| Common Name: | ULTRA DAWN BLUE (95435353), LEMON (98960813), ORANGE DISHWASHING LIQUID/ANTIBACT |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 12/20/2011 |
| SDS Format: | No Format Specified |
| Item Number(s): | 1JYZ5, 22C554 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G
MATERIAL SAFETY DATA SHEET
THE PROCTER & GAMBLE COMPANY
P&G HOUSEHOLD CARE
FABRIC & HOME CARE INNOVATION CENTER
5299 SPRING GROVE AVENUE
CINCINNATI, OH 45217-1087
MSDS #: RQ1102048
SUPERSEDES: RQ 1008529
ISSUE DATE: 12/20/2011
ISSUE DATE: 01/04/2011
| SECTION I - PRODUCT IDENTIFICATION |  |
IDENTITY:
LIQUID HAND DISHWASHING DETERGENTS AND ANTIBACTERIAL HAND SOAPS
FINISHED PRODUCT
BRANDS: ULTRA DAWN
BLUE (95435353)
LEMON (98960813)
ORANGE DISHWASHING LIQUID/ANTIBACTERIAL HAND SOAP (99697890)
APPLE BLOSSOM DISHWASHING LIQUID/ANTIBACTERIAL HAND SOAP (99697885)
EXTRA ACTION DISHWASHING LIQUID/ANTIBACTERIAL HAND SOAP (99697880)
PURE ESSENTIALS SPARKLING MIST (98822285)
PURE ESSENTIALS CITRUS INFUSION (98827120)
HONEYSUCKLE & RAIN (95064063)
JASMINE & LAVENDER (95361409)
HAWAIIAN PINEAPPLE (99618407)
THAI DRAGONFRUIT (99618406)
NEW ZEALAND SPRINGS (99618408)
MEDITERANEAN LAVENDER (99858577)
P&G TELEPHONE NUMBER: 1-800-725-3296
OR CALL LOCAL POISON CONTROL CENTER OR YOUR PHYSICIAN.
| SECTION II - HAZARDS IDENTIFICATION | |
POTENTIAL HEALTH HAZARDS (ACUTE AND CHRONIC):
(SEE SECTION 11 FOR MORE INFORMATION)
INGESTION: INGESTION MAY CAUSE TRANSIENT GASTROINTESTINAL IRRITATION.
EYE CONTACT: MAY CAUSE MILD, TRANSIENT IRRITATION.
SKIN: TRANSIENT IRRITATION WITH PROLONGED EXPOSURE TO CONCENTRATED
MATERIAL.
INHALATION: N/A
SIGNS AND SYMPTOMS OF EXPOSURE:
INGESTION: MAY RESULT IN NAUSEA, VOMITING, AND/OR DIARRHEA.
EYE CONTACT: MAY CAUSE STINGING, TEARING, ITCHING, SWELLING, AND/OR REDNESS.
SKIN:
PROLONGED CONTACT WITH CONCENTRATED MATERIAL MAY BE DRYING OR TRANSIENTLY
IRRITATING TO SKIN.
INHALATION: N/A
POTENTIAL ENVIRONMENTAL EFFECTS: (SEE SECTION 12 FOR MORE INFORMATION)
| SECTION III - COMPOSITION AND INGREDIENTS | |
INGREDIENTS LISTED ON THE PRODUCT LABEL ARE:
BIODEGRADABLE SURFACTANTS AND NO PHOSPHATE. FOR ANTIBACTERIAL HAND SOAPS,
ACTIVE INGREDIENT IS TRICLOSAN AT 0.1%. INACTIVE INGREDIENTS FOR
ANTIBACTERIAL HAND SOAPS ARE LISTED IN THE DRUG FACTS BOX ON BACK LABEL.
HAZARDOUS INGREDIENTS AS DEFINED BY OSHA, 29 CFR 1910.1200. AND/OR WHMIS
UNDER THE HPA:
CHEMICAL NAME COMMON NAME CAS NO. COMPOSITION LD50/LC50
RANGE
ETHYL ALCOHOL ETHANOL 64-17-5 1 - 5% LD50 (ORAL, RAT)
-
7.06 G/KG
ALCOHOL SODIUM 68585-34-2 10-30% LD50 (ORAL, RAT)
-
ETHOXYSULFATE, LAURETH TOTAL >2 G/KG
SODIUM SALT SULFATE ANIONIC
SURFACTANT
ALCOHOL SODIUM 68585-47-7 LD50 (ORAL, RAT)
-
SULFATES, LAURYL >2 G/KG
SODIUM SALT SULFATE
AMINES, ALKYL 70592-80-2 3 - 7% LD50 (ORAL, RAT)
-
C10-16 DIMETHYL 1.33 G/KG
ALKYLDIMETHYL, AMINE
N-OXIDES OXIDE
THESE SUBSTANCES ARE LISTED BECAUSE IN THEIR PURE BULK FORM THEY MEET THE
OSHA AND/OR WHMIS DEFINITION OF HAZARDOUS. ANY HAZARDS ASSOCIATED WITH THIS
FINISHED PRODUCT ARE LISTED IN SECTION II OF THIS MSDS.
| SECTION IV - FIRST AID INFORMATION | |
FIRST AID PROCEDURES:
INGESTION: DRINK 1 OR 2 GLASSES OF WATER.
EYE CONTACT: FLUSH THOROUGHLY WITH WATER FOR 15 MINUTES.
SKIN:
IF PROLONGED CONTACT OCCURS, RINSE THOROUGHLY WITH WATER. IF SPILLED ON
CLOTHING, CHANGE CLOTHES. IF SYMPTOMS PERSIST OR RECUR, SEEK MEDICAL
ATTENTION.
INHALATION: N/A
OTHER:
CONSUMER PRODUCT PACKAGE HAS THE FOLLOWING PRECAUTIONARY STATEMENT ON THE
BACK LABEL: "FOR EXTERNAL USE ONLY. KEEP OUT OF THE REACH OF CHILDREN. IF
DAWN GETS IN EYES, RINSE THOROUGHLY WITH WATER. IF SWALLOWED, DRINK A GLASS
OF WATER TO DILUTE."
| SECTION V - FIRE FIGHTING INFORMATION | |
FLAMMABLE PROPERTIES:
THE LIQUID HAND DISHWASHING DETERGENTS HAVE A FLASHPOINT OF 115-135 DEG. F
(46.1-57.2 DEG. C) PENSKY-MARTENS (CLOSED CUP). HOWEVER, THE DETERGENTS DO
NOT SUSTAIN COMBUSTION ACCORDING TO ASTM D4206.
FLAMMABLE PROPERTIES:
UPPER FLAMMABLE LIMIT: N/A
LOWER FLAMMABLE LIMIT: N/A
EXPLOSIVE LIMITS:
UEL: N/A
LEL: N/A
AUTO-IGNITION TEMPERATURE: N/A
HAZARDOUS COMBUSTION PRODUCTS: N/A
EXPLOSION DATA (SENSITIVITY TO MECHANICAL IMPACT): N/A
EXPLOSION DATA (SENSITIVITY TO STATIC DISCHARGE): N/A
EXTINGUISHING MEDIA:
SUITABLE: CO2, WATER OR DRY CHEMICAL MAY BE USED.
UNSUITABLE: N/K
PROTECTION OF FIREFIGHTERS:
SPECIFIC HAZARDS ARISING FROM THE MATERIAL: NONE.
| SECTION VI - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS: NONE
ENVIRONMENTAL PRECAUTIONS:
DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS. SOLUTIONS OF THE DETERGENTS MAY BE ALLOWED TO BE FLUSHED DOWN
SEWER - FIRST CHECK WITH YOUR LOCAL WATER TREATMENT PLANT. RECYCLING IS
RECOMMENDED FOR UNDILUTED SCRAP PRODUCT. DO NOT LANDFILL.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
PREVENT SPILLS FROM REACHING A WATERWAY. SORBENTS MAY BE USED. READ "WASTE
DISPOSAL METHOD" BELOW FOR FURTHER INFORMATION.
| SECTION VII - HANDLING AND STORAGE | |
PRECAUTIONS TO BE TAKEN IN HANDLING: NO SPECIAL PRECAUTIONS NECESSARY.
PRECAUTIONS TO BE TAKEN IN STORAGE: NO SPECIAL PRECAUTIONS NECESSARY.
| SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
RECOMMENDED EXPOSURE GUIDELINES:
ETHANOL (CAS# 64-17-5):
ACGIH-TLV: 1000 PPM
OSHA Z-1 PEL: 1000 PPM
ENGINEERING CONTROLS: N/A
PERSONAL PROTECTIVE EQUIPMENT (PPE): N/A
EYE/FACE PROTECTION: NONE REQUIRED WITH NORMAL HOUSEHOLD USE.
INDUSTRIAL SETTING:
FOR SPLASH PROTECTION, USE CHEMICAL GOGGLES. EYE WASH FOUNTAIN IS
RECOMMENDED.
SKIN PROTECTION: NONE REQUIRED WITH NORMAL HOUSEHOLD USE.
INDUSTRIAL SETTING:
PROTECTIVE GLOVES (RUBBER, NEOPRENE) SHOULD BE USED FOR PROLONGED DIRECT
CONTACT.
RESPIRATORY PROTECTION: NO SPECIAL PRECAUTIONS FOR CASUAL EXPOSURE.
VENTILATION:
LOCAL EXHAUST: NONE REQUIRED WITH NORMAL CONSUMER USE.
INDUSTRIAL (GENERAL): NORMAL/GENERAL DILUTION VENTILATION IS ACCEPTABLE.
SPECIAL: NONE
OTHER: NONE
| SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE (COLOR, PHYSICAL FORM, SHAPE): CLEAR, OPAQUE OR COLORED LIQUIDS.
ODOR: PERFUMED
ODOR THRESHOLD: N/A
PHYSICAL STATE: LIQUID HAND DISHWASHING SOLUTION
VAPOR PRESSURE (MMHg): N/K
VAPOR DENSITY (AIR=1): N/K
BOILING POINT: N/K
PARTITION COEFFICIENT (n-OCTANOL/WATER): N/K
FLASH POINT (METHOD USED):
115-135 DEG. F (46.1-57.2 DEG. C) PENSKY-MARTENS (CLOSED CUP) BUT DO NOT
SUSTAIN COMBUSTION ACCORDING TO ASTM D4206.
RESERVE ALKALINITY: N/A
SOLUBILITY IN WATER: COMPLETE
DECOMPOSITION TEMPERATURE: N/K
EVAPORATION RATE (nBuOAc=1): N/K
SPECIFIC GRAVITY/DENSITY: CA. 1
MELTING/FREEZING POINT: APPROX. 30 DEG. F (-1.1 DEG. C)
pH (10% SOLUTION): 9
VOLATILE ORGANIC COMPOUND (VOC):
NOT APPLICABLE - PRODUCT NOT REGULATED FOR VOC CONTENT AT STATE OR FEDERAL
LEVEL
| SECTION X - STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: STABLE
CONDITIONS TO AVOID: NONE KNOWN
INCOMPATIBLE MATERIALS: NONE
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN
POSSIBILITY OF HAZARDOUS REACTIONS: NONE KNOWN
| SECTION XI - TOXICOLOGICAL INFORMATION | |
LIQUID HAND DISHWASHING DETERGENTS HAVE A RELATIVELY LOW ORDER OF TOXICITY,
MAY CAUSE TRANSIENT IRRITATION AND ARE EXPECTED TO BE EMETIC.
CHRONIC EFFECTS: NO CHRONIC HEALTH EFFECTS REPORTED.
TARGET ORGANS: NO TARGET ORGANS REPORTED.
CARCINOGENICITY: THIS FINISHED PRODUCT IS NOT CARCINOGENIC.
NTP: NO
IARC: NO
OSHA: NO
| SECTION XII - ECOLOGICAL INFORMATION | |
ALL SURFACTANTS ARE READILY BIODEGRADABLE.
| SECTION XIII - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
DISPOSAL SHOULD BE IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL AND LOCAL
REGULATIONS
NON HOUSEHOLD SETTING:
PRODUCTS COVERED BY THIS MSDS, IN THEIR ORIGINAL FORM, WHEN DISPOSED AS
WASTE, ARE CONSIDERED NON HAZARDOUS WASTE ACCORDING TO FEDERAL RCRA
REGULATIONS (40 CFR 261). DISPOSAL SHOULD BE IN ACCORDANCE WITH LOCAL,
STATE AND FEDERAL REGULATIONS. SOLUTIONS OF DILUTED DETERGENT IN THE COURSE
OF USE, MAY BE ALLOWED TO BE FLUSHED DOWN SEWER. FIRST CHECK WITH YOUR
LOCAL WATER TREATMENT PLANT. RECYCLING IS RECOMMENDED FOR UNDILUTED SCRAP
PRODUCT. DO NOT LANDFILL.
CALIFORNIA HAZARDOUS WASTE:
NOT HAZARDOUS, IN ACCORDANCE WITH 22 CCR 66261.20 THROUGH 22 CCR 66261.24
HOUSEHOLD USE:
HOUSEHOLD PRODUCT IS SAFE FOR DISPOSAL DOWN THE DRAIN DURING DETERGENT USE
OR IN THE TRASH. DISPOSE OF EMPTY BOTTLE IN THE TRASH OR RECYCLE WHERE
FACILITIES EXIST.
| SECTION XIV - TRANSPORT INFORMATION | |
PRODUCTS COVERED BY THIS MSDS, IN THEIR ORIGINAL FORM, ARE NOT REGULATED
FOR TRANSPORTATION.
GROUND TRANSPORT (US DOT): NOT REGULATED
AIR TRANSPORT (IATA): NOT REGULATED
MARINE/WATER TRANSPORT (IMDG): NOT REGULATED
| SECTION XV - REGULATORY INFORMATION | |
UNITED STATES:
ALL INTENTIONALLY-ADDED COMPONENTS OF THIS PRODUCT ARE LISTED ON THE US
TSCA INVENTORY.
THIS PRODUCT IS NOT SUBJECT TO WARNING LABELING UNDER CALIFORNIA
PROPOSITION 65.
EPA REG. NO.: NOT APPLICABLE
THIS PRODUCT CONTAINS THE FOLLOWING SARA 313/302/304/311/312 CHEMICALS:
NONE
THIS PRODUCT CONTAINS THE FOLLOWING CERCLA CHEMICALS:
CHEMICAL NAME CAS NUMBER MAX RANGE IN PRODUCT (%)
ETHANOL 64-17-5 5.0%
STATE RIGHT-TO-KNOW:
THE FOLLOWING INGREDIENTS PRESENT IN THE FINISHED PRODUCT ARE LISTED ON
STATE RIGHT-TO-KNOW LISTS OR STATE WORKER EXPOSURE LISTS:
INGREDIENT CAS # MAX LEVEL STATE
IL MA NJ PA RI
ETHANOL 64-17-5 5.0% X X X X X
PERFUMES CONTAINED WITHIN THE PRODUCTS COVERED BY THIS MSDS COMPLY WITH
APPROPRIATE IFRA GUIDANCE
CANADA:
ALL INGREDIENTS ARE CEPA APPROVED FOR IMPORT TO CANADA BY PROCTER & GAMBLE.
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THIS MSDS CONTAINS
ALL INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
| SECTION XVI - OTHER INFORMATION | |
PERFUMES CONTAINED WITHIN THE PRODUCTS COVERED BY THIS MSDS COMPLY WITH
APPROPRIATE IFRA GUIDANCE.
P&G HAZARD RATING:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
4=EXTREME
3=HIGH
2=MODERATE
1=SLIGHT
0=NOT SIGNIFICANT
*N/A. - NOT APPLICABLE
*N/K. - NOT KNOWN
DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND
HEALTH.
DISCLAIMER:
THIS MSDS IS INTENDED TO PROVIDE A BRIEF SUMMARY OF OUR KNOWLEDGE AND
GUIDANCE REGARDING THE USE OF THIS MATERIAL. THE INFORMATION CONTAINED HERE
HAS BEEN COMPILED FROM SOURCES CONSIDERED BY PROCTER & GAMBLE TO BE
DEPENDABLE AND IS ACCURATE TO THE BEST OF THE COMPANY'S KNOWLEDGE. IT IS
NOT MEANT TO BE AN ALL-INCLUSIVE DOCUMENT ON WORLDWIDE HAZARD COMMUNICATION
REGULATIONS.
THIS INFORMATION IS OFFERED IN GOOD FAITH. EACH USER OF THIS MATERIAL NEEDS
TO EVALUATE THE CONDITIONS OF USE AND DESIGN THE APPROPRIATE PROTECTIVE
MECHANISMS TO PREVENT EMPLOYEE EXPOSURES, PROPERTY DAMAGE OR RELEASE TO THE
ENVIRONMENT. PROCTER & GAMBLE ASSUMED NO RESPONSIBILITY FOR INJURY TO THE
RECIPIENT OR THIRD PERSONS, OR FOR ANY DAMAGE TO ANY PROPERTY RESULTING
FROM MISUSE OF THE PRODUCT.
ULTRA DAWN HAND DISHWASHING LIQUIDS AND ANTIBACTERIAL HAND SOAPS