| Common Name: | CANADIAN PVC HEAVY DUTY CLEAR OR GREY CEMENT |
| Manufacturer: | OATEY |
| SDS Revision Date: | 9/11/2012 |
| SDS Format: | ANSI-OSHA |
| Item Number(s): | 29FH97, 29FJ04, 49K210 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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OATEY(R*)
LO-VOC
SCAQMD 1168/316A
COMPLIANT
MATERIAL SAFETY DATA SHEET
MSDS NUMBER: 1102C
| SECTION 1 PRODUCT AND COMPANY IDENTIFICATION |  |
TRADE NAME: OATEY CANADIAN PVC HEAVY DUTY CLEAR OR GREY CEMENT
PRODUCT NOS.:
CLEAR 31011, 31476, 31477, 31478, 31479 GREY 31510, 31511, 31512, 31513,
31514
PRODUCT USE: CEMENT FOR PVC PLASTIC PIPE
FORMULA: PVC RESIN IN SOLVENT SOLUTION
SYNONYMS: PVC PLASTIC PIPE CEMENT
FIRM NAME & ADDRESS:
OATEY COMPANY
4700 WEST 160TH STREET
CLEVELAND, OHIO 44135
WWW.OATEY.COM
FIRM PHONE NO: (216) 267-7100
EMERGENCY PHONE NOS.:
FOR EMERGENCY FIRST AID CALL: 1-877-740-5015.
FOR CHEMICAL TRANSPORTATION EMERGENCIES ONLY, CALL CHEMTREC AT:
1-800-424-9300.
OUTSIDE THE U.S.: 1-703-527-3887.
PREPARED BY: TECHNICAL DEPARTMENT
PREPARATION DATE: 09/11/2012
| SECTION 2 HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
CLEAR OR GRAY LIQUID WITH AN ETHER-LIKE ODOR. EXTREMELY FLAMMABLE LIQUID
AND VAPOR. VAPORS MAY CAUSE FLASH FIRE. MAY CAUSE EYE AND SKIN IRRITATION.
INHALATION OF VAPORS OR MIST MAY CAUSE RESPIRATORY IRRITATION AND CENTRAL
NERVOUS SYSTEM EFFECTS. SWALLOWING MAY CAUSE IRRITATION, NAUSEA, VOMITING,
DIARRHEA AND KIDNEY OR LIVER DISORDERS. ASPIRATION HAZARD. MAY BE FATAL IF
SWALLOWED. SYMPTOMS MAY BE DELAYED.
| SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENTS %WT/WT CAS NUMBER
TETRAHYDROFURAN 30 - 60% 109-99-9
METHYL ETHYL KETONE 7 - 13% 78-93-3
ACETONE 10 - 20% 67-64-1
PVC RESIN (NON-HAZARDOUS) 10 - 20% 9002-86-2
CYCLOHEXANONE 10 - 30% 108-94-1
AMORPHOUS FUMED SILICA (NON-HAZARDOUS) 1 - 5% 112945-52-5
INGREDIENTS ACGIH TLV TWA OSHA PEL TWA OTHER
TETRAHYDROFURAN 50 PPM (SKIN) 200 PPM 25 PPM (MFG)
100 PPM STEL
METHYL ETHYL KETONE 200 PPM 200 PPM NONE
300 PPM
ACETONE 500 PPM 1000 PPM NONE
750 PPM STEL
PVC RESIN (NON-HAZARDOUS) 10 MG/M3 15 MG/M3 NONE
CYCLOHEXANONE 20 PPM (SKIN) 50 PPM NONE
50 PPM STEL
AMORPHOUS FUMED SILICA 10 MG/M3 NONE NONE
(NON-HAZARDOUS) ESTABLISHED
OSHA HAZARD CLASSIFICATION: FLAMMABLE, IRRITANT, ORGAN EFFECTS
| SECTION 4 FIRST AID MEASURES | |
SKIN:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY. WASH ALL EXPOSED AREAS WITH SOAP
AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE DRIED
CEMENT WITH OATEY PLUMBER'S HAND CLEANER OR BABY OIL.
EYES:
IF MATERIAL GETS INTO EYES OR IF FUMES CAUSE IRRITATION, IMMEDIATELY FLUSH
EYES WITH PLENTY OF WATER UNTIL CHEMICAL IS REMOVED. IF IRRITATION
PERSISTS, GET MEDICAL ATTENTION IMMEDIATELY.
INHALATION:
IF SYMPTOMS OF EXPOSURE DEVELOP, REMOVE TO FRESH AIR. IF BREATHING BECOMES
DIFFICULT, ADMINISTER OXYGEN. ADMINISTER ARTIFICIAL RESPIRATION IF
BREATHING HAS STOPPED. SEEK IMMEDIATE MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. RINSE MOUTH WITH WATER. NEVER GIVE ANYTHING BY
MOUTH TO A PERSON WHO IS UNCONSCIOUS OR DROWSY. GET IMMEDIATE MEDICAL
ATTENTION BY CALLING A POISON CONTROL CENTER, OR HOSPITAL EMERGENCY ROOM.
IF MEDICAL ADVICE CANNOT BE OBTAINED, THEN TAKE THE PERSON AND PRODUCT TO
THE NEAREST MEDICAL EMERGENCY TREATMENT CENTER OR HOSPITAL.
| SECTION 5 FIRE FIGHTING MEASURES | |
FLASH POINT METHOD: / 14 - 23 DEGREES F. (-10 TO -5 DEGREES C) / CCCFP
FLAMMABILITY:
LEL: 1.8% VOLUME
UEL: 11.8% VOLUME
EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, OR FOAM TO EXTINGUISH FIRE. COOL FIRE EXPOSED
CONTAINER WITH WATER. WATER MAY BE INEFFECTIVE AS AN EXTINGUISHING AGENT.
SPECIAL FIRE FIGHTING PROCEDURE:
FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE CLOTHING FOR FIRES IN AREAS WHERE CHEMICALS
ARE USED OR STORED
UNUSUAL FIRE AND EXPLOSION HAZARDS:
EXTREMELY FLAMMABLE LIQUID. KEEP AWAY FROM HEAT AND ALL SOURCES OF IGNITION
INCLUDING SPARKS, FLAMES, LIGHTED CIGARETTES AND PILOT LIGHTS. CONTAINERS
MAY RUPTURE OR EXPLODE IN THE HEAT OF A FIRE. VAPORS ARE HEAVIER THAN AIR
AND MAY TRAVEL TO A REMOTE IGNITION SOURCE AND FLASH BACK. THIS PRODUCT
CONTAINS TETRAHYDROFURAN THAT MAY FORM EXPLOSIVE ORGANIC PEROXIDE WHEN
EXPOSED TO AIR OR LIGHT OR WITH AGE.
HAZARDOUS DECOMPOSITION PRODUCTS:
COMBUSTION WILL PRODUCE TOXIC AND IRRITATING VAPORS INCLUDING CARBON
MONOXIDE, CARBON DIOXIDE AND HYDROGEN CHLORIDE.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
SPILL OR LEAK PROCEDURES:
REMOVE ALL SOURCES OF IGNITION AND VENTILATE AREA. STOP LEAK IF IT CAN BE
DONE WITHOUT RISK. PERSONNEL CLEANING UP THE SPILL SHOULD WEAR APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT, INCLUDING RESPIRATORS IF VAPOR
CONCENTRATIONS ARE HIGH. SOAK UP SPILL WITH AN INERT ABSORBENT SUCH AS
SAND, EARTH OR OTHER NON-COMBUSTING MATERIAL. PUT ABSORBENT MATERIAL IN
COVERED, LABELED METAL CONTAINERS. PREVENT LIQUID FROM ENTERING
WATERCOURSES, SEWERS AND NATURAL WATERWAYS. REPORT RELEASES TO AUTHORITIES
AS REQUIRED. SEE SECTION 13 FOR DISPOSAL INFORMATION.
| SECTION 7 HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING VAPORS OR
MISTS. USE WITH ADEQUATE VENTILATION (EQUIVALENT TO OUTDOORS). WASH
THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE IN THE WORK AREA.
KEEP PRODUCT AWAY FROM HEAT, SPARKS, FLAMES AND ALL OTHER SOURCES OF
IGNITION. NO SMOKING IN STORAGE OR USE AREAS. KEEP CONTAINERS CLOSED WHEN
NOT IN USE.
STORAGE:
STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE
MATERIALS. KEEP CONTAINERS CLOSED WHEN NOT IN USE.
OTHER:
"EMPTY" CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. FOLLOW ALL
MSDS PRECAUTIONS IN HANDLING EMPTY CONTAINERS. DO NOT CUT OR WELD ON OR
NEAR EMPTY OR FULL CONTAINERS.
| SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
VENTILATION:
OPEN DOORS & WINDOWS. PROVIDE VENTILATION CAPABLE OF MAINTAINING EMISSIONS
AT THE POINT OF USE BELOW RECOMMENDED EXPOSURE LIMITS. IF USED IN ENCLOSED
AREA, USE EXHAUST FANS. EXHAUST FANS SHOULD BE EXPLOSION-PROOF OR SET UP IN
A WAY THAT FLAMMABLE CONCENTRATIONS OF SOLVENT VAPORS ARE NOT EXPOSED TO
ELECTRICAL FIXTURES OR HOT SURFACES.
RESPIRATORY PROTECTION:
FOR OPERATIONS WHERE THE EXPOSURE LIMIT MAY BE EXCEEDED, A NIOSH APPROVED
ORGANIC VAPOR RESPIRATOR OR SUPPLIED AIR RESPIRATOR IS RECOMMENDED.
EQUIPMENT SELECTION DEPENDS ON CONTAMINANT TYPE AND CONCENTRATION, SELECT
IN ACCORDANCE WITH 29 CFR 1910.134 AND GOOD INDUSTRIAL HYGIENE PRACTICE.
FOR FIREFIGHTING, USE SELF-CONTAINED BREATHING APPARATUS.
SKIN PROTECTION:
RUBBER GLOVES ARE SUITABLE FOR NORMAL USE OF THE PRODUCT. FOR LONG
EXPOSURES CHEMICAL RESISTANT GLOVES MAY BE REQUIRED SUCH AS 4H(TM) OR
SILVER SHIELD(TM) TO AVOID PROLONGED SKIN CONTACT.
EYE PROTECTION: SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES.
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT: 151 DEGREES F / 66 DEGREES C
MELTING POINT: NOT APPLICABLE
VAPOR PRESSURE: 145 MMHg @ 20 DEGREES C
VAPOR DENSITY (AIR = 1): 2.5
VOLATILE COMPONENTS: 80-84%
SOLUBILITY IN WATER: NEGLIGIBLE
PH: NOT APPLICABLE
SPECIFIC GRAVITY: 0.94 +/- 0.02 @ 20 DEGREES C
EVAPORATION RATE (BUAC = 1): 5.5 - 8.0
APPEARANCE: CLEAR OR GRAY LIQUID
ODOR: ETHER-LIKE
WILL DISSOLVE IN: TETRAHYDROFURAN
MATERIAL IS: LIQUID
| SECTION 10 STABILITY AND REACTIVITY | |
STABILITY: STABLE.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, FLAMES AND OTHER SOURCES OF IGNITION.
HAZARDOUS DECOMPOSITION PRODUCTS:
COMBUSTION WILL PRODUCE TOXIC AND IRRITATING VAPORS INCLUDING CARBON
MONOXIDE, CARBON DIOXIDE AND HYDROGEN CHLORIDE.
INCOMPATIBILITY/MATERIALS TO AVOID:
OXIDIZING AGENTS, ALKALIS, AMINES, AMMONIA, ACIDS, CHLORINE COMPOUNDS,
CHLORINATED INORGANICS (POTASSIUM, CALCIUM AND SODIUM HYPOCHLORITE) AND
HYDROGEN PEROXIDES. MAY ATTACK PLASTIC, RESINS AND RUBBER.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| SECTION 11 TOXICOLOGICAL INFORMATION | |
INHALATION:
VAPORS OR MISTS MAY CAUSE MUCOUS MEMBRANE AND RESPIRATORY IRRITATION,
COUGHING, HEADACHE, DIZZINESS, DULLNESS, NAUSEA, SHORTNESS OF BREATH AND
VOMITING. HIGH CONCENTRATIONS MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION,
NARCOSIS AND UNCONSCIOUSNESS. MAY CAUSE KIDNEY, LIVER AND LUNG DAMAGE.
SKIN:
MAY CAUSE IRRITATION WITH REDNESS, ITCHING AND PAIN. METHYL ETHYL KETONE
AND CYCLOHEXANONE MAY BE ABSORBED THROUGH THE SKIN CAUSING EFFECTS SIMILAR
TO THOSE LISTED UNDER INHALATION.
EYE:
VAPORS MAY CAUSE IRRITATION. DIRECT CONTACT MAY CAUSE IRRITATION WITH
REDNESS, STINGING AND TEARING OF THE EYES. MAY CAUSE EYE DAMAGE.
INGESTION:
SWALLOWING MAY CAUSE ABDOMINAL PAIN, NAUSEA, VOMITING AND DIARRHEA.
ASPIRATION DURING SWALLOWING OR VOMITING CAN CAUSE CHEMICAL PNEUMONIA AND
LUNG DAMAGE. MAY CAUSE KIDNEY AND LIVER DAMAGE.
CHRONIC TOXICITY:
PROLONGED OR REPEATED OVEREXPOSURE CAUSE DERMATITIS AND DAMAGE TO THE
KIDNEY, LIVER, LUNGS AND CENTRAL NERVOUS SYSTEM.
TOXICITY DATA:
ACETONE:
ORAL RAT LD50: 5,800 MG/KG
INHALATION RAT LC50: 50,100 MG/M3/8 HOURS
CYCLOHEXANONE:
ORAL RAT LD50: 1,620 MG/KG
INHALATION RAT LC50: 8,000 PPM/4 HOURS
SKIN RABBIT LD50: 1 ML/KG
TETRAHYDROFURAN:
ORAL RAT LD50: 1,650 MG/KG
INHALATION RAT LC50: 21,000 PPM/3 HOURS
METHYL ETHYL KETONE:
ORAL RAT LD50: 2,737 MG/KG
INHALATION RAT LC50: 23,500 MG/M3/8 HOURS
SKIN RABBIT LD50: 6,480 MG/KG
SENSITIZATION: NONE OF THE COMPONENTS ARE KNOWN TO CAUSE SENSITIZATION.
CARCINOGENICITY:
NONE OF THE COMPONENTS ARE LISTED AS A CARCINOGEN OR SUSPECT CARCINOGEN BY
NTP, IARC OR OSHA. THE NATIONAL TOXICOLOGY PROGRAM HAS REPORTED THAT
EXPOSURE OF MICE AND RATS TO TETRAHYDROFURAN (THF) VAPOR LEVELS UP TO 1800
PPM 6 HR/DAY, 5 DAYS/WEEK FOR THEIR LIFETIME CAUSED AN INCREASED INCIDENCE
OF KIDNEY TUMORS IN MALE RATS AND LIVER TUMORS IN FEMALE MICE. THE
SIGNIFICANCE OF THESE FINDINGS FOR HUMAN HEALTH IS UNCLEAR AT THIS TIME,
AND MAY BE RELATED TO "SPECIES SPECIFIC" EFFECTS. ELEVATED INCIDENCES OF
TUMORS IN HUMANS HAVE NOT BEEN REPORTED FOR THF. ACGIH HAS CLASSIFIED
CYCLOHEXANONE (CYH) AND TETRAHYDROFURAN AS "A3," CONFIRMED ANIMAL
CARCINOGENS WITH UNKNOWN RELEVANCE TO HUMANS.
MUTAGENICITY:
CYCLOHEXANONE HAS BEEN POSITIVE IN BACTERIAL AND MAMMALIAN ASSAYS. ACETONE,
METHYL ETHYL KETONE AND TETRAHYDROFURAN ARE GENERALLY THOUGHT NOT TO BE
MUTAGENIC.
REPRODUCTIVE TOXICITY:
METHYL ETHYL KETONE AND CYCLOHEXANONE HAVE BEEN SHOWN TO CAUSE EMBRYOFETAL
TOXICITY AND BIRTH DEFECTS IN LABORATORY ANIMALS. ACETONE AND
TETRAHYDROFURAN HAS BEEN FOUND TO CAUSE ADVERSE DEVELOPMENTAL EFFECTS ONLY
WHEN EXPOSURE LEVELS CAUSE OTHER TOXIC EFFECTS TO THE MOTHER.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
PERSONS WITH PRE-EXISTING SKIN, LUNG, KIDNEY OR LIVER DISORDERS MAY BE AT
INCREASED RISK FROM EXPOSURE TO THIS PRODUCT.
| SECTION 12 ECOLOGICAL INFORMATION | |
THIS PRODUCT IS NOT EXPECTED TO BE TOXIC TO AQUATIC ORGANISMS.
CYCLOHEXANONE:
96 HOUR LC50 VALUES FOR FISH IS OVER: 100 MG/L.
TETRAHYDROFURAN:
96 HOUR LC50 FATHEAD MINNOW: 2160 MG/L.
ACETONE:
96 HOUR LC50 FOR FISH IS GREATER THAN: 100 MG/L.
METHYL ETHYL KETONE:
96 HOUR LC50 FOR FISH IS GREATER THAN: 100 MG/L.
VOC INFORMATION:
THIS PRODUCT EMITS VOC'S (VOLATILE ORGANIC COMPOUNDS) IN ITS USE. MAKE SURE
THAT USE OF THIS PRODUCT COMPLIES WITH LOCAL VOC EMISSION REGULATIONS,
WHERE THEY EXIST.
VOC LEVEL: MAXIMUM 510 G/L PER SCAQMD TEST METHOD 316A.
| SECTION 13 DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL:
DISPOSE IN ACCORDANCE WITH CURRENT LOCAL, STATE AND FEDERAL REGULATIONS.
RCRA HAZARDOUS WASTE NUMBER: U002, U057, U159, U213
EPA HAZARDOUS WASTE ID NUMBER: D001, D035, F003, F0005
EPA HAZARD WASTE NUMBER:
IGNITABLE WASTE. TOXIC WASTE (METHYL ETHYL KETONE CONTENT)
| SECTION 14 TRANSPORT INFORMATION | |
DOT:
LESS THAN 1 LITER GREATER THAN 1 LITER
(0.3 GAL) (0.3 GAL)
UN/NA NUMBER NONE UN1133
PROPER SHIPPING NAME CONSUMER COMMODITY ADHESIVES
HAZARD CLASS ORM-D 3
PACKING GROUP NONE PGII
HAZARD LABELS NONE FLAMMABLE LIQUID
IMDG:
UN NUMBER UN1133 UN1133
PROPER SHIPPING NAME ADHESIVES ADHESIVES
HAZARD CLASS 3 3
PACKING GROUP II II
LABEL NONE (LIMITED CLASS 3 (FLAMMABLE LIQUID)
QUANTITIES ARE
EXPECTED FROM
LABELING)
FLASH POINT (DEG C) -10 TO -5 DEGREES C -10 TO -5 DEGREES C
2008 NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER: 127
| SECTION 15 REGULATORY INFORMATION | |
HAZARD CATEGORY FOR SECTION 311/312:
ACUTE HEALTH, CHRONIC HEALTH, FLAMMABLE
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (TPQ):
THIS PRODUCT DOES NOT CONTAIN CHEMICALS REGULATED UNDER SARA SECTION 302.
SECTION 313 TOXIC CHEMICALS:
THIS PRODUCT DOES NOT CONTAIN CHEMICALS SUBJECT TO SARA TITLE III SECTION
313 REPORTING REQUIREMENTS.
CERCLA 103 REPORTABLE QUANTITY:
SPILLS OF THIS PRODUCT OVER THE RQ (REPORTABLE QUANTITY) MUST BE REPORTED
TO THE NATIONAL RESPONSE CENTER. THE RQ FOR THE PRODUCT, BASED ON THE RQ
FOR TETRAHYDROFURAN (60% MAXIMUM) OF 1,000 LBS, IS 1,667 LBS.
MANY STATES HAVE MORE STRINGENT RELEASE REPORTING REQUIREMENTS. REPORT
SPILLS REQUIRED UNDER FEDERAL, STATE AND LOCAL REGULATIONS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS TRACE AMOUNTS OF CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER. UNDER NORMAL USE CONDITIONS, EXPOSURE TO THESE
CHEMICALS AT LEVELS ABOVE THE STATE OF CALIFORNIA "NO SIGNIFICANT RISK
LEVEL" (NSRL) ARE UNLIKELY. THE USE OF PROPER PERSONAL PROTECTIVE EQUIPMENT
(PPE) AND VENTILATION GUIDELINES NOTED IN SECTION 8 WILL MINIMIZE EXPOSURE
TO THESE CHEMICALS.
TSCA INVENTORY:
ALL OF THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY.
CANADIAN WHIMS CLASSIFICATION:
CLASS B, DIVISION 2; CLASS D, DIVISION 2, SUBDIVISION B; CLASS D, DIVISION
2, SUBDIVISION A. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE
HAZARD CRITERIA OF THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS
CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR.
| SECTION 16 OTHER INFORMATION | |
NFPA AND HMIS:
NFPA HAZARD SIGNAL:
HEALTH 2
FLAMMABILITY 3
REACTIVITY 1
SPECIAL NONE
HMIS HAZARD SIGNAL:
HEALTH 2*
FLAMMABILITY 3
REACTIVITY 1
PPE G
DISCLAIMER:
THE INFORMATION HEREIN HAS BEEN COMPILED FROM SOURCES BELIEVED TO BE
RELIABLE, UP-TO-DATE, AND IS ACCURATE TO THE BEST OF OUR KNOWLEDGE.
HOWEVER, WE CANNOT GIVE ANY GUARANTEES REGARDING INFORMATION FROM OTHER
SOURCES, AND EXPRESSLY DO NOT MAKE WARRANTIES, NOR ASSUME ANY LIABILITY
FOR ITS USE.
TEMPLATE: TMPL-CN-EL