| Common Name: | DAWN HEAVY DUTY DEGREASER - READY TO USE |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 1/31/2012 |
| SDS Format: | No Format Specified |
| Item Number(s): | 22C551 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PROCTER & GAMBLE PROFESSIONAL(R*)
MATERIAL SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
MATERIAL NAME: DAWN HEAVY DUTY DEGREASER - READY TO USE
PRODUCT CODE: 15154367
VERSION #: 06
REVISION DATE: 01-31-2012
MANUFACTURER: PROCTER & GAMBLE PROFESSIONAL
ADDRESS:
2 P&G PLAZA
CINCINNATI
OHIO
45202
US
P&G TELEPHONE NUMBER: 1-800-332-7787
EMERGENCY 24-HR TELEPHONE#:
CHEMTREC: 1-800-424-9300
| 2. HAZARDS IDENTIFICATION | |
POTENTIAL HEALTH EFFECTS:
ROUTES OF EXPOSURE: INGESTION. INHALATION. SKIN CONTACT. EYE CONTACT.
EYES:
HEALTH INJURIES ARE NOT KNOWN OR EXPECTED UNDER NORMAL USE. ACCIDENTAL
EXPOSURE WILL CAUSE A MILD BUT TRANSIENT IRRITATION.
SKIN:
HEALTH INJURIES ARE NOT KNOWN OR EXPECTED UNDER NORMAL USE. MAY CAUSE
TRANSIENT IRRITATION. SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS.
INHALATION:
HEALTH INJURIES ARE NOT KNOWN OR EXPECTED UNDER NORMAL USE. MAY CAUSE
IRRITATION TO THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT.
INGESTION:
HEALTH INJURIES ARE NOT KNOWN OR EXPECTED UNDER NORMAL USE. INGESTION MAY
CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA.
POTENTIAL ENVIRONMENTAL EFFECTS:
CONSIDERING THE LIMITED AMOUNT APPLIED DURING USE AND THE SIZE OF THE
CONTAINER, THE RISK OF ADVERSE EFFECTS IS CONSIDERED SMALL.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
COMPONENTS CAS # PERCENT
LIALKYL BENZENE SULFONATE 68081-81-2 1-5
SODIUM CARBONATE 497-19-8 1-5
2-AMINOETHANOL 141-43-5 0.1-1
| 4. FIRST AID MEASURES | |
FIRST AID PROCEDURES:
EYE CONTACT:
AFTER INITIAL FLUSHING, REMOVE ANY CONTACT LENSES AND CONTINUE FLUSHING
FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND
PERSISTS.
SKIN CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS
AND PERSISTS.
INHALATION: MOVE TO FRESH AIR.
INGESTION:
DRINK 1 OR 2 GLASSES OF WATER. IF INGESTION OF A LARGE AMOUNT DOES OCCUR,
CALL A POISON CONTROL CENTER IMMEDIATELY.
| 5. FIRE FIGHTING MEASURES | |
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER. WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2).
PROTECTION OF FIREFIGHTERS:
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED POSITIVE
PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, PROTECTIVE CLOTHING AND
FACE MASK.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
KEEP UNNECESSARY PERSONNEL AWAY. WEAR SUITABLE PROTECTIVE CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
CLEAN-UP METHODS AND MATERIALS AND CONTAINMENT MEASURES:
IN CASE OF SPILLS, BEWARE OF SLIPPERY FLOORS AND SURFACES. USE A
NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND OR EARTH TO SOAK UP THE
PRODUCT AND PLACE INTO A CONTAINER FOR LATER DISPOSAL. FOLLOWING PRODUCT
RECOVERY, FLUSH AREA WITH WATER.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. KEEP CONTAINER CLOSED WHEN
NOT IN USE. NEVER RETURN SPILLS IN ORIGINAL CONTAINERS FOR RE-USE. KEEP
OUT OF REACH OF CHILDREN.
STORAGE: STORE IN A COOL AND WELL-VENTILATED PLACE. KEEP FROM FREEZING.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
2-AMINOETHANOL STEL 6 PPM
(141-43-5)
TWA 3 PPM
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
2-AMINOETHANOL PEL 3 PPM
(141-43-5) 6 MG/M3
ENGINEERING CONTROLS: PROVIDE ADEQUATE VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT:
EYE / FACE PROTECTION: NOT NORMALLY NEEDED.
SKIN PROTECTION:
NOT NORMALLY NEEDED. FOR PROLONGED OR REPEATED SKIN CONTACT USE SUITABLE
PROTECTIVE GLOVES. RECOMMENDED GLOVES INCLUDE RUBBER OR NEOPRENE.
RESPIRATORY PROTECTION: NOT NORMALLY NEEDED.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
| 9. PHYSICAL & CHEMICAL PROPERTIES | |
COLOR: LIGHT PURPLE
ODOR: SCENTED
ODOR THRESHOLD: NOT AVAILABLE.
PHYSICAL STATE: LIQUID.
PH: 10.4
MELTING POINT: NOT AVAILABLE.
FREEZING POINT: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT: 213.8 DEG. F (101.195480697 DEG. C) ESTIMATED
EVAPORATION RATE: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.12
SOLUBILITY (WATER): COMPLETE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE
VOC: 0.4%
PERCENT VOLATILE: 80.3% ESTIMATED
| 10. CHEMICAL STABILITY & REACTIVITY INFORMATION | |
CHEMICAL STABILITY: THIS IS A STABLE MATERIAL.
CONDITIONS TO AVOID: NONE.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| 11. TOXICOLOGICAL INFORMATION | |
TOXICOLOGICAL DATA:
COMPONENTS TEST RESULTS
2-AMINOETHANOL (141-43-5) ACUTE DERMAL LD50 RABBIT: 1025 MG/KG
ACUTE ORAL LD50 GUINEA PIG: 620 MG/KG
ACUTE ORAL LD50 MOUSE: 700 MG/KG
ACUTE ORAL LD50 RAT: 10.2 G/KG
ACUTE OTHER LD50 MOUSE: 50 MG/KG
ACUTE OTHER LD50 RAT: 67 MG/KG
SODIUM CARBONATE (497-19-8) ACUTE INHALATION LC50 GUINEA PIG:
0.8 MG/L 2 HOURS
ACUTE INHALATION LC50 MOUSE: 1.2 MG/L 2 HOURS
ACUTE INHALATION LC50 RAT: 2.3 MG/L 2 HOURS
ACUTE ORAL LD50 RAT: 4090 MG/KG
ACUTE OTHER LD50 MOUSE: 116.6 MG/KG 30 DAYS
LIALKYL BENZENE SULFONATE ACUTE ORAL LD50 RAT: 0.7 - 1.3 G/KG
(68081-81-2)
SENSITIZATION: NOT AVAILABLE.
CHRONIC EFFECTS: NOT AVAILABLE.
SKIN CORROSION/IRRITATION: NOT AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL EFFECTS:
BASED ON ECOTOXICITY AND FATE DATA FOR THE INDIVIDUAL INGREDIENTS IN THIS
SPECIFIC FORMULATION, AND FOR RELATED CONSUMER HOUSEHOLD CLEANING PRODUCTS
FORMULATIONS, THIS PRODUCT IS NOT CONSIDERED HARMFUL TO AQUATIC ORGANISMS
OR TO CAUSE LONG-TERM ADVERSE EFFECTS IN THE ENVIRONMENT AT RELEVANT
ENVIRONMENTAL CONCENTRATIONS. THIS PRODUCT IS INTENDED FOR DISPERSIVE USE
AND SHOULD NOT BE DISPOSED OF DIRECTLY INTO THE ENVIRONMENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
THIS PRODUCT, IN ITS PRESENT STATE, WHEN DISCARDED OR DISPOSED OF, IS NOT
A HAZARDOUS WASTE ACCORDING TO FEDERAL REGULATIONS (40 CFR 261.4 (B)(4)).
UNDER RCRA, IT IS THE RESPONSIBILITY OF THE USER OF THE PRODUCT TO
DETERMINE, AT THE TIME OF DISPOSAL, WHETHER THE PRODUCT MEETS RCRA
CRITERIA FOR HAZARDOUS WASTE. DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED AS DANGEROUS GOODS.
IMDG: NOT REGULATED AS DANGEROUS GOODS.
IATA: NOT REGULATED AS DANGEROUS GOODS.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
CERCLA (SUPERFUND) REPORTABLE QUANTITY: NONE
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD - YES
DELAYED HAZARD - NO
FIRE HAZARD - NO
PRESSURE HAZARD - NO
REACTIVITY HAZARD - NO
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SECTION 311 HAZARDOUS CHEMICAL: NO
STATE REGULATIONS:
ILLRTK: CONTAINS NO ILLINOIS RIGHT TO KNOW TOXIC SUBSTANCES.
US - CONNECTICUT HAZARDOUS MATERIAL SURVEY: LISTED SUBSTANCE
2-AMINOETHANOL (CAS 141-43-5) LISTED
US - ILLINOIS CHEMICAL SAFETY ACT: LISTED SUBSTANCE
US - MASSACHUSETTS RTK - SUBSTANCE: LISTED SUBSTANCE
CONTAINS NO MASSACHUSETTS RIGHT TO KNOW SUBSTANCES.
US - NEW JERSEY COMMUNITY RTK (EHS SURVEY): LISTED SUBSTANCE
US - NEW JERSEY RTK - HAZARDOUS SUBSTANCE:
US - NEW JERSEY RTK - SPECIAL HAZARD: LISTED SUBSTANCE
2-AMINOETHANOL (CAS 141-43-5) ETHANOLAMINE SPEC_HAZAROUS
US - NEW JERSEY RTK - SUBSTANCES: LISTED SUBSTANCE
2-AMINOETHANOL (CAS 141-43-5) ETHANOLAMINE LISTED
US - PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES: LISTED SUBSTANCE
2-AMINOETHANOL (CAS 141-43-5) LISTED
US - RHODE ISLAND RTK - HAZARDOUS SUBSTANCES: LISTED SUBSTANCE
2-AMINOETHANOL (CAS 141-43-5) LISTED
CANADIAN REGULATIONS:
ALL INGREDIENTS ARE CEPA APPROVED FOR IMPORT TO CANADA BY PROCTER &
GAMBLE. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH HAZARD
CRITERIA OF THE CONTROLLED PRODUCTS REGULATIONS AND THE MSDS CONTAINS ALL
THE INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
INVENTORY STATUS:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY (YES/NO)*
UNITED STATES & TOXIC SUBSTANCES CONTROL YES
PUERTO RICO ACT (TSCA) INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
HMIS(R*) RATINGS:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
DISCLAIMER:
THIS MSDS IS INTENDED TO PROVIDE A BRIEF SUMMARY OF OUR KNOWLEDGE AND
GUIDANCE REGARDING THE USE OF THIS MATERIAL. THE INFORMATION CONTAINED
HERE HAS BEEN COMPILED FROM SOURCES CONSIDERED BY PROCTER & GAMBLE TO BE
DEPENDABLE AND IS ACCURATE TO THE BEST OF THE COMPANY'S KNOWLEDGE. IT IS
NOT MEANT TO BE AN ALL-INCLUSIVE DOCUMENT ON WORLDWIDE HAZARD
COMMUNICATION REGULATIONS.
THIS INFORMATION IS OFFERED IN GOOD FAITH. EACH USER OF THIS MATERIAL
NEEDS TO EVALUATE THE CONDITIONS OF USE AND DESIGN THE APPROPRIATE
PROTECTIVE MECHANISMS TO PREVENT EMPLOYEE EXPOSURES, PROPERTY DAMAGE OR
RELEASE TO THE ENVIRONMENT. PROCTER & GAMBLE ASSUMES NO RESPONSIBILITY
FOR INJURY TO THE RECIPIENT OR THIRD PERSONS, OR FOR ANY DAMAGE TO ANY
PROPERTY RESULTING FROM MISUSE OF THE PRODUCT.
MSDS NO.: 15154367
PRINT DATE: 01-31-2012
MSDS US PGP