| Common Name: | NICKEL-SAFE ICE MACHINE CLEANER (4287) |
| Manufacturer: | NU-CALGON WHOLESALER |
| SDS Revision Date: | 6/1/2011 |
| SDS Format: | No Format Specified |
| Item Number(s): | 22NV29, 3CFP9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
NU-CALGON
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: NICKEL-SAFE ICE MACHINE CLEANER (4287)
CAS #: MIXTURE
PRODUCT USE: DESCALER
MANUFACTURER:
NU-CALGON
2008 ALTOM COURT
ST. LOUIS, MO 63146
US
PHONE: 314-469-7000 / 800-554-5499
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION. CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
POTENTIAL SHORT TERM HEALTH EFFECTS:
ROUTES OF EXPOSURE: EYE, SKIN CONTACT, INHALATION, INGESTION.
EYES: MAY CAUSE SEVERE IRRITATION OR CHEMICAL BURNS.
SKIN:
THIS PRODUCT IS NON-CORROSIVE BASED ON TEST DATA. MAY CAUSE MILD SKIN
IRRITATION.
INHALATION:
EXCESSIVE INTENTIONAL INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION
AND CENTRAL NERVOUS SYSTEM EFFECTS (HEADACHE, DIZZINESS).
INGESTION:
HARMFUL IF SWALLOWED. MAY CAUSE STOMACH DISTRESS, NAUSEA OR VOMITING.
TARGET ORGANS: EYES. RESPIRATORY SYSTEM. SKIN.
CHRONIC EFFECTS:
PROLONGED OR REPEATED EXPOSURE CAN CAUSE DRYING, DEFATTING AND DERMATITIS.
SIGNS AND SYMPTOMS:
SYMPTOMS MAY INCLUDE DISCOMFORT OR PAIN, EXCESS BLINKING AND TEAR
PRODUCTION, WITH MARKED REDNESS AND SWELLING OF THE CONJUNCTIVA.
OSHA REGULATORY STATUS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
POTENTIAL ENVIRONMENTAL EFFECTS:
COMPONENTS OF THIS PRODUCT HAVE BEEN IDENTIFIED AS HAVING POTENTIAL
ENVIRONMENTAL CONCERNS.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
INGREDIENT(S) CAS # PERCENT
PHOSPHORIC ACID 7664-38-2 15 - 40
CITRIC ACID 77-92-9 1 - 5
| 4. FIRST AID MEASURES | |
FIRST AID PROCEDURES:
EYE CONTACT:
IMMEDIATELY FLUSH WITH COOL WATER. REMOVE CONTACT LENSES, IF APPLICABLE,
AND CONTINUE FLUSHING FOR 15 MINUTES. OBTAIN MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH COOL WATER FOR 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. DISCARD OR WASH WELL BEFORE REUSE. OBTAIN MEDICAL
ATTENTION IF IRRITATION PERSISTS.
INHALATION:
IF SYMPTOMS DEVELOP MOVE VICTIM TO FRESH AIR. IF SYMPTOMS PERSIST, OBTAIN
MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. IF VOMITING OCCURS NATURALLY, HAVE VICTIM LEAN
FORWARD TO REDUCE RISK OF ASPIRATION. NEVER GIVE ANYTHING BY MOUTH IF VICTIM
IS UNCONSCIOUS, OR IS CONVULSING. OBTAIN MEDICAL ATTENTION.
NOTES TO PHYSICIAN: SYMPTOMS MAY BE DELAYED.
GENERAL ADVICE:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS SAFETY DATA SHEET TO THE
DOCTOR IN ATTENDANCE. AVOID CONTACT WITH EYES AND SKIN. KEEP OUT OF REACH OF
CHILDREN.
| 5. FIRE FIGHTING MEASURES | |
FLAMMABLE PROPERTIES: NOT FLAMMABLE BY WHMIS/OSHA CRITERIA.
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING: MEDIA DRY CHEMICAL. FOAM. CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA: NOT AVAILABLE
PROTECTION OF FIREFIGHTERS:
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NOT AVAILABLE
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE CLOTHING INCLUDING SELF CONTAINED
BREATHING APPARATUS.
HAZARDOUS COMBUSTION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF PHOSPHORUS. OXIDES OF CARBON.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NOT AVAILABLE
SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
KEEP UNNECESSARY PERSONNEL AWAY. DO NOT TOUCH OR WALK THROUGH SPILLED
MATERIAL. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING
APPROPRIATE PROTECTIVE CLOTHING. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK.
ENVIRONMENTAL PRECAUTIONS:
DO NOT DISCHARGE INTO LAKES, STREAMS, PONDS OR PUBLIC WATERS.
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO SO WITHOUT RISK. PREVENT ENTRY INTO WATERWAYS,
SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS FOR CLEANING UP:
BEFORE ATTEMPTING CLEAN UP, REFER TO HAZARD DATA GIVEN ABOVE. SMALL SPILLS
MAY BE ABSORBED WITH NON-REACTIVE ABSORBENT AND PLACED IN SUITABLE, COVERED,
LABELLED CONTAINERS. PREVENT LARGE SPILLS FROM ENTERING SEWERS OR WATERWAYS.
CONTACT EMERGENCY SERVICES AND SUPPLIER FOR ADVICE. NEVER RETURN SPILLS TO
ORIGINAL CONTAINERS FOR RE-USE.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE GOOD INDUSTRIAL HYGIENE PRACTICES IN HANDLING THIS MATERIAL.
WHEN USING DO NOT EAT OR DRINK.
AVOID CONTACT WITH SKIN AND CLOTHING.
AVOID CONTACT WITH EYES.
AVOID BREATHING VAPORS OR MISTS OF THIS PRODUCT.
KEEP CONTAINER TIGHTLY CLOSED.
USE ONLY WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.
STORAGE:
KEEP OUT OF REACH OF CHILDREN. STORE IN A CLOSED CONTAINER AWAY FROM
INCOMPATIBLE MATERIALS.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE LIMITS:
INGREDIENT(S) EXPOSURE LIMITS
CITRIC ACID ACGIH-TLV:
TWA: 10 MG/M3
OSHA-PEL:
TWA: 10 MG/M3
PHOSPHORIC ACID ACGIH-TLV:
TWA: 1 MG/M3
STEL: 3 MG/M3
OSHA-PEL:
TWA: 1 MG/M3
ENGINEERING CONTROLS: GENERAL VENTILATION NORMALLY ADEQUATE.
PERSONAL PROTECTIVE EQUIPMENT:
EYE / FACE PROTECTION: CHEMICAL SPLASH GOGGLES.
HAND PROTECTION: RUBBER GLOVES. CONFIRM WITH A REPUTABLE SUPPLIER FIRST.
SKIN AND BODY PROTECTION: AS REQUIRED BY EMPLOYER CODE.
RESPIRATORY PROTECTION:
AVOID BREATHING MISTS OR VAPORS. WHERE EXPOSURE GUIDELINE LEVELS MAY BE
EXCEEDED, USE AN APPROVED NIOSH RESPIRATOR.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. WHEN
USING DO NOT EAT OR DRINK. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER
HANDLING THE PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID.
COLOR: GREEN
FORM: LIQUID
ODOR: MILD CHEMICAL
ODOR THRESHOLD: NOT AVAILABLE
PHYSICAL STATE: LIQUID
PH: <1
MELTING POINT: NOT AVAILABLE
FREEZING POINT: -0.40 DEG. F (-18 DEG. C)
BOILING POINT: >199.40 DEG. F (> 93 DEG. C)
POUR POINT: NOT AVAILABLE
EVAPORATION RATE: NOT AVAILABLE
FLASH POINT: NONE
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
FLAMMABILITY LIMITS IN AIR, LOWER, % BY VOLUME: NOT AVAILABLE
FLAMMABILITY LIMITS IN AIR, UPPER, % BY VOLUME: NOT AVAILABLE
VAPOR PRESSURE: NOT AVAILABLE
VAPOR DENSITY: NOT AVAILABLE
SPECIFIC GRAVITY: 1.19
OCTANOL/WATER COEFFICIENT: NOT AVAILABLE
SOLUBILITY (H2O): COMPLETE
VOC (WEIGHT %): NOT AVAILABLE
VISCOSITY: NOT AVAILABLE
PERCENT VOLATILE: NOT AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
REACTS VIGOROUSLY WITH ALKALINE MATERIAL. THIS PRODUCT MAY REACT WITH
REDUCING AGENTS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID: DO NOT MIX WITH OTHER CHEMICALS.
INCOMPATIBLE MATERIALS: BASES. REDUCING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF PHOSPHORUS. MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON.
| 11. TOXICOLOGICAL INFORMATION | |
COMPONENT ANALYSIS - LC50:
INGREDIENT(S) LC50
CITRIC ACID NOT AVAILABLE
PHOSPHORIC ACID NOT AVAILABLE
COMPONENT ANALYSIS - ORAL LD50:
INGREDIENT(S) LD50
CITRIC ACID 5040 MG/KG MOUSE; 3000 MG/KG RAT
PHOSPHORIC ACID 1530 MG/KG RAT
EFFECTS OF ACUTE EXPOSURE:
EYE: MAY CAUSE SEVERE IRRITATION OR CHEMICAL BURNS.
SKIN:
THIS PRODUCT IS NON-CORROSIVE BASED ON TEST DATA. MAY CAUSE MILD SKIN
IRRITATION.
INHALATION:
EXCESSIVE INTENTIONAL INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION AND
CENTRAL NERVOUS SYSTEM EFFECTS (HEADACHE, DIZZINESS).
INGESTION:
HARMFUL IF SWALLOWED. MAY CAUSE STOMACH DISTRESS, NAUSEA OR VOMITING.
SENSITIZATION: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
CHRONIC EFFECTS: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
CARCINOGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
MUTAGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
REPRODUCTIVE EFFECTS: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
TERATOGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
NAME OF TOXICOLOGICALLY SYNERGISTIC PRODUCTS: NOT AVAILABLE
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
COMPONENTS OF THIS PRODUCT HAVE BEEN IDENTIFIED AS HAVING POTENTIAL
ENVIRONMENTAL CONCERNS.
ECOTOXICITY - FRESHWATER FISH - ACUTE TOXICITY DATA:
CITRIC ACID 77-92-9 96 HR LC50 LEPOMIS MACROCHIRUS:
1516 MG/L [STATIC]
PHOSPHORIC ACID 7664-38-2 96 HR LC50 GAMBUSIA AFFINIS:
3 - 3.5 MG/L
ECOTOXICITY - WATER FLEA - ACUTE TOXICITY DATA:
CITRIC ACID 77-92-9 72 HR EC50 DAPHNIA MAGNA: 120 MG/L
PHOSPHORIC ACID 7664-38-2 12 HR EC50 DAPHNIA MAGNA: 4.6 MG/L
PERSISTENCE / DEGRADABILITY: NOT AVAILABLE
BIOACCUMULATION / ACCUMULATION: NOT AVAILABLE
MOBILITY IN ENVIRONMENTAL MEDIA: NOT AVAILABLE
ENVIRONMENTAL EFFECTS: NOT AVAILABLE
AQUATIC TOXICITY: NOT AVAILABLE
PARTITION COEFFICIENT: NOT AVAILABLE
CHEMICAL FATE INFORMATION: NOT AVAILABLE
OTHER ADVERSE EFFECTS: NOT AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS.
WASTE FROM RESIDUES / UNUSED PRODUCTS: NOT AVAILABLE
CONTAMINATED PACKAGING: NOT AVAILABLE
| 14. TRANSPORT INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION (DOT): NOT REGULATED AS DANGEROUS GOODS.
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
NOT REGULATED AS DANGEROUS GOODS.
| 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS AND THE MSDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
CANADA - WHMIS - INGREDIENT DISCLOSURE LIST:
CITRIC ACID 77-92-9 1%
PHOSPHORIC ACID 7664-38-2 1%
WHMIS STATUS: CONTROLLED
WHMIS CLASSIFICATION: CLASS D - DIVISION 2B
WHMIS LABELING: D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA):
29 CFR 1910.1200 HAZARDOUS CHEMICAL: YES
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
U.S. - CERCLA/SARA - HAZARDOUS SUBSTANCES AND THEIR REPORTABLE QUANTITIES:
PHOSPHORIC ACID 7664-38-2 5000 LB FINAL RQ; 2270 KG FINAL RQ
U.S. - CWA (CLEAN WATER ACT) - HAZARDOUS SUBSTANCES:
PHOSPHORIC ACID 7664-38-2 PRESENT
CERCLA (SUPERFUND) REPORTABLE QUANTITY:
PHOSPHORIC ACID: 5000.0000
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SECTION 311 HAZARDOUS CHEMICAL: YES
CLEAN AIR ACT (CAA): NOT AVAILABLE
CLEAN WATER ACT (CWA): NOT AVAILABLE
STATE REGULATIONS:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
U.S. - CALIFORNIA - 8 CCR SECTION 339 - DIRECTOR'S LIST OF HAZARDOUS
SUBSTANCES:
PHOSPHORIC ACID 7664-38-2 PRESENT
U.S. - LOUISIANA - REPORTABLE QUANTITY LIST FOR POLLUTANTS:
PHOSPHORIC ACID 7664-38-2 5000 LB FINAL RQ; 2270 KG FINAL RQ
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST:
PHOSPHORIC ACID 7664-38-2 PRESENT
U.S. - MINNESOTA - HAZARDOUS SUBSTANCE LIST:
PHOSPHORIC ACID 7664-38-2 PRESENT
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST:
PHOSPHORIC ACID 7664-38-2 SN 1516
U.S. - NEW YORK - REPORTING OF RELEASES PART 597 - LIST OF HAZARDOUS
SUBSTANCES:
PHOSPHORIC ACID 7664-38-2 5000 LB RQ (AIR); 100 LB RQ
(LAND/WATER)
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST:
PHOSPHORIC ACID 7664-38-2 ENVIRONMENTAL HAZARD
U.S. - RHODE ISLAND - HAZARDOUS SUBSTANCE LIST:
PHOSPHORIC ACID 7664-38-2 TOXIC; FLAMMABLE
INVENTORY NAME:
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION (YES/NO)*
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY YES
PUERTO RICO
A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
HMIS:
HEALTH 2/
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA:
2
0
0
LEGEND:
SEVERE: 4
SERIOUS: 3
MODERATE: 2
SLIGHT: 1
MINIMAL: 0
DISCLAIMER:
INFORMATION CONTAINED HEREIN WAS OBTAINED FROM SOURCES CONSIDERED
TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY EFFORT HAS BEEN MADE TO
ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME CASES DATA IS NOT
AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL PRODUCT USE ARE
BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF THIS MATERIAL
HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL APPLICABLE
LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED OR IMPLIED,
IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES, INJURIES OR
CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR RELIANCE ON ANY
INFORMATION CONTAINED IN THIS DOCUMENT.
ISSUE DATE: 01-JUN-2011
EFFECTIVE DATE: 01-AUG-2011
EXPIRY DATE: 01-AUG-2014
PREPARED BY: NU-CALGON TECHNICAL SERVICE (314) 469-7000
OTHER INFORMATION:
FOR AN UPDATED MSDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED IN
SECTION 1 OF THIS DOCUMENT.
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