| Common Name: | SEALED LEAD ACID BATTERIES, SEALED MAINTENANCE FREE LEAD ACID BATTERIES |
| Manufacturer: | NINGBO SHENGYANG POWER SUPPLY & ELECTRIC APPLIANCE |
| SDS Revision Date: | 1/18/2010 |
| SDS Format: | ANSI-OSHA |
| Item Number(s): | 5RHL9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LT
LANDER TESTING
REPORT NO.: LDBG-MSDS-1001180201
REPORT ID: 81091374
MATERIAL SAFETY DATA SHEET
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND OF THE COMPANY/UNDERTAKING
PRODUCT NAME: SEALED LEAD ACID BATTERIES
USAGE: LIGHT FITTING
MANUFACTURER/SUPPLIER:
NINGBO SHENGYANG POWER SUPPLY AND ELECTRIC APPLIANCE CO., LTD
ADDRESS:
HUDI, LINSHAN TOWN
YUYAO, ZHEJIANG
P.R. CHINA
CONTACT PERSON: GUANGMING QI
E-MAIL: INFO@SY-POWER.COM
TEL: +86-574-62062289
FAX: +86-574-62062287
FURTHER INFORMATION OBTAINABLE FROM:
NINGBO SHENGYANG POWER SUPPLY AND ELECTRIC APPLIANCE CO., LTD
INFORMATION IN CASE OF EMERGENCY:
TEL: +86-574-62062289
| 2. HAZARDS IDENTIFICATION | |
NOTE:
UNDER NORMAL CONDITIONS OF USE. THIS PRODUCT DOES NOT PRESENT A HEALTH
HAZARD. THE FOLLOWING INFORMATION IS PROVIDED FOR BATTERY ELECTROLYTE
(ACID) AND LEAD FOR EXPOSURE THAT MAY OCCUR DURING BATTERY PRODUCTION
OR CONTAINER BREAKAGE OR UNDER EXTREME HEAT CONDITIONS SUCH AS FIRE.
POTENTIAL HEALTH EFFECTS:
EYE:
BATTERY ELECTROLYTE (ACID) CAN CAUSE SEVERE IRRITATION, BURNS, AND CORNEA
DAMAGE UPON CONTACT.
SKIN:
BATTERY ELECTROLYTE (ACID) CAN CAUSE SEVERE IRRITATION, BURNS AND
ULCERATION.
INHALATION:
ACID MIST MAY BE GENERATED DURING BATTERY OVERCHARGING AND MAY CAUSE
RESPIRATORY IRRITATION. SEEPAGE OF ACID FROM BROKEN BATTERIES MAY PRESENT
INHALATION EXPOSURE IN A CONFINED AREA.
INGESTION:
HANDS CONTAMINATED BY CONTACT WITH INTERNAL COMPONENTS OF A BATTERY CAN
CAUSE INGESTION OF LEAD/LEAD COMPOUNDS. HANDS SHOULD BE WASHED PRIOR TO
EATING, DRINKING, OR SMOKING.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THE INGREDIENT LIST FOR THE FINISHED PRODUCT(S) IS AS FOLLOWS:
INGREDIENT/SUBSTANCE CAS# WEIGHT %
LEAD (Pb, PbO2, PbSO4) 7439-92-1 ABOUT 63%
SULFURIC ACID 7664-93-9 ABOUT 20%
ABS 750 ABOUT 12%
FIBERGLASS SEPARATOR 65997-17-3 ABOUT 5%
| 4. FIRST AID MEASURES | |
SULFURIC ACID PRECAUTIONS:
EYE CONTACT:
CALL PHYSICIAN IMMEDIATELY AND FLUSH WITH WATER UNTIL PHYSICIAN ARRIVES.
SKIN CONTACT:
IF CONTACT WITH ACID, TAKE OFF THE POLLUTED CLOTH AND RINSE THOROUGHLY WITH
WATER FOR AT LEAST 15 MINUTES. SEE PHYSICIAN IMMEDIATELY IF CONTACT AREA IS
LARGE OR IF BLISTERS FORM.
INHALATION:
IF INHALED, REMOVE EXPOSED PERSON TO FRESH AIR. IF BREATHING IS DIFFICULT,
OXYGEN MAY BE ADMINISTERED. IF BREATHING HAS STOPPED, ARTIFICIAL
RESPIRATION SHOULD BE STARTED IMMEDIATELY. SEEK MEDICAL ATTENTION
IMMEDIATELY.
INGESTION:
CALL OR SEE PHYSICIAN IMMEDIATELY. IF PATIENT IS CONSCIOUS, FLUSH MOUTH
WITH WATER, HAVE THE PATIENT DRINK MILK OR SODIUM BICARBONATE SOLUTION.
DO NOT GIVE ANYTHING TO AN UNCONSCIOUS PERSON.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: DRY CHEMICAL, FOAM OR CARBON DIOXIDE.
SPECIAL FIRE FIGHTING PROCEDURES:
USE POSITIVE PRESSURE, SELF-CONTAINED BREATHING APPARATUS.
UNUSUAL FIRE AND EXPLOSION HAZARD:
THE SEALED LEAD ACID BATTERY IS NOT CONSIDERED FLAMMABLE, BUT IT WILL BURN
IF INVOLVED IN A FIRE. A SHORT CIRCUIT CAN ALSO RESULT IN A FIRE. ACID
MISTS, SMOKE AND DECOMPOSITION PRODUCTS MAY BE PRODUCED. REMOVE ALL
IGNITION SOURCES. COOL BATTERY(S) TO PREVENT RUPTURE.
| 6. ACCIDENTAL RELEASE MEASURES | |
SPILLAGES:
REMOVE COMBUSTIBLE MATERIALS AND ALL SOURCES OF IGNITION. AVOID CONTACT
WITH ACID MATERIALS. USE SODA ASH. BAKING SODA OR LIME TO NEUTRALIZE ANY
ACID THAT MAY BE RELEASED. IF BATTERY IS BROKEN, WEAR CHEMICAL GOGGLES AND
ACID-RESISTANT GLOVES FOR HANDLING THE PARTS.
| 7. HANDLING AND STORAGE | |
HANDLING:
DO NOT PUNCTURE OR ATTEMPT TO OPEN BATTERY CASE. DO NOT SUBJECT PRODUCT TO
OPEN FLAME OR FIRE AND AVOID SITUATIONS THAT COULD CAUSE ARCING BETWEEN
TERMINALS. OBSERVE GOOD PERSONAL HYGIENE, INCLUDING WASHING HANDS BEFORE
EATING. PROHIBIT EATING, DRINKING AND SMOKING IN CONTAMINATED AREAS.
STORAGE:
STORE IN COOL, DRY, WELL VENTILATED AREA. REMOVED FROM DIRECT SUNLIGHT,
HEAT & IGNITION SOURCES, REDUCING AGENTS & FOODSTUFFS. KEEP OUT OF REACH
OF CHILDREN, PETS AND INCOMPATIBLE MATERIALS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROL:
STORE SEALED LEAD ACID BATTERIES AT AMBIENT TEMPERATURE. DO NOT SUBJECT
PRODUCT TO OPEN FLAME OR FIRE. AVOID CONDITIONS THAT COULD CAUSE ARCING
BETWEEN TERMINALS.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
NONE REQUIRED UNDER NORMAL HANDLING OF FINISHED PRODUCT.
EYE/FACE PROTECTION:
NONE REQUIRED UNDER NORMAL CONDITIONS OF USE FINISHED PRODUCT. IF NECESSARY
TO HANDLE BROKEN PRODUCT, CHEMICAL SPLASH GOGGLES ARE RECOMMENDED.
HAND, SKIN AND BODY PROTECTION:
NONE REQUIRED FOR NORMAL HANDLING OF FINISHED PRODUCT. IF NECESSARY TO
HANDLE BROKEN PRODUCT, VINYLCOATED, PVC, GAUNTLET-TYPE GLOVES WITH ROUGH
FINISH ARE RECOMMENDED.
HYGIENE MEASURES:
USE ONLY WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. AVOID
CONTACT WITH SKIN AND EYES. EMERGENCY EYEWASH AND SAFETY SHOWER SHOULD BE
LOCATED NEARBY.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
ODOR: ODORLESS
COLOR: BLACK
FORM: SQUARE (SULFURIC ACID IS A CLEAR, COLORLESS LIQUID WITH ACIDIC ODOR.)
PH: N/A
MELTING POINT/RANGE: N/A
BOILING POINT/RANGE: N/A
IGNITION TEMPERATURE: N/A
FLASH POINT: N/A
DANGER OF EXPLOSION: NOT HAPPEN UNDER NORMAL USE
SPECIFIC GRAVITY: >1
RELATIVE VAPOR DENSITY (AIR=1): N/A
SOLUBILITY IN WATER: INSOLUBLE (SULFURIC ACID IS 100% SOLUBLE IN WATER.)
EXPLOSION LIMITS IN AIR - UPPER: N/A
EXPLOSION LIMITS IN AIR - LOWER: N/A
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
INCOMPATIBILITY (MATERIALS TO AVOID):
STRONG REDUCING AGENTS, MOST METALS, CARBIDES, ETC.
CONDITIONS TO AVOID: HEAT, SPARK, FLAMES AND OTHER SOURCES OF IGNITION.
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF LEAD AND SULFUR, HYDROGEN.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| 11. TOXICOLOGICAL INFORMATION | |
LEAD:
TOXIC BY INGESTION OR INHALATION. CHRONIC POISON.
TYPICAL TLV/TWA AS POWDER: 0.15 MG/M3.
TYPICAL PEL: 0.05 MG/M3.
SULFURIC ACID:
CORROSIVE, THE MORE CONCENTRATED SOLUTIONS CAN CAUSE SERIOUS BURNS TO
THE MOUTH, EYES AND SKIN. HARMFUL BY INGESTION AND THROUGH SKIN CONTACT.
FIBERGLASS SEPARATOR:
SKIN, EYE AND RESPIRATORY IRRITANT. SKIN CONTACT MAY CAUSE MILD ALLERGIC
REACTION OR ITCHINESS.
TYPICAL PEL: 5 MG/M3 RESPIRABLE DUST.
TYPICAL TLV: 10 MG/M3.
TOXICITY DATA:
SULFURIC ACID (CAS#7664-93-9):
UNR-MAN LDLO: 135 MG/KG
ORL-RAT LD50: 2140 MG/KG (25% SOLUTION)
IHL-MUS LC50: 320 MG/M3/2H
IHL-GPG LC50: 18 MG/M3.
| 12. ECOLOGICAL INFORMATION | |
THIS INFORMATION IS ONLY RELEVANT FOR DESTROYED BATTERIES AND REFER TO THE
COMPONENTS ONLY.
LEAD AND LEAD COMPOUNDS CAN BE DISSOLVED IN AN ACIDIC OR ALKALINE
ENVIRONMENT. CHEMICAL AND PHYSICAL TREATMENT IS REQUIRED FOR THE
ELIMINATION OF LEAD FROM WATER.
LEAD COMPOUNDS ARE VERY TOXIC TO AQUATIC ORGANISMS AND MAY CAUSE LONG
TERM-ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT (R50/53).
| 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
BATTERY ELECTROLYTE (ACID):
NEUTRALIZE AS ABOVE FOR A SPILL, COLLECT RESIDUE, AND PLACE IN A DRUM OR
SUITABLE CONTAINER. DISPOSE OF AS A HAZARDOUS WASTE. DISPOSE OF IN
ACCORDANCE WITH ALL APPLICABLE LOCAL AND NATIONAL REGULATIONS.
| 14. TRANSPORT INFORMATION | |
PROPER SHIPPING NAME AND IDENTIFICATION:
BATTERIES, WET, NONSPILLABLE, ELECTRIC STORAGE
IATA/ICAO: UNREGULATED, MEETS THE REQUIREMENTS OF SPECIAL PROVISION A67.
TRANSPORT ATTENTION:
BATTERIES MUST BE SECURELY PACKED TO PREVENT SHORT CIRCUITING.
| 15. REGULATORY INFORMATION | |
EU (EUROPEAN) REGULATIONS: REACH (EC) NO 1907/2006.
EUROPEAN COMMUNITIES (EC) HAZARD CLASSIFICATION ACCORDING TO DIRECTIVES
67/548/EEC AND 1999/45/EC.
R-PHRASES: 35, 36, 38
S-PHRASES: 1/2, 26, 30, 45
FOR DETAILED REGULATIONS, CONTACT THE APPROPRIATE AGENCY IN YOUR COUNTRY.
| 16. OTHER INFORMATION | |
FURTHER INFORMATION:
THIS MSDS HAS BEEN ELABORATED ACCORDING TO REACH REGULATION.
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
DEPARTMENT ISSUING MSDS:
NINGBO SHENGYANG POWER SUPPLY AND ELECTRIC APPLIANCE CO., LTD
ISSUE DATE: JANUARY 18, 2010
THIS MSDS SERVICE IS PROVIDED BY ZHEJIANG LANDER STANDARD TECHNOLOGY CO.,
LTD.
SIGNED FOR AND ON BEHALF OF LANDER TESTING LAB
WEIPING GE
CHEMISTRY LAB ENGINEER
DATE: JANUARY 22, 2010
REMARKS:
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP. THIS DATA SHEET
MAY ONLY BE REPRODUCED AND DISTRIBUTED IN FULL. IF YOU WANT TO SEARCH
THE REPORT ITEM, YOU CAN ENTER IN WWW.LTLAB.COM.CN THEN INPUT ID NUMBER.
ZHEJIANG LANDER STANDARD TECHNOLOGY CO., LTD.
ADD:
5F 182 GENSHAN WEST RD
HANGZHOU, ZHEJIANG 310004
CHINA
TEL: +(86) 571-86434444-1001
FAX: +(86) 571-87906666 28024444
FREE LINE: 800 801 1110
HTTP://WWW.LTLAB.COM.CN
E-MAIL: INFO@LTLAB.COM.CN
MSDS SHEET ON BATTERY
NINGBO SHENGYANG POWER SUPPLY & ELECTRIC APPLIANCE CO., LTD
LIAN SHAN TOWN
YU YAO CITY
ZHE JIANG
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: SEALED MAINTENANCE FREE LEAD ACID BATTERIES
DATE: 4/8/03
ISSUED BY: ENGINEERING
TELEPHONE NO: 0086-574-62057088
| HAZARDOUS COMPONENTS | |
COMPONENTS % WEIGHT TLV LD50 ORAL LC50 LC50
INHALATION CONTACT
LEAD (Pb, ABOUT 63% N/A (500) MG/KG N/A N/A
PbO2, PbSo)
SULFURIC ACID ABOUT 20% 1 MG/M3 (2.140) MG/KG N/A N/A
FIBERGLASS ABOUT 5% N/A N/A N/A N/A
SEPARATOR
ABS 750 ABOUT 12% N/A N/A N/A N/A
| PHYSICAL DATA | |
COMPONENTS DENSITY MELTING SOLUBILITY ODOR APPEARANCE
POINT (H2O)
LEAD 11.34 327.4 DEG. C NONE NONE SLIVER-GRAY
(BOILING) METAL
LEAD 6.2 1070 DEG. C 40 MG/L NONE WHITE POWDER
SULFATE (BOILING) (15 DEG. C)
LEAD 9.4 290 DEG. C NONE NONE BROWN POWDER
DIOXIDE (BOILING)
SULFURIC ABOUT ABOUT 100% ACIDIC CLEAR COLORLESS
ACID 1.3 114 DEG. C LIQUID
(BOILING)
FIBERGLASS N/A N/A SLIGHT TOXIC WHITE FIBROUS
SEP. GLASS
750 ABS N/A N/A NONE NO SOLID
ODOR
| FLAMMABILITY DATA | |
COMPONENTS FLASH POINT EXPLOSIVE LIMITS COMMENTS
LEAD NONE NONE
SULFURIC ACID NONE NONE
HYDROGEN N/A 4% - 74.2% SEALED BATTERIES CAN
EMIT HYDROGEN ONLY IF
OVER CHARGED (FLOAL
VOLTAGE >2.4 VPC)
FIBERGLASS SEP. N/A N/A TOXIC VAPORS MAY BE
RELEASED.
IN CASE OF FIRE:
WEAR SELF-CONTAINED
BREATHING APPARATUS.
750 ABS NONE N/A TEMPERATURES OVER
320 DEG. C (610 DEG. F)
MAY RELEASE COMBUSTIBLE
GASES.
IN CASE OF FIRE:
WEAR POSITIVE PRESSURE
SELF-CONTAINED BREATHING
APPARATUS.
| FIRST AID | |
SULFURIC ACID PRECAUTIONS:
SKIN CONTACT:
FLUSH WITH WATER, SEE PHYSICIAN IF CONTACT AREA IS LARGE OR IF BLISTERS
FORM.
EYE CONTACT:
CALL PHYSICIAN IMMEDIATELY AND FLUSH WITH WATER UNTIL PHYSICIAN ARRIVES.
INGESTION:
CALL PHYSICIAN. IF PATIENT IS CONSCIOUS, FLUSH MOUTH WITH WATER, HAVE THE
PATIENT DRINK MILK OR SODIUM BICARBONATE SOLUTION.
DO NOT GIVE ANYTHING TO AN UNCONSCIOUS PERSON.
| REACTIVITY DATA | |
COMPONENT: SULFURIC ACID
STABILITY: STABLE AT ALL TEMPERATURES
POLYMERIZATION: WILL NOT POLYMARIZE
INCOMPATIBILITY: REACTIVE METALS, STRONG BASSES, MOST ORGANIC COMPOUNDS
DECOMPOSITION PRODUCTS:
SULFURIC DIOXIDE, TRIOXIDE, HYDROGEN SULFIDE, HYDROGEN
CONDITIONS TO AVOID:
PROHIBIT SMOKING, SPARKS, ETC. FROM BATTERY CHARGING AREA. AVOID MIXING
ACID WITH OTHER CHEMICALS.