| Common Name: | WASP AND HORNET KILLER PLUS 14010 |
| Manufacturer: | CRC |
| SDS Revision Date: | 10/5/2011 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4JB47 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CRC(R*)
MATERIAL SAFETY DATA SHEET
| SECTION 1: PRODUCT & COMPANY IDENTIFICATION |  |
PRODUCT NAME: CRC(R*) WASP AND HORNET KILLER PLUS(TM)
PRODUCT NUMBER (S): 14010
PRODUCT USE: WASP AND HORNET INSECTICIDE
MANUFACTURER / SUPPLIER CONTACT INFORMATION:
IN UNITED STATES:
CRC INDUSTRIES, INC.
885 LOUIS DRIVE
WARMINSTER, PA 18974
WWW.CRCINDUSTRIES.COM
1-215-674-4300 (GENERAL)
(800) 521-3168 (TECHNICAL)
(800) 272-4620 (CUSTOMER SERVICE)
IN CANADA:
CRC CANADA CO.
2-1246 LORIMAR DRIVE
MISSISSAUGA, ONTARIO L5S 1R2
WWW.CRC-CANADA.CA
1-905-670-2291
IN MEXICO:
CRC INDUSTRIES MEXICO
AV. BENITO JUAREZ 4055 G
COLONIA ORQUIDEA
SAN LUIS POTOSIO, SLP CP 78394
WWW.CRC-MEXICO.COM
52-444-824-1666
24-HR EMERGENCY - CHEMTREC: (800) 424-9300 OR (703) 527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
CAUTION:
FLAMMABLE. HARMFUL OR FATAL IF SWALLOWED. EYE IRRITANT. CONTENTS UNDER
PRESSURE.
APPEARANCE & ODOR: CLEAR LIQUID, PETROLEUM ODOR
POTENTIAL HEALTH EFFECTS:
ACUTE EFFECTS:
EYE: MAY CAUSE MODERATE EYE IRRITATION.
SKIN:
MAY CAUSE SKIN IRRITATION. PROLONGED CONTACT MAY ALLOW MATERIAL TO BE
ABSORBED THROUGH THE SKIN.
INHALATION:
MAY CAUSE RESPIRATORY IRRITATION. OVEREXPOSURE TO VAPORS MAY LEAD TO CENTRAL
NERVOUS SYSTEM EFFECTS SUCH AS HEADACHE AND DROWSINESS, FOLLOWED BY
DIZZINESS AND NAUSEA.
INGESTION:
MAY CAUSE GASTROINTESTINAL DISCOMFORT OR IRRITATION OF THE THROAT.
ASPIRATION OF THIS MATERIAL INTO THE LUNGS, EITHER WHILE SWALLOWING OR
VOMITING, MAY LEAD TO CHEMICAL PNEUMONITIS, WHICH COULD BE FATAL. SIGNS OF
LUNG INVOLVEMENT INCLUDE INCREASED RESPIRATORY RATE, INCREASED HEART RATE,
AND A BLUISH DISCOLORATION OF THE SKIN.
CHRONIC EFFECTS: REPEATED SKIN CONTACT MAY CAUSE CONTACT DERMATITIS.
TARGET ORGANS: CENTRAL NERVOUS SYSTEM
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: PRE-EXISTING SKIN CONDITIONS
SEE SECTION 11 FOR TOXICOLOGY AND CARCINOGENICITY INFORMATION ON PRODUCT
INGREDIENTS.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS NUMBER % BY WT.
HYDROTREATED LIGHT DISTILLATE 64742-47-8 90 - 100
TETRAMETHRIN 7696-12-0 0.200
PHENOTHRIN 26002-80-2 0.125
CARBON DIOXIDE 124-38-9 1 - 5
| SECTION 4: FIRST AID MEASURES | |
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. CALL A PHYSICIAN IF
IRRITATION PERSISTS.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND WASH AFFECTED AREA WITH SOAP AND WATER.
CALL A PHYSICIAN IF IRRITATION PERSISTS. WASH CONTAMINATED CLOTHING PRIOR TO
RE-USE.
INHALATION:
REMOVE PERSON TO FRESH AIR. KEEP PERSON CALM. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT GIVE OXYGEN. CALL A
PHYSICIAN.
INGESTION:
DO NOT INDUCE VOMITING DUE TO ASPIRATION HAZARD. IF VOMITING OCCURS, LOWER
HEAD BELOW KNEES TO AVOID ASPIRATION. SEEK IMMEDIATE MEDICAL ATTENTION.
NOTE TO PHYSICIANS: TREAT SYMPTOMATICALLY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
FLAMMABLE PROPERTIES:
THIS PRODUCT IS FLAMMABLE IN ACCORDANCE WITH AEROSOL FLAMMABILITY
DEFINITIONS.(SEE 16 CFR 1500.3(C)(6)).
FLASH POINT: 205 DEG. F / 96 DEG. C (PMCC)
AUTOIGNITION TEMPERATURE: ND
UPPER EXPLOSIVE LIMIT: 5.0
LOWER EXPLOSIVE LIMIT: 0.7
FIRE AND EXPLOSION DATA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHERS APPROPRIATE FOR A CLASS B FIRE.
PRODUCTS OF COMBUSTION: OXIDES OF CARBON
EXPLOSION HAZARDS:
AEROSOL CONTAINERS, WHEN EXPOSED TO HEAT FROM FIRE, MAY BUILD PRESSURE AND
EXPLODE.
PROTECTION OF FIRE-FIGHTERS:
FIREFIGHTERS SHOULD WEAR SELF-CONTAINED, NIOSH-APPROVED BREATHING APPARATUS
FOR PROTECTION AGAINST SUFFOCATION AND POSSIBLE TOXIC DECOMPOSITION
PRODUCTS.PROPER EYE AND SKIN PROTECTION SHOULD BE PROVIDED. USE WATER SPRAY
TO KEEPFIRE-EXPOSED CONTAINERS COOL AND TO KNOCK DOWN VAPORS WHICH MAY
RESULT FROM PRODUCT DECOMPOSITION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS: USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8.
ENVIRONMENTAL PRECAUTIONS:
TAKE PRECAUTIONS TO PREVENT CONTAMINATION OF GROUND AND SURFACE WATERS. DO
NOT FLUSH INTO SEWERS OR STORM DRAINS.
METHODS FOR CONTAINMENT & CLEAN-UP:
DIKE AREA TO CONTAIN SPILL. VENTILATE THE AREA WITH FRESH AIR. IF IN
CONFINED SPACE OR LIMITED AIR CIRCULATION AREA, CLEAN-UP WORKERS SHOULD WEAR
APPROPRIATE RESPIRATORY PROTECTION. RECOVER OR ABSORB SPILLED MATERIAL USING
AN ABSORBENT DESIGNED FOR CHEMICAL SPILLS. PLACE USED ABSORBENTS INTO PROPER
WASTE CONTAINERS.
| SECTION 7: HANDLING AND STORAGE | |
HANDLING PROCEDURES:
AVOID BREATHING VAPORS. USE OUTSIDE OR WITH ADEQUATE VENTILATION. AVOID
CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT USE NEAR SPARKS, OPEN FLAMES OR
OTHER SOURCES OF IGNITION. USE CAUTION AROUND ENERGIZED EQUIPMENT. THE METAL
CONTAINER WILL CONDUCT ELECTRICITY IF IT CONTACTS A LIVE SOURCE. THIS MAY
RESULT IN INJURY TO THE USER FROM ELECTRICAL SHOCK AND/OR FLASH FIRE. FOR
PRODUCT USE INSTRUCTIONS, PLEASE SEE THE PRODUCT LABEL.
STORAGE PROCEDURES:
STORE IN A COOL DRY AREA OUT OF DIRECT SUNLIGHT. AEROSOL CANS MUST BE
MAINTAINED BELOW 120 DEG. F / 49 DEG. C TO PREVENT CANS FROM RUPTURING.
AEROSOL STORAGE LEVEL: III
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
COMPONENT OSHA ACGIH OTHER UNIT
TWA STEL TWA STEL TWA SOURCE
HYDROTREATED NE NE NE NE NE
LIGHT DISTILLATE
TETRAMETHRIN NE NE NE NE NE
PHENOTHRIN NE NE NE NE NE
CARBON DIOXIDE 5000 NE 5000 30000 NE PPM
N.E. - NOT ESTABLISHED
(C) - CEILING
(S) - SKIN
(V) - VACATED
CONTROLS AND PROTECTION:
ENGINEERING CONTROLS:
AREA SHOULD HAVE VENTILATION TO PROVIDE FRESH AIR. LOCAL EXHAUST VENTILATION
IS GENERALLY PREFERRED BECAUSE IT CAN CONTROL THE EMISSIONS OF THE
CONTAMINANT AT THE SOURCE, PREVENTING DISPERSION INTO THE GENERAL WORK AREA.
USE MECHANICAL MEANS IF NECESSARY TO MAINTAIN VAPOR LEVELS BELOW THE
EXPOSURE GUIDELINES. IF WORKING IN A CONFINED SPACE, FOLLOW APPLICABLE OSHA
REGULATIONS.
RESPIRATORY PROTECTION:
NONE REQUIRED FOR NORMAL WORK WHERE ADEQUATE VENTILATION IS PROVIDED. IF
ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE APPLICABLE
EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH ORGANIC
VAPOR CARTRIDGE. AIR MONITORING IS NEEDED TO DETERMINE ACTUAL EMPLOYEE
EXPOSURE LEVELS. USE A SELF-CONTAINED BREATHING APPARATUS IN CONFINED SPACES
AND FOR EMERGENCIES.
EYE/FACE PROTECTION:
FOR NORMAL CONDITIONS, WEAR SAFETY GLASSES. WHERE THERE IS REASONABLE
PROBABILITY OF LIQUID CONTACT, WEAR SPLASH-PROOF GOGGLES.
SKIN PROTECTION:
USE PROTECTIVE GLOVES SUCH AS NEOPRENE OR NITRILE. ALSO, USE FULL PROTECTIVE
CLOTHING IF THERE IS PROLONGED OR REPEATED CONTACT OF LIQUID WITH SKIN.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: CLEAR
ODOR: PETROLEUM
ODOR THRESHOLD: ND
SPECIFIC GRAVITY: 0.79
INITIAL BOILING POINT: 435 DEG. F / 224 DEG. C
FREEZING POINT: ND
VAPOR PRESSURE: <0.1 MMHg @ 68 DEG. F / 20 DEG. C
VAPOR DENSITY: >2 (AIR = 1)
EVAPORATION RATE: SLOW
SOLUBILITY: NEGLIGIBLE IN WATER
COEFFICIENT OF WATER/OIL DISTRIBUTION: ND
pH: NA
VOLATILE ORGANIC COMPOUNDS:
WT %: 1.4
G/L: 11.06
LBS./GAL: 0.09
| SECTION 10: STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: TEMPERATURE EXTREMES; SOURCES OF IGNITION
INCOMPATIBLE MATERIALS: STRONG ACIDS, BASES AND OXIDIZERS
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON
POSSIBILITY OF HAZARDOUS REACTIONS: NO
| SECTION 11: TOXICOLOGICAL INFORMATION | |
LONG-TERM TOXICOLOGICAL STUDIES HAVE NOT BEEN CONDUCTED FOR THIS PRODUCT.
THE FOLLOWING INFORMATION IS AVAILABLE FOR COMPONENTS OF THIS PRODUCT.
ACUTE TOXICITY:
COMPONENT ORAL LD50 (RAT) DERMAL LD50 INHALATION LC50(RAT)
HYDROTREATED >5 G/KG >2 G/KG (RABBIT) >5 MG/L/4H
LIGHT DISTILLATE
ACTIVE INGREDIENT >6.31 G/KG >2 G/KG (RAT) >5.34 MG/L
MIXTURE
CARBON DIOXIDE NO DATA NO DATA 470,000 PPM/30M
CHRONIC TOXICITY:
COMPONENT OSHA IARC NTP IRRITANT SENSITIZER
CARCINOGEN CARCINOGEN CARCINOGEN
HYDROTREATED NO NO NO E (MILD) / UNKNOWN
LIGHT S (MODERATE)
DISTILLATE
ACTIVE NO NO NO E & R (MILD) / NO
INGREDIENT S (MODERATE)
MIXTURE
CARBON NO NO NO NO NO
DIOXIDE
E - EYE
S - SKIN
R - RESPIRATORY
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE
TERATOGENICITY: NO INFORMATION AVAILABLE
MUTAGENICITY: NO INFORMATION AVAILABLE
SYNERGISTIC EFFECTS: NO INFORMATION AVAILABLE
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOLOGICAL STUDIES HAVE NOT BEEN CONDUCTED FOR THIS PRODUCT. THE FOLLOWING
INFORMATION IS AVAILABLE FOR COMPONENTS OF THIS PRODUCT.
ECOTOXICITY: NO INFORMATION AVAILABLE
PERSISTENCE / DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATION / ACCUMULATION: NO INFORMATION AVAILABLE
MOBILITY IN ENVIRONMENT: NO INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
WASTE CLASSIFICATION:
THE DISPENSED LIQUID PRODUCT IS NOT A RCRA HAZARDOUS WASTE. FULL OR PARTIAL
FULL CONTAINERS SHOULD BE PUNCTURED AND DRAINED. EMPTY CONTAINERS MAY BE
RECYCLED OR DISCARDED. CONTACT YOUR STATE OR LOCAL REGULATORY AGENCY FOR
MORE DETAILS.
ALL DISPOSAL ACTIVITIES MUST COMPLY WITH FEDERAL, STATE, PROVINCIAL AND
LOCAL REGULATIONS. LOCAL REGULATIONS MAY BE MORE STRINGENT THAN STATE,
PROVINCIAL OR NATIONAL REQUIREMENTS.
| SECTION 14: TRANSPORT INFORMATION | |
US DOT (GROUND): CONSUMER COMMODITY, ORM-D
ICAO/IATA (AIR): CONSUMER COMMODITY, ID8000, 9
IMO/IMDG (WATER): AEROSOLS, UN1950, 2.1, LIMITED QUANTITY
SPECIAL PROVISIONS: NONE
| SECTION 15: REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TOXIC SUBSTANCES CONTROL ACT (TSCA):
ALL INGREDIENTS ARE EITHER LISTED ON THE TSCA INVENTORY OR ARE EXEMPT.
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT
(CERCLA):
REPORTABLE QUANTITIES (RQ'S) EXIST FOR THE FOLLOWING INGREDIENTS: NONE
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS
RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
SUPERFUND AMENDMENTS REAUTHORIZATION ACT (SARA) TITLE III:
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (EHS): NONE
SECTION 311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
REACTIVE HAZARD: NO
RELEASE OF PRESSURE: YES
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
SECTION 313 TOXIC CHEMICALS:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
TETRAMETHRIN (0.200%), PHENOTHRIN (0.125%)
CLEAN AIR ACT:
SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS): NONE
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION:
THIS PRODUCT IS REGULATED BY THE HAZARD COMMUNICATIONS STANDARD.
U.S. STATE REGULATIONS:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROP 65):
THIS PRODUCT MAY CONTAIN THE FOLLOWING CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: NONE
CONSUMER PRODUCTS VOC REGULATIONS:
IN STATES WITH CONSUMER PRODUCTS VOC REGULATIONS, THIS PRODUCT IS COMPLIANT
UNDER THE FOLLOWING CATEGORIES:
WASP & HORNET INSECTICIDE AND CRAWLING BUG INSECTICIDE
STATE RIGHT TO KNOW:
NEW JERSEY: 7696-12-0, 26002-80-2, 95-63-6 (<0.5%)
PENNSYLVANIA: 95-63-6 (<0.5%)
MASSACHUSETTS: NONE
RHODE ISLAND: NONE
CANADIAN REGULATIONS:
CONTROLLED PRODUCTS REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS AND THE MSDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
WHMIS HAZARD CLASS: A, B5, D2B
CANADIAN DSL INVENTORY:
ALL INGREDIENTS ARE EITHER LISTED ON THE DSL INVENTORY OR ARE EXEMPT.
EUROPEAN UNION REGULATIONS:
ROHS COMPLIANCE:
THIS PRODUCT IS COMPLIANT WITH DIRECTIVE 2002/95/EC OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL OF 27 JANUARY 2003. THIS PRODUCT DOES NOT
CONTAIN ANY OF THE RESTRICTED SUBSTANCES AS LISTED IN ARTICLE 4(1) OF THE
ROHS DIRECTIVE.
ADDITIONAL REGULATORY INFORMATION:
EPA (FIFRA) REGISTRATION # 55809-3. THIS PRODUCT IS REGISTERED IN ALL 50
UNITED STATES AND PUERTO RICO. WASP AND HORNET KILLER PLUS(TM) IS NOT
REGISTERED AND CANNOT BE SOLD OUTSIDE OF THE UNITED STATES AND PUERTO RICO.
| SECTION 16: OTHER INFORMATION | |
HMIS(R*) (II):
HEALTH 2
FLAMMABILITY 2
REACTIVITY 0
PPE B
NFPA:
2
2
0
RATINGS RANGE FROM 0 (NO HAZARD) TO 4 (SEVERE HAZARD)
PREPARED BY: MICHELLE RUDNICK
CRC #: 431J
REVISION DATE: 10/05/2011
CHANGES SINCE LAST REVISION:
SECTION 15: ADDITIONAL REGULATORY INFORMATION
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC MATERIAL
AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED IN
COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO THE
BEST OF CRC INDUSTRIES' KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY CRC
TO BE ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND DIRECTIONS
ON THE LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION CONTAINED ON THIS
MSDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY PROFESSIONAL, OR CRC
INDUSTRIES.
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
CAS: CHEMICAL ABSTRACT SERVICE
CFR: CODE OF FEDERAL REGULATIONS
DOT: DEPARTMENT OF TRANSPORTATION
DSL: DOMESTIC SUBSTANCE LIST
G/L: GRAMS PER LITER
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
IMO: INTERNATIONAL MARITIME ORGANIZATION
LBS./GAL: POUNDS PER GALLON
LC: LETHAL CONCENTRATION
LD: LETHAL DOSE
NA: NOT APPLICABLE
ND: NOT DETERMINED
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY & HEALTH
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NTP: NATIONAL TOXICOLOGY PROGRAM
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PMCC: PENSKY-MARTENS CLOSED CUP
PPE: PERSONAL PROTECTION EQUIPMENT
PPM: PARTS PER MILLION
ROHS: RESTRICTION OF HAZARDOUS SUBSTANCES
STEL: SHORT TERM EXPOSURE LIMIT
TCC: TAG CLOSED CUP
TWA: TIME WEIGHTED AVERAGE
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM