| Common Name: | A/C EASYSEAL (4050-06) |
| Manufacturer: | NU-CALGON WHOLESALER |
| SDS Revision Date: | 6/24/2009 |
| SDS Format: | No Format Specified |
| Item Number(s): | 13D663, 13D664 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NU-CALGON
MATERIAL SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: A/C EASYSEAL (4050-06)
CAS #: MIXTURE
PRODUCT USE:
SEALANT FOR SEALING REFRIGERANT LEAKS IN REFRIGERATION AND AC SYSTEMS
MANUFACTURER:
NU-CALGON
2008 ALTOM COURT
ST. LOUIS, MO 63146
US
PHONE: 314-469-7000 / 800-554-5499
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)
HMIS:
HEALTH 2*
FLAMMABILITY 4
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA:
2
4
0
LEGEND:
SEVERE 4
SERIOUS 3
MODERATE 2
SLIGHT 1
MINIMAL 0
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
EXTREMELY FLAMMABLE. CONTENTS UNDER PRESSURE. CONTAINERS MAY EXPLODE WHEN
HEATED.
EYE IRRITANT. SKIN IRRITATION POSSIBLE WITH PROLONGED EXPOSURE.
CONTAINS A POTENTIAL MUTAGEN.
POTENTIAL SHORT TERM HEALTH EFFECTS:
ROUTES OF EXPOSURE: EYE, SKIN CONTACT, INHALATION, INGESTION.
EYES: CONTACT WITH LIQUID OR MIST WILL IRRITATE THE EYES.
SKIN: CONTACT WITH LIQUID MAY CAUSE SKIN IRRITATION.
INHALATION:
EXCESSIVE INTENTIONAL INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION
AND CENTRAL NERVOUS SYSTEM EFFECTS (HEADACHE, DIZZINESS).
INGESTION:
NOT A NORMAL ROUTE OF EXPOSURE. MAY CAUSE STOMACH DISTRESS, NAUSEA OR
VOMITING.
TARGET ORGANS: BLOOD. EYES. LIVER. RESPIRATORY SYSTEM. SKIN.
CHRONIC EFFECTS:
PROLONGED OR REPEATED EXPOSURE CAN CAUSE DRYING, DEFATTING AND DERMATITIS.
SIGNS AND SYMPTOMS:
SYMPTOMS MAY INCLUDE REDNESS, EDEMA, DRYING, DEFATTING AND CRACKING OF THE
SKIN. SYMPTOMS OF OVEREXPOSURE MAY BE HEADACHE, DIZZINESS, TIREDNESS,
NAUSEA AND VOMITING.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
INGREDIENT(S) CAS # PERCENT
BUTANE 106-97-8 10 - 30
PROPANE 74-98-6 10 - 30
ETHANOL 64-17-5 1 - 5
| 4. FIRST AID MEASURES | |
FIRST AID PROCEDURES:
EYE CONTACT:
IMMEDIATELY FLUSH WITH COOL WATER. REMOVE CONTACT LENSES, IF APPLICABLE,
AND CONTINUE FLUSHING FOR 15 MINUTES. OBTAIN MEDICAL ATTENTION
IMMEDIATELY.
SKIN CONTACT:
FLUSH WITH COOL WATER. WASH WITH SOAP AND WATER. OBTAIN MEDICAL ATTENTION
IF IRRITATION PERSISTS.
INHALATION:
IF SYMPTOMS DEVELOP, MOVE VICTIM TO FRESH AIR. IF SYMPTOMS PERSIST, OBTAIN
MEDICAL ATTENTION. IF BREATHING HAS STOPPED, TRAINED PERSONNEL SHOULD
ADMINISTER CPR IMMEDIATELY.
INGESTION:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH IF VICTIM IS
UNCONSCIOUS, OR IS CONVULSING. OBTAIN MEDICAL ATTENTION.
NOTES TO PHYSICIAN: SYMPTOMS MAY BE DELAYED.
GENERAL ADVICE:
DO NOT PUNCTURE OR INCINERATE CONTAINER. KEEP AWAY FROM SOURCES OF
IGNITION. NO SMOKING. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE
LABEL WHERE POSSIBLE). ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW
THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE. AVOID CONTACT WITH
EYES AND SKIN. KEEP OUT OF REACH OF CHILDREN.
| 5. FIRE FIGHTING MEASURES | |
FLAMMABLE PROPERTIES:
FLAMMABLE AEROSOL BY FLAME PROJECTION TEST. CONTAINERS MAY EXPLODE WHEN
HEATED.
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA: CARBON DIOXIDE. DRY CHEMICAL. FOAM.
UNSUITABLE EXTINGUISHING MEDIA: NOT AVAILABLE
PROTECTION OF FIREFIGHTERS:
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED
TO HEAT OR FLAME. COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL
WELL AFTER FIRE IS OUT.
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE CLOTHING INCLUDING SELF CONTAINED
BREATHING APPARATUS.
HAZARDOUS COMBUSTION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON. OXIDES OF SILICON.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NOT AVAILABLE
SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
KEEP UNNECESSARY PERSONNEL AWAY. DO NOT TOUCH OR WALK THROUGH SPILLED
MATERIAL. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. KEEP PEOPLE AWAY FROM AND UPWIND
OF SPILL/LEAK.
METHODS FOR CONTAINMENT:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). STOP LEAK IF YOU CAN DO SO WITHOUT RISK. PREVENT ENTRY
INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS FOR CLEANING UP:
BEFORE ATTEMPTING CLEAN UP, REFER TO HAZARD DATA GIVEN ABOVE. REMOVE
SOURCES OF IGNITION. ALTHOUGH THE CHANCE OF A SIGNIFICANT SPILL OR LEAK IS
UNLIKELY IN AEROSOL CONTAINERS, IN THE EVENT OF SUCH AN OCCURRENCE, ABSORB
SPILLED MATERIAL WITH A NON-FLAMMABLE ABSORBENT SUCH AS SAND OR
VERMICULITE.
| 7. HANDLING AND STORAGE | |
HANDLING: USE GOOD INDUSTRIAL HYGIENE PRACTICES IN HANDLING THIS MATERIAL.
STORAGE:
KEEP OUT OF REACH OF CHILDREN. DO NOT STORE AT TEMPERATURES ABOVE
49 DEG. C (120.2 DEG. F). KEEP AWAY FROM HEAT, OPEN FLAMES OR OTHER
SOURCES OF IGNITION.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE LIMITS:
INGREDIENT(S) EXPOSURE LIMITS
BUTANE ACGIH-TLV:
TWA: 1000 PPM
OSHA-PEL:
NOT ESTABLISHED
ETHANOL ACGIH-TLV:
TWA: 1000 PPM
OSHA-PEL:
TWA: 1000 PPM
PROPANE ACGIH-TLV:
TWA: 1000 PPM
OSHA-PEL:
TWA: 1000 PPM
ENGINEERING CONTROLS: GENERAL VENTILATION NORMALLY ADEQUATE.
PERSONAL PROTECTIVE EQUIPMENT:
EYE / FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS.
HAND PROTECTION: RUBBER GLOVES. CONFIRM WITH A REPUTABLE SUPPLIER FIRST.
SKIN AND BODY PROTECTION: AS REQUIRED BY EMPLOYER CODE.
RESPIRATORY PROTECTION:
WHERE EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AN APPROVED NIOSH
RESPIRATOR.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
WHEN USING DO NOT EAT OR DRINK. WASH HANDS BEFORE BREAKS AND IMMEDIATELY
AFTER HANDLING THE PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COMPRESSED LIQUEFIED GAS
COLOR: COLORLESS
FORM: SPRAY
ODOR: AMINE
ODOR THRESHOLD: NOT AVAILABLE
PHYSICAL STATE: GAS
pH: NOT AVAILABLE
MELTING POINT: NOT AVAILABLE
FREEZING POINT: NOT AVAILABLE
BOILING POINT: 61.66 DEG. C (143 DEG. F)
FLASH POINT: 55.68 DEG. C (132.23 DEG. F) TAG CLOSED CUP
EVAPORATION RATE: <1
FLAMMABILITY LIMITS IN AIR, LOWER, % BY VOLUME: NOT AVAILABLE
FLAMMABILITY LIMITS IN AIR, UPPER, % BY VOLUME: NOT AVAILABLE
VAPOR PRESSURE: 117.74 HPA
VAPOR DENSITY: >1 (AIR=1)
SPECIFIC GRAVITY: 9.1
OCTANOL/WATER COEFFICIENT: NOT AVAILABLE
SOLUBILITY (H2O): NOT AVAILABLE
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
VOC (WEIGHT %): NOT AVAILABLE
VISCOSITY: NOT AVAILABLE
PERCENT VOLATILE: NOT AVAILABLE
| 10. STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID:
AEROSOL CONTAINERS ARE UNSTABLE AT TEMPERATURES ABOVE 49 DEG. C
(120.2 DEG. F). DO NOT MIX WITH OTHER CHEMICALS.
INCOMPATIBLE MATERIALS: CAUSTICS. ACIDS. OXIDIZERS.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON. OXIDES OF SILICON.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
| 11. TOXICOLOGICAL INFORMATION | |
COMPONENT ANALYSIS - LC50:
INGREDIENT(S) LC50
BUTANE 658 MG/L/4H RAT
ETHANOL 31623 PPM RAT
PROPANE 658 MG/L/4H RAT
COMPONENT ANALYSIS - ORAL LD50:
INGREDIENT(S) LD50
BUTANE NOT AVAILABLE
ETHANOL 3450 MG/KG MOUSE
7060 MG/KG RAT
PROPANE NOT AVAILABLE
EFFECTS OF ACUTE EXPOSURE:
EYE: CONTACT WITH LIQUID OR MIST WILL IRRITATE THE EYES.
SKIN: CONTACT WITH LIQUID MAY CAUSE SKIN IRRITATION.
INHALATION:
EXCESSIVE INTENTIONAL INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION
AND CENTRAL NERVOUS SYSTEM EFFECTS (HEADACHE, DIZZINESS).
INGESTION:
NOT A NORMAL ROUTE OF EXPOSURE. MAY CAUSE STOMACH DISTRESS, NAUSEA OR
VOMITING.
SENSITIZATION: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
CHRONIC EFFECTS: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
CARCINOGENICITY: SEE BELOW.
ACGIH - THRESHOLD LIMIT VALUES - CARCINOGENS:
ETHANOL 64-17-5 A4 - NOT CLASSIFIABLE AS A HUMAN
CARCINOGEN
IARC - GROUP 1 (CARCINOGENIC TO HUMANS):
ETHANOL 64-17-5 MONOGRAPH 96 (2007) (IN ALCOHOLIC
BEVERAGES)
MUTAGENICITY:
MUTAGENIC EFFECTS WERE OBSERVED IN SOMATIC AND REPRODUCTIVE CELLS OF LIVE
ANIMALS (RATS AND MICE) EXPOSED TO HIGH ORAL DOSES OF ETHANOL.
REPRODUCTIVE EFFECTS: HAZARDOUS BY WHMIS/OSHA CRITERIA.
TERATOGENICITY:
ANIMAL STUDIES DEMONSTRATE THAT INGESTION OF ETHANOL CAN CAUSE
EMBRYOTOXICITY, TERATOGENICITY AND FETOTOXICITY IN THE PRESENCE OF
MATERNAL TOXICITY.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
COMPONENTS OF THIS PRODUCT HAVE BEEN IDENTIFIED AS HAVING POTENTIAL
ENVIRONMENTAL CONCERNS.
ECOTOXICITY - FRESHWATER FISH SPECIES DATA:
ETHANOL 64-17-5 96 HR LC50 ONCORHYNCHUS MYKISS:
12.0-16.0 ML/L (STATIC)
96 HR LC50 PIMEPHALES PROMELAS:
>100 MG/L (STATIC)
96 HR LC50 PIMEPHALES PROMELAS:
13400-15100 MG/L (FLOW-THROUGH)
ECOTOXICITY - MICROTOX DATA:
ETHANOL 64-17-5 5 MIN EC50 PHOTOBACTERIUM PHOSPHOREUM:
35470 MG/L
30 MIN EC50 PHOTOBACTERIUM
PHOSPHOREUM: 34634 MG/L
ECOTOXICITY - WATER FLEA DATA:
ETHANOL 64-17-5 48 HR LC50 DAPHNIA MAGNA: 9268 MG/L
24 HR EC50 DAPHNIA MAGNA: 10800 MG/L
ENVIRONMENTAL EFFECTS: NOT AVAILABLE
AQUATIC TOXICITY: NOT AVAILABLE
PERSISTENCE / DEGRADABILITY: NOT AVAILABLE
BIOACCUMULATION / ACCUMULATION: NOT AVAILABLE
PARTITION COEFFICIENT: NOT AVAILABLE
MOBILITY IN ENVIRONMENTAL MEDIA: NOT AVAILABLE
CHEMICAL FATE INFORMATION: NOT AVAILABLE
OTHER ADVERSE EFFECTS: NOT AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
WASTE CODES: NOT AVAILABLE
DISPOSAL INSTRUCTIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
WASTE FROM RESIDUES / UNUSED PRODUCTS: NOT AVAILABLE
CONTAMINATED PACKAGING: NOT AVAILABLE
| 14. TRANSPORT INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION (DOT): CONSUMER COMMODITY ORM-D
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA): CONSUMER COMMODITY
| 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE CONTROLLED PRODUCTS REGULATIONS AND THE MSDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
CANADA - CEPA - HIGH PRIORITY CHEMICALS AS IDENTIFIED BY DSL
CATEGORIZATION:
BUTANE 106-97-8 BATCH 4, PUBLISHED NOVEMBER 17, 2007
CANADA - WHMIS - INGREDIENT DISCLOSURE LIST:
BUTANE 106-97-8 1%
ETHANOL 64-17-5 0.1%
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
CERCLA/SARA HAZARDOUS SUBSTANCES: NOT APPLICABLE.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA):
29 CFR 1910.1200 HAZARDOUS CHEMICAL: YES
CERCLA (SUPERFUND) REPORTABLE QUANTITY: NONE
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD - YES
DELAYED HAZARD - YES
FIRE HAZARD - YES
PRESSURE HAZARD - YES
REACTIVITY HAZARD - NO
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SECTION 311 HAZARDOUS CHEMICAL: YES
CLEAN AIR ACT (CAA): NOT AVAILABLE
CLEAN WATER ACT (CWA): NOT AVAILABLE
WHMIS STATUS: CONTROLLED
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS, CLASS B - DIVISION 5 - FLAMMABLE AEROSOL,
CLASS D - DIVISION 2A, 2B
WHMIS LABELING:
A - COMPRESSED GAS
B - FLAMMABLE AND COMBUSTIBLE MATERIAL
D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
STATE REGULATIONS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
U.S. - CALIFORNIA - 8 CCR SECTION 339 - DIRECTOR'S LIST OF HAZARDOUS
SUBSTANCES:
BUTANE 106-97-8 PRESENT
ETHANOL 64-17-5 PRESENT (REFERS TO SOLUTIONS GREATER
THAN OR EQUAL TO 25% WHICH ARE NOT
BEVERAGE ALCOHOLS)
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY:
ETHANOL 64-17-5 DEVELOPMENTAL TOXICITY, INITIAL DATE
10/1/87 (WHEN IN ALCOHOLIC BEVERAGES)
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST:
BUTANE 106-97-8 PRESENT
ETHANOL 64-17-5 TERATOGEN
PROPANE 74-98-6 PRESENT
U.S. - MINNESOTA - HAZARDOUS SUBSTANCE LIST:
BUTANE 106-97-8 PRESENT
ETHANOL 64-17-5 PRESENT
PROPANE 74-98-6 SIMPLE ASPHYXIANT
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST:
BUTANE 106-97-8 SN 0273
ETHANOL 64-17-5 SN 0844
PROPANE 74-98-6 SN 1594
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST:
BUTANE 106-97-8 PRESENT
ETHANOL 64-17-5 PRESENT
PROPANE 74-98-6 PRESENT
U.S. - RHODE ISLAND - HAZARDOUS SUBSTANCE LIST:
BUTANE 106-97-8 TOXIC; FLAMMABLE
ETHANOL 64-17-5 TOXIC; FLAMMABLE
PROPANE 74-98-6 TOXIC; FLAMMABLE
INVENTORY NAME:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST NO
(NDSL)
UNITED STATES & PUERTO TOXIC SUBSTANCES CONTROL ACT YES
RICO (TSCA) INVENTORY
A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
DISCLAIMER:
INFORMATION CONTAINED HEREIN WAS OBTAINED FROM SOURCES CONSIDERED
TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY EFFORT HAS BEEN MADE TO
ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME CASES DATA IS NOT
AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL PRODUCT USE ARE
BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF THIS MATERIAL
HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL APPLICABLE
LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED OR IMPLIED,
IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES, INJURIES OR
CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR RELIANCE ON
ANY INFORMATION CONTAINED IN THIS DOCUMENT.
ISSUE DATE: 24-JUN-2009
EFFECTIVE DATE: 15-JUN-2009
EXPIRY DATE: 15-JUN-2012
PREPARED BY:
NU-CALGON TECHNICAL SERVICE
(314) 469-7000
#19314