINAL DISTURBANCES.
CHRONIC EFFECTS:
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. REPEATED
OR PROLONGED EXPOSURE TO SPRAY OR MIST MAY PRODUCE RESPIRATORY TRACT
IRRITATION LEADING TO FREQUENT ATTACKS OF BRONCHIAL INFECTION.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
PRODUCT/INGREDIENT NAME ACGIH IARC EPA NIOSH NTP OSHA
HYDROGEN PEROXIDE A3 3
ADDITIONAL INFORMATION: SEE TOXICOLOGICAL INFORMATION (SECTION 11)
*HAZARD DETERMINATION SYSTEM (HDS):
HEALTH 2
FLAMMABILITY 0
REACTIVITY 0
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
NAME OF HAZARDOUS INGREDIENTS CAS NUMBER % BY WEIGHT
HYDROGEN PEROXIDE; PEROXIDE 7722-84-1 1 - 10
DIPROPYLENE GLYCOL N-PROPYL ETHER; 2- 29911-27-1 1 - 5
PROPANOL, 1-(1-METHYL-2-PROPOXYETHOXY)
| SECTION 4. FIRST AID MEASURES | |
EYE CONTACT:
CHECK FOR AND REMOVE ANY CONTACT LENSES. IMMEDIATELY FLUSH EYES WITH PLENTY
OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING THE UPPER AND LOWER
EYELIDS. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH
CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION OCCURS.
INHALATION:
MOVE EXPOSED PERSON TO FRESH AIR. IF IRRITATION PERSISTS, GET MEDICAL
ATTENTION.
INGESTION:
WASH OUT MOUTH WITH WATER. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO
BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. IF AFFECTED PERSON IS CONSCIOUS, GIVE PLENTY OF WATER TO DRINK. GET
MEDICAL ATTENTION IMMEDIATELY.
| SECTION 5. FIRE FIGHTING MEASURES | |
FLASH POINT: NONE.
FLAMMABLE LIMITS: NOT DETERMINED.
FLAMMABILITY: NON-COMBUSTIBLE.
FIRE HAZARD:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST. MAY EMIT TOXIC FUMES UNDER FIRE CONDITIONS.
FIRE-FIGHTING PROCEDURES:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
2
0
0
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
SPILL CLEAN UP:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). STOP LEAK
IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH WATER AND MOP
UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN
INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER.
| SECTION 7. HANDLING AND STORAGE | |
HANDLING:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). AVOID
CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT INGEST. AVOID BREATHING VAPOR
OR MIST. WASH THOROUGHLY AFTER HANDLING. DO NOT REUSE CONTAINER.
STORAGE:
STORE IN ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL
AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10)
AND FOOD AND DRINK. STORE BELOW 120 DEG. F (49 DEG. C). AVOID CONTACT WITH
ORGANIC MATERIALS. EXPOSURE TO SUNLIGHT ACCELERATES DECOMPOSITION. KEEP
CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT
HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT
LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. KEEP OUT OF THE REACH OF
CHILDREN.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRODUCT NAME EXPOSURE LIMITS
HYDROGEN PEROXIDE; PEROXIDE ACGIH TLV (UNITED STATES, 2/2010).
TWA: 1 PPM 8 HOUR(S).
TWA: 1.4 MG/M3 8 HOUR(S).
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 1 PPM 8 HOUR(S).
TWA: 1.4 MG/M3 8 HOUR(S).
NIOSH REL (UNITED STATES, 6/2009).
TWA: 1 PPM 10 HOUR(S).
TWA: 1.4 MG/M3 10 HOUR(S).
OSHA PEL (UNITED STATES, 11/2006).
TWA: 1 PPM 8 HOUR(S).
TWA: 1.4 MG/M3 8 HOUR(S).
PERSONAL PROTECTIVE EQUIPMENT (PPE):
SAFETY GLASSES
GLOVES
EYES: SAFETY GLASSES.
BODY:
FOR PROLONGED OR REPEATED HANDLING, USE THE FOLLOWING TYPE OF GLOVES:
NEOPRENE GLOVES. NITRILE GLOVES. RUBBER GLOVES.
RESPIRATORY:
AVOID BREATHING VAPORS, SPRAY OR MISTS. PROVIDE EXHAUST VENTILATION OR
OTHER ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS
BELOW THEIR RESPECTIVE OCCUPATIONAL EXPOSURE LIMITS.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID. (THIN LIQUID)
pH: 2.5 TO 3.5
BOILING POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.03
SOLUBILITY:
SOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
COLOR: CLEAR. GREEN.
ODOR: PLEASANT. (LEMONGRASS)
VAPOR PRESSURE: NOT DETERMINED.
VAPOR DENSITY: NOT DETERMINED.
EVAPORATION RATE: 1 (WATER = 1)
VOC (CONSUMER): 0 G/L
| SECTION 10. STABILITY AND REACTIVITY | |
STABILITY AND REACTIVITY: THE PRODUCT IS STABLE.
INCOMPATIBILITY:
KEEP AWAY FROM HEAT, SPARKS AND FLAME. SLIGHTLY REACTIVE OR INCOMPATIBLE
WITH THE FOLLOWING MATERIALS:
OXIDIZING MATERIALS, REDUCING MATERIALS, ORGANIC MATERIALS AND ALKALIS.
HAZARDOUS POLYMERIZATION:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS POLYMERIZATION WILL
NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSES ON HEATING. CARBON OXIDES (CO, CO2)
| SECTION 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
HYDROGEN PEROXIDE LD50 ORAL RAT 1232 MG/KG
1-(1-METHYL-2- LD50 DERMAL RABBIT >2000 MG/KG
PROPOXYETHOXY) LD50 DERMAL RABBIT 5660 (MICRO)L/KG
PROPAN-2-OL LD50 ORAL RAT >2000 MG/KG
LD50 ORAL RAT >1500 MG/KG
LD50 ORAL RAT 1620 (MICRO)L/KG
| SECTION 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL EFFECTS: NOT AVAILABLE.
AQUATIC ECOTOXICITY:
PRODUCT/INGREDIENT NAME TEST RESULT SPECIES EXPOSURE
HYDROGEN PEROXIDE ACUTE EC50 24 DAPHNIA - WATER 48 HOURS
PPM FRESH WATER FLEA - DAPHNIA
MAGNA - <24 HOURS
ACUTE EC50 2320 DAPHNIA - WATER 48 HOURS
(MICRO)G/L FLEA - DAPHNIA
FRESH WATER MAGNA - NEONATE
- <24 HOURS
ACUTE LC50 FISH 96 HOURS
16.4 MG/L
ACUTE LC50 26.7 FISH - BLUEGILL 96 HOURS
PPM FRESH WATER - LEPOMIS
MACROCHIRUS -
JUVENILE
(FLEDGLING,
HATCHLING,
WEANLING)
ACUTE LC50 22 FISH - RAINBOW 96 HOURS
PPM FRESH WATER TROUT, DONALDSON
TROUT -
ONCORHYNCHUS
MYKISS - JUVENILE
(FLEDGLING,
HATCHLING,
WEANLING)
| SECTION 13. DISPOSAL CONSIDERATIONS | |
WASTE INFORMATION:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
ENVIRONMENTAL CONTROL REGULATIONS. CONSULT YOUR LOCAL OR REGIONAL
AUTHORITIES FOR ADDITIONAL INFORMATION.
WASTE STREAM:
CODE: (NONE.)
CLASSIFICATION: (NON-HAZARDOUS WASTE)
| SECTION 14. TRANSPORT INFORMATION | |
REGULATORY UN NUMBER PROPER SHIPPING CLASSES PG* LABEL
INFORMATION NAME
DOT CLASSIFICATION NOT REGULATED. NONE.
NOTE:
DOT CLASSIFICATION APPLIES TO MOST PACKAGE SIZES. FOR SPECIFIC CONTAINER
SIZE CLASSIFICATIONS OR FOR SIZE EXCEPTIONS, REFER TO THE BILL OF LADING
WITH YOUR SHIPMENT.
PG*: PACKING GROUP
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313 TOXIC CHEMICAL NOTIFICATION AND RELEASE REPORTING:
NO PRODUCTS WERE FOUND.
CLEAN WATER ACT (CWA) 307: NO PRODUCTS WERE FOUND.
CLEAN WATER ACT (CWA) 311: NO PRODUCTS WERE FOUND.
CLEAN AIR ACT (CAA) 112 REGULATED TOXIC SUBSTANCES: NO PRODUCTS WERE FOUND.
ALL COMPONENTS OF THIS PRODUCT ARE LISTED OR EXEMPT FROM LISTING ON TSCA
INVENTORY.
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
STATE REGULATIONS:
CALIFORNIA PROP 65: NO PRODUCTS WERE FOUND.
| SECTION 16. OTHER INFORMATION | |
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE NAMED SUPPLIER NOR ANY OF ITS SUBSIDIARIES
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
*NOTE:
HAZARD DETERMINATION SYSTEM (HDS) RATINGS ARE BASED ON A 0-4 RATING SCALE,
WITH 0 REPRESENTING MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING
SIGNIFICANT HAZARDS OR RISKS ALTHOUGH THESE RATINGS ARE NOT REQUIRED ON
MSDSS UNDER 29 CFR 1910.1200, THE PREPARER MAY CHOOSE TO PROVIDE THEM. HDS
RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED PROGRAM TO RELAY THE
MEANINGS OF THIS SCALE.