| Common Name: | TITEBOND PROVANTAGE TUB SURROUND ADHESIVE, 2431 |
| Manufacturer: | FRANKLIN INTERNATIONAL |
| SDS Revision Date: | 10/22/2010 |
| SDS Format: | No Format Specified |
| Item Number(s): | 5JGV1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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FRANKLIN INTERNATIONAL
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: TITEBOND PROVANTAGE TUB SURROUND ADHESIVE
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
ADDRESS:
FRANKLIN INTERNATIONAL
2020 BRUCK STREET
COLUMBUS, OH 43207
CONTACT PERSON: FRANKLIN TECHNICAL SERVICES
TELEPHONE: (800) 877-4583
EMERGENCY PHONE:
FRANKLIN SECURITY: (614) 445-1300
PRODUCT CODE: 2431
DATE OF REVISION: 10/22/2010.
PRINT DATE: 10/22/2010.
CHEMTREC (24 HOUR): (800) 424-9300
CHEMTREC INTERNATIONAL: (703) 527-3887
PRODUCT USE: CONSTRUCTION ADHESIVE
PRODUCT TYPE: PROPRIETARY POLYMER
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL STATE: LIQUID. [PASTE.]
ODOR: SOLVENT(S) [STRONG]
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
EMERGENCY OVERVIEW:
DANGER!
EXTREMELY FLAMMABLE LIQUID AND VAPOR. FLAMMABLE. VAPOR MAY CAUSE FLASH
FIRE. CAUSES DIGESTIVE TRACT BURNS. HARMFUL IF INHALED. CAUSES RESPIRATORY
TRACT AND SKIN IRRITATION. MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF
SWALLOWED. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION.
POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER.
EXTREMELY FLAMMABLE LIQUID. HARMFUL BY INHALATION. CORROSIVE TO THE
DIGESTIVE TRACT. CAUSES BURNS. MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR
IF SWALLOWED. IRRITATING TO RESPIRATORY SYSTEM AND SKIN. MODERATELY
IRRITATING TO EYES. DEFATTING TO THE SKIN. KEEP AWAY FROM HEAT, SPARKS AND
FLAME. DO NOT BREATHE VAPOR OR MIST. DO NOT INGEST. DO NOT GET IN EYES.
AVOID CONTACT WITH SKIN AND CLOTHING. CONTAINS MATERIAL WHICH MAY CAUSE
CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL OF EXPOSURE. USE ONLY
WITH ADEQUATE VENTILATION. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL
READY FOR USE. WASH THOROUGHLY AFTER HANDLING.
ROUTES OF ENTRY: DERMAL CONTACT. EYE CONTACT. INHALATION. INGESTION.
POTENTIAL ACUTE HEALTH EFFECTS:
INHALATION:
TOXIC BY INHALATION. IRRITATING TO RESPIRATORY SYSTEM. EXPOSURE TO
DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SERIOUS EFFECTS MAY BE
DELAYED FOLLOWING EXPOSURE. INHALATION CAUSES HEADACHES, DIZZINESS,
DROWSINESS AND NAUSEA AND MAY LEAD TO UNCONSCIOUSNESS.
INGESTION:
HARMFUL IF SWALLOWED. CORROSIVE TO THE DIGESTIVE TRACT. CAUSES BURNS.
SKIN:
HARMFUL IN CONTACT WITH SKIN. IRRITATING TO SKIN. PROLONGED OR REPEATED
CONTACT CAN DEFAT THE SKIN AND LEAD TO IRRITATION, CRACKING AND/OR
DERMATITIS.
EYES:
MODERATELY IRRITATING TO EYES. THIS PRODUCT MAY IRRITATE EYES UPON CONTACT.
POTENTIAL CHRONIC HEALTH EFFECTS:
CHRONIC EFFECTS:
PROLONGED OR REPEATED CONTACT CAN DEFAT THE SKIN AND LEAD TO IRRITATION,
CRACKING AND/OR DERMATITIS.
CARCINOGENICITY:
CONTAINS MATERIAL WHICH MAY CAUSE CANCER. RISK OF CANCER DEPENDS ON
DURATION AND LEVEL OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TARGET ORGANS:
CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS:
GASTROINTESTINAL TRACT, EYE, LENS OR CORNEA.
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS:
KIDNEYS, LUNGS, LIVER, MUCOUS MEMBRANES, PERIPHERAL NERVOUS SYSTEM, UPPER
RESPIRATORY TRACT, SKIN, CENTRAL NERVOUS SYSTEM (CNS), NOSE/SINUSES.
OVER-EXPOSURE SIGNS/SYMPTOMS:
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
STOMACH PAINS
SKIN:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
DRYNESS
CRACKING
EYES:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
WATERING
REDNESS
MEDICAL CONDITIONS AGGRAVATED BY OVER-EXPOSURE: NONE KNOWN.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
UNITED STATES:
NAME CAS NUMBER %
METHYL ACETATE 79-20-9 10 - 25
OXYDIPROPYL DIBENZOATE 27138-31-4 5 - 10
DIETHYLENE OXIMIDE 110-91-8 1 - 5
VINYL ACETATE 108-05-4 0.1 - 0.5
CANADA:
NAME CAS NUMBER %
METHYL ACETATE 79-20-9 10 - 25
OXYDIPROPYL DIBENZOATE 27138-31-4 5 - 10
DIETHYLENE OXIMIDE 110-91-8 1 - 5
METHANOL 67-56-1 0.1 - 0.5
VINYL ACETATE 108-05-4 0.1 - 0.5
MEXICO:
NAME CAS NUMBER UN NUMBER % IDLH CLASSIFICATION
H F R SPECIAL
DIETHYLENE 110-91-8 2054 1 - 5 1400 PPM 3 3 0
OXIMIDE
OXYDIPROPYL 27138-31-4 NOT 5 - 10 2 0 0
DIBENZOATE AVAILABLE.
METHYL 79-20-9 UN1993 10 - 25 3100 PPM 0 3 0
ACETATE
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
| 4. FIRST AID MEASURES | |
EYE CONTACT:
CHECK FOR AND REMOVE ANY CONTACT LENSES. IMMEDIATELY FLUSH EYES WITH PLENTY
OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING THE UPPER AND LOWER
EYELIDS. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH
CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE. GET MEDICAL
ATTENTION IMMEDIATELY.
INHALATION:
MOVE EXPOSED PERSON TO FRESH AIR. IF NOT BREATHING, IF BREATHING IS
IRREGULAR OR IF RESPIRATORY ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION
OR OXYGEN BY TRAINED PERSONNEL. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR,
TIE, BELT OR WAISTBAND. GET MEDICAL ATTENTION IMMEDIATELY.
INGESTION:
WASH OUT MOUTH WITH WATER. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO
BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL ATTENTION IMMEDIATELY.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE
DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE
FOR 48 HOURS.
| 5. FIRE-FIGHTING MEASURES | |
FLAMMABILITY OF THE PRODUCT:
EXTREMELY FLAMMABLE LIQUID. IN A FIRE OR IF HEATED, A PRESSURE INCREASE
WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A SUBSEQUENT
EXPLOSION.
EXTINGUISHING MEDIA:
SUITABLE: USE DRY CHEMICAL, CO2, WATER SPRAY (FOG) OR FOAM.
NOT SUITABLE: DO NOT USE WATER JET.
SPECIAL EXPOSURE HAZARDS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF THE
INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
SHUT OFF ALL IGNITION SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD AREA.
DO NOT BREATHE VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8).
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DISPOSE OF VIA A LICENSED WASTE
DISPOSAL CONTRACTOR. ABSORB WITH AN INERT MATERIAL.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR
CONFINED AREAS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE,
ABSORBENT MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND
PLACE IN CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION
13). USE SPARK-PROOF TOOLS AND EXPLOSION-PROOF EQUIPMENT. DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). EATING,
DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS MATERIAL IS
HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND FACE BEFORE
EATING, DRINKING AND SMOKING. DO NOT GET IN EYES OR ON SKIN OR CLOTHING. DO
NOT BREATHE VAPOR OR MIST. DO NOT INGEST. USE ONLY WITH ADEQUATE
VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. DO
NOT ENTER STORAGE AREAS AND CONFINED SPACES UNLESS ADEQUATELY VENTILATED.
KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE FROM A
COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. STORE AND USE
AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE. USE
EXPLOSION-PROOF ELECTRICAL (VENTILATING, LIGHTING AND MATERIAL HANDLING)
EQUIPMENT. USE NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST
ELECTROSTATIC DISCHARGES. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN
BE HAZARDOUS. DO NOT REUSE CONTAINER.
STORAGE:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN A SEGREGATED AND
APPROVED AREA. STORE IN ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT
IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10) AND FOOD AND DRINK. ELIMINATE ALL IGNITION SOURCES.
SEPARATE FROM OXIDIZING MATERIALS. KEEP CONTAINER TIGHTLY CLOSED AND SEALED
UNTIL READY FOR USE. CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY
RESEALED AND KEPT UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED
CONTAINERS. USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL
CONTAMINATION.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
UNITED STATES:
INGREDIENT EXPOSURE LIMITS
METHYL ACETATE ACGIH TLV (UNITED STATES, 2/2010).
TWA: 200 PPM 8 HOUR(S).
TWA: 606 MG/M3 8 HOUR(S).
STEL: 250 PPM 15 MINUTE(S).
STEL: 757 MG/M3 15 MINUTE(S).
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 200 PPM 8 HOUR(S).
TWA: 610 MG/M3 8 HOUR(S).
STEL: 250 PPM 15 MINUTE(S).
STEL: 760 MG/M3 15 MINUTE(S).
NIOSH REL (UNITED STATES, 6/2009).
TWA: 200 PPM 10 HOUR(S).
TWA: 610 MG/M3 10 HOUR(S).
STEL: 250 PPM 15 MINUTE(S).
STEL: 760 MG/M3 15 MINUTE(S).
OSHA PEL (UNITED STATES, 6/2010).
TWA: 200 PPM 8 HOUR(S).
TWA: 610 MG/M3 8 HOUR(S).
DIETHYLENE OXIMIDE ACGIH TLV (UNITED STATES, 2/2010).
ABSORBED THROUGH SKIN.
TWA: 20 PPM 8 HOUR(S).
TWA: 71 MG/M3 8 HOUR(S).
OSHA PEL 1989 (UNITED STATES, 3/1989).
ABSORBED THROUGH SKIN.
TWA: 20 PPM 8 HOUR(S).
TWA: 70 MG/M3 8 HOUR(S).
STEL: 30 PPM 15 MINUTE(S).
STEL: 105 MG/M3 15 MINUTE(S).
NIOSH REL (UNITED STATES, 6/2009).
ABSORBED THROUGH SKIN.
TWA: 20 PPM 10 HOUR(S).
TWA: 70 MG/M3 10 HOUR(S).
STEL: 30 PPM 15 MINUTE(S).
STEL: 105 MG/M3 15 MINUTE(S).
OSHA PEL (UNITED STATES, 6/2010).
ABSORBED THROUGH SKIN.
TWA: 20 PPM 8 HOUR(S).
TWA: 70 MG/M3 8 HOUR(S).
VINYL ACETATE ACGIH TLV (UNITED STATES, 2/2010).
TWA: 10 PPM 8 HOUR(S).
TWA: 35 MG/M3 8 HOUR(S).
STEL: 15 PPM 15 MINUTE(S).
STEL: 53 MG/M3 15 MINUTE(S).
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 10 PPM 8 HOUR(S).
TWA: 30 MG/M3 8 HOUR(S).
STEL: 20 PPM 15 MINUTE(S).
STEL: 60 MG/M3 15 MINUTE(S).
NIOSH REL (UNITED STATES, 6/2009).
CEIL: 4 PPM 15 MINUTE(S).
CEIL: 15 MG/M3 15 MINUTE(S).
CANADA:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT LIST NAME TWA (8 HOURS) STEL (15 MINS)
PPM MG/M3 OTHER PPM MG/M3 OTHER
METHYL ACETATE US ACGIH 2/2010 200 606 250 757
AB 4/2009 200 606 250 757
BC 10/2009 200 250
ON 7/2010 200 606 250 757
QC 6/2008 200 606 250 757
DIETHYLENE OXIMIDE US ACGIH 2/2010 20 71
AB 4/2009 20 71
BC 10/2009 20
ON 7/2010 20 70 30 105
QC 6/2008 20 71
METHANOL US ACGIH 2/2010 200 262 250 328
AB 4/2009 200 262 250 328
BC 10/2009 200 250
ON 7/2010 200 262 250 328
QC 6/2008 200 262 250 328
VINYL ACETATE US ACGIH 2/2010 10 35 15 53
AB 4/2009 10 35 15 53
BC 10/2009 10 15
ON 7/2010 10 35 15 53
QC 6/2008 10 35 15 53
INGREDIENT LIST NAME CEILING NOTATIONS
PPM MG/M3 OTHER
METHYL ACETATE US ACGIH 2/2010
AB 4/2009
BC 10/2009
ON 7/2010
QC 6/2008
DIETHYLENE OXIMIDE US ACGIH 2/2010 [1]
AB 4/2009 [1]
BC 10/2009 [1]
ON 7/2010 [1]
QC 6/2008 [1]
METHANOL US ACGIH 2/2010 [1]
AB 4/2009 [1]
BC 10/2009 [1]
ON 7/2010 [1]
QC 6/2008 [1]
VINYL ACETATE US ACGIH 2/2010
AB 4/2009
BC 10/2009
ON 7/2010
QC 6/2008
[1]ABSORBED THROUGH SKIN.
MEXICO:
INGREDIENT EXPOSURE LIMITS
METHYL ACETATE NOM-010-STPS (MEXICO, 9/2000).
LMPE-PPT: 200 PPM 8 HOUR(S).
LMPE-PPT: 610 MG/M3 8 HOUR(S).
LMPE-CT: 760 MG/M3 15 MINUTE(S).
LMPE-CT: 250 PPM 15 MINUTE(S).
DIETHYLENE OXIMIDE NOM-010-STPS (MEXICO, 9/2000).
ABSORBED THROUGH SKIN.
LMPE-PPT: 20 PPM 8 HOUR(S).
LMPE-PPT: 70 MG/M3 8 HOUR(S).
LMPE-CT: 105 MG/M3 15 MINUTE(S).
LMPE-CT: 30 PPM 15 MINUTE(S).
CONSULT LOCAL AUTHORITIES FOR ACCEPTABLE EXPOSURE LIMITS.
RECOMMENDED MONITORING PROCEDURES:
IF THIS PRODUCT CONTAINS INGREDIENTS WITH EXPOSURE LIMITS, PERSONAL,
WORKPLACE ATMOSPHERE OR BIOLOGICAL MONITORING MAY BE REQUIRED TO DETERMINE
THE EFFECTIVENESS OF THE VENTILATION OR OTHER CONTROL MEASURES AND/OR THE
NECESSITY TO USE RESPIRATORY PROTECTIVE EQUIPMENT.
ENGINEERING MEASURES:
USE ONLY WITH ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
PERSONAL PROTECTION:
RESPIRATORY:
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
HANDS:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY.
EYES:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS OR DUSTS.
SKIN:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID. [PASTE.]
FLASH POINT:
CLOSED CUP: -12.222 DEG. C (10 DEG. F) [SETAFLASH.]
COLOR: BEIGE. [LIGHT]
ODOR: SOLVENT(S) [STRONG]
BOILING/CONDENSATION POINT: 54.444 DEG. C (130 DEG. F)
RELATIVE DENSITY: 1.33983
VOLATILITY: 28.65% (W/W)
EVAPORATION RATE: >1 (BUTYL ACETATE. = 1)
VOC (LESS WATER, LESS EXEMPT SOLVENTS): 36.28 G/L
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
| 10. STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
HAZARDOUS POLYMERIZATION:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS POLYMERIZATION WILL
NOT OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME). DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT OR
SOURCES OF IGNITION.
MATERIALS TO AVOID:
HIGHLY REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS:
OXIDIZING MATERIALS
INCOMPATIBILITY:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS:
METALS, ACIDS AND ALKALIS.
DIETHYLENE OXIMIDE:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS: OXIDIZING MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
CONDITIONS OF REACTIVITY:
HIGHLY FLAMMABLE IN THE PRESENCE OF THE FOLLOWING MATERIALS OR CONDITIONS:
OPEN FLAMES, SPARKS AND STATIC DISCHARGE AND HEAT.
| 11. TOXICOLOGICAL INFORMATION | |
UNITED STATES:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
METHYL ACETATE LD50 DERMAL RABBIT >5 G/KG
LD50 ORAL RAT >5 G/KG
LDLO RAT 8 G/KG
SUBCUTANEOUS
DIETHYLENE OXIMIDE LD ORAL RAT 2300 MG/KG
LD ORAL RAT 1500 MG/KG
LD50 ORAL RAT 1050 MG/KG
LD50 DERMAL RABBIT 500 MG/KG
LD50 DERMAL RABBIT 500
(MICRO)L/KG
LD50 ORAL RAT 1738 MG/KG
LDLO UNREPORTED RAT 1600 MG/KG
TDLO ORAL RAT 500 MG/KG
LC50 INHALATION RAT 8000 PPM 8 HOURS
GAS.
OXYDIPROPYL DIBENZOATE LD50 DERMAL RAT >2000 MG/KG
LD50 ORAL RAT 3295 MG/KG
VINYL ACETATE LD50 DERMAL RABBIT 2335 MG/KG
LD50 ORAL RAT 2900 MG/KG
LC50 INHALATION RAT 11400 MG/M3 4 HOURS
VAPOR
CHRONIC TOXICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
IRRITATION/CORROSION:
CONCLUSION/SUMMARY:
SKIN:
PROLONGED OR REPEATED CONTACT CAN DEFAT THE SKIN AND LEAD TO IRRITATION,
CRACKING AND/OR DERMATITIS.
EYES: THIS PRODUCT MAY IRRITATE EYES UPON CONTACT.
RESPIRATORY:
HIGH VAPOR CONCENTRATIONS CAN CAUSE HEADACHES, DIZZINESS, DROWSINESS AND
NAUSEA AND MAY LEAD TO UNCONSCIOUSNESS.
SENSITIZER: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY:
CLASSIFICATION:
PRODUCT/INGREDIENT NAME ACGIH IARC EPA NIOSH NTP OSHA
DIETHYLENE OXIMIDE A4 3
VINYL ACETATE A3 2B
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
REPRODUCTIVE TOXICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CANADA:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
METHYL ACETATE LD50 DERMAL RABBIT >5 G/KG
LD50 ORAL RAT >5 G/KG
LDLO RAT 8 G/KG
SUBCUTANEOUS
DIETHYLENE OXIMIDE LD ORAL RAT 2300 MG/KG
LD ORAL RAT 1500 MG/KG
LD50 ORAL RAT 1050 MG/KG
LD50 DERMAL RABBIT 500 MG/KG
LD50 DERMAL RABBIT 500
(MICRO)L/KG
LD50 ORAL RAT 1738 MG/KG
LDLO UNREPORTED RAT 1600 MG/KG
TDLO ORAL RAT 500 MG/KG
LC50 INHALATION RAT 8000 PPM 8 HOURS
GAS.
OXYDIPROPYL DIBENZOATE LD50 DERMAL RAT >2000 MG/KG
LD50 ORAL RAT 3295 MG/KG
METHANOL LD50 DERMAL RABBIT 15800 MG/KG
LD50 RAT 7529 MG/KG
INTRAPERITONEAL
LD50 INTRAVENOUS RAT 2131 MG/KG
LD50 ORAL RAT 5600 MG/KG
TDLO ORAL RAT 8 G/KG
TDLO ORAL RAT 3 G/KG
TDLO RAT 3000 MG/KG
INTRAPERITONEAL
TDLO ORAL RAT 3500 MG/KG
TDLO RAT 3490 MG/KG
INTRAPERITONEAL
LC50 INHALATION RAT 145000 PPM 1 HOURS
GAS.
LC50 INHALATION RAT 64000 PPM 4 HOURS
GAS.
LC50 INHALATION RAT 64000 PPM 8 HOURS
GAS.
VINYL ACETATE LD50 DERMAL RABBIT 2335 MG/KG
LD50 ORAL RAT 2900 MG/KG
LC50 INHALATION RAT 11400 MG/M3 4 HOURS
VAPOR
CHRONIC TOXICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
IRRITATION/CORROSION:
CONCLUSION/SUMMARY:
SKIN:
PROLONGED OR REPEATED CONTACT CAN DEFAT THE SKIN AND LEAD TO IRRITATION,
CRACKING AND/OR DERMATITIS.
EYES: THIS PRODUCT MAY IRRITATE EYES UPON CONTACT.
RESPIRATORY:
HIGH VAPOR CONCENTRATIONS CAN CAUSE HEADACHES, DIZZINESS, DROWSINESS AND
NAUSEA AND MAY LEAD TO UNCONSCIOUSNESS.
SENSITIZER: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY:
CLASSIFICATION:
PRODUCT/INGREDIENT NAME ACGIH IARC EPA NIOSH NTP OSHA
DIETHYLENE OXIMIDE A4 3
VINYL ACETATE A3 2B
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
REPRODUCTIVE TOXICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MEXICO:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
DIETHYLENE OXIMIDE LD ORAL RAT 2300 MG/KG
LD ORAL RAT 1500 MG/KG
LD50 ORAL RAT 1050 MG/KG
LD50 DERMAL RABBIT 500 MG/KG
LD50 DERMAL RABBIT 500
(MICRO)L/KG
LD50 ORAL RAT 1738 MG/KG
LDLO UNREPORTED RAT 1600 MG/KG
TDLO ORAL RAT 500 MG/KG
LC50 INHALATION RAT 8000 PPM 8 HOURS
GAS.
OXYDIPROPYL DIBENZOATE LD50 DERMAL RAT >2000 MG/KG
LD50 ORAL RAT 3295 MG/KG
METHYL ACETATE LD50 DERMAL RABBIT >5 G/KG
LD50 ORAL RAT >5 G/KG -
LDLO RAT 8 G/KG
SUBCUTANEOUS
CHRONIC TOXICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
IRRITATION/CORROSION:
CONCLUSION/SUMMARY:
SKIN:
PROLONGED OR REPEATED CONTACT CAN DEFAT THE SKIN AND LEAD TO IRRITATION,
CRACKING AND/OR DERMATITIS.
EYES: THIS PRODUCT MAY IRRITATE EYES UPON CONTACT.
RESPIRATORY:
HIGH VAPOR CONCENTRATIONS CAN CAUSE HEADACHES, DIZZINESS, DROWSINESS AND
NAUSEA AND MAY LEAD TO UNCONSCIOUSNESS.
SENSITIZER: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY:
CLASSIFICATION:
PRODUCT/INGREDIENT NAME ACGIH IARC EPA NIOSH NTP OSHA
DIETHYLENE OXIMIDE A4 3
VINYL ACETATE A3 2B
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
REPRODUCTIVE TOXICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
UNITED STATES:
AQUATIC ECOTOXICITY:
PRODUCT/INGREDIENT TEST RESULT SPECIES EXPOSURE
NAME
METHYL ACETATE ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
408000 PIMEPHALES PROMELAS -
(MICRO)G/L JUVENILE (FLEDGLING,
FRESH WATER HATCHLING, WEANLING) -
26 TO 34 DAYS
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
399000 TO PIMEPHALES PROMELAS -
422000 32 DAYS -
(MICRO)G/L 18.6 MM - 0.103 G
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
320000 TO PIMEPHALES PROMELAS -
348000 28 TO 32 DAYS -
(MICRO)G/L 17.5 MM -0.087 G
FRESH WATER
DIETHYLENE OXIMIDE ACUTE LC50: FISH - TILAPIA - 96 HOURS
>1000000 TILAPIA SP. -
(MICRO)G/L 47.6 MM - 2 G
MARINE WATER
ACUTE LC50: FISH - INLAND 96 HOURS
400000 SILVERSIDE - MENIDIA
(MICRO)G/L BERYLLINA -
MARINE WATER 40 TO 100 MM
ACUTE LC50: FISH - RAINBOW TROUT, 96 HOURS
380000 DONALDSON TROUT -
(MICRO)G/L ONCORHYNCHUS MYKISS
FRESH WATER
ACUTE LC50: FISH - BLUEGILL - 96 HOURS
350000 LEPOMIS MACROCHIRUS -
(MICRO)G/L 33 TO 75 MM
FRESH WATER
ACUTE LC50: FISH - WESTERN 96 HOURS
320000 TO MOSQUITOFISH - GAMBUSIA
560000 AFFINIS - ADULT -
(MICRO)G/L 50 MM - 1.8 G
MARINE WATER
ACUTE LC50: FISH - WHITE MULLET - 96 HOURS
100000 TO VALAMUGIL ENGELI -
180000 110.9 MM - 14.9 G
(MICRO)G/L
MARINE WATER
ACUTE LC50: FISH - ZEBRA DANIO - 96 HOURS
>1000 DANIO RERIO
(MICRO)G/L
VINYL ACETATE ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
26000 PIMEPHALES PROMELAS -
(MICRO)G/L 4 DAYS
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
24000 TO PIMEPHALES PROMELAS -
30510 3.8 TO 6.4 CM -
(MICRO)G/L 1 TO 2 G
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
24000 PIMEPHALES PROMELAS -
(MICRO)G/L ADULT
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
23000 PIMEPHALES PROMELAS -
(MICRO)G/L 4 DAYS
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
20000 PIMEPHALES PROMELAS -
(MICRO)G/L ADULT
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
19730 TO PIMEPHALES PROMELAS -
25110 3.8 TO 6.4 CM -
(MICRO)G/L 1 TO 2 G
FRESH WATER
ACUTE LC50: FISH - BLUEGILL - 96 HOURS
18000 TO LEPOMIS MACROCHIRUS -
21540 3.8 TO 6.4 CM -
(MICRO)G/L 1 TO 2 G
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
15000 PIMEPHALES PROMELAS -
(MICRO)G/L 1 DAYS
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
14000 PIMEPHALES PROMELAS -
(MICRO)G/L 1 DAYS
FRESH WATER
ACUTE LC50: CRUSTACEANS - COMMON 48 HOURS
10000 TO SHRIMP, SAND SHRIMP -
100000 CRANGON CRANGON -
(MICRO)G/L LARVAE
MARINE WATER
BIODEGRADABILITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CANADA:
AQUATIC ECOTOXICITY:
PRODUCT/INGREDIENT TEST RESULT SPECIES EXPOSURE
NAME
METHYL ACETATE ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
408000 PIMEPHALES PROMELAS -
(MICRO)G/L JUVENILE (FLEDGLING,
FRESH WATER HATCHLING, WEANLING) -
26 TO 34 DAYS
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
399000 TO PIMEPHALES PROMELAS -
422000 32 DAYS -
(MICRO)G/L 18.6 MM - 0.103 G
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
320000 TO PIMEPHALES PROMELAS -
348000 28 TO 32 DAYS -
(MICRO)G/L 17.5 MM -0.087 G
FRESH WATER
DIETHYLENE OXIMIDE ACUTE LC50: FISH - TILAPIA - 96 HOURS
>1000000 TILAPIA SP. -
(MICRO)G/L 47.6 MM - 2 G
MARINE WATER
ACUTE LC50: FISH - INLAND 96 HOURS
400000 SILVERSIDE - MENIDIA
(MICRO)G/L BERYLLINA -
MARINE WATER 40 TO 100 MM
ACUTE LC50: FISH - RAINBOW TROUT, 96 HOURS
380000 DONALDSON TROUT -
(MICRO)G/L ONCORHYNCHUS MYKISS
FRESH WATER
ACUTE LC50: FISH - BLUEGILL - 96 HOURS
350000 LEPOMIS MACROCHIRUS -
(MICRO)G/L 33 TO 75 MM
FRESH WATER
ACUTE LC50: FISH - WESTERN 96 HOURS
320000 TO MOSQUITOFISH - GAMBUSIA
560000 AFFINIS - ADULT -
(MICRO)G/L 50 MM - 1.8 G
MARINE WATER
ACUTE LC50: FISH - WHITE MULLET - 96 HOURS
100000 TO VALAMUGIL ENGELI -
180000 110.9 MM - 14.9 G
(MICRO)G/L
MARINE WATER
ACUTE LC50: FISH - ZEBRA DANIO - 96 HOURS
>1000 DANIO RERIO
(MICRO)G/L
METHANOL ACUTE EC50: DAPHNIA - WATER FLEA - 48 HOURS
22200 TO DAPHNIA OBTUSA -
23400 MG/L NEONATE - <24 HOURS
FRESH WATER
ACUTE EC50: FISH - RAINBOW TROUT, 96 HOURS
13000000 TO DONALDSON TROUT -
13400000 ONCORHYNCHUS MYKISS -
(MICRO)G/L JUVENILE (FLEDGLING,
FRESH WATER HATCHLING, WEANLING) -
0.813 G
ACUTE EC50: FISH - BLUEGILL - 96 HOURS
12700000 TO LEPOMIS MACROCHIRUS -
13700000 JUVENILE (FLEDGLING,
(MICRO)G/L HATCHLING, WEANLING) -
FRESH WATER 3.07 G
ACUTE EC50: DAPHNIA - WATER FLEA - 48 HOURS
>10000000 DAPHNIA MAGNA -
(MICRO)G/L 6 TO 24 HOURS
FRESH WATER
ACUTE EC50: DAPHNIA - WATER FLEA - 48 HOURS
24500000 TO DAPHNIA MAGNA - LARVAE
29350000 - <24 HOURS
(MICRO)G/L
FRESH WATER
ACUTE LC50: FISH - ZEBRA DANIO - 96 HOURS
290 MG/L DANIO RERIO - EGG
FRESH WATER
ACUTE LC50: DAPHNIA - WATER FLEA - 48 HOURS
3289 TO 4395 DAPHNIA MAGNA - NEONATE
MG/L - <24 HOURS
FRESH WATER
ACUTE LC50: FISH - BLUEGILL - 96 HOURS
>1000 MG/L LEPOMIS MACROCHIRUS -
FRESH WATER 6 MONTHS -
40 MM - 0.81 G
ACUTE LC50: FISH - HOOKNOSE - 96 HOURS
10000000 TO AGONUS CATAPHRACTUS -
33000000 ADULT
(MICRO)G/L
MARINE WATER
ACUTE LC50: CRUSTACEANS - COMMON 48 HOURS
2500000 SHRIMP, SAND SHRIMP -
(MICRO)G/L CRANGON CRANGON - ADULT
MARINE WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
>100000 PIMEPHALES PROMELAS -
(MICRO)G/L JUVENILE (FLEDGLING,
FRESH WATER HATCHLING, WEANLING) -
0.2 TO 0.5 G
VINYL ACETATE ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
26000 PIMEPHALES PROMELAS -
(MICRO)G/L 4 DAYS
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
24000 PIMEPHALES PROMELAS -
(MICRO)G/L ADULT
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
24000 TO 30510 PIMEPHALES PROMELAS -
(MICRO)G/L 3.8 TO 6.4 CM -
FRESH WATER 1 TO 2 G
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
23000 PIMEPHALES PROMELAS -
(MICRO)G/L 4 DAYS
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
20000 PIMEPHALES PROMELAS -
(MICRO)G/L ADULT
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
19730 TO 25110 PIMEPHALES PROMELAS -
(MICRO)G/L 3.8 TO 6.4 CM -
FRESH WATER 1 TO 2 G
ACUTE LC50: FISH - BLUEGILL - 96 HOURS
18000 TO 21540 LEPOMIS MACROCHIRUS -
(MICRO)G/L 3.8 TO 6.4 CM -
FRESH WATER 1 TO 2 G
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
15000 PIMEPHALES PROMELAS -
(MICRO)G/L 1 DAYS
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
14000 PIMEPHALES PROMELAS -
(MICRO)G/L 1 DAYS
FRESH WATER
ACUTE LC50: CRUSTACEANS - COMMON 48 HOURS
10000 TO SHRIMP, SAND SHRIMP -
100000 CRANGON CRANGON -
(MICRO)G/L LARVAE
MARINE WATER
BIODEGRADABILITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MEXICO:
AQUATIC ECOTOXICITY:
PRODUCT/INGREDIENT TEST RESULT SPECIES EXPOSURE
NAME
DIETHYLENE OXIMIDE ACUTE LC50: FISH - TILAPIA - TILAPIA 96 HOURS
>1000000 SP. - 47.6 MM - 2 G
(MICRO)G/L
MARINE WATER
ACUTE LC50: FISH - INLAND 96 HOURS
400000 SILVERSIDE - MENIDIA
(MICRO)G/L BERYLLINA - 40 TO 100 MM
MARINE WATER
ACUTE LC50: FISH - RAINBOW TROUT, 96 HOURS
380000 DONALDSON TROUT -
(MICRO)G/L ONCORHYNCHUS MYKISS
FRESH WATER
ACUTE LC50: FISH - BLUEGILL - 96 HOURS
350000 LEPOMIS MACROCHIRUS -
(MICRO)G/L 33 TO 75 MM
FRESH WATER
ACUTE LC50: FISH - WESTERN 96 HOURS
320000 TO MOSQUITOFISH - GAMBUSIA
560000 AFFINIS - ADULT -
(MICRO)G/L 50 MM - 1.8 G
MARINE WATER
ACUTE LC50: FISH - WHITE MULLET - 96 HOURS
100000 TO VALAMUGIL ENGELI -
180000 110.9 MM - 14.9 G
(MICRO)G/L
MARINE WATER
ACUTE LC50: FISH - ZEBRA DANIO - 96 HOURS
>1000 DANIO RERIO
(MICRO)G/L
METHYL ACETATE ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
408000 PIMEPHALES PROMELAS -
(MICRO)G/L JUVENILE (FLEDGLING,
FRESH WATER HATCHLING, WEANLING) -
26 TO 34 DAYS
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
399000 TO PIMEPHALES PROMELAS -
422000 32 DAYS -
(MICRO)G/L 18.6 MM - 0.103 G
FRESH WATER
ACUTE LC50: FISH - FATHEAD MINNOW - 96 HOURS
320000 TO PIMEPHALES PROMELAS -
348000 28 TO 32 DAYS -
(MICRO)G/L 17.5 MM -0.087 G
FRESH WATER
BIODEGRADABILITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
EMPTY CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL
AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. DISPOSE OF SURPLUS AND
NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL CONTRACTOR. DISPOSAL
OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES COMPLY
WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. AVOID DISPERSAL
OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS.
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
REFER TO SECTION 7: HANDLING AND STORAGE AND SECTION 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION FOR ADDITIONAL HANDLING INFORMATION AND
PROTECTION OF EMPLOYEES.
| 14. TRANSPORT INFORMATION | |
REGULATORY INFORMATION UN NUMBER PROPER SHIPPING NAME CLASSES
DOT CLASSIFICATION 1133 CONSUMER COMMODITY ORM-D
TDG CLASSIFICATION 1133 ADHESIVES, CONTAINING 3
FLAMMABLE LIQUID
MEXICO CLASSIFICATION 1133 ADHESIVES, CONTAINING 3
FLAMMABLE LIQUID
ADR/RID CLASS 1133 ADHESIVES, CONTAINING 3
FLAMMABLE LIQUID
IMDG CLASS 1133 ADHESIVES, CONTAINING 3
FLAMMABLE LIQUID
IATA-DGR CLASS ID8000 CONSUMER COMMODITY 9
REGULATORY INFORMATION PG* LABEL ADDITIONAL INFORMATION
DOT CLASSIFICATION III
TDG CLASSIFICATION III CLASS 3, FLAMMABLE REMARKS
LIQUIDS LIMITED QUANTITY
MEXICO CLASSIFICATION III CLASS 3, FLAMMABLE
LIQUIDS
ADR/RID CLASS III CLASS 3, FLAMMABLE
LIQUIDS
IMDG CLASS III CLASS 3 - FLAMMABLE REMARKS
LIQUIDS LIMITED QUANTITY
IATA-DGR CLASS III CLASS 9, CLASS/
DIVISION 9
PACKING GROUP III
PG*: PACKING GROUP
| 15. REGULATORY INFORMATION | |
UNITED STATES:
HCS CLASSIFICATION:
FLAMMABLE LIQUID
TOXIC MATERIAL
CORROSIVE MATERIAL
CARCINOGEN
U.S. FEDERAL REGULATIONS:
TSCA 4(A) FINAL TEST RULES: METHYL ACETATE
TSCA 8(A) PAIR: METHYL ACETATE
TSCA 8(A) IUR: WATER; WATER
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
TSCA 12(B) ONE-TIME EXPORT: METHYL ACETATE
SARA 302/304/311/312 EXTREMELY HAZARDOUS SUBSTANCES:
NO PRODUCTS WERE FOUND.
SARA 302/304 EMERGENCY PLANNING AND NOTIFICATION: NO PRODUCTS WERE FOUND.
SARA 302/304/311/312 HAZARDOUS CHEMICALS:
METHYL ACETATE; DIETHYLENE OXIMIDE
SARA 311/312 MSDS DISTRIBUTION - CHEMICAL INVENTORY - HAZARD
IDENTIFICATION:
TITEBOND PROVANTAGE TUB SURROUND ADHESIVE:
FIRE HAZARD, IMMEDIATE (ACUTE) HEALTH HAZARD, DELAYED (CHRONIC) HEALTH
HAZARD
DEA LIST I CHEMICALS (PRECURSOR CHEMICALS): NOT LISTED
DEA LIST II CHEMICALS (ESSENTIAL CHEMICALS): NOT LISTED
SARA 313:
PRODUCT NAME CAS NUMBER CONCENTRATION
FORM R - REPORTING REQUIREMENTS:
DIETHYLENE OXIMIDE 110-91-8 1 - 5
VINYL ACETATE 108-05-4 0.1 - 0.5
SUPPLIER NOTIFICATION:
VINYL ACETATE 108-05-4 0.1 - 0.5
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE MSDS AND ANY COPYING
AND REDISTRIBUTION OF THE MSDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE MSDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS SPILL: NONE OF THE COMPONENTS ARE LISTED.
MASSACHUSETTS SUBSTANCES:
THE FOLLOWING COMPONENTS ARE LISTED: METHYL ACETATE; MORPHOLINE
NEW JERSEY HAZARDOUS SUBSTANCES:
THE FOLLOWING COMPONENTS ARE LISTED:
METHYL ACETATE; ACETIC ACID, METHYL ESTER; VINYL ACETATE; ACETIC ACID
ETHENYL ESTER; MORPHOLINE
NEW JERSEY SPILL: NONE OF THE COMPONENTS ARE LISTED.
NEW JERSEY TOXIC CATASTROPHE PREVENTION ACT:
NONE OF THE COMPONENTS ARE LISTED.
PENNSYLVANIA RTK HAZARDOUS SUBSTANCES:
THE FOLLOWING COMPONENTS ARE LISTED:
ACETIC ACID, METHYL ESTER; ACETIC ACID ETHENYL ESTER; MORPHOLINE
CANADA:
WHMIS (CANADA):
CLASS B-2: FLAMMABLE LIQUID
CLASS D-1B: MATERIAL CAUSING IMMEDIATE AND SERIOUS TOXIC EFFECTS (TOXIC).
CLASS D-2A: MATERIAL CAUSING OTHER TOXIC EFFECTS (VERY TOXIC).
CLASS E: CORROSIVE MATERIAL
CANADIAN LISTS:
CEPA TOXIC SUBSTANCES: NONE OF THE COMPONENTS ARE LISTED.
CANADIAN ARET: NONE OF THE COMPONENTS ARE LISTED.
CANADIAN NPRI: NONE OF THE COMPONENTS ARE LISTED.
ALBERTA DESIGNATED SUBSTANCES: NONE OF THE COMPONENTS ARE LISTED.
ONTARIO DESIGNATED SUBSTANCES: NONE OF THE COMPONENTS ARE LISTED.
QUEBEC DESIGNATED SUBSTANCES: NONE OF THE COMPONENTS ARE LISTED.
CANADA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS AND THE MSDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
MEXICO:
CLASSIFICATION:
NFPA:
HEALTH 2
FLAMMABILITY 3
REACTIVITY 0
SPECIAL
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AICS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA INVENTORY (IECSC): ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN INVENTORY: NOT DETERMINED.
KOREA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
NEW ZEALAND INVENTORY OF CHEMICALS (NZIOC):
ALL COMPONENTS ARE LISTED OR EXEMPTED.
PHILIPPINES INVENTORY (PICCS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE I CHEMICALS: NOT LISTED
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE II CHEMICALS: NOT LISTED
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE III CHEMICALS: NOT LISTED
| 16. OTHER INFORMATION | |
LABEL REQUIREMENTS:
EXTREMELY FLAMMABLE LIQUID AND VAPOR. FLAMMABLE. VAPOR MAY CAUSE FLASH
FIRE. CAUSES DIGESTIVE TRACT BURNS. HARMFUL IF INHALED. CAUSES RESPIRATORY
TRACT AND SKIN IRRITATION. MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF
SWALLOWED. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION.
POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER.
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2*
FLAMMABILITY 3
PHYSICAL HAZARDS 0
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON MSDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK OF
THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS MAY BE
PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
DATE OF PRINTING: 10/22/2010.
DATE OF ISSUE: 10/22/2010.
DATE OF PREVIOUS ISSUE: 10/20/2010.
VERSION: 1
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.