| Common Name: | LITHIUM ION MANGANESE OXIDE BATTERY 3S1P BM18650Z1 |
| Manufacturer: | BATTERIEN-MONTAGE-ZENTRUM GERMANY |
| SDS Revision Date: | 5/30/2012 |
| SDS Format: | No Format Specified |
| Item Number(s): | 19H297 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
BMZ
THE BATTERY EXPERTS
BATTERIEN-MONTAGE-ZENTRUM GMBH
AM SPORTPLATZ 28-30
D-63791 KARLSTEIN AM MAIN
TEL: +49 (0)6188 9956-0
FAX: +49 (0)6188-9956-900
E-MAIL: MAIL@BMZ-GMBH.DE
INTERNET: WWW.BMZ-GMBH.DE
PRODUCT SAFETY DATA SHEET
LITHIUM ION MANGANESE OXIDE BATTERY
3S1P BM18650Z1
ITEM NO.: 6449
| 1. IDENTIFICATION OF THE SUBSTANCE AND OF THE MANUFACTURER |  |
IDENTIFICATION:
PRODUCT CATEGORY: LITHIUM ION BATTERY
MODEL NAME: 3S1P BM18650Z1
NOMINAL VOLTAGE: 10,8 V
NOMINAL CAPACITY: 1,5 AH
NOMINAL ENERGY: 16,2 WH
CHEMICAL SYSTEM: LITHIUM ION MANGANESE OXIDE / GRAPHITE
RECHARGEABLE:
(X) YES
( ) NO
MANUFACTURER:
NAME AND ADDRESS:
BATTERIEN-MONTAGE-ZENTRUM GMBH
AM SPORTPLATZ 28-30
D-63791 KARLSTEIN AM MAIN
PHONE: +49 (0) 6188 / 9956-0
TELEFAX: +49 (0) 6188 / 9956-900
E-MAIL: MAIL@BMZ-GMBH.DE
KARLSTEIN, 30.05.2012
I.A. DR. JOCHEN MAHLIB (DIPL-CHEM.)
RICHTLINIENBEAUFTRAGER / COMPLIANCE OFFICER
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
IN GENERAL LITHIUM ION RECHARGEABLE BATTERIES ARE CLASSIFIED AS DANGEROUS
GOOD CLASS 9 (SUBSECTION 2 (1) TRANSPORT OF HAZARDOUS GOODS ACT).
THE NOMINAL VOLTAGE IN VOLT AND NOMINAL CAPACITY IN AMPERE HOURS MUST BE
MARKED OUTSIDE THE HOUSING.
HAZARDS:
IF CATHODE AND ANODE OF THE BATTERY COME INTO CONTACT WITH OTHER METALS,
HEAT CAN BUILD UP AND ELECTROLYTE FLUID CAN LEAK.
ELECTROLYTE FLUID IS FLAMMABLE. IN CASE OF ELECTROLYTE LEAKAGE, PUT THE
BATTERY OUT OF FIRE RANGE IMMEDIATELY.
TOXICITY:
IF A BATTERY BURNS, THE VAPORS CAN IRRITATE EYES, SKIN AND THE RESPIRATORY
TRACT.
| 3. REACTION EQUATION, COMPOSITION AND | |
INFORMATION ON INGREDIENTS
OXIDATION: LiXC6 -> Li1-XC6 + X Li(+) + X E(-)
REDUCTION: Li1-XMn2O4 + X Li(+) + X E(-) -> LiMn2O4
CATHODE:
LITHIUM ION MANGANESE OXIDE (ACTIVE MATERIAL): 20-30 WT%
POLYVINYLIDENE FLUORIDE (BINDER):
CARBON BLACK (CONDUCTIVE MATERIAL):
ANODE:
GRAPHITE (ACTIVE MATERIAL): 5-20 WT%
POLYVINYLIDENE FLUORIDE (BINDER):
ELECTROLYTE:
ORGANIC SOLVENTS, LITHIUM SALT: 10-20 WT%
OTHERS:
HEAVY METALS SUCH AS MERCURY, CADMIUM, LEAD AND CHROMIUM ARE NOT USED IN
THE CELLS.
| 4. FIRST AID MEASURES | |
THE CHEMICALS ARE CONTAINED IN SEALED CANS. UPON NORMAL CONDITIONS OF USE,
RISK OF EXPOSURE OCCURS ONLY IF THE BATTERY IS MECHANICALLY ABUSED.
IF CHEMICALS LEAK ATTEND THESE ADVICES:
INHALATION:
CONTENTS OF AN OPENED BATTERY CAN CAUSE RESPIRATORY IRRITATION. PROVIDE
FRESH AIR AND CALL A DOCTOR.
SKIN CONTACT:
CONTENTS OF AN OPENED BATTERY CAN CAUSE SKIN IRRITATION.
WASH SKIN WITH SOAP AND WATER.
EYE CONTACT:
CONTENTS OF AN OPENED BATTERY CAN CAUSE EYE IRRITATION.
IMMEDIATELY FLUSH EYES THOROUGHLY WITH WATER FOR 15 MINUTES AND SEEK
MEDICAL ATTENTION.
| 5. FIRE FIGHTING MEASURES | |
IN CASE OF FIRE: USE DRY CHEMICAL EXTINGUISHERS.
CAUTION:
BEFORE STARTING TO EXTINGUISH THE FIRE, BE SURE, THAT YOU ARE AT WINDWARD
OF FIRE. SO YOU CANNOT INHALE TOXIC VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
WIPE UP LEAKED ELECTROLYTE FLUID WITH AN ABSORBENT CLOTH.
IF THERE IS A LOT OF LEAKED ELECTROLYTE, YOU SHOULD WEAR:
PROTECTIVE CLOTHING
GAS MASK FOR ORGANIC GASES
SAFETY GOGGLES
GAUNTLETS
PUT THE BATTERY OUT OF FIRE RANGE IMMEDIATELY.
| 7. HANDLING AND STORAGE | |
HANDLING:
DO NOT OPEN THE BATTERY. DO NOT CRUSH, DISASSEMBLE, DROP OR SOLDER.
CHARGING:
CHARGE WITHIN LIMITS OF +32 DEG. F TO +113 DEG. F TEMPERATURE
CHARGE ONLY WITH SPECIFIED CHARGER DESIGNED FOR THIS BATTERY.
DISCHARGING:
DISCHARGE WITHIN LIMITS OF -4 DEG. F TO +140 DEG. F TEMPERATURE.
CAUTION: WRONG HANDLING CAN CAUSE FIRE OR EXPLOSION.
STORAGE:
STORAGE TEMPERATURE: -4 DEG. F TO +113 DEG. F
HUMIDITY RANGE: 0% TO 80%
WELL VENTILATED AREA.
SHORT CIRCUIT CAN RANSOM BURN.
DO NOT STORE WITH METAL OBJECTS.
| 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
SEE POINT 7 ADVICES MUST BE OBSERVED.
YOU HAVE TO CHECK CONTINUOUSLY THAT STORAGE TEMPERATURE IS WITHIN THE
BOUNDS.
YOU HAVE TO CHECK THE VENTILATION THAT HUMIDITY RANGE IS WITHIN THE
BOUNDS, TOO.
FOR NORMAL USE YOU DON'T NEED ANY PROTECTIVE EQUIPMENT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: 3 CELLS IN BLACK PLASTIC HOUSING.
WEIGHT: 193 G
CHEMICAL PROPERTIES: SEE POINT 3
| 10. STABILITY AND REACTIVITY | |
DURING A LONG STORAGE THE CAPACITY WILL BE REDUCED AND THE LIFESPAN OF THE
BATTERY WILL BE SHORTER. THE PLASTIC HOUSING CAN BE DAMAGED BY LEAKING
ELECTROLYTE.
| 11. TOXICOLOGICAL INFORMATION | |
UPON NORMAL USE THERE WILL BE NO LEAKING AND NOBODY CAN COME INTO CONTACT
WITH TOXICALLY INGREDIENTS OF THE BATTERY.
| 12. ECOLOGICAL INFORMATION | |
UPON NORMAL USE THERE WON'T BE ANY ENVIRONMENTAL POLLUTION.
IF THE BATTERY IS UNUSABLE, YOU MUST RECYCLE IT. SEE POINT 13.
| 13. DISPOSAL CONSIDERATIONS | |
THE BATTERY IS HAZARDOUS WASTE.
IT IS NOT ALLOWED TO DISPOSE IT WITH COMMON WASTE.
IF THE BATTERY IS UNUSABLE, DISPOSE IT ACCORDING TO THE APPLICABLE
RECYCLING REGULATIONS.
| 14. TRANSPORTATION INFORMATION | |
NOTE:
ONLY REGULARLY INSTRUCTED PERSONNEL IS ALLOWED TO BE INVOLVED IN THE
TRANSPORTATION OF LITHIUM BATTERIES!
IF LITHIUM BATTERIES ARE TRANSPORTED PER AIR, THE INVOLVED PERSONNEL MUST
HAVE BEEN REGULARLY TRAINED BY THE GERMAN FEDERAL OFFICE OF CIVIL AVIATION
OR ITS AUTHORIZED TRAINING COMPANIES!
IN THE FOLLOWING THE DANGEROUS GOODS REGULATIONS OF THE CORRESPONDING
CARRIERS ARE CITED ONLY IN PART. BMZ EXCLUDES ANY LIABILITY!
TRANSPORTATION ACCORDING TO GUIDELINE UN 3480/3481 (1):
AS THE NOMINAL ENERGY IS NOT MORE THAN 100 WH YOU NEEDN'T TO TRANSPORT THE
BATTERY AS DANGEROUS GOOD, IF THE REGULATIONS OF THE CORRESPONDING CARRIER
ARE FULFILLED:
YOU CAN APPLY THE SPECIAL PROVISION 188 OF THE REGULATIONS ON THE CARRIAGE
OF DANGEROUS GOODS ADR/RID (2), IMDG-CODE (4) AND ADN (5) AS WELL AS
PACKING INSTRUCTION 965, PART II; OF THE REGULATION ON THE CARRIAGE ON
DANGEROUS GOODS IATA (3) WITH FOLLOWING REQUIREMENTS:
THE NOMINAL ENERGY OF THE BATTERY IS NOT MORE THAN 100 WH.
IT MUST HAVE PASSED THE UN TRANSPORTATION TEST ACCORDING TO THE UN MANUAL
OF TESTS AND CRITERIA, PART III, SECTION 38.3.
ENSURE THAT LITHIUM BATTERIES ARE INDIVIDUALLY PACKED IN FULLY ENCLOSED
INNER PACKAGING.
THE BATTERY MUST BE PROTECTED AGAINST SHORT CIRCUIT.
PROTECTOR FOR INWARD OVER PRESSURE.
THE PACKAGE MUST WITHSTAND A FREE FALL FROM A HEIGHT OF 1.2 M WITHOUT
DISPLACING THE CONTENT.
ROAD AND RAILWAY: ADR / RID 2011 (2)
THE INNER PACKAGE MUST BE PACKED IN STRONG OUTER PACKAGES, PACKAGE GROUP
II. PACKING INSTRUCTIONS SEE SECTIONS 4.1.1.1., 4.1.1.2. AND 4.1.1.5.
WEIGHT LIMITATION:
30 KG PER PACKAGE, UNLESS BATTERIES ARE PACKED IN OR WITH EQUIPMENT.
SPECIAL PROVISIONS: 188, 230, 310, 348, 636, 656
AIR: IATA 2012 (3)
PACKING INSTRUCTIONS: P965, P966, P967 (SECTION 2)
WEIGHT LIMITATION: 10 KG PER PACKAGE
SPECIAL PROVISIONS: A48, A88, A99, A154, A164, A181, A183
SEA: IMDG-CODE 2011 (4)
THE INNER PACKAGE MUST BE PACKED IN STRONG OUTER PACKAGES, PACKAGE GROUP
II. PACKING INSTRUCTIONS SEE SECTIONS 4.1.1.1., 4.1.1.2. AND 4.1.1.5.
WEIGHT LIMITATION:
30 KG PER PACKAGE, UNLESS BATTERIES ARE PACKED IN OR WITH EQUIPMENT.
SPECIAL PROVISIONS: 188, 230, 310, 348, 957
INLAND NAVIGATION: ADN 2011 (5)
THE INNER PACKAGE MUST BE PACKED IN STRONG OUTER PACKAGES, PACKAGE GROUP
II. PACKING INSTRUCTIONS SEE SECTIONS 4.1.1.1., 4.1.1.2. AND 4.1.1.5.
WEIGHT LIMITATION:
30 KG PER PACKAGE, UNLESS BATTERIES ARE PACKED IN OR WITH EQUIPMENT.
SPECIAL PROVISIONS: 188, 230, 310, 348, 636, 656
ADR/RID, IMDG-CODE, ADN:
EACH SHIPMENT MUST HAVE THE FOLLOWING LABEL AND COVERING NOTE SEE BELOW:
IF DAMAGED
CAUTION!
LITHIUM ION BATTERIES
IF THE PACKAGE IS DAMAGED, IT MUST BE QUARANTINED, INSPECTED AND REPACKED.
FOR MORE INFORMATION, CALL: +49 171 5441 333
INFORMATION: +49 6188 9956 0 ODER / OR SVEN.BAUER@BMZ-GMBH.DE
EMERGENCY CALL: +49 171 5441 333, 24 H
IATA:
EACH SHIPMENT MUST HAVE THE FOLLOWING LABEL AND COVERING NOTE SEE BELOW:
CAUTION!
IF DAMAGED
LITHIUM-ION-BATTERIES
DO NOT LOAD OR TRANSPORT
PACKAGE IF DAMAGED
FOR MORE INFORMATION, CALL: +49 (0)171 5441333
SIZE: 12 X 11 [CM]
INFORMATION: +49 6188 9956 0 ODER / OR SVEN.BAUER@BMZ-GMBH.DE
EMERGENCY CALL: +49 171 544 1333, 24 H
COVERING NOTE:
CAUTION:
THE PACKAGES IN THIS CONSIGNMENT CONSIST OF LITHIUM ION BATTERIES
SHIPMENT MUST BE HANDLED WITH CARE
DAMAGING CAN CAUSE FIRE OR EXPLOSION
IF THE PACKAGE IS DAMAGED IT MUST BE QUARANTINED, INSPECTED AND REPACKED
FOR FURTHER INFORMATION CONTACT:
PHONE: +49 171 5441 333
| 15. REGULATORY INFORMATION | |
(1) UN 3480 / UN 3481:
TRANSPORTATION REGULATIONS FOR LITHIUM ION BATTERIES INCLUDING THE TESTS
ACCORDING TO THE "UN MANUAL OF TESTS AND CRITERIA, PART III, SECTION 38.3".
(2) ADR / RID 2011:
REGULATIONS ON THE TRANSPORTATION OF DANGEROUS GOODS BY ROAD AND RAILWAY.
(3) IATA 2012: REGULATIONS ON THE TRANSPORTATION OF DANGEROUS GOODS BY AIR.
(4) IMDG-CODE 2011:
REGULATIONS ON THE TRANSPORTATION OF DANGEROUS GOODS BY SEA.
(5) ADN 2011:
REGULATIONS ON THE TRANSPORTATION OF DANGEROUS GOODS BY INLAND NAVIGATION.
| 16. OTHER INFORMATION | |
NONE
GESCHAFTSFUHRER:
HRB-NR. 5890 ASCHAFFENBURG
COMMERZBANK
SPARKASSE ASCHAFFENBURG
DEUTSCHE BANK
SVEN BAUER:
SI. NR.: 122/50444
BIC: COBADEFF795
BIC: BYLADEM1ASA
BIC: DEUTDEFF508
THORSTEN GOTTHARDT:
UST.-ID-NR.: DE 811770243
IBAN: DE35795400490105770200
BLZ: 79540049
BAN: DE71795500000240004283
BLZ: 79550000
IBAN: DE85508700050010501500
BLZ: 50870005
CLAUDIA REIMER:
KTO. 1057702
KTO. 240004283
KTO. 010501500