| Common Name: | ZIP GRIP 4404 - 14 GM |
| Manufacturer: | ITW DEVCON |
| SDS Revision Date: | 6/30/2012 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3ZDT8, 9L136 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DEVCON(R*)
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: ZIP GRIP 4404 - 14 GM
PRODUCT CODE: 44044
STOCK NO.: 70144
MANUFACTURER NAME: ITW DEVCON
ADDRESS:
30 ENDICOTT STREET
DANVERS, MA 01923
GENERAL PHONE NUMBER: (978) 777-1100
EMERGENCY PHONE NUMBER: (800) 424-9300
CHEMTREC:
FOR EMERGENCIES IN THE US, CALL CHEMTREC: 800-424-9300
MSDS REVISION DATE: JUNE 30, 2012
MSDS FORMAT: ACCORDING TO ANSI Z400.1-2004
HMIS:
HEALTH HAZARD 2*
FIRE HAZARD 2
REACTIVITY 2
PERSONAL PROTECTION X
* CHRONIC HEALTH EFFECTS
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS# INGREDIENT PERCENT
ETHYL-2-CYANOACRYLATE 7085-85-0 60 - 100 BY WEIGHT
| SECTION 3 - HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING!
CONTAINS CYANOACRYLATE ESTERS. BONDS BODY TISSUE IN SECONDS. CAN CAUSE
SEVERE EYE INJURY.
ROUTE OF EXPOSURE: EYES. SKIN. INHALATION. INGESTION.
POTENTIAL HEALTH EFFECTS:
EYE:
CAN CAUSE MODERATE IRRITATION, BURNING SENSATION, TEARING, REDNESS, AND
SWELLING. OVEREXPOSURE MAY CAUSE LACRIMATION, CONJUNCTIVITIS, CORNEAL
DAMAGE AND PERMANENT INJURY.
SKIN:
CAN CAUSE SKIN IRRITATION; ITCHING, REDNESS, RASHES, HIVES, BURNING, AND
SWELLING.
INHALATION:
RESPIRATORY TRACT IRRITANT. HIGH CONCENTRATION MAY CAUSE DIZZINESS,
HEADACHE, AND ANESTHETIC EFFECTS.
INGESTION:
CAUSES IRRITATION, A BURNING SENSATION OF THE MOUTH, THROAT AND
GASTROINTESTINAL TRACT AND ABDOMINAL PAIN.
CHRONIC HEALTH EFFECTS:
PROLONGED SKIN CONTACT MAY LEAD TO BURNING ASSOCIATED WITH SEVERE
REDDENING, SWELLING, AND POSSIBLE TISSUE DESTRUCTION.
SIGNS/SYMPTOMS:
OVEREXPOSURE CAN CAUSE HEADACHES, DIZZINESS, NAUSEA, AND VOMITING.
TARGET ORGANS: EYES. SKIN. RESPIRATORY SYSTEM. DIGESTIVE SYSTEM.
AGGRAVATION OF PRE-EXISTING CONDITIONS:
INDIVIDUALS WITH PRE-EXISTING SKIN DISORDERS, ASTHMA, ALLERGIES OR KNOWN
SENSITIZATION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
| SECTION 4 - FIRST AID MEASURES | |
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 TO 20 MINUTES.
ENSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS WITH
FINGERS. GET IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH SKIN WITH PLENTY OF SOAP AND WATER FOR 15 TO 20 MINUTES,
WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION OR GIVE OXYGEN BY TRAINED PERSONNEL. SEEK IMMEDIATE MEDICAL
ATTENTION.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL
CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLAMMABLE PROPERTIES: COMBUSTIBLE.
FLASH POINT: >170 DEG. F (76.6 DEG. C)
FLASH POINT METHOD: TAG CLOSED CUP (TCC)
AUTO IGNITION TEMPERATURE: NOT DETERMINED.
LOWER FLAMMABLE/EXPLOSIVE LIMIT: NOT DETERMINED.
UPPER FLAMMABLE/EXPLOSIVE LIMIT: NOT DETERMINED.
FIRE FIGHTING INSTRUCTIONS:
EVACUATE AREA OF UNPROTECTED PERSONNEL. USE COLD WATER SPRAY TO COOL FIRE
EXPOSED CONTAINERS TO MINIMIZE RISK OF RUPTURE. DO NOT ENTER CONFINED FIRE
SPACE WITHOUT FULL PROTECTIVE GEAR. IF POSSIBLE, CONTAIN FIRE RUN-OFF
WATER.
EXTINGUISHING MEDIA:
USE CARBON DIOXIDE (CO2) OR DRY CHEMICAL WHEN FIGHTING FIRES INVOLVING
THIS MATERIAL.
UNSUITABLE MEDIA: WATER MAY CAUSE FROTHING.
PROTECTIVE EQUIPMENT:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA), MSHA/NIOSH
(APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
UNUSUAL FIRE HAZARDS:
SEALED CONTAINERS AT ELEVATED TEMPERATURES MAY RUPTURE EXPLOSIVELY AND
SPREAD FIRE DUE TO POLYMERIZATION.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONNEL PRECAUTIONS:
EVACUATE AREA AND KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM ENTERING
THE SPILL AREA.
ENVIRONMENTAL PRECAUTIONS:
AVOID RUNOFF INTO STORM SEWERS, DITCHES, AND WATERWAYS.
SPILL CLEANUP MEASURES:
ABSORB SPILL WITH INERT MATERIAL (E,G., DRY SAND OR EARTH), THEN PLACE IN
A CHEMICAL WASTE CONTAINER. PROVIDE VENTILATION. CLEAN UP SPILLS
IMMEDIATELY OBSERVING PRECAUTIONS IN THE PROTECTIVE EQUIPMENT SECTION.
AFTER REMOVAL, FLUSH SPILL AREA WITH SOAP AND WATER TO REMOVE TRACE
RESIDUE.
AVOID PERSONAL CONTACT AND BREATHING VAPORS OR MISTS. VENTILATE AREA. USE
PROPER PERSONAL PROTECTIVE EQUIPMENT AS LISTED IN SECTION 8.
OTHER PRECAUTIONS:
PUMP OR SHOVEL TO STORAGE/SALVAGE VESSELS. ADD INHIBITOR TO PREVENT
POLYMERIZATION.
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING:
USE WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR, AEROSOL OR MIST.
STORAGE:
STORE IN A COOL, DRY, WELL VENTILATED AREA AWAY FROM SOURCES OF HEAT AND
INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
SPECIAL HANDLING PROCEDURES:
PROVIDE APPROPRIATE VENTILATION/RESPIRATORY PROTECTION AGAINST
DECOMPOSITION PRODUCTS (SEE SECTION 10) DURING WELDING/FLAME CUTTING
OPERATIONS AND TO PROTECT AGAINST DUST DURING SANDING/GRINDING OF CURED
PRODUCT.
HYGIENE PRACTICES: WASH THOROUGHLY AFTER HANDLING.
| SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE | |
GUIDELINES
ENGINEERING CONTROLS:
USE APPROPRIATE ENGINEERING CONTROL SUCH AS PROCESS ENCLOSURES, LOCAL
EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE
LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. GOOD GENERAL VENTILATION SHOULD
BE SUFFICIENT TO CONTROL AIRBORNE LEVELS. WHERE SUCH SYSTEMS ARE NOT
EFFECTIVE WEAR SUITABLE PERSONAL PROTECTIVE EQUIPMENT, WHICH PERFORMS
SATISFACTORILY AND MEETS OSHA OR OTHER RECOGNIZED STANDARDS. CONSULT WITH
LOCAL PROCEDURES FOR SELECTION, TRAINING, INSPECTION AND MAINTENANCE OF
THE PERSONAL PROTECTIVE EQUIPMENT.
EYE/FACE PROTECTION:
WEAR APPROPRIATE PROTECTIVE GLASSES OR SPLASH GOGGLES AS DESCRIBED BY
29 CFR 1910.133, OSHA EYE AND FACE PROTECTION REGULATION, OR THE EUROPEAN
STANDARD EN 166.
SKIN PROTECTION DESCRIPTION:
WEAR APPROPRIATE PROTECTIVE GLOVES AND OTHER PROTECTIVE APPAREL TO PREVENT
SKIN CONTACT. CONSULT MANUFACTURER'S DATA FOR PERMEABILITY DATA.
RESPIRATORY PROTECTION:
A NIOSH APPROVED AIR-PURIFYING RESPIRATOR WITH AN ORGANIC VAPOR CARTRIDGE
OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE
CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS. PROTECTION PROVIDED
BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN UNCONTROLLED RELEASE,
EXPOSURE LEVELS ARE NOT KNOWN, OR ANY OTHER CIRCUMSTANCES WHERE AIR
PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION.
OTHER PROTECTIVE:
FACILITIES STORING OR UTILIZING THIS MATERIAL SHOULD BE EQUIPPED WITH AN
EYEWASH AND A DELUGE SHOWER SAFETY STATION.
EXPOSURE GUIDELINES:
ETHYL-2-CYANOACRYLATE:
GUIDELINE ACGIH: 0.2 PPM
TLV-TWA: 0.2 PPM
NOTES: ONLY ESTABLISHED PEL AND TLV VALUES FOR THE INGREDIENTS ARE LISTED.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE APPEARANCE: VISCOUS. LIQUID..
COLOR: COLOURLESS
ODOR: SLIGHTLY PUNGENT.
BOILING POINT: >300 DEG. F (148.8 DEG. C)
MELTING POINT: NOT DETERMINED.
SPECIFIC GRAVITY: 1.05
SOLUBILITY: <0.1%
VAPOR DENSITY: >1 (AIR = 1)
VAPOR PRESSURE: 0.17 MMHg @ 68 DEG. F
PERCENT VOLATILE: 0
EVAPORATION RATE: NOT DETERMINED.
PH: NOT DETERMINED.
MOLECULAR FORMULA: MIXTURE
MOLECULAR WEIGHT: MIXTURE
FLASH POINT: >170 DEG. F (76.6 DEG. C)
FLASH POINT METHOD: TAG CLOSED CUP (TCC)
AUTO IGNITION TEMPERATURE: NOT DETERMINED.
VOC CONTENT: NOT DETERMINED.
PERCENT SOLIDS BY WEIGHT: 100
| SECTION 10 - STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: UNSTABLE.
HAZARDOUS POLYMERIZATION:
POLYMERIZATION MAY OCCUR UNDER CERTAIN CONDITIONS.
CONDITIONS TO AVOID:
EXTREME HEAT, SPARKS, AND OPEN FLAME. INCOMPATIBLE MATERIALS, OXIDIZERS
AND OXIDIZING CONDITIONS. OXYGEN-FREE ATMOSPHERES OR INERT GAS BLANKETING.
FREEZING CONDITIONS. MATERIAL CAN SOFTEN PAINT AND RUBBER.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS (EG PEROXIDES, NITRATES), REDUCING AGENTS, ACIDS, BASES,
AZO-COMPOUNDS, CATALYTIC METALS (EG COPPER, IRON), HALOGENS. FREE RADICAL
INITIATORS. OXYGEN SCAVENGERS.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
ETHYL-2-CYANOACRYLATE:
RTECS NUMBER: UD3330050
SKIN:
ADMINISTRATION ONTO THE SKIN - RABBIT:
>2000 MG/KG [DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE]
ADMINISTRATION ONTO THE SKIN - RABBIT: 500 (MICRO)L/24H
ADMINISTRATION ONTO THE SKIN - RABBIT: 0.5 GM
INGESTION:
ORAL - RAT LD50:
>5 ML/KG [BEHAVIORAL - SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
GASTROINTESTINAL - OTHER CHANGES]
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICITY: NO ECOTOXICITY DATA WAS FOUND FOR THE PRODUCT.
ENVIRONMENTAL FATE: NO ENVIRONMENTAL INFORMATION FOUND FOR THIS PRODUCT.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL:
CONSULT WITH THE US EPA GUIDELINES LISTED IN 40 CFR PART 261.3 FOR THE
CLASSIFICATIONS OF HAZARDOUS WASTE PRIOR TO DISPOSAL. FURTHERMORE, CONSULT
WITH YOUR STATE AND LOCAL WASTE REQUIREMENTS OR GUIDELINES, IF APPLICABLE,
TO ENSURE COMPLIANCE. ARRANGE DISPOSAL IN ACCORDANCE TO THE EPA AND/OR
STATE AND LOCAL GUIDELINES.
RCRA NUMBER: NOT DETERMINED.
| SECTION 14 - TRANSPORT INFORMATION | |
DOT SHIPPING NAME: NON REGULATED.
DOT UN NUMBER: NOT APPLICABLE.
DOT HAZARD CLASS: NOT APPLICABLE.
DOT PACKING GROUP: NOT APPLICABLE.
| SECTION 15 - REGULATORY INFORMATION | |
ETHYL-2-CYANOACRYLATE:
TSCA INVENTORY STATUS: LISTED
CANADA DSL: LISTED
CANADIAN REGULATIONS.:
WHMIS HAZARD CLASS(ES): D2B; B3
ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DOMESTIC SUBSTANCES
LIST.
| SECTION 16 - ADDITIONAL INFORMATION | |
HMIS HEALTH HAZARD 2*
HMIS FIRE HAZARD 2
HMIS REACTIVITY 2
HMIS PERSONAL PROTECTION X
MSDS REVISION DATE: JUNE 30, 2012
MSDS AUTHOR: ACTIO CORPORATION
DISCLAIMER:
THIS HEALTH AND SAFETY INFORMATION IS CORRECT TO THE BEST OF OUR KNOWLEDGE
AND BELIEF AT THE DATE OF ITS PUBLICATION BUT WE CANNOT ACCEPT LIABILITY
FOR ANY LOSS, INJURY OR DAMAGE WHICH MAY RESULT FROM ITS USE. THE
INFORMATION GIVEN IN THE DATA SHEET IS DESIGNED ONLY AS A GUIDANCE FOR
SAFE HANDLING, STORAGE AND THE USE OF THE SUBSTANCE. IT IS NOT A
SPECIFICATION NOR DOES IT GUARANTEE ANY SPECIFIC PROPERTIES. ALL CHEMICALS
SHOULD BE HANDLED ONLY BY COMPETENT PERSONNEL, WITHIN A CONTROLLED
ENVIRONMENT.
COPYRIGHT(C) 1996-2011 ACTIO CORPORATION. ALL RIGHTS RESERVED.
PRODUCT: ZIP GRIP 4404 - 14 GM
MANUFACTURER:
REVISION: 06/30/2012
VERSION: 0