| Common Name: | ULTRA TIDE HE - HIGH EFFICIENCY (ALL SCENTS: REGULAR SCENT, CLEAN BREEZE) |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 3/2/2011 |
| SDS Format: | No Format Specified |
| Item Number(s): | 46F045 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G
MATERIAL SAFETY DATA SHEET
MSDS #: RQ1000740
THE PROCTER & GAMBLE COMPANY
P&G HOUSEHOLD CARE
FABRIC & HOME CARE INNOVATION CENTER
5299 SPRING GROVE AVENUE
CINCINNATI, OH 45217-1087
SUPERSEDES: FH/H/2007/ECCE-732RF9
REVISION DATE: 3/02/11
ISSUE DATE: 9/1/04
| SECTION I - PRODUCT IDENTIFICATION |  |
IDENTITY: GRANULAR LAUNDRY DETERGENT FINISHED PRODUCT
BRANDS:
ULTRA TIDE HE - HIGH EFFICIENCY (ALL SCENTS: REGULAR SCENT, CLEAN BREEZE)
P&G TELEPHONE NUMBER:
1-800-879-8433 OR CALL LOCAL POISON CONTROL CENTER OR YOUR PHYSICIAN.
TRANSPORTATION EMERGENCY (24 HOUR) TELEPHONE NUMBER - CHEMTREC:
1-800-424-9300 - U.S. AND CANADA
1-703-527-3887 - FOR CALLS ORIGINATING ELSEWHERE.
| SECTION II - HAZARDS IDENTIFICATION | |
POTENTIAL HEALTH HAZARDS (ACUTE AND CHRONIC):
(SEE SECTION 11 FOR MORE INFORMATION)
INGESTION: MAY CAUSE TRANSIENT GASTROINTESTINAL IRRITATION.
EYE CONTACT: CONTACT MAY CAUSE MILD, TRANSIENT IRRITATION.
SKIN CONTACT: PROLONGED CONTACT MAY CAUSE MILD, TRANSIENT IRRITATION.
INHALATION:
HEAVY EXPOSURE TO DUST MAY CAUSE TRANSIENT RESPIRATORY TRACT IRRITATION.
PROLONGED OR REPEATED HEAVY EXPOSURE TO DUST MAY CAUSE RESPIRATORY
SENSITIZATION OR SYMPTOMATIC RESPONSES.
SIGNS AND SYMPTOMS OF EXPOSURE:
INGESTION:
POSSIBLE MILD GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING, AND/OR
DIARRHEA.
EYE CONTACT:
EYE CONTACT WITH THE PRODUCT OR ITS AQUEOUS SOLUTION MAY PRODUCE TRANSIENT
SUPERFICIAL IRRITATION.
SKIN CONTACT:
PROLONGED CONTACT WITH THE PRODUCT OR ITS AQUEOUS SOLUTION MAY PRODUCE
TRANSIENT SUPERFICIAL IRRITATION.
INHALATION:
HEAVY EXPOSURE TO DUST MAY CAUSE TRANSIENT RESPIRATORY TRACT IRRITATION.
MEDICAL CONDITIONS GENERALLY KNOWN TO BE AGGRAVATED BY EXPOSURE: N/K.
POTENTIAL ENVIRONMENTAL EFFECTS: (SEE SECTION 12 FOR MORE INFORMATION)
| SECTION III - COMPOSITION AND INGREDIENTS | |
INGREDIENTS LISTED ON THE PRODUCT LABEL ARE:
BIODEGRADABLE ANIONIC SURFACTANTS AND ENZYMES.
HAZARDOUS INGREDIENTS AS DEFINED BY OSHA, 29 CFR 1910.1200, AND/OR WHMIS
UNDER THE HPA:
THIS PRODUCT IS HAZARDOUS UNDER U.S. OSHA HAZARD COMMUNICATION
(EYE IRRITANT). WITH INCREASED EXPOSURE COMPARED WITH CONSUMER USE, THIS
MIXTURE, WHEN TESTED AS A WHOLE, IS CONSIDERED AN INHALATION HAZARD
(ENZYMES).
COMMON NAME CHEMICAL NAME CAS NO. COMPOSITION
RANGE
SODA ASH SODIUM CARBONATE 497-19-8 15-40%
ANIONIC ALKYL SULFATE, 68955-19-1 10-30% TOTAL
SURFACTANTS SODIUM SALT & ANIONIC
PROPRIETARY SURFACTANT
LINEAR ALKYL 68081-81-2
SULFONATE
ALCOHOL 68585-34-2
ETHOXYSULFATE,
SODIUM SALT
BENZENE SULFONIC 68910-32-7
ACID,
MONOETHANOLAMINE
SALT
PERCARBONATE SODIUM CARBONATE 15630-89-4 3-7%
PEROXIDE
SILICATE SILICATE 1344-09-8 3-7%
ZEOLITE SILICIC ACID, 1344-00-9 10-30%
ALUMINUM SALT
LD50/LC50
1.9 G/KG
(RATS, ORAL)
1.3 - 2.1 G/KG
(RATS, ORAL)
0.7 - 1.3 G/KG
(RATS, ORAL)
>2 G/KG (RATS,
ORAL)
NOT AVAILABLE
1.0 - 3 G/KG
(RATS, ORAL)
1.3 G/KG
(RATS, ORAL)
N/A
| SECTION IV - FIRST AID INFORMATION | |
FIRST AID PROCEDURES:
INGESTION:
DILUTE BY DRINKING 1-2 GLASSES OF WATER. DO NOT INDUCE VOMITING. IF SYMPTOMS
PERSIST, CONSULT A PHYSICIAN.
EYE CONTACT:
FLUSH EYES THOROUGHLY WITH LUKEWARM WATER FOR 15 MINUTES. IF IRRITATION
PERSISTS, CONSULT A PHYSICIAN.
SKIN CONTACT:
RINSE EXPOSED AREA WITH WATER. IF IRRITATION PERSISTS, CONSULT A PHYSICIAN.
INHALATION:
LEAVE DUSTY AREA. IN RARE CASES A RESPIRATORY REACTION CAN OCCUR WHICH MAY
INCLUDE TIGHTNESS OF CHEST AND DIFFICULTY BREATHING. IF THIS OCCURS, SEEK
MEDICAL ATTENTION IMMEDIATELY.
NOTE TO PHYSICIAN (IF APPLICABLE):
OTHER:
CONSUMER PRODUCT PACKAGE HAS THE FOLLOWING PRECAUTIONARY STATEMENT:
US:
FRONT LABEL:
"CAUTION:
EYE IRRITANT. MAY BE HARMFUL IF SWALLOWED. SEE CAUTION ON BACK PANEL."
BACK PANEL:
"CAUTION:
IN CASE OF EYE CONTACT, FLUSH WITH WATER. IF SWALLOWED, GIVE A GLASSFUL OF
WATER OR MILK. CALL A PHYSICIAN. KEEP OUT OF REACH OF CHILDREN."
CANADA:
"CAUTION:
MAY IRRITATE EYES. DO NOT GET IN EYES. KEEP OUT OF REACH OF CHILDREN. MAY BE
HARMFUL IF SWALLOWED.
FIRST AID TREATMENT:
CONTAINS BIODEGRADABLE ANIONIC SURFACTANTS AND ENZYMES. IF SWALLOWED, GIVE A
GLASSFUL OF WATER OR MILK AND CALL A POISON CONTROL CENTRE OR DOCTOR
IMMEDIATELY. DO NOT INDUCE VOMITING. IF IN EYES, RINSE THEM WELL WITH WATER
FOR 15 MINUTES.
| SECTION V - FIRE FIGHTING INFORMATION | |
FLASH POINT (METHOD USED): N/A
FLAMMABLE PROPERTIES:
UPPER FLAMMABLE/EXPLOSIVE LIMIT: N/A
LOWER FLAMMABLE/EXPLOSIVE LIMIT: N/A
AUTO-IGNITION TEMPERATURE: N/A
HAZARDOUS COMBUSTION PRODUCTS: N/K
EXPLOSION DATA (SENSITIVITY TO MECHANICAL IMPACT): N/K
EXPLOSION DATA (SENSITIVITY TO STATIC DISCHARGE): N/K
EXTINGUISHING MEDIA:
SUITABLE: CO2, WATER, OR DRY CHEMICAL
UNSUITABLE: N/K
PROTECTION OF FIREFIGHTERS:
SPECIFIC HAZARDS ARISING FROM THE MATERIAL: N/K
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF-CONTAINED BREATHING APPARATUS AND
NORMAL TURNOUT GEAR.
| SECTION VI - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
MINIMIZE DUST LEVELS WHILE COLLECTING PRODUCT (SEE "INHALATION" HEALTH
EFFECTS). PREVENT EXPOSURE TO DUST WITH NIOSH APPROVED RESPIRATORS WITH HEPA
FILTERS. MINIMIZE PROLONGED SKIN CONTACT BY USING GLOVES.
ENVIRONMENTAL PRECAUTIONS:
DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL, STATE/PROVINCIAL AND
LOCAL REGULATIONS. SMALL (HOUSEHOLD) SOLUTIONS MAY BE DISPOSED OF IN SEWER.
DRY PRODUCT MAY BE LANDFILLED IF PERMITTED BY LOCAL REGULATIONS. DISCARD
EMPTY CONTAINER IN TRASH. WASTE WATER CONTAINING PRODUCT MAY BE SEVERED IN
COMPLIANCE WITH ALL FEDERAL AND STATE/PROVINCIAL REGULATIONS, AND LOCAL
ORDINANCES.
METHODS FOR CONTAINMENT:
FOR DRY PRODUCT SPILLS, COLLECT MATERIAL IN AN APPROVED CONTAINER WHILE
MINIMIZING DUST GENERATION. VACUUM, AS APPROPRIATE, REMAINING DUST ON FLOOR.
METHODS FOR CLEANUP:
RECYCLE OR DISPOSE OF PRODUCT, AS NECESSARY, IN ACCORDANCE WITH REGULATIONS.
FLUSH SMALL (HOUSEHOLD) QUANTITIES DOWN ACCEPTABLE SANITARY/PROCESS SEWER.
WIPE UP SMALL SPILLS WITH A DAMP CLOTH. DISPOSE OF ACCORDING TO LOCAL
REGULATIONS.
OTHER INFORMATION (IF APPLICABLE):
| SECTION VII - HANDLING AND STORAGE | |
PRECAUTIONS TO BE TAKEN IN HANDLING: AVOID BREATHING PRODUCT DUST.
PRECAUTIONS TO BE TAKEN IN STORAGE:
STORE IN A COOL, DRY PLACE. KEEP PRODUCT DRY TO MAINTAIN FREE-FLOWING
GRANULES.
| SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES: MINIMIZE DUST.
ENGINEERING CONTROLS: N/A
PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION: NONE REQUIRED FOR NORMAL HANDLING.
SKIN PROTECTION: NONE REQUIRED FOR NORMAL HANDLING.
RESPIRATORY PROTECTION: NONE REQUIRED FOR NORMAL HANDLING.
| SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE (COLOR, PHYSICAL FORM, SHAPE):
WHITE POWDER WITH OR WITHOUT COLORED SPECKLES
ODOR: SCENTED AND/OR UNSCENTED.
ODOR THRESHOLD: N/A
PHYSICAL STATE: SOLID GRANULES AT 68 DEG. F (20 DEG. C)
VAPOR PRESSURE (MMHg): N/A
VAPOR DENSITY (AIR=1): N/A
BOILING POINT: N/A
PARTITION COEFFICIENT (n-OCTANOL/WATER): N/A
FLASH POINT (METHOD USED): N/A
RESERVE ALKALINITY: APPROX. 5-8.75 G NaOH/100 ML (AT pH=9.5)
SOLUBILITY IN WATER: MOSTLY SOLUBLE AT 68 DEG. F (20 DEG. C)
DECOMPOSITION TEMPERATURE: N/A
EVAPORATION RATE (nBuOAc=1): N/A
SPECIFIC GRAVITY/DENSITY: DENSITY 420-650 G/L
MELTING/FREEZING POINT: N/A
pH (OF A 1% SOLUTION): 10-11.5
VOLATILE ORGANIC COMPOUND (VOC):
NOT APPLICABLE - PRODUCT NOT REGULATED FOR VOC CONTENT AT STATE OR FEDERAL
LEVEL.
| SECTION X - STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: STABLE.
CONDITIONS TO AVOID: OPEN FLAME.
INCOMPATIBLE MATERIALS: N/K
HAZARDOUS DECOMPOSITION PRODUCTS: N/K
POSSIBILITY OF HAZARDOUS REACTIONS: N/K
| SECTION XI - TOXICOLOGICAL INFORMATION | |
GRANULAR DETERGENT HAS A RELATIVE LOW ORDER OF TOXICITY. IF INGESTED, IT MAY
RESULT IN MILD GASTROINTESTINAL IRRITATION, DIARRHEA, AND/OR VOMITING. EYE
CONTACT WITH THE PRODUCT OR ITS AQUEOUS SOLUTION MAY PRODUCE TRANSIENT
SUPERFICIAL IRRITATION.
CHRONIC EFFECTS: NO CHRONIC HEALTH EFFECTS REPORTED.
TARGET ORGANS: NO TARGET ORGANS REPORTED.
CARCINOGENICITY: THIS FINISHED CONSUMER PRODUCT IS NOT CARCINOGENIC.
NTP: NO*
IARC: NO*
*NTP AND IARC INFORMATION CONFIRMED VIA ARIEL.
| SECTION XII - ECOLOGICAL INFORMATION | |
BASED ON ECOTOXICITY AND CHEMICAL FATE DATA THE INGREDIENTS IN THIS PRODUCT
ARE NOT EXPECTED TO HARM THE ENVIRONMENT WHEN DISPOSED OF THROUGH NORMAL
ROUTES OF USE. THE SURFACTANTS IN THIS DETERGENT ARE READILY BIODEGRADABLE
AND WELL REMOVED DURING SEWAGE TREATMENT PROCESSING.
| SECTION XIII - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
DISPOSAL SHOULD BE IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL AND LOCAL
REGULATIONS.
NON-HOUSEHOLD SETTING (FEDERAL):
PRODUCTS COVERED BY THIS MSDS, IN THEIR ORIGINAL FORM, WHEN DISPOSED AS
WASTE, ARE CONSIDERED NON-HAZARDOUS WASTE ACCORDING TO FEDERAL RCRA
REGULATIONS (40 CFR 261). DISPOSAL SHOULD BE IN ACCORDANCE WITH LOCAL,
STATE AND FEDERAL REGULATIONS.
NON-HOUSEHOLD SETTING (CALIFORNIA):
HAZARDOUS, IN ACCORDANCE WITH 22 CCR 66261.20 THROUGH 22 CCR 66261.24
HOUSEHOLD USE:
CONSUMER MAY DISCARD EMPTY CONTAINER IN TRASH, OR RECYCLE WHERE FACILITIES
EXIST. CONSUMER PRODUCED HOUSEHOLD SOLUTIONS MAY BE DISPOSED OF DOWN THE
DRAIN WITH RUNNING WATER. PRODUCT USED IN HOUSEHOLD MAY BE DISPOSED OF IN
REFUSE OR IN SEWER.
| SECTION XIV - TRANSPORT INFORMATION | |
PRODUCTS COVERED BY THIS MSDS, IN THEIR ORIGINAL FORM, ARE NOT REGULATED FOR
TRANSPORTATION.
GROUND TRANSPORT (US DOT): NOT REGULATED
AIR TRANSPORT (IATA): NOT REGULATED
MARINE/WATER TRANSPORT (IMDG): NOT REGULATED
| SECTION XV - REGULATORY INFORMATION | |
UNITED STATES:
ALL INTENTIONALLY ADDED COMPONENTS OF THIS PRODUCT ARE LISTED ON THE US TSCA
INVENTORY.
EPA REGISTRATION NUMBER: NOT APPLICABLE.
SARA 313/302/304/311/312 CHEMICALS: NONE
CALIFORNIA:
THIS PRODUCT HAS BEEN EVALUATED AND DOES NOT REQUIRE WARNING LABELING UNDER
CALIFORNIA PROPOSITION 65.
CALIFORNIA REGISTRATION NUMBER: NOT APPLICABLE.
STATE RIGHT-TO-KNOW AND CERCLA:
THE FOLLOWING INGREDIENTS PRESENT IN THE FINISHED PRODUCT ARE LISTED ON
STATE RIGHT-TO-KNOW LISTS OR STATE WORKER EXPOSURE LISTS:
INGREDIENT CAS# LEVEL CERCLA STATE
RQ IL MA NJ PA RI
ZEOLITE 1344-00-9 10-30% N/A X
CANADA:
ALL INGREDIENTS ARE CEPA APPROVED FOR IMPORT TO CANADA BY PROCTER & GAMBLE.
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THIS MSDS CONTAINS
ALL INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
SODIUM CARBONATE (CAS# 497-19-8) IS LISTED ON THE CANADIAN WHMIS INGREDIENT
DISCLOSURE LIST (IDL) AS ITEM 1431, WITH A THRESHOLD OF 1%.
| SECTION XVI - OTHER INFORMATION | |
PERFUMES CONTAINED WITHIN THE PRODUCTS COVERED BY THIS MSDS COMPLY WITH
APPROPRIATE IFRA GUIDANCE.
P&G HAZARD RATING:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
4=EXTREME
3=HIGH
2=MODERATE
1=SLIGHT
0=NOT SIGNIFICANT
*N/A. - NOT APPLICABLE
*N/K. - NOT KNOWN
DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND
HEALTH.
DISCLAIMER:
THIS MSDS IS INTENDED TO PROVIDE A BRIEF SUMMARY OF OUR KNOWLEDGE AND
GUIDANCE REGARDING THE USE OF THIS MATERIAL. THE INFORMATION CONTAINED HERE
HAS BEEN COMPILED FROM SOURCES CONSIDERED BY PROCTER & GAMBLE TO BE
DEPENDABLE AND IS ACCURATE TO THE BEST OF THE COMPANY'S KNOWLEDGE. IT IS NOT
MEANT TO BE AN ALL-INCLUSIVE DOCUMENT ON WORLDWIDE HAZARD COMMUNICATION
REGULATIONS.
THIS INFORMATION IS OFFERED IN GOOD FAITH. EACH USER OF THE MATERIAL NEEDS
TO EVALUATE THE CONDITIONS OF USE AND DESIGN THE APPROPRIATE PROTECTIVE
MECHANISMS TO PREVENT EMPLOYEE EXPOSURES, PROPERTY DAMAGE OR RELEASE TO THE
ENVIRONMENT. PROCTER & GAMBLE ASSUMED NO RESPONSIBILITY FOR INJURY TO THE
RECIPIENT OR THIRD PERSONS, OR FOR ANY DAMAGE TO ANY PROPERTY RESULTING FROM
MISUSE OF THE PRODUCT.