| Common Name: | PVC MEDIUM CLEAR OR GRAY CEMENT - LO-VOC |
| Manufacturer: | OATEY |
| SDS Revision Date: | 6/6/2012 |
| SDS Format: | No Format Specified |
| Item Number(s): | 29FH89, 29FH99 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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OATEY(R*)
LO-VOC
SCAQMD 1168/316A COMPLIANT
MATERIAL NAME: OATEY PVC MEDIUM CLEAR OR GRAY CEMENT - LO-VOC
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
MSDS: #1101E
PART NUMBERS:
CLEAR - 30350, 31017, 31018, 31019, 31020, 31021, 31550, 31551, 31552,
31553, 31946, 31947, 31948, 31949, 32222, 32223, 32224, 32225 GRAY - 30883,
30884, 30885, 30886, 30887, 31930, 31931, 31932, 31933
MANUFACTURER INFORMATION:
OATEY CO.
4700 WEST 160TH STREET
CLEVELAND, OH 44135
PHONE: 216-267-7100
FOR EMERGENCY FIRST AID CALL: 1-877-740-5015.
FOR CHEMICAL TRANSPORTATION EMERGENCIES ONLY, CALL CHEMTREC AT:
1-800-424-9300.
OUTSIDE THE U.S.: 1-703-527-3887.
| SECTION 2 - HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
FLAMMABLE LIQUIDS - CATEGORY 2
ACUTE TOXICITY ORAL - CATEGORY 4
ACUTE TOXICITY DERMAL - CATEGORY 4
ACUTE TOXICITY INHALATION - CATEGORY 4
EYE DAMAGE/IRRITATION - CATEGORY 2A
CARCINOGENICITY - CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY SINGLE EXPOSURE - CATEGORY 3
GHS LABEL ELEMENTS:
SYMBOL(S):
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
HARMFUL IF SWALLOWED.
HARMFUL IN CONTACT WITH SKIN.
HARMFUL IF INHALED.
CAUSES SERIOUS EYE IRRITATION.
CONTAINS A CHEMICAL CLASSIFIED BY THE US EPA AS A SUSPECTED POSSIBLE
CARCINOGEN.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES AND HOT SURFACES. - NO SMOKING.
KEEP CONTAINER TIGHTLY CLOSED.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
AVOID BREATHING FUME/GAS/MIST/VAPORS.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
RESPONSE:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SWALLOWED:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL. RINSE MOUTH.
DO NOT INDUCE VOMITING.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO.
CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF EXPOSED OR CONCERNED GET MEDICAL ADVICE/ATTENTION.
IN CASE OF FIRE: USE DRY CHEMICAL, CO2, OR FOAM TO EXTINGUISH FIRE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CAS # COMPONENT PERCENT
109-99-9 TETRAHYDROFURAN 30-50
67-64-1 ACETONE 10-25
78-93-3 METHYL ETHYL KETONE 10-25
9002-86-2 PVC (CHLOROETHYLENE, POLYMER) 12-20
108-94-1 CYCLOHEXANONE 10-20
112945-52-5 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 1-5
| SECTION 4 - FIRST AID MEASURES | |
FIRST AID:
EYES:
IF MATERIAL GETS INTO EYES OR IF FUMES CAUSE IRRITATION, IMMEDIATELY FLUSH
EYES WITH PLENTY OF WATER UNTIL CHEMICAL IS REMOVED. IF IRRITATION PERSISTS,
GET MEDICAL ATTENTION IMMEDIATELY.
FIRST AID:
SKIN:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY. WASH ALL EXPOSED AREAS WITH SOAP
AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE DRIED CEMENT
WITH HAND CLEANER OR BABY OIL.
FIRST AID:
INGESTION:
DO NOT INDUCE VOMITING. RINSE MOUTH WITH WATER. NEVER GIVE ANYTHING BY MOUTH
TO A PERSON WHO IS UNCONSCIOUS OR DROWSY. GET IMMEDIATE MEDICAL ATTENTION
BY CALLING A POISON CONTROL CENTER, OR HOSPITAL EMERGENCY ROOM. IF MEDICAL
ADVICE CANNOT BE OBTAINED, THEN TAKE THE PERSON AND PRODUCT TO THE NEAREST
MEDICAL EMERGENCY TREATMENT CENTER OR HOSPITAL.
FIRST AID:
INHALATION:
IF SYMPTOMS OF EXPOSURE DEVELOP, REMOVE TO FRESH AIR. IF BREATHING BECOMES
DIFFICULT, ADMINISTER OXYGEN. ADMINISTER ARTIFICIAL RESPIRATION IF BREATHING
HAS STOPPED. SEEK IMMEDIATE MEDICAL ATTENTION.
| SECTION 5 - FIRE FIGHTING MEASURES | |
GENERAL FIRE HAZARDS:
SEE SECTION 9 FOR FLAMMABILITY PROPERTIES.
HIGHLY FLAMMABLE LIQUID AND VAPOR. KEEP AWAY FROM HEAT AND ALL SOURCES OF
IGNITION INCLUDING SPARKS, FLAMES, LIGHTED CIGARETTES AND PILOT LIGHTS.
CONTAINERS MAY RUPTURE OR EXPLODE IN THE HEAT OF A FIRE. VAPORS ARE HEAVIER
THAN AIR AND MAY TRAVEL TO A REMOTE IGNITION SOURCE AND FLASH BACK. THIS
PRODUCT CONTAINS TETRAHYDROFURAN THAT MAY FORM EXPLOSIVE ORGANIC PEROXIDE
WHEN EXPOSED TO AIR OR LIGHT OR WITH AGE.
HAZARDOUS COMBUSTION PRODUCTS:
COMBUSTION WILL PRODUCE TOXIC AND IRRITATING VAPORS INCLUDING CARBON
MONOXIDE, CARBON DIOXIDE AND HYDROGEN CHLORIDE.
EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, OR FOAM TO EXTINGUISH FIRE. COOL FIRE EXPOSED
CONTAINER WITH WATER. WATER MAY BE INEFFECTIVE AS AN EXTINGUISHING AGENT.
UNSUITABLE EXTINGUISHING MEDIA: NONE.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE CLOTHING FOR FIRES IN AREAS WHERE CHEMICALS
ARE USED OR STORED.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
RECOVERY AND NEUTRALIZATION: STOP LEAK IF IT CAN BE DONE WITHOUT RISK.
MATERIALS AND METHODS FOR CLEAN-UP:
REMOVE ALL SOURCES OF IGNITION AND VENTILATE AREA. SOAK UP SPILL WITH AN
INERT ABSORBENT SUCH AS SAND, EARTH OR OTHER NONCOMBUSTING MATERIAL. PUT
ABSORBENT MATERIAL IN COVERED, LABELED METAL CONTAINERS.
EMERGENCY MEASURES: ISOLATE AREA. KEEP UNNECESSARY PERSONNEL AWAY.
PERSONAL PRECAUTIONS AND PROTECTIVE EQUIPMENT:
PERSONNEL CLEANING UP THE SPILL SHOULD WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT, INCLUDING RESPIRATORS IF VAPOR CONCENTRATIONS ARE HIGH.
ENVIRONMENTAL PRECAUTIONS:
PREVENT LIQUID FROM ENTERING WATERCOURSES, SEWERS AND NATURAL WATERWAYS.
PREVENTION OF SECONDARY HAZARDS: NONE
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING PROCEDURES:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING VAPORS OR MISTS.
USE WITH ADEQUATE VENTILATION (EQUIVALENT TO OUTDOORS). WASH THOROUGHLY
AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE IN THE WORK AREA. KEEP PRODUCT
AWAY FROM HEAT, SPARKS, FLAMES AND ALL OTHER SOURCES OF IGNITION. NO SMOKING
IN STORAGE OR USE AREAS. KEEP CONTAINERS CLOSED WHEN NOT IN USE.
OTHER:
"EMPTY" CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. FOLLOW ALL
SDS PRECAUTIONS IN HANDLING EMPTY CONTAINERS. DO NOT CUT OR WELD ON OR NEAR
EMPTY OR FULL CONTAINERS.
STORAGE PROCEDURES:
STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE MATERIALS.
KEEP CONTAINERS CLOSED WHEN NOT IN USE.
INCOMPATIBILITIES:
OXIDIZING AGENTS, ALKALIS, AMINES, AMMONIA, ACIDS, CHLORINE COMPOUNDS,
CHLORINATED INORGANICS (POTASSIUM, CALCIUM AND SODIUM HYPOCHLORITE) AND
HYDROGEN PEROXIDES. MAY ATTACK PLASTIC, RESINS AND RUBBER.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
COMPONENT EXPOSURE LIMITS:
TETRAHYDROFURAN (109-99-9):
ACGIH:
50 PPM TWA
100 PPM STEL
SKIN - POTENTIAL SIGNIFICANT CONTRIBUTION TO OVERALL EXPOSURE BY THE
CUTANEOUS ROUTE
OSHA:
200 PPM TWA
590 MG/M3 TWA
NIOSH:
200 PPM TWA; 590 MG/M3 TWA
250 PPM STEL; 735 MG/M3 STEL
ACETONE (67-64-1):
ACGIH:
500 PPM TWA
750 PPM STEL
OSHA:
1000 PPM TWA
2400 MG/M3 TWA
NIOSH:
250 PPM TWA
590 MG/M3 TWA
METHYL ETHYL KETONE (78-93-3):
ACGIH:
200 PPM TWA
300 PPM STEL
OSHA:
200 PPM TWA
590 MG/M3 TWA
NIOSH:
200 PPM TWA; 590 MG/M3 TWA
300 PPM STEL; 885 MG/M3 STEL
PVC (CHLOROETHYLENE, POLYMER) (9002-86-2):
ACGIH: 1 MG/M3 TWA (RESPIRABLE FRACTION)
CYCLOHEXANONE (108-94-1):
ACGIH:
20 PPM TWA
50 PPM STEL
SKIN - POTENTIAL SIGNIFICANT CONTRIBUTION TO OVERALL EXPOSURE BY THE
CUTANEOUS ROUTE
OSHA:
50 PPM TWA
200 MG/M3 TWA
NIOSH:
25 PPM TWA
100 MG/M3 TWA
POTENTIAL FOR DERMAL ABSORPTION
ENGINEERING MEASURES:
OPEN DOORS & WINDOWS. PROVIDE VENTILATION CAPABLE OF MAINTAINING EMISSIONS
AT THE POINT OF USE BELOW RECOMMENDED EXPOSURE LIMITS. IF USED IN ENCLOSED
AREA, USE EXHAUST FANS. EXHAUST FANS SHOULD BE EXPLOSION-PROOF OR SET UP
IN A WAY THAT FLAMMABLE CONCENTRATIONS OF SOLVENT VAPORS ARE NOT EXPOSED
TO ELECTRICAL FIXTURES OR HOT SURFACES.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY:
FOR OPERATIONS WHERE THE EXPOSURE LIMIT MAY BE EXCEEDED, A NIOSH APPROVED
ORGANIC VAPOR RESPIRATOR OR SUPPLIED AIR RESPIRATOR IS RECOMMENDED.
EQUIPMENT SELECTION DEPENDS ON CONTAMINANT TYPE AND CONCENTRATION, SELECT
IN ACCORDANCE WITH 29 CFR 1910.134 AND GOOD INDUSTRIAL HYGIENE PRACTICE.
FOR FIREFIGHTING, USE SELF-CONTAINED BREATHING APPARATUS.
PERSONAL PROTECTIVE EQUIPMENT:
HANDS:
RUBBER GLOVES ARE SUITABLE FOR NORMAL USE OF THE PRODUCT. FOR LONG EXPOSURES
CHEMICAL RESISTANT GLOVES MAY BE REQUIRED SUCH AS 4H(TM) OR SILVER
SHIELD(TM) TO AVOID PROLONGED SKIN CONTACT.
PERSONAL PROTECTIVE EQUIPMENT:
EYES: SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES.
PERSONAL PROTECTIVE EQUIPMENT:
SKIN AND BODY: NO ADDITIONAL PROTECTIVE EQUIPMENT NEEDED.
| SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR
ODOR: ETHER-LIKE
PHYSICAL STATE: LIQUID
PH: NA
VAPOR PRESSURE: 145 MMHg @ 20 DEG. C
VAPOR DENSITY: 2.5
BOILING POINT: 151 DEG. F (66 DEG. C)
MELTING POINT: NA
SOLUBILITY (H2O): NEGLIGIBLE
SPECIFIC GRAVITY: 0.93 +/- 0.02 @ 20 DEG. C
EVAPORATION RATE (BUAC = 1): 5.5 - 8.0
VOC: 80-84%
OCTANOL/H2O COEFF.: ND
FLASH POINT: 14-23 DEG. F (-10 TO -5 DEG. C)
FLASH POINT METHOD: CCCFP
UPPER FLAMMABILITY LIMIT (UFL): 11.8
LOWER FLAMMABILITY LIMIT (LFL): 1.8
BURNING RATE: ND
AUTO IGNITION: ND
| SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION | |
CHEMICAL STABILITY: THIS IS A STABLE MATERIAL.
HAZARDOUS REACTION POTENTIAL: WILL NOT OCCUR.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, FLAMES AND OTHER SOURCES OF IGNITION.
INCOMPATIBLE PRODUCTS:
OXIDIZING AGENTS, ALKALIS, AMINES, AMMONIA, ACIDS, CHLORINE COMPOUNDS,
CHLORINATED INORGANICS (POTASSIUM, CALCIUM AND SODIUM HYPOCHLORITE) AND
HYDROGEN PEROXIDES. MAY ATTACK PLASTIC, RESINS AND RUBBER.
HAZARDOUS DECOMPOSITION PRODUCTS:
COMBUSTION WILL PRODUCE TOXIC AND IRRITATING VAPORS INCLUDING CARBON
MONOXIDE, CARBON DIOXIDE AND HYDROGEN CHLORIDE.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
COMPONENT ANALYSIS - LD50/LC50:
TETRAHYDROFURAN (109-99-9):
INHALATION LC50 RAT: 53.9 MG/L 4 H
INHALATION LC50 RAT: 180 MG/L 1 H
ORAL LD50 RAT: 1650 MG/KG
ACETONE (67-64-1):
ORAL LD50 RAT: 5800 MG/KG
METHYL ETHYL KETONE (78-93-3):
INHALATION LC50 MOUSE: 32 G/M3 4 H
ORAL LD50 RAT: 2737 MG/KG
DERMAL LD50 RABBIT: 6480 MG/KG
CYCLOHEXANONE (108-94-1):
INHALATION LC50 RAT: 10.7 MG/L 4 H
INHALATION LC50 RAT: 8000 PPM 4 H
ORAL LD50 RAT: 800 MG/KG
DERMAL LD50 RABBIT: 948 MG/KG
SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE (112945-52-5):
ORAL LD50 RAT: 3160 MG/KG
POTENTIAL HEALTH EFFECTS:
SKIN CORROSION PROPERTY/STIMULATIVENESS:
MAY CAUSE IRRITATION WITH REDNESS, ITCHING AND PAIN. METHYL ETHYL KETONE
AND CYCLOHEXANONE MAY BE ABSORBED THROUGH THE SKIN CAUSING EFFECTS SIMILAR
TO THOSE LISTED UNDER INHALATION.
POTENTIAL HEALTH EFFECTS:
EYE CRITICAL DAMAGE / STIMULATIVENESS:
VAPORS MAY CAUSE IRRITATION. DIRECT CONTACT MAY CAUSE IRRITATION WITH
REDNESS, STINGING AND TEARING OF THE EYES. MAY CAUSE EYE DAMAGE.
POTENTIAL HEALTH EFFECTS:
INGESTION:
SWALLOWING MAY CAUSE ABDOMINAL PAIN, NAUSEA, VOMITING AND DIARRHEA.
ASPIRATION DURING SWALLOWING OR VOMITING CAN CAUSE CHEMICAL PNEUMONIA AND
LUNG DAMAGE. MAY CAUSE KIDNEY AND LIVER DAMAGE.
POTENTIAL HEALTH EFFECTS:
INHALATION:
VAPORS OR MISTS MAY CAUSE MUCOUS MEMBRANE AND RESPIRATORY IRRITATION,
COUGHING, HEADACHE, DIZZINESS, DULLNESS, NAUSEA, SHORTNESS OF BREATH AND
VOMITING. HIGH CONCENTRATIONS MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION,
NARCOSIS AND UNCONSCIOUSNESS. MAY CAUSE KIDNEY, LIVER AND LUNG DAMAGE.
RESPIRATORY ORGANS SENSITIZATION/SKIN SENSITIZATION:
THIS PRODUCT IS NOT REPORTED TO HAVE ANY SKIN SENSITIZATION EFFECTS.
GENERATIVE CELL MUTAGENICITY:
CYCLOHEXANONE HAS BEEN POSITIVE IN BACTERIAL AND MAMMALIAN ASSAYS. ACETONE,
METHYL ETHYL KETONE AND TETRAHYDROFURAN ARE GENERALLY THOUGHT NOT TO BE
MUTAGENIC.
CARCINOGENICITY:
A:
GENERAL PRODUCT INFORMATION:
IN 2012 USEPA INTEGRATED RISK INFORMATION SYSTEM (IRIS) REVIEWED A TWO
SPECIES INHALATION LIFETIME STUDY ON THF CONDUCTED BY NTP (1998). MALE
RATS DEVELOPED RENAL TUMORS AND FEMALE MICE DEVELOPED LIVER TUMORS WHILE
NEITHER THE FEMALE RATS NOR THE MALE MICE SHOWED SIMILAR RESULTS. BECAUSE
THE CARCINOGENIC MECHANISMS COULD NOT BE IDENTIFIED CLEARLY IN EITHER
SPECIES FOR EITHER TUMOR, THE EPA DETERMINED THAT THE MALE RAT AND FEMALE
MOUSE FINDINGS ARE RELEVANT TO THE ASSESSMENT OF CARCINOGENIC POTENTIAL IN
HUMANS. THEREFORE, THE IRIS REVIEW CONCLUDES THAT THESE DATA IN AGGREGATE
INDICATE THAT THERE IS "SUGGESTIVE EVIDENCE OF CARCINOGENIC POTENTIAL"
FOLLOWING EXPOSURE TO THF BY ALL ROUTES OF EXPOSURE.
B:
COMPONENT CARCINOGENICITY:
TETRAHYDROFURAN (109-99-9):
ACGIH: A3 - CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS
ACETONE (67-64-1):
ACGIH: A4 - NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
PVC (CHLOROETHYLENE, POLYMER) (9002-86-2):
ACGIH: A4 - NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
IARC: SUPPLEMENT 7 [1987]; MONOGRAPH 19 [1979] (GROUP 3 (NOT CLASSIFIABLE))
CYCLOHEXANONE (108-94-1):
ACGIH: A3 - CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS
IARC: MONOGRAPH 71 [1999]; MONOGRAPH 47 [1989] (GROUP 3 (NOT CLASSIFIABLE))
SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE (112945-52-5):
IARC:
MONOGRAPH 68 [1997] (LISTED UNDER AMORPHOUS SILICA)
(GROUP 3 (NOT CLASSIFIABLE))
REPRODUCTIVE TOXICITY:
METHYL ETHYL KETONE AND CYCLOHEXANONE HAVE BEEN SHOWN TO CAUSE EMBRYOFETAL
TOXICITY AND BIRTH DEFECTS IN LABORATORY ANIMALS. ACETONE AND
TETRAHYDROFURAN HAS BEEN FOUND TO CAUSE ADVERSE DEVELOPMENTAL EFFECTS ONLY
WHEN EXPOSURE LEVELS CAUSE OTHER TOXIC EFFECTS TO THE MOTHER.
SPECIFIED TARGET ORGAN GENERAL TOXICITY:
SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION. INHALATION OF HIGH CONCENTRATIONS MAY
CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION, NARCOSIS AND UNCONSCIOUSNESS. MAY
CAUSE KIDNEY, LIVER AND LUNG DAMAGE.
SPECIFIED TARGET ORGAN GENERAL TOXICITY:
REPEATED EXPOSURE:
THIS PRODUCT IS NOT REPORTED TO HAVE ANY SPECIFIC TARGET ORGAN TOXICITY
REPEAT EXPOSURE EFFECTS.
ASPIRATION RESPIRATORY ORGANS HAZARD:
ASPIRATION DURING SWALLOWING OR VOMITING CAN CAUSE CHEMICAL PNEUMONIA AND
LUNG DAMAGE. MAY CAUSE KIDNEY AND LIVER DAMAGE.
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICITY:
A:
GENERAL PRODUCT INFORMATION:
THIS PRODUCT IS NOT EXPECTED TO BE TOXIC TO AQUATIC ORGANISMS.
B:
COMPONENT ANALYSIS - ECOTOXICITY - AQUATIC TOXICITY:
TETRAHYDROFURAN (109-99-9):
TEST & SPECIES CONDITIONS
96 HR LC50 PIMEPHALES PROMELAS 1970-2360 MG/L
[FLOW-THROUGH]
96 HR LC50 PIMEPHALES PROMELAS 2700-3600 MG/L
[STATIC]
24 HR EC50 DAPHNIA MAGNA 5930 MG/L
ACETONE (67-64-1):
TEST & SPECIES CONDITIONS
96 HR LC50 ONCORHYNCHUS MYKISS 4.74 - 6.33 ML/L
96 HR LC50 PIMEPHALES PROMELAS 6210 - 8120 MG/L
[STATIC]
96 HR LC50 LEPOMIS MACROCHIRUS 8300 MG/L
48 HR EC50 DAPHNIA MAGNA 10294 - 17704 MG/L
[STATIC]
48 HR EC50 DAPHNIA MAGNA 12600 - 12700 MG/L
METHYL ETHYL KETONE (78-93-3):
TEST & SPECIES CONDITIONS
96 HR LC50 PIMEPHALES PROMELAS 3130-3320 MG/L
[FLOW-THROUGH]
48 HR EC50 DAPHNIA MAGNA >520 MG/L
48 HR EC50 DAPHNIA MAGNA 5091 MG/L
48 HR EC50 DAPHNIA MAGNA 4025 - 6440 MG/L
[STATIC]
CYCLOHEXANONE (108-94-1):
TEST & SPECIES CONDITIONS
96 HR LC50 PIMEPHALES PROMELAS 481-578 MG/L
[FLOW-THROUGH]
96 HR LC50 PIMEPHALES PROMELAS 8.9 MG/L
96 HR EC50 CHLORELLA VULGARIS 20 MG/L
24 HR EC50 DAPHNIA MAGNA 800 MG/L
PERSISTENCE/DEGRADABILITY: NO INFORMATION AVAILABLE FOR THE PRODUCT.
BIOACCUMULATION: NO INFORMATION AVAILABLE FOR THE PRODUCT.
MOBILITY IN SOIL: NO INFORMATION AVAILABLE FOR THE PRODUCT.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL INSTRUCTIONS:
SEE SECTION 7 FOR HANDLING PROCEDURES. SEE SECTION 8 FOR PERSONAL PROTECTIVE
EQUIPMENT RECOMMENDATIONS.
DISPOSAL OF CONTAMINATED CONTAINERS OR PACKAGING:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 14 - TRANSPORTATION INFORMATION | |
DOT INFORMATION:
FOR GREATER THAN 1 LITER (0.3 GAL):
SHIPPING NAME: ADHESIVES
UN #: 1133
HAZARD CLASS: 3
PACKING GROUP: II
REQUIRED LABEL(S): FLAMMABLE LIQUID
FOR LESS THAN 1 LITER (0.3 GAL):
SHIPPING NAME: CONSUMER COMMODITY, ORM-D
IMDG INFORMATION:
FOR GREATER THAN 1 LITER (0.3 GAL):
SHIPPING NAME: ADHESIVES
UN #: 1133
HAZARD CLASS: 3
PACKING GROUP: II
REQUIRED LABEL(S): FLAMMABLE LIQUID
FOR LESS THAN 1 LITER (0.3 GAL):
SHIPPING NAME: ADHESIVES
UN #: 1133
HAZARD CLASS: 3
PACKING GROUP: II
REQUIRED LABEL(S): NONE (LIMITED QUANTITIES ARE EXPECTED FROM LABELING)
| SECTION 15 - REGULATORY INFORMATION | |
REGULATORY INFORMATION:
US FEDERAL REGULATIONS:
COMPONENT ANALYSIS:
THIS MATERIAL CONTAINS ONE OR MORE OF THE FOLLOWING CHEMICALS REQUIRED
TO BE IDENTIFIED UNDER SARA SECTION 302 (40 CFR 355 APPENDIX A), SARA
SECTION 313 (40 CFR 372.65) AND/OR CERCLA (40 CFR 302.4).
TETRAHYDROFURAN (109-99-9):
CERCLA:
1000 LB FINAL RQ
454 KG FINAL RQ
ACETONE (67-64-1):
CERCLA:
5000 LB FINAL RQ
2270 KG FINAL RQ
METHYL ETHYL KETONE (78-93-3):
CERCLA:
5000 LB FINAL RQ
2270 KG FINAL RQ
CYCLOHEXANONE (108-94-1):
CERCLA:
5000 LB FINAL RQ
2270 KG FINAL RQ
STATE REGULATIONS:
COMPONENT ANALYSIS - STATE:
THE FOLLOWING COMPONENTS APPEAR ON ONE OR MORE OF THE FOLLOWING STATE
HAZARDOUS SUBSTANCES LISTS:
COMPONENT CAS CA MA MN NJ PA RI
TETRAHYDROFURAN 109-99-9 YES YES YES YES YES NO
ACETONE 67-64-1 YES YES YES YES YES NO
METHYL ETHYL KETONE 78-93-3 YES YES YES YES YES NO
PVC (CHLOROETHYLENE, POLYMER) 9002-86-2 NO NO NO YES NO NO
CYCLOHEXANONE 108-94-1 YES YES YES YES YES NO
COMPONENT ANALYSIS - WHMIS IDL:
THE FOLLOWING COMPONENTS ARE IDENTIFIED UNDER THE CANADIAN HAZARDOUS
PRODUCTS ACT INGREDIENT DISCLOSURE LIST:
COMPONENT CAS # MINIMUM CONCENTRATION
TETRAHYDROFURAN 109-99-9 1%
ACETONE 67-64-1 1%
METHYL ETHYL KETONE 78-93-3 1%
CYCLOHEXANONE 108-94-1 0.1%
ADDITIONAL REGULATORY INFORMATION:
A:
GENERAL PRODUCT INFORMATION:
THIS PRODUCT CONTAINS TRACE AMOUNTS OF CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER. UNDER NORMAL USE CONDITIONS, EXPOSURE TO THESE
CHEMICALS AT LEVELS ABOVE THE STATE OF CALIFORNIA "NO SIGNIFICANT RISK
LEVEL" (NSRL) ARE UNLIKELY. THE USE OF PROPER PERSONAL PROTECTIVE EQUIPMENT
(PPE) AND VENTILATION GUIDELINES NOTED IN SECTION 8 WILL MINIMIZE EXPOSURE
TO THESE CHEMICALS.
B:
COMPONENT ANALYSIS - INVENTORY:
COMPONENT CAS # TSCA CAN EEC
TETRAHYDROFURAN 109-99-9 YES DSL EINECS
ACETONE 67-64-1 YES DSL EINECS
METHYL ETHYL KETONE 78-93-3 YES DSL EINECS
PVC (CHLOROETHYLENE, POLYMER) 9002-86-2 YES DSL ELINCS
CYCLOHEXANONE 108-94-1 YES DSL EINECS
SILICA, AMORPHOUS, FUMED, 112945-52-5 NO DSL NO
CRYSTALLINE-FREE
| SECTION 16 - OTHER INFORMATION | |
KEY/LEGEND:
EPA = ENVIRONMENTAL PROTECTION AGENCY
TSCA = TOXIC SUBSTANCE CONTROL ACT
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
IARC = INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
NIOSH = NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH
NTP = NATIONAL TOXICOLOGY PROGRAM
OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION.
NJTSR = NEW JERSEY TRADE SECRET REGISTRY.
LITERATURE REFERENCES: NONE
OTHER INFORMATION:
NFPA AND HMIS:
NFPA HAZARD SIGNAL:
HEALTH 2
FLAMMABILITY 3
REACTIVITY 1
SPECIAL NONE
HMIS HAZARD SIGNAL:
HEALTH 2*
FLAMMABILITY 3
REACTIVITY 1
PPE G
DISCLAIMER:
THE INFORMATION HEREIN HAS BEEN COMPILED FROM SOURCES BELIEVED TO BE
RELIABLE, UP-TO-DATE, AND IS ACCURATE TO THE BEST OF OUR KNOWLEDGE.
HOWEVER, WE CANNOT GIVE ANY GUARANTEES REGARDING INFORMATION FROM OTHER
SOURCES, AND EXPRESSLY DO NOT MAKE WARRANTIES, NOR ASSUME ANY LIABILITY
FOR ITS USE.
ISSUE DATE: 06/06/12
REVISION: 1.0000
PRINT DATE: 9/27/2012