| Common Name: | TIDE PODS VARIANTS: TIDE PODS MYSTIC FOREST, TIDE PODS OCEAN MIST, TIDE PODS SPR |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 2/1/2011 |
| SDS Format: | No Format Specified |
| Item Number(s): | 40K039 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G
THE PROCTER & GAMBLE COMPANY
P & G HOUSEHOLD CARE
FABRIC & HOME CARE INNOVATION CENTER
5299 SPRING GROVE AVENUE
CINCINNATI, OH 45217-1087
MATERIAL SAFETY DATA SHEET
MSDS: RQ1003262
ISSUE DATE: FEBRUARY 2011
| SECTION I - PRODUCT IDENTIFICATION |  |
IDENTITY: 3-IN-1 DETERGENT - UNIT DOSE LIQUID LAUNDRY DETERGENT
THIS MSDS APPLIES TO THE FOLLOWING TIDE PODS VARIANTS:
TIDE PODS MYSTIC FOREST
TIDE PODS OCEAN MIST
TIDE PODS SPRING MEADOW
EMERGENCY TELEPHONE NUMBER:
24HR P&G OPERATOR: 1-800-879-8433
TRANSPORTATION EMERGENCIES:
CHEMTREC: 1-800-424-9300
* THIS MSDS APPLIES TO ALL USES/HANDLING OF THESE PRODUCTS IN A RETAIL
PACKAGE FOR CONSUMER HOME USE.
| SECTION II - HAZARDS IDENTIFICATION | |
HEALTH HAZARDS (ACUTE AND CHRONIC):
INGESTION: MAY CAUSE TRANSIENT GASTROINTESTINAL IRRITATION.
EYE CONTACT: MAY CAUSE MODERATE IRRITATION.
SKIN CONTACT:
PROLONGED CONTACT WITH CONCENTRATED MATERIAL MAY BE DRYING OR TRANSIENTLY
IRRITATING TO SKIN.
INHALATION: MAY CAUSE TRANSIENT RESPIRATORY IRRITATION.
SIGNS AND SYMPTOMS OF EXPOSURE:
INGESTION: MAY RESULT IN NAUSEA, VOMITING, AND/OR DIARRHEA.
EYE CONTACT:
MAY CAUSE STINGING, TEARING, ITCHING, SWELLING, AND/OR REDNESS.
SKIN:
PROLONGED CONTACT WITH CONCENTRATED MATERIAL MAY BE DRYING OR TRANSIENTLY
IRRITATING TO SKIN.
INHALATION: MAY CAUSE TRANSIENT RESPIRATORY IRRITATION.
| SECTION III - COMPOSITION AND INGREDIENTS | |
INGREDIENTS/CHEMICAL NAME:
ANIONIC AND NONIONIC SURFACTANTS, ETHOXYLATED POLYETHYLENE POLYAMINE
(POLYMER) AND ENZYMES.
HAZARDOUS INGREDIENTS AS DEFINED BY OSHA, 29 CFR 1910.1200.
COMMON NAME CHEMICAL NAME CAS NO. COMPOSITION LD50
RANGE
POLYMER ETHOXYLATED 68130-99-4 3-7% >5 G/KG
POLYETHYLENE
POLYAMINE
ANIONIC ALCOHOLS, SULFATED, 68910-32-7 15-40% TOTAL 1.09 G/KG
SURFACTANTS NEUTRALIZED
ALCOHOLS, 162201-45-8 5. G/KG
ETHOXYLATED,
SULFATED,
NEUTRALIZED
NON-IONIC ALCOHOLS 68002-97-1 7-13% >1000 MG/KG
SURFACTANTS ETHOXYLATED
| SECTION IV - FIRST AID INFORMATION | |
EMERGENCY AND FIRST AID PROCEDURES:
INGESTION:
DRINK A GLASSFUL OF WATER OR MILK AND CALL A POISON CONTROL CENTER OR
DOCTOR IMMEDIATELY. DO NOT INDUCE VOMITING.
EYE CONTACT:
RINSE IMMEDIATELY WITH WATER FOR 15 MINUTES AND SEEK MEDICAL CARE.
SKIN: RINSE THOROUGHLY WITH WATER. REMOVE CONTAMINATED CLOTHING.
IF SYMPTOMS PERSIST OR REOCCUR, SEEK MEDICAL ATTENTION.
OTHER:
CONSUMER PRODUCT PACKAGE HAS A CAUTION STATEMENT:
"CAUTION:
EYE IRRITANT. MAY BE HARMFUL IF SWALLOWED. KEEP OUT OF REACH OF CHILDREN.
DO NOT INGEST. MAY IRRITATE EYES. DO NOT GET IN EYES. TO PREVENT PACS FROM
DISSOLVING BEFORE USE, YOU SHOULD ALWAYS CLOSE THE PACKAGE AND HANDLE WITH
DRY HANDS.
FIRST AID TREATMENT:
CONTAINS NONIONIC AND ANIONIC SURFACTANTS, ETHOXYLATED POLYETHYLENE
POLYAMINE (POLYMER) AND ENZYMES. IF SWALLOWED, GIVE A GLASS OF WATER OR
MILK AND CALL A POISON CONTROL CENTER OR DOCTOR IMMEDIATELY. DO NOT INDUCE
VOMITING. IF IN EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER FOR 15
MINUTES, AND SEEK MEDICAL ADVICE. IF ON SKIN OR CLOTHING, REMOVE
CONTAMINATED CLOTHING AND RINSE SKIN WELL WITH WATER.
| SECTION V - FIRE FIGHTING INFORMATION | |
FLAMMABLE PROPERTIES:
FLASHPOINT: >200F. MATERIAL DOES NOT SUSTAIN COMBUSTION.
EXPLOSIVE LIMITS:
LEL: N/A
UEL: N/A
AUTOIGNITION TEMPERATURE: N/A
SUITABLE EXTINGUISHING MEDIA: CO2, WATER, FOAM, DRY CHEMICAL.
UNSUITABLE EXTINGUISHING MEDIA: NOT KNOWN.
PROTECTION OF FIRE FIGHTERS:
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL MIXTURE: NOT KNOWN.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
STANDARD SELF-CONTAINED BREATHING APPARATUS (SCBA) AND FULL FIRE FIGHTING
TURN-OUT GEAR.
| SECTION VI - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION VIII).
ENVIRONMENTAL PRECAUTIONS:
DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL REGULATIONS. SMALL OR
HOUSEHOLD QUANTITIES MAY BE DISPOSED OF IN REFUSE OR IN SEWER. FIRST CHECK
WITH YOUR LOCAL WATER TREATMENT PLANT. FOR LARGER QUANTITIES, INCINERATION
IS PREFERRED. DO NOT LANDFILL.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
FLUSH SMALL OR HOUSEHOLD QUANTITIES DOWN ACCEPTABLE SEWER (CONTAINS
BIODEGRADABLE SURFACTANTS). PREVENT SPILLS FROM REACHING A WATERWAY.
SORBENTS MAY BE USED.
| SECTION VII - HANDLING AND STORAGE | |
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
NO UNUSUAL PRECAUTIONS NECESSARY.
OTHER PRECAUTIONS:
INDUSTRIAL SETTING:
WHEN HANDLING BULK LIQUID, OPERATIONS OR PROCEDURES WHICH PRODUCE MISTS
OR AEROSOLS SHOULD BE AVOIDED..
| SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION | |
RESPIRATORY PROTECTION (SPECIFY TYPE): NONE REQUIRED WITH NORMAL USE.
VENTILATION:
LOCAL EXHAUST: NONE REQUIRED WITH NORMAL CONSUMER USE.
MECHANICAL (GENERAL): NORMAL/GENERAL DILUTION VENTILATION IS ACCEPTABLE.
SPECIAL: NONE
OTHER: NONE
EYE PROTECTION: NONE REQUIRED WITH NORMAL CONSUMER USE.
INDUSTRIAL SETTING:
CHEMICAL GOGGLES OR OTHER LIQUID/AEROSOL TIGHT EYE PROTECTION SHOULD BE
USED IF SPLASH OR EXPOSURE IS POSSIBLE.
PROTECTIVE GLOVES: NONE REQUIRED WITH NORMAL HOUSEHOLD USE.
INDUSTRIAL SETTING:
PROTECTIVE GLOVES (RUBBER, NEOPRENE) SHOULD BE USED IF HANDLING OF THE
MATERIAL COULD RESULT IN INCIDENTAL OR PROLONGED CONTACT.
OTHER PROTECTIVE EQUIPMENT: NONE REQUIRED WITH NORMAL USE.
| SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
TIDE PODS IS A THREE COMPARTMENT UNIT DOSE PRODUCT. THE COMPARTMENTS ARE
WHITE, BLUE AND ORANGE.
FLASH POINT: >200 DEG. F
ODOR: ALL PRODUCTS CONTAIN PERFUME/FRAGRANCE
EVAPORATION RATE (NBUOAC=1): NOT KNOWN
ODOR THRESHOLD: NOT KNOWN.
EXPLOSIVE LIMITS:
LEL: N/A
UEL: N/A
PHYSICAL STATE: LIQUID.
PERCENT VOLATILE BY VOLUME (%):
VAPOR PRESSURE (MMHg): 16 MMHg @ 20 DEG. C
SPECIFIC GRAVITY (H2O=1): 1.0675
VAPOR DENSITY (AIR=1): NOT KNOWN
MELTING/FREEZING POINT: N/A
BOILING POINT RANGE DEG. F:
PH: 6.8-7.4
COEFFICIENT OF WATER/OIL DISTRIBUTION: N/A
RESERVE ALKALINITY: N/A
SOLUBILITY IN WATER: COMPLETELY SOLUBLE.
| SECTION X - STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: STABLE.
CONDITIONS TO AVOID: NONE KNOWN.
MATERIALS TO AVOID: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE KNOWN.
| SECTION XI - TOXICOLOGICAL INFORMATION | |
LIQUIDTAB TIDE FORMULAS HAVE A LOW ORDER OF TOXICITY. IF INGESTED, IT MAY
BE MILDLY IRRITATING. IT IS EXPECTED TO BE MODERATELY EMETIC.
LD50 (ORAL, ESTIMATED): >2 G/KG
ED50 (EMESIS, ESTIMATED): APPROX. 0.5 G/KG
CHRONIC EFFECTS: NO CHRONIC HEALTH EFFECTS REPORTED.
TARGET ORGANS: NO TARGET ORGANS REPORTED.
CARCINOGENICITY:
NTP: NO
IARC: NO
OSHA: NO
| SECTION XII - ECOLOGICAL INFORMATION | |
BASED ON ECOTOXICITY AND ENVIRONMENTAL FATE DATA FOR THE INDIVIDUAL
INGREDIENTS IN THESE MIXTURES, AND FOR RELATED CONSUMER HOUSEHOLD CLEANING
PRODUCT FORMULATIONS, IT IS EXPECTED THAT THESE MIXTURES WOULD EXHIBIT A
NON-HAZARDOUS ORDER OF TOXICITY AT RELEVANT ENVIRONMENTAL CONCENTRATIONS.
| SECTION XIII - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
PRODUCTS COVERED BY THIS MSDS, IN THEIR ORIGINAL FORM, WHEN DISPOSED AS
WASTE, ARE CONSIDERED NON-HAZARDOUS WASTE ACCORDING TO FEDERAL RCRA
REGULATIONS (40 CFR 261). DISPOSAL SHOULD BE IN ACCORDANCE WITH ALL
FEDERAL, STATE/PROVINCIAL AND LOCAL REGULATIONS.
HOUSEHOLD USE:
CONSUMER PRODUCED HOUSEHOLD SOLUTIONS MAY BE DISPOSED OF DOWN THE DRAIN
WITH RUNNING WATER. CONSUMER MAY DISCARD EMPTY CONTAINER IN TRASH, OR
RECYCLE WHERE FACILITIES EXIST.
| SECTION XIV - TRANSPORT INFORMATION | |
US DOT:
THESE PRODUCTS ARE NOT REGULATED WHEN TRANSPORTED BY GROUND IN FINISHED
PRODUCT PACKAGING.
BULK PACKAGES (>119 GALLONS) ARE REGULATED AS:
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S.
(ALCOHOL ETHOXYLATES), 9, III, MARINE POLLUTANT.
IATA: THESE PRODUCTS ARE NOT REGULATED WHEN TRANSPORTED BY AIR.
IMDG: THESE PRODUCTS ARE NOT REGULATED WHEN TRANSPORTED BY VESSEL.
| SECTION XV - REGULATORY INFORMATION | |
UNITED STATES:
ALL INTENTIONALLY-ADDED COMPONENTS OF THESE PRODUCTS ARE LISTED ON THE US
TSCA INVENTORY.
EPA REGISTRATION NUMBER: NA
SARA 313/302/304/311/312 CHEMICALS: NONE
CALIFORNIA:
THESE PRODUCTS HAVE BEEN EVALUATED AND DO NOT REQUIRE WARNING LABELING
UNDER CALIFORNIA PROPOSITION 65.
STATE RIGHT-TO-KNOW AND CERCLA:
THE FOLLOWING INGREDIENTS PRESENT IN THE FINISHED PRODUCT ARE LISTED ON
STATE RIGHT-TO-KNOW LISTS OR STATE WORKER EXPOSURE LISTS:
INGREDIENT CAS # LEVEL CERCLA RQ STATE
IL MA NJ PA RI
PROPYLENE GLYCOL 57-55-6 7-13% NA X X X
ETHANOLAMINE 141-43-5 1-5% NA X X X X
CANADA:
ALL INGREDIENTS ARE CEPA APPROVED FOR IMPORT TO CANADA BY PROCTER & GAMBLE.
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THIS MSDS CONTAINS
ALL INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
| SECTION XVI - OTHER INFORMATION | |
PERFUMES CONTAINED WITHIN THESE PRODUCTS COVERED BY THIS MSDS COMPLY WITH
APPROPRIATE IFRA GUIDANCE.
P&G HAZARD RATING:
HEALTH 2
FLAMMABILITY 1
REACTIVITY 0
4=EXTREME
3=HIGH
2=MODERATE
1=SLIGHT
0=NOT SIGNIFICANT
*N/A. - NOT APPLICABLE
*N/K. - NOT KNOWN
DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND
HEALTH.
DISCLAIMER:
THIS MSDS IS INTENDED TO PROVIDE A BRIEF SUMMARY OF OUR KNOWLEDGE AND
GUIDANCE REGARDING THE USE OF THIS MATERIAL. THE INFORMATION CONTAINED
HERE HAS BEEN COMPILED FROM SOURCES CONSIDERED BY PROCTER & GAMBLE TO BE
DEPENDABLE AND IS ACCURATE TO THE BEST OF THE COMPANY'S KNOWLEDGE. IT IS
NOT MEANT TO BE AN ALL-INCLUSIVE DOCUMENT ON WORLDWIDE HAZARD COMMUNICATION
REGULATIONS.
THIS INFORMATION IS OFFERED IN GOOD FAITH. EACH USER OF THIS MATERIAL NEEDS
TO EVALUATE THE CONDITIONS OF USE AND DESIGN THE APPROPRIATE PROTECTIVE
MECHANISMS TO PREVENT EMPLOYEE EXPOSURES, PROPERTY DAMAGE OR RELEASE TO THE
ENVIRONMENT. PROCTER & GAMBLE ASSUMED NO RESPONSIBILITY FOR INJURY TO THE
RECIPIENT OR THIRD PERSONS, OR FOR ANY DAMAGE TO ANY PROPERTY RESULTING
FROM MISUSE OF THE PRODUCT.