| Common Name: | BEN'S 30 WILDERNESS FORMULA, ECO-SPRAY |
| Manufacturer: | TENDER |
| SDS Revision Date: | 4/13/2012 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3UUJ4, 40P489, 9UDJ4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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TENDER CORPORATION
MATERIAL SAFETY DATA SHEET
SAFETY DATA SHEET
PREPARED ACCORDING TO 29 CFR 1910.1200, REGULATION (EC) NO. 1272/2008 (GHS)
AND CANADIAN CONTROLLED PRODUCTS ACT (CPR)
| SECTION 1: PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: BEN'S 30 WILDERNESS FORMULA, ECO-SPRAY
EPA REG. NO.: 56575-11
PRODUCT CODE: 0001-1430
MSDS DATE: APRIL 13, 2012
MSDS REVISION NO.: 2
USE: INSECT REPELLENT
MANUFACTURER: TENDER CORPORATION
ADDRESS:
106 BURNDY ROAD
LITTLETON, NH 03561
INFORMATION CALLS: 800-258-4696
E-MAIL: CUSTOMERSERVICE@TENDERCORP.COM
FAX PHONE: 603-444-6735
EMERGENCY PHONE:
SPILLS:
VEOLIA: (800) 354-2382
MEDICAL:
POISON CONTROL CENTER INFORMATION: (800) 258-4696
HMIS HAZARD RATING:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
PERSONAL PROTECTION X
| SECTION 2: HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
CLEAR, DEET ODOR, NON-FLAMMABLE BUT COMBUSTIBLE, WATER SOLUBLE, LIQUID IN
PRESSURIZED CAN
HAZARD CLASSIFICATION: WARNING
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
PICTOGRAM: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENT(S):
H302: HARMFUL IF SWALLOWED
H319: CAUSES SERIOUS EYE IRRITATION
H412:
HARMFUL TO AQUATIC ORGANISMS AND MAY CAUSE LONG-TERM ADVERSE EFFECTS
IN THE AQUATIC ENVIRONMENT
PRECAUTIONARY STATEMENT(S):
P102: KEEP OUT OF THE REACH OF CHILDREN
P234: KEEP IN ORIGINAL CONTAINER
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING
P301+330+331+315:
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL
ADVICE/ATTENTION.
P273: AVOID RELEASE TO THE ENVIRONMENT
ROUTES OF EXPOSURE: DERMAL, ORAL
POTENTIAL HEALTH EFFECTS:
INHALATION: MAY CAUSE IRRITATION TO LUNGS
SKIN CONTACT:
DO NOT USE OVER CUTS, WOUNDS OR IRRITATED SKIN
PRE-EXISTING SKIN DISORDERS MAY BE AGGRAVATED BY EXPOSURE
EYE CONTACT:
PROLONGED CONTACT MAY CAUSE IRRITATION, WITH REDNESS, PAIN, TEARING,
BLURRED VISION AND CONJUNCTIVITIS.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT CONC.(%) CAS NO. EC NO. CLASSIFICATION
DEET (N,N-DIETHYL- 29 TO 31 134-62-3 205-149-7 WHMIS D2B-TOXIC
M-TOLUAMIDE) EU-XN;XI; R22-36/38
R52-53
WATER 30 TO 40 7732-18-5 231-791-2 NONE
DIPROPYLENE GLYCOL 20 TO 30 34590-94-8 252-104-2 WHMIS CLASS B3
MONOMETHYL ETHER COMBUSTIBLE LIQUID
PROPYLENE GLYCOL 25 TO 30 57-55-6 200-338-0 NONE
SEE SECTION 8 - "EXPOSURE CONTROLS/PERSONAL PROTECTION" FOR EXPOSURE
GUIDELINES
| SECTION 4: FIRST AID MEASURES | |
INHALATION:
MOVE VICTIM TO FRESH AIR. APPLY ARTIFICIAL RESPIRATION IF INDICATED.
CONTACT A PHYSICIAN IF WARRANTED.
CONTACT WITH SKIN:
TAKE OFF CONTAMINATED CLOTHING. IMMEDIATELY WASH GENTLY AND THOROUGHLY WITH
LUKE WARM, GENTLY FLOWING WATER AND NON-ABRASIVE SOAP FOR 15-20 MINS. IF
SKIN IRRITATION OR RASH OCCURS, SEE A DOCTOR. THOROUGHLY CLEAN CLOTHING
BEFORE REUSE OR DISPOSE OF SAFELY.
CONTACT WITH EYES:
IMMEDIATELY FLUSH THE CONTAMINATED EYE(S) WITH LUKEWARM, GENTLY FLOWING
WATER FOR 15-20 MINUTES, WHILE HOLDING THE EYELID(S) OPEN. REMOVE CONTACT
LENSES, IF PRESENT AND EASY TO DO. TAKE CARE NOT TO RINSE CONTAMINATED
WATER INTO THE UNAFFECTED EYE OR ONTO THE FACE. IF IRRITATION OR PAIN
PERSISTS, SEE A DOCTOR.
INGESTION:
HAVE VICTIM RINSE MOUTH WITH WATER. NEVER GIVE ANYTHING BY MOUTH IF THE
VICTIM IS RAPIDLY LOSING CONSCIOUSNESS, OR IS UNCONSCIOUS OR CONVULSING.
DO NOT INDUCE VOMITING. CONTACT A PHYSICIAN IF WARRANTED.
| SECTION 5: FIRE-FIGHTING MEASURES | |
FIRE AND EXPLOSIVE PROPERTIES:
NON FLAMMABLE - THIS PRODUCT IS COMBUSTIBLE BUT NOT FLAMMABLE OR EXPLOSIVE
FLASH POINT: >250 DEG. C
FLAMMABLE LIMITS: NOT APPLICABLE
EXTINGUISHING MEDIA:
WATER SPRAY
CARBON DIOXIDE
DRY CHEMICAL OR FOAM
SPECIFIC HAZARDS:
IN CASE OF FIRE, HAZARDOUS COMBUSTION GASES MAY BE FORMED:
CARBON MONOXIDE (CO)
CARBON DIOXIDE (CO2)
NITROGEN OXIDES (NOX)
PROTECT EQUIPMENT FOR FIREFIGHTERS:
USE SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING
FURTHER INFORMATION:
FIRE RESIDUES AND CONTAMINATED FIREFIGHTING WATER MUST BE DISPOSED OF IN
ACCORDANCE WITH LOCAL REGULATIONS
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
FOR LARGE SPILLS:
ISOLATE THE HAZARD AREA. KEEP OUT UNNECESSARY AND UNPROTECTED PERSONNEL.
INCREASE VENTILATION TO AREA OR MOVE LEAKING CONTAINER TO A WELL-VENTILATED
AND SECURE AREA. USE THE PERSONAL PROTECTIVE EQUIPMENT RECOMMENDED IN
SECTION 8 OF THIS MSDS. REVIEW SECTION 7 (HANDLING) OF THIS MSDS BEFORE
PROCEEDING WITH CLEANUP.
ENVIRONMENTAL PRECAUTIONS: DO NOT CONTAMINATE WATER BY DISPOSAL OF WASTES
METHOD FOR CONTAINMENT AND CLEAN-UP:
PREVENT PRODUCT FROM ENTERING DRAINS AND VENTILATION SYSTEMS. CONTAIN AND
SOAK UP SPILL WITH ABSORBENT THAT DOES NOT REACT WITH SPILLED PRODUCT.
PLACE USED ABSORBENT INTO SUITABLE, COVERED LABELED CONTAINERS FOR
DISPOSAL.
LARGE SPILLS:
DIKE SPILL PRODUCT TO PREVENT RUNOFF. RECOVER CONTAMINATED WATER FOR
APPROPRIATE DISPOSAL.
REPORT SPILLS TO LOCAL HEALTH, SAFETY AND ENVIRONMENTAL AUTHORITIES, AS
REQUIRED.
| SECTION 7: HANDLING AND STORAGE | |
HANDLING:
READ ENTIRE LABEL BEFORE USING. USE STRICTLY IN ACCORDANCE WITH LABEL
PRECAUTIONARY STATEMENTS AND DIRECTIONS.
DO NOT CONTAMINATE FOOD OR FEED.
STORAGE:
KEEP PRODUCT IN ITS ORIGINAL CONTAINER.
KEEP CONTAINER TIGHTLY CLOSED.
STORE THIS PRODUCT IN A COOL, DRY PLACE AWAY FROM HEAT OR DIRECT SUNLIGHT.
PROTECT FROM FREEZING.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
GENERAL VENTILATION IS USUALLY ADEQUATE. WHEN HANDLING LARGE QUANTITIES OF
CONCENTRATED PRODUCT; USE LOCAL EXHAUST VENTILATION, IF NECESSARY.
PERSONAL PROTECTIVE EQUIPMENT (PPE): NONE REQUIRED.
EXPOSURE GUIDELINES:
INGREDIENT CAS NO. % EXPOSURE LIMITS
ACGIH ACGIH OSHA
TLV-TWA TLV-STEL PEL-TWA
DIPROPYLENEGLYCOL 34590-94-8 <20 150 PPM 150 PPM 100 PPM
MONOMETHYL ETHER
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR LIQUID
ODOR: INSECTICIDAL (DEET)
PH: 7.0
BOILING POINT: NOT DETERMINED
MELTING POINT: NOT DETERMINED
RELATIVE DENSITY (H2O=1) @25 DEG. C: 1.0 TO 1.2 GM/ML
VAPOR PRESSURE (MMHg) @ DEG. C: NOT APPLICABLE
VAPOR DENSITY (AIR=1): NOT APPLICABLE
FLASH POINT: GREATER THAN 250 DEG. C
SOLUBILITY IN WATER: SOLUBLE
SOLUBILITY IN SOLVENTS: SOLUBLE IN ALCOHOL
VISCOSITY: 5-25 CPS @ 25 DEG. C
VOLATILE ORGANIC COMPOUNDS (VOC): <16%
PARTITION COEFFICIENT: NOT DETERMINED
| SECTION 10: STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: EXTREME TEMPERATURES
INCOMPATIBILITY (MATERIAL TO AVOID): OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE, NITROGEN OXIDES
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE PREPARATION HAS NOT BEEN TESTED FOR ALL TOXICOLOGICAL EFFECTS; SOME
ARE CLASSIFIED ON THE BASIS OF THE KNOWN HAZARDS OF THE COMPONENTS.
ACUTE ORAL TOXICITY:
LD50: GREATER THAN 3,129 MG/KG FEMALE RAT
METHOD: OPPTS 870.1100, OECD 425
SOURCE: PRODUCT TESTED 2004
ACUTE INHALATION TOXICITY:
LC50: GREATER THAN 5.11 MG/L
METHOD OPPTS 870.1300, OECD 403
SOURCE: PRODUCT TESTED 2008
ACUTE DERMAL TOXICITY:
LD50: GREATER THAN 2000 MG/KG FEMALE & MALE RAT
METHOD: OPPTS 870.1200, OECD 402
SOURCE: PRODUCT TESTED 2008
IRRITANT EFFECT ON SKIN:
SLIGHTLY IRRITATING, IRRITATION CLEARED BY 72HRS (PDII: 1.3)
METHOD: OPPTS 870.2500, OECD 404
SOURCE: PRODUCT TESTED 2004
IRRITANT EFFECT ON EYES:
SEVERLY IRRITATING, IRRITATION CLEARED BY 14 DAYS (MMTS 28.7)
METHOD: OPPTS 870.2400, OECD 405
SOURCE: PRODUCT TESTED 2004
SENSITIZATION: NOT DETERMINED
METHOD:
SOURCE:
MUTAGENICITY: NOT MUTAGENIC
METHOD: AMES TEST OPPTS 870.5100, OECD 471
SOURCE: PRODUCT TESTED 2008
CARCINOGENICITY/REPRODUCTIVE TOXICITY:
NOT DETERMINED; NONE OF THE COMPONENTS PRESENT IN THIS MATERIAL AT
CONCENTRATIONS OF 0.1% OR GREATER ARE LISTED BY IARC, NTP, OSHA OR ACGIH
AS BEING CARCINOGENS.
SOURCE: SAFETY DATA SHEETS OF COMPONENTS
SPECIFIC TARGET ORGAN TOXICITY:
SINGLE EXPOSURE (GHS): NO DATA AVAILABLE
REPEATED EXPOSURE (GHS): NO DATA AVAILABLE
SIGNS AND SYMPTOMS OF EXPOSURE:
POTENTIAL HEALTH EFFECTS:
INHALATION: MAY CAUSE IRRITATION TO LUNGS
SKIN CONTACT:
DO NOT USE OVER CUTS, WOUNDS OR IRRITATED SKIN. PRE-EXISTING SKIN DISORDERS
MAY BE AGGRAVATED BY EXPOSURE
EYE CONTACT:
PROLONGED CONTACT MAY CAUSE IRRITATION, WITH REDNESS, PAIN, TEARING,
BLURRED VISION AND CONJUNCTIVITIS.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
TARGET ORGANS: CENTRAL NERVOUS SYSTEM
| SECTION 12: ECOLOGICAL INFORMATION | |
GENERAL COMMENTS:
ECOTOXICOLOGICAL DATA HAVE NOT BEEN DETERMINED SPECIFICALLY FOR THIS
PRODUCT, BUT IT IS CLASSIFIED ON THE BASIS OF THE KNOWN HAZARDS OF THE
COMPONENTS. THIS SECTION IS NOT REQUIRED BY WHMIS.
MOBILITY:
THE PRODUCT IS WATER-BASED AND EXPECTED TO BE MOBILE IN THE AQUATIC
ENVIRONMENT.
BIODEGRADABILITY:
N,N-DIETHYL-M-TOLUAMIDE - 83.8% (28D)
METHOD: OECD 301B
SOURCE: LITERATURE
BIOACCUMULATION:
N,N-DIETHYL-M-TOLUAMIDE IS NOT READILY BIODEGRADABLE IN THE ENVIRONMENT,
ACCORDING TO ECBI/07/00 REV. 3 (29/8/00)
TOXICITY:
N,N-DIETHYL-M-TOLUAMIDE HAS BEEN SHOWN TO BE TOXIC TO AQUATIC ORGANISMS.
LC50 APPROX. 97 MG/L (96H RAINBOW TROUT)
METHOD: OECD 203
SOURCE: LITERATURE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD: DO NOT REUSE ANY EMPTY CONTAINERS.
US:
THIS PRODUCT IS NOT A HAZARDOUS SOLID WASTE AS DEFINED IN RESOURCE
CONSERVATION RECOVERY ACT REGULATIONS (40 CFR 261)AND SHOULD BE DISPOSED
OF ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS DISPOSE OF PARTIALLY
FILLED AND EMPTY CONTAINERS BY WRAPPING AND DISCARDING IN TRASH.
INTERNATIONAL:
THIS PRODUCT SHOULD NOT BE DISPOSED OF VIA THE DRAINS OR BY LANDFILL.
DISPOSAL MUST BE IN ACCORDANCE WITH CURRENT NATIONAL AND LOCAL REGULATIONS.
CHEMICAL RESIDUES GENERALLY COUNT AS SPECIAL WASTE, AND THEIR DISPOSAL MAY
BE REGULATED IN THE EC MEMBER COUNTRIES THROUGH CORRESPONDING LAWS AND
REGULATIONS. WE RECOMMEND THAT YOU CONTACT EITHER THE AUTHORITIES OR
APPROVED WASTE DISPOSAL COMPANIES WHO WILL ADVISE YOU ON HOW TO DISPOSE OF
SPECIAL WASTE.
GENERAL EU REQUIREMENTS ARE GIVEN IN THE WASTE FRAMEWORK DIRECTIVE
(75/442/EEC) AND THE HAZARDOUS WASTE DIRECTIVE (91/689/EEC). PACKAGING MAY
CONTAIN RESIDUES OF THE PRODUCT AND SHOULD BE TREATED ACCORDINGLY.
| SECTION 14: TRANSPORT INFORMATION | |
SHIPPING INFORMATION:
MARINE POLLUTANT: NO
REGULATION UN NO. PROPER CLASS PACKAGE ADDITIONAL
SHIPPING NAME GROUP INFORMATION
U.S. DEPARTMENT OF N/A CONSUMER ORM-D N/A
TRANSPORTATION COMMODITY
(DOT) - NONBULK
U.S. DEPARTMENT OF NOT
TRANSPORTATION REGULATED
(DOT) - BULK
CANADIAN TRANSPORTATION N/A CONSUMER ORM-D N/A
OF DANGEROUS GOODS(TDG) COMMODITY
INTERNATIONAL MARITIME NOT
DANGEROUS GOODS (IMDG) REGULATED
INTERNATIONAL AIR N/A CONSUMER ORM-D N/A
TRANSPORT ASSOC. COMMODITY
(IATA)
THE TRANSPORTATION REGULATIONS ARE CITED ACCORDING TO INTERNATIONAL
REGULATIONS AND IN THE FORM APPLICABLE TO THE UNITED STATES AND CANADA.
POSSIBLE NATIONAL DEVIATIONS IN OTHER COUNTRIES ARE NOT CONSIDERED.
| SECTION 15: REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA (TOXIC SUBSTANCE CONTROL ACT):
ALL COMPONENTS OF THIS PRODUCT ARE LISTED OR EXEMPT ON THE TSCA LIST
CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): NONE
CERCLA HAZARDOUS SUBSTANCE: NONE
CERCLA REPORTABLE QUANITIY: NONE
RCRA 261 (RESOURCE CONSERVATION RECOVERY ACT):
THIS PRODUCT IS NOT DEFINED AS A HAZARDOUS SOLID WASTE..
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT):
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (TPQ): NONE
311/312 HAZARD CLASS: NONE
313 REPORTABLE INGREDIENTS: NONE
U.S. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 WARNING: NONE
STATES RIGHT TO KNOW: PENNSYLVANIA - PROPYLENE GLYCOL (57-55-6)
CANADIAN REGULATIONS:
WHMIS CLASSIFICATION:
B3: COMBUSTABLE LIQUID
D2B: TOXIC
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR.
DOMESTIC SUBSTANCE LIST (DSL)/NON-DOMESTIC SUBSTANCE LIST (NDSL):
ALL COMPONENTS ARE LISTED OR EXEMPT
CANADIAN INGREDIENT DISCLOSURE LIST:
N,N-DIETHYL-M-TOLUAMIDE(134-62-3), DIPROPYLENEGLYCOL MONOMETHYL ETHER
(34590-94-8), AND PROPYLENE GLYCOL (57-55-6)
EU REGULATIONS:
LABELING IN ACCORDANCE WITH EC-DIRECTIVES:
HAZARD SYMBOLS:
TOXIC TO AQUATIC ORGANISMS
IRRITANT
HAZARDOUS COMPONENT(S) TO BE INDICATED ON LABEL:
N,N-DIETHYL-M-TOLUAMIDE(CAS # 134-62-3)
R PHRASES:
22: HARMFUL IF SWALLOWED
36/38: IRRITATING TO EYES AND SKIN
52/53:
HARMFUL TO AQUATIC ORGANISMS AND MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT
S PHRASES:
2: KEEP OUT OF THE REACH OF CHILDREN
26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE
49: KEEP ONLY IN THE ORIGINAL CONTAINER
61:
AVOID RELEASE TO THE ENVIRONMENT. REFER TO SPECIAL INSTRUCTIONS/SAFETY DATA
SHEET.
| SECTION 16: OTHER INFORMATION | |
HMIS:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
SPECIAL NONE
4=EXTREME
3=HIGH
2=MODERATE
1=SLIGHT
0=INSIGNIFICANT
REVISED SECTIONS OR REASON FOR REVISION:
ORIGIN DATE: APRIL 21, 2011
1-(6-7-11)-CORRECTED CAS # FOR WATER
2-(4-13-12)-FORMATING CHANGES, ADDED PRODUCT CODE, E-MAIL, REMOVED SKIN
IRRATION WARNINGH-315 PER ACTUAL PRODUCT TESTING RESULTS
DISCLAIMER:
THE INFORMATION PROVIDED HEREIN WAS BELIEVED TO BE ACCURATE, TO THE BEST
KNOWLEDGE OF TENDER CORPORATION, AT THE TIME OF PREPARATION FROM A
COMPILATION OF SOURCES BELIEVED TO BE RELIABLE AND IS FURNISHED WITHOUT
WARRANTY, EXPRESSED OR IMPLIED. IT IS THE RESPONSIBILITY OF THE USER TO
INVESTIGATE AND UNDERSTAND OTHER PERTINENT SOURCES OF INFORMATION, TO
COMPLY WITH ALL LAWS AND PROCEDURES APPLICABLE TO THE SAFE HANDLING,
STORAGE AND USE OF THIS PRODUCT AND TO DETERMINE THE SUITABILITY OF THE
PRODUCT FOR ITS INTENDED USE. THIS DATA SHEET RELATES ONLY TO THE SPECIFIC
PRODUCT LISTED AND DOES NOT RELATE TO USE IN COMBINATION OR IN ANY PROCESS
WITH OTHER MATERIALS
DATE PRINTED: 16 JANUARY 2013