| Common Name: | LITHIUM-ION BATTERY - RECHARGEABLE |
| Manufacturer: | MILWAUKEE ELECTRIC TOOL |
| SDS Revision Date: | 9/1/2012 |
| SDS Format: | ANSI-OSHA |
| Item Number(s): | 22UT57, 32NN03, 32NN04, 32NN07, 32NN08, 32NN10, 32NN11, 32NN13, 32NN15, 32NN17, 32NT20, 32NT21, 32NT23, 32NT24, 32NT32, 32NT33, 32NT36, 32NT37, 32NT40, 32NT41, 32ZU71, 35GJ99, 35GK10 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MILWAUKEE(R*)
MATERIAL SAFETY DATA SHEET
MAY BE USED TO COMPLY WITH OSHA'S HAZARD COMMUNICATION STANDARD 29 CFR
1910.1200. THIS STANDARD MUST BE CONSULTED FOR SPECIFIC REQUIREMENTS.
| SECTION 1: PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LITHIUM-ION BATTERY - RECHARGEABLE
PRODUCT NUMBERS:
#48-11-0490; V4B: RATED 4 VOLTS, 0.8G ELC, 10 WATT-HOURS (WH) MAXIMUM.
#48-11-1815; C18B; M18B; 982-2 (ALBION); Li18 (OEM):
18V, 2.3G ELC, 27 WH MAX.
#48-11-1820; M18B2: 18V, 3.0G ELC, 36 WH MAX.
#48-11-1828; C18B; M18BX; Li18 (OEM): 18V, 4.5G ELC, 54 WH MAX.
#48-11-1840; M18B4: 18V, 6.0G ELC, 72 WH MAX.
#48-11-1830; V18B; MV18B: 18V, 4.5G ELC, 54 WH MAX.
#48-11-2401; C12B; M12B; 0700913615 (WURTH); 1004-3 (ALBION); Li12B (OEM):
12V, 1.4G ELC, 18 WH MAX.
#48-11-2420; M12B2: 12V, 1.8G ELC, 24 WH MAX.
#48-11-2402; C12BX; M12BX; 0700913630 (WURTH); Li12BX (OEM):
12V, 2.7G ELC, 36 WH MAX.
#48-11-2440; M12B4: 12V, 3.6G ELC, 48 WH MAX.
#48-11-2830; V28B; M28BX; Li28V (WURTH); Li-2-28V (WURTH); Li28M (OEM):
28V, 6.3G ELC, 84 WH MAX
MILWAUKEE ELECTRIC TOOL CORPORATION
13135 WEST LISBON ROAD
BROOKFIELD, WISCONSIN 53005-2550
USA
WWW.MILWAUKEETOOL.COM
COMPANY PHONE NUMBER: 1-262-781-3600 OR 1-800-729-3878
EMERGENCY CONTACT NUMBER (UNITED STATES ONLY): 1-800-424-9300 (CHEMTREC)
FOR INTERNATIONAL: 1-703-527-3887
DRAWING NUMBER: 58-97-0500
ISSUE DATE: SEPTEMBER 2012
SUPERSEDED DATE: NOVEMBER 2011
| SECTION 2: HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
APPEARANCE/ODOR: SOLID ARTICLE, ODORLESS
WARNING: NO EXPOSURE DURING ROUTINE HANDLING OF PRODUCT.
HYDROFLUORIC ACID EXPOSURE DURING FIRE FIGHTING:
THIS INFORMATION IS GIVEN FOR THE USE OF PROFESSIONAL FIRE FIGHTERS
RESPONDING TO A WAREHOUSE FIRE WHERE FIRE FROM OTHER MATERIALS MAY
INCINERATE BATTERIES. THIS SECTION IS PROVIDED SOLELY IN CASE OF EXPOSURE,
DURING FIREFIGHTING, TO THE COMBUSTION BY-PRODUCTS.
FLAMMABLE:
ORGANIC COMPONENTS WILL BURN IF CELL IS INCINERATED. COMBUSTION OF CELL
CONTENTS MAY CAUSE EVOLUTION OF HYDROGEN FLUORIDE.
POTENTIAL HEALTH EFFECTS:
FLUORIDE INTERFERES WITH NERVE IMPULSE CONDUCTION CAUSING SEVERE PAIN OR
ABSENCE OF SENSATIONS
LIKELY ROUTES OF EXPOSURE:
EYE CONTACT, SKIN CONTACT, SKIN ABSORPTION, INHALATION. HYDROFLUORIC ACID
IS EXTREMELY CORROSIVE. CONTACT WITH HYDROGEN FLUORIDE FUMES IS TO BE
AVOIDED. PERMISSIBLE EXPOSURE LIMIT IS 3 PPM. IN CASE OF CONTACT WITH
HYDROGEN FLUORIDE FUMES, IMMEDIATELY LEAVE THE AREA AND SEEK FIRST AID AND
EMERGENCY MEDICAL ATTENTION. SYMPTOMS MAY HAVE DELAYED ONSET. FLUORIDE
IONS PENETRATE SKIN READILY CAUSING DESTRUCTION OF DEEP TISSUE LAYERS EVEN
BONE. FLUORIDE INTERFERES WITH NERVE IMPULSE CONDUCTION CAUSING SEVERE
PAIN OR ABSENCE OF SENSATIONS. IMMEDIATELY FLUSH EYES OR SKIN WITH WATER
FOR AT LEAST 20 MINUTES TO NEUTRALIZE THE ACIDITY AND REMOVE SOME
FLUORIDE. REMOVE AND DESTROY ALL CONTAMINATED CLOTHING AND PERMEABLE
PERSONAL POSSESSIONS. BEFORE RE-USE, IMPERMEABLE POSSESSIONS SHOULD BE
SOAKED IN BENZALKONIUM CHLORIDE AFTER WASHING. FOLLOWING FLUSHING OF THE
AFFECTED AREAS, AN ICED AQUEOUS SOLUTION OF BENZALKONIUM CHLORIDE OR 2.5%
CALCIUM GLUCONATE GEL SHOULD BE APPLIED TO REACT WITH THE FLUORIDE ION.
COMPRESSES AND WRAPS MAY BE USED FOR AREAS WHERE IMMERSION IS NOT
PRACTICAL. MEDICATED DRESSING SHOULD BE CHANGED EVERY 2 MINUTES. EXPOSURE
TO HYDROFLUORIC ACID FUMES SUFFICIENT TO CAUSE PAIN REQUIRES IMMEDIATE
HOSPITALIZATION FOR MONITORING FOR PULMONARY EDEMA.
| SECTION 3: COMPOSITION / INFORMATION OF INGREDIENTS | |
INGREDIENT % BY WEIGHT CAS #
ALUMINUM FOIL 0.1 - 10 7429-90-5
BIPHENYL (BP) 0.1 - 0.3 92-52-4
COPPER FOIL 0.1 - 10 7440-50-8
LINEAR & CYCLIC CARBONATE SOLVENTS 0 - 17 N/A
GRAPHITE POWDER/CARBON 10 - 30 7440-44-0
METAL OXIDE OR OTHER ELECTROLYTE 10 - 50 CONFIDENTIAL
(PROPRIETARY)
LITHIUM HEXAFLUROPHOSPHATE (LiPF6) 0 - 5 21324-40-3
POLYVINYLIDENE FLOURIDE (PVDF) 0.1 - 5 24937-79-9
STYRENE BUTADIENE RUBBER (SBR) <5 N/A
ALUMINUM, STEEL, NICKEL AND OTHER REMAINDER N/A
INERT MATERIALS
| SECTION 4: FIRST AID MEASURES | |
NO EXPOSURE DURING ROUTINE HANDLING OF PRODUCT. RISK OF EXPOSURE OCCURS
ONLY IF THE BATTERY IS MECHANICALLY OR ELECTRICALLY ABUSED.
EYE CONTACT: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. WASH WITH SOAP AND
WATER
INHALATION: N/A
INGESTION:
INGESTION IS NOT LIKELY, GIVEN THE PHYSICAL SIZE AND STATE OF THE CELL.
| SECTION 5: FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. USE
AGENT APPROPRIATE FOR SURROUNDING MATERIALS.
UNSUITABLE EXTINGUISHING MEDIA: NONE.
PRODUCTS OF COMBUSTION:
ORGANIC COMPONENTS WILL BURN IF INCINERATED. COMBUSTION OF CELL CONTENTS
MAY CAUSE EVOLUTION OF HYDROGEN FLUORIDE. IN CASE OF FIRE IN AN ADJACENT
AREA, USE WATER, CO2, OR DRY CHEMICAL EXTINGUISHERS IF CELLS ARE PACKED IN
THEIR ORIGINAL CONTAINERS SINCE THE FUEL OF THE FIRE IS BASICALLY PAPER
PRODUCTS.
PROTECTION OF FIREFIGHTERS:
HYDROFLUORIC ACID EXPOSURE DURING FIRE FIGHTING:
THIS INFORMATION IS GIVEN FOR THE USE OF PROFESSIONAL FIRE FIGHTERS
RESPONDING TO A WAREHOUSE FIRE WHERE FIRE FROM OTHER MATERIALS MAY
INCINERATE BATTERIES. THIS SECTION IS PROVIDED SOLELY IN CASE OF EXPOSURE,
DURING FIREFIGHTING, TO THE COMBUSTION BY-PRODUCTS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
USE STANDARD INDUSTRIAL CLOTHING IN NORMAL USE. IF HANDLING LARGE
CONTAINERS OF CELLS WEAR STEEL-TOED FOOTWEAR.
ENVIRONMENTAL PRECAUTIONS: NO SPECIAL PRECAUTIONS NECESSARY.
METHODS FOR CONTAINMENT:
TRANSPORT CONTAINER OUTDOORS. HOLD BURNED CELLS AND FIRE CLEANUP SOLIDS
FOR DISPOSAL AS POTENTIAL HAZARDOUS WASTE. UNBURNED CELLS ARE NOT
HAZARDOUS WASTE. A FIRE WITH OVER 100 KG OF CELLS BURNT WILL LIKELY
REQUIRE REPORTING TO ENVIRONMENTAL OFFICIALS. ALWAYS CONSULT AND OBEY ALL
INTERNATIONAL, FEDERAL AND LOCAL ENVIRONMENTAL LAWS.
METHODS FOR CLEAN-UP:
OTHER INFORMATION:
| SECTION 7: HANDLING AND STORAGE | |
HANDLING:
USE ONLY APPROVED CHARGING EQUIPMENT. DO NOT DISASSEMBLE BATTERY OR
BATTERY PACK. DO NOT PUNCTURE, CRUSH OR DISPOSE OF IN FIRE.
STORAGE:
STORE IN A COOL, DRY PLACE AWAY FROM SPARKS AND FLAME. KEEP BELOW
125 DEG. C. KEEP ABOVE -60 DEG. C. CHARGE BETWEEN 0 DEG. C AND 45 DEG. C.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES: NOT NECESSARY UNDER CONDITIONS OF NORMAL USE
ENGINEERING CONTROLS: NOT NECESSARY UNDER CONDITIONS OF NORMAL USE
EYE/FACE PROTECTION: NOT NECESSARY UNDER CONDITIONS OF NORMAL USE
SKIN PROTECTION: NOT NECESSARY UNDER CONDITIONS OF NORMAL USE
RESPIRATORY PROTECTION: NOT NECESSARY UNDER CONDITIONS OF NORMAL USE
GENERAL HYGIENE CONSIDERATIONS:
NOT NECESSARY UNDER CONDITIONS OF NORMAL USE
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
COLOR: N/A
ODOR: NONE
ODOR THRESHOLD: NONE
PHYSICAL STATE: SOLID
PH: N/A
FREEZING POINT: N/A
BOILING POINT: N/A
FLASH POINT: N/A
EVAPORATION RATE: N/A
FLAMMABILITY (SOLID, GAS):
ORGANIC COMPONENTS WILL BURN IF CELL IS INCINERATED.
UPPER FLAMMABILITY LIMIT: N/A
LOWER FLAMMABILITY LIMIT: N/A
VAPOR PRESSURE: N/A
VAPOR DENSITY: N/A
SPECIFIC GRAVITY: N/A
SOLUBILITY (WATER): N/A
PARTITION COEFFICIENT (N-OCTANOL/WATER): N/A
AUTO-IGNITION TEMPERATURE: N/A
PERCENT VOLATILE, WT. %: N/A
VOLATILE ORGANIC COMPOUND (VOC): N/A
CONTENT, WT. %:
| SECTION 10: STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID:
DO NOT CRUSH, PUNCTURE, INCINERATE, IMMERSE IN WATER OR HEAT OVER
212 DEG. F (100 DEG. C). STEEL CASING SLOWLY DISSOLVES IN STRONG MINERAL
ACIDS.
INCOMPATIBLE MATERIALS: WATER, HEAT AND STRONG ACIDS
HAZARDOUS DECOMPOSITION:
HYDROGEN FLUORIDE, PHOSPHORUS OXIDES, CARBON MONOXIDE, CARBON DIOXIDE,
LITHIUM HYDROXIDE, MANGANESE OXIDES, ALUMINUM OXIDE, POSSIBLE
FLUORO-COMPOUNDS, CARBON SOOT
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR. SPONTANEOUS DECOMPOSITION WILL
NOT OCCUR AT NORMAL TEMPERATURE.
| SECTION 11: TOXICOLOGY INFORMATION | |
ACUTE EFFECTS:
ORAL LD50: NONE IN ROUTINE HANDLING OF PRODUCT.
DERMAL LD50: NONE IN ROUTINE HANDLING OF PRODUCT.
INHALATION: NONE IN ROUTINE HANDLING OF PRODUCT.
EYE IRRITATION: NONE IN ROUTINE HANDLING OF PRODUCT.
SKIN IRRITATION: NONE IN ROUTINE HANDLING OF PRODUCT.
SENSITIZATION: NONE IN ROUTINE HANDLING OF PRODUCT.
CHRONIC EFFECT:
CARCINOGENICITY: NONE IN ROUTINE HANDLING OF PRODUCT.
MUTAGENICITY: NONE IN ROUTINE HANDLING OF PRODUCT.
REPRODUCTIVE EFFECTS: NONE IN ROUTINE HANDLING OF PRODUCT.
DEVELOPMENTAL EFFECTS: NONE IN ROUTINE HANDLING OF PRODUCT.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICITY: NONE IN ROUTINE HANDLING OF PRODUCT.
PERSISTENCE/DEGRADABILITY: NONE IN ROUTINE HANDLING OF PRODUCT.
BIOACCUMULATION/ACCUMULATION: NONE IN ROUTINE HANDLING OF PRODUCT.
MOBILITY IN ENVIRONMENT: NONE IN ROUTINE HANDLING OF PRODUCT.
| SECTION 13: DISPOSAL CONSIDERATIONS: | |
DISPOSAL:
DISPOSE IN ACCORDANCE WITH APPROPRIATE REGULATIONS. ALWAYS CONSULT AND
OBEY ALL INTERNATIONAL, FEDERAL, PROVINCIAL/STATE AND LOCAL HAZARDOUS
WASTE DISPOSAL LAWS. SOME JURISDICTIONS REQUIRE RECYCLING OF THIS SPENT
PRODUCT. BATTERY RECYCLING IS ENCOURAGED. LITHIUM ION BATTERIES ARE SAFE
FOR DISPOSAL IN THE NORMAL MUNICIPAL WASTE STREAM SINCE THEY ARE NOT
DEFINED BY THE FEDERAL GOVERNMENT AS HAZARDOUS WASTE. HOWEVER, LITHIUM ION
BATTERIES ARE RECYCLABLE.
THIS PRODUCT DOES NOT CONTAIN MERCURY, CADMIUM OR LITHIUM (METAL).
DO NOT INCINERATE OR SUBJECT BATTERY CELLS TO TEMPERATURES IN EXCESS OF
212 DEG. F (100 DEG. C).
| SECTION 14: TRANSPORTATION INFORMATION | |
U.S. DOT HMR (RE: GROUND TRANSPORT):
PROPER SHIPPING DESCRIPTION:
UN3090 LITHIUM BATTERIES/UN3091 LITHIUM BATTERIES PACKED WITH OR CONTAINED
IN EQUIPMENT; CLASS 9; PG II.
MILWAUKEE RECHARGEABLE LITHIUM-ION TYPE BATTERIES ARE "EXCEPTED"
FROM FULL HAZARDOUS MATERIAL REGULATION BASED ON ELC CONTENT AND/OR
WATT-HOUR (WH) RATING, AND COMPLIANT PACKAGING PER 49 CFR 172.102, SPECIAL
PROVISION 188.
CANADA TDG (RE: GROUND TRANSPORT):
PROPER SHIPPING DESCRIPTION:
UN3480 LITHIUM-ION BATTERIES/UN3481 LITHIUM-ION BATTERIES PACKED WITH OR
CONTAINED IN EQUIPMENT; CLASS 9; PG II.
MILWAUKEE RECHARGEABLE LITHIUM-ION BATTERIES ARE "EXCEPTED" FROM FULL
DANGEROUS GOODS REGULATION BASED ON WATT-HOUR (WH) RATING, AND COMPLIANT
PACKAGING PER TDG SCHEDULE 2, SPECIAL PROVISION 34.
INTERNATIONAL DGR (RE: AIR, SEA, GROUND TRANSPORT):
PROPER SHIPPING DESCRIPTION:
UN3480 LITHIUM-ION BATTERIES/UN3481 LITHIUM-ION BATTERIES PACKED WITH OR
CONTAINED IN EQUIPMENT; CLASS 9; PG II.
MILWAUKEE RECHARGEABLE LITHIUM-ION BATTERIES ARE "EXCEPTED" FROM FULL
DANGEROUS GOODS REGULATION BASED ON WATT-HOUR (WH) RATING, AND COMPLIANT
PACKAGING AS DESCRIBED IN THE FOLLOWING INTERNATIONAL DANGEROUS GOOD
REGULATIONS:
ICAO TECHNICAL INSTRUCTIONS: PACKING INSTRUCTIONS 965; 966; 967.
IATA DANGEROUS GOODS REGULATIONS: PACKING INSTRUCTIONS 965; 966; 967.
IMDG CODE: SPECIAL PROVISION 188.
UN MODEL REGULATIONS ON THE TRANSPORT OF DANGEROUS GOODS:
SPECIAL PROVISION 188.
UN EUROPEAN AGREEMENTS (ADR/RID/ADN): SPECIAL PROVISION 188.
AUSTRALIAN DANGEROUS GOODS (ADG): SPECIAL PROVISION 188.
UN BATTERY TESTING:
MILWAUKEE RECHARGEABLE LITHIUM-ION BATTERIES LISTED IN SECTION 1 HAVE
PASSED THE RELEVANT TRANSPORTATION TEST REQUIREMENTS AS DESCRIBED IN THE
UN MANUAL OF TESTS AND CRITERIA, PART III, SECTION 38.3, "LITHIUM
BATTERIES".
UN SECTION 38.3 TEST REPORTS ARE MAINTAINED ON FILE AT THE CORPORATE
HEADQUARTERS OF MILWAUKEE ELECTRIC TOOL CORPORATION LOCATED AT
13135 W. LISBON RD., BROOKFIELD, WI, USA 53005-2550.
| SECTION 15: REGULATORY INFORMATION | |
GLOBAL INVENTORIES:
TSCA:
UNITED STATES:
SEE SEC. 14. COMPLIANT WITH, RELEVANT TRANSPORTATION TEST REQUIREMENTS AS
DESCRIBED IN THE UN MANUAL OF TESTS & CRITERIA, PART III, SUB-SECTION
38.3.
DSL:
CANADA:
SEE SEC. 14. COMPLIANT WITH, RELEVANT TRANSPORTATION TEST REQUIREMENTS AS
DESCRIBED IN THE UN MANUAL OF TESTS & CRITERIA, PART III, SUB-SECTION
38.3.
ECL:
KOREA:
COMPLIANT WITH, RELEVANT TRANSPORTATION TEST REQUIREMENTS AS DESCRIBED IN
THE UN MANUAL OF TESTS & CRITERIA, PART III, SUB-SECTION 38.3.
PICCS:
PHILIPPINES:
COMPLIANT WITH, RELEVANT TRANSPORTATION TEST REQUIREMENTS AS DESCRIBED IN
THE UN MANUAL OF TESTS & CRITERIA, PART III, SUB-SECTION 38.3.
ENCS:
JAPAN:
COMPLIANT WITH, RELEVANT TRANSPORTATION TEST REQUIREMENTS AS DESCRIBED IN
THE UN MANUAL OF TESTS & CRITERIA, PART III, SUB-SECTION 38.3.
AICS:
AUSTRALIA:
COMPLIANT WITH, RELEVANT TRANSPORTATION TEST REQUIREMENTS AS DESCRIBED IN
THE UN MANUAL OF TESTS & CRITERIA, PART III, SUB-SECTION 38.3.
IECS:
CHINA:
COMPLIANT WITH, RELEVANT TRANSPORTATION TEST REQUIREMENTS AS DESCRIBED IN
THE UN MANUAL OF TESTS & CRITERIA, PART III, SUB-SECTION 38.3.
EINECS:
EUROPEAN UNION:
COMPLIANT WITH, RELEVANT TRANSPORTATION TEST REQUIREMENTS AS DESCRIBED IN
THE UN MANUAL OF TESTS & CRITERIA, PART III, SUB-SECTION 38.3.
SARA 313 INFORMATION:
SARA TITLE III SECTION 313:
THIS PRODUCT DOES NOT CONTAIN REGULATED LEVELS OF ANY TOXIC CHEMICAL
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) AND 40 CFR
PART 372.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65):
THIS PRODUCT DOES NOT CONTAIN REGULATED LEVELS OF ANY TOXIC CHEMICAL
SUBJECT TO THE REPORTING REQUIREMENTS OF CALIFORNIA SAFE DRINKING WATER
AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65)
WHMIS:
CANADIAN WORKPLACE:
THIS PRODUCT DOES NOT CONTAIN REGULATED LEVELS OF ANY TOXIC CHEMICAL
SUBJECT TO THE REPORTING REQUIREMENTS
| SECTION 16: OTHER INFORMATION | |
NFPA 704:
NATIONAL FIRE PROTECTION ASSOCIATION:
HEALTH N/A
FIRE N/A
REACTIVITY N/A
0 = MINIMAL HAZARD
1 = SLIGHT HAZARDOUS
2 = MODERATE HAZARD
3 = SEVERE HAZARD
THE INFORMATION AND RECOMMENDATIONS SET FORTH ARE MADE IN GOOD FAITH AND
BELIEVED TO BE ACCURATE AS OF THE DATE OF PREPARATION. MILWAUKEE ELECTRIC
TOOL CORPORATION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE
ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THERETO.
MET P/N 58-97-0500
06A