| Common Name: | DELO 400, HEAVY DUTY PREDILUTED 50/50 COOLANT/ANTIFREEZE PHOSPHATE FREE (CONTAIN |
| Manufacturer: | CHEVRON TEXACO |
| SDS Revision Date: | 6/22/2004 |
| SDS Format: | ANSI-OSHA |
| Item Number(s): | 20UU43, 20VP10 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
CHEVRON
B & M ENTERPRISES
2002 EAST LOCUST COURT
ONTARIO, CA 91761
| SECTION 1 PRODUCT AND COMPANY IDENTIFICATION |  |
CHEVRON DELO(R*) 400
PRODUCT NUMBER(S):
CPS235101, CPS235109, CPS235117, CPS235118, CPS235119, CPS235120, CPS235200
SYNONYMS:
CHEVRON DELO(R*) 400 MULTIGRADE SAE 15W-40, CHEVRON DELO(R*) 400 SAE 10W,
CHEVRON DELO(R*) 400 SAE 10W-30, CHEVRON DELO(R*) 400 SAE 20, CHEVRON
DELO(R*) 400 SAE 30, CHEVRON DELO(R*) 400 SAE 40, CHEVRON DELO(R*) 400 SAE
50
COMPANY IDENTIFICATION:
CHEVRONTEXACO GLOBAL LUBRICANTS
6001 BOLLINGER CANYON RD.
SAN RAMON, CA 94583
UNITED STATES OF AMERICA
WWW.CHEVRON-LUBRICANTS.COM
TRANSPORTATION EMERGENCY RESPONSE:
CHEMTREC: (800) 424-9300 OR (703) 527-3887
HEALTH EMERGENCY:
CHEVRONTEXACO EMERGENCY INFORMATION CENTER:
LOCATED IN THE USA. INTERNATIONAL COLLECT CALLS ACCEPTED.
(800) 231-0623 OR (510) 231-0623
PRODUCT INFORMATION:
EMAIL: LUBEMSDS@CHEVRONTEXACO.COM
PRODUCT INFORMATION: (800) LUBE TEK
MSDS REQUESTS: (800) 414-6737
| SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS NUMBER AMOUNT
HIGHLY REFINED MINERAL OIL (C15 - C50) MIXTURE 70 - 95% WEIGHT
ZINC ALKYL DITHIOPHOSPHATE 68649-42-3 1 - 5% WEIGHT
| SECTION 3 HAZARDS IDENTIFICATION | |
IMMEDIATE HEALTH EFFECTS:
EYE: NOT EXPECTED TO CAUSE PROLONGED OR SIGNIFICANT EYE IRRITATION.
SKIN:
CONTACT WITH THE SKIN IS NOT EXPECTED TO CAUSE PROLONGED OR SIGNIFICANT
IRRITATION. NOT EXPECTED TO BE HARMFUL TO INTERNAL ORGANS IF ABSORBED
THROUGH THE SKIN.
INGESTION: NOT EXPECTED TO BE HARMFUL IF SWALLOWED.
INHALATION:
NOT EXPECTED TO BE HARMFUL IF INHALED. CONTAINS A PETROLEUM-BASED MINERAL
OIL. MAY CAUSE RESPIRATORY IRRITATION OR OTHER PULMONARY EFFECTS FOLLOWING
PROLONGED OR REPEATED INHALATION OF OIL MIST AT AIRBORNE LEVELS ABOVE THE
RECOMMENDED MINERAL OIL MIST EXPOSURE LIMIT. SYMPTOMS OF RESPIRATORY
IRRITATION MAY INCLUDE COUGHING AND DIFFICULTY BREATHING.
| SECTION 4 FIRST AID MEASURES | |
EYE:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. AS A PRECAUTION, REMOVE
CONTACT LENSES, IF WORN, AND FLUSH EYES WITH WATER.
SKIN:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. AS A PRECAUTION, REMOVE
CLOTHING AND SHOES IF CONTAMINATED. TO REMOVE THE MATERIAL FROM SKIN,
USE SOAP AND WATER. DISCARD CONTAMINATED CLOTHING AND SHOES OR THOROUGHLY
CLEAN BEFORE REUSE.
INGESTION:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. DO NOT INDUCE VOMITING.
AS A PRECAUTION, GET MEDICAL ADVICE.
INHALATION:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. IF EXPOSED TO EXCESSIVE LEVELS
OF MATERIAL IN THE AIR, MOVE THE EXPOSED PERSON TO FRESH AIR. GET MEDICAL
ATTENTION IF COUGHING OR RESPIRATORY DISCOMFORT OCCURS.
| SECTION 5 FIRE FIGHTING MEASURES | |
FIRE CLASSIFICATION:
OSHA CLASSIFICATION (29 CFR 1910.1200):
NOT CLASSIFIED BY OSHA AS FLAMMABLE OR COMBUSTIBLE.
NFPA RATINGS:
HEALTH 0
FLAMMABILITY 1
REACTIVITY 0
FLAMMABLE PROPERTIES:
FLASHPOINT (CLEVELAND OPEN CUP): 200 DEG. C (392 DEG. F) (MIN)
AUTOIGNITION: NO DATA AVAILABLE
FLAMMABILITY (EXPLOSIVE) LIMITS (% BY VOLUME IN AIR):
LOWER: NOT APPLICABLE
UPPER: NOT APPLICABLE
EXTINGUISHING MEDIA:
USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE (CO2) TO EXTINGUISH
FLAMES.
PROTECTION OF FIRE FIGHTERS:
FIRE FIGHTING INSTRUCTIONS:
THIS MATERIAL WILL BURN ALTHOUGH IT IS NOT EASILY IGNITED. FOR FIRES
INVOLVING THIS MATERIAL, DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE SPACE
WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING SELF-CONTAINED BREATHING
APPARATUS.
COMBUSTION PRODUCTS:
HIGHLY DEPENDENT ON COMBUSTION CONDITIONS. A COMPLEX MIXTURE OF AIRBORNE
SOLIDS, LIQUIDS, AND GASES INCLUDING CARBON MONOXIDE, CARBON DIOXIDE, AND
UNIDENTIFIED ORGANIC COMPOUNDS WILL BE EVOLVED WHEN THIS MATERIAL UNDERGOES
COMBUSTION. COMBUSTION MAY FORM OXIDES OF: NITROGEN, PHOSPHORUS, SULFUR.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
PROTECTIVE MEASURES:
ELIMINATE ALL SOURCES OF IGNITION IN VICINITY OF SPILLED MATERIAL.
SPILL MANAGEMENT:
STOP THE SOURCE OF THE RELEASE IF YOU CAN DO IT WITHOUT RISK. CONTAIN
RELEASE TO PREVENT FURTHER CONTAMINATION OF SOIL, SURFACE WATER OR
GROUNDWATER. CLEAN UP SPILL AS SOON AS POSSIBLE, OBSERVING PRECAUTIONS IN
EXPOSURE CONTROLS/PERSONAL PROTECTION. USE APPROPRIATE TECHNIQUES SUCH AS
APPLYING NON-COMBUSTIBLE ABSORBENT MATERIALS OR PUMPING. WHERE FEASIBLE AND
APPROPRIATE, REMOVE CONTAMINATED SOIL. PLACE CONTAMINATED MATERIALS IN
DISPOSABLE CONTAINERS AND DISPOSE OF IN A MANNER CONSISTENT WITH APPLICABLE
REGULATIONS.
REPORTING:
REPORT SPILLS TO LOCAL AUTHORITIES AND/OR THE U.S. COAST GUARD'S NATIONAL
RESPONSE CENTER AT (800) 424-8802 AS APPROPRIATE OR REQUIRED.
| SECTION 7 HANDLING AND STORAGE | |
PRECAUTIONARY MEASURES: KEEP OUT OF THE REACH OF CHILDREN.
GENERAL HANDLING INFORMATION:
AVOID CONTAMINATING SOIL OR RELEASING THIS MATERIAL INTO SEWAGE AND
DRAINAGE SYSTEMS AND BODIES OF WATER.
STATIC HAZARD:
ELECTROSTATIC CHARGE MAY ACCUMULATE AND CREATE A HAZARDOUS CONDITION WHEN
HANDLING THIS MATERIAL. TO MINIMIZE THIS HAZARD, BONDING AND GROUNDING MAY
BE NECESSARY BUT MAY NOT, BY THEMSELVES, BE SUFFICIENT. REVIEW ALL
OPERATIONS WHICH HAVE THE POTENTIAL OF GENERATING AND ACCUMULATING AN
ELECTROSTATIC CHARGE AND/OR A FLAMMABLE ATMOSPHERE (INCLUDING TANK AND
CONTAINER FILLING, SPLASH FILLING, TANK CLEANING, SAMPLING, GAUGING, SWITCH
LOADING, FILTERING, MIXING, AGITATION, AND VACUUM TRUCK OPERATIONS) AND USE
APPROPRIATE MITIGATING PROCEDURES. FOR MORE INFORMATION, REFER TO OSHA
STANDARD 29 CFR 1910.106, 'FLAMMABLE AND COMBUSTIBLE LIQUIDS', NATIONAL
FIRE PROTECTION ASSOCIATION (NFPA 77, 'RECOMMENDED PRACTICE ON STATIC
ELECTRICITY', AND/OR THE AMERICAN PETROLEUM INSTITUTE (API) RECOMMENDED
PRACTICE 2003, 'PROTECTION AGAINST IGNITIONS ARISING OUT OF STATIC,
LIGHTNING, AND STRAY CURRENTS'.
CONTAINER WARNINGS:
CONTAINER IS NOT DESIGNED TO CONTAIN PRESSURE. DO NOT USE PRESSURE TO EMPTY
CONTAINER OR IT MAY RUPTURE WITH EXPLOSIVE FORCE. EMPTY CONTAINERS RETAIN
PRODUCT RESIDUE (SOLID, LIQUID, AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. EMPTY CONTAINERS
SHOULD BE COMPLETELY DRAINED, PROPERLY CLOSED, AND PROMPTLY RETURNED TO A
DRUM RECONDITIONER OR DISPOSED OF PROPERLY.
| SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
GENERAL CONSIDERATIONS:
SPECIAL NOTE:
DO NOT USE IN BREATHING AIR APPARATUS OR MEDICAL EQUIPMENT.
CONSIDER THE POTENTIAL HAZARDS OF THIS MATERIAL (SEE SECTION 3),
APPLICABLE EXPOSURE LIMITS, JOB ACTIVITIES, AND OTHER SUBSTANCES IN THE
WORK PLACE WHEN DESIGNING ENGINEERING CONTROLS AND SELECTING PERSONAL
PROTECTIVE EQUIPMENT, IF ENGINEERING CONTROLS OR WORK PRACTICES ARE NOT
ADEQUATE TO PREVENT EXPOSURE TO HARMFUL LEVELS OF THIS MATERIAL, THE
PERSONAL PROTECTIVE EQUIPMENT LISTED BELOW IS RECOMMENDED. THE USER SHOULD
READ AND UNDERSTAND ALL INSTRUCTIONS AND LIMITATIONS SUPPLIED WITH THE
EQUIPMENT SINCE PROTECTION IS USUALLY PROVIDED FOR A LIMITED TIME OR UNDER
CERTAIN CIRCUMSTANCES.
ENGINEERING CONTROLS: USE IN A WELL-VENTILATED AREA.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
NO SPECIAL EYE PROTECTION IS NORMALLY REQUIRED. WHERE SPLASHING IS
POSSIBLE, WEAR SAFETY GLASSES WITH SIDE SHIELDS AS A GOOD SAFETY PRACTICE.
SKIN PROTECTION:
NO SPECIAL PROTECTIVE CLOTHING IS NORMALLY REQUIRED. WHERE SPLASHING IS
POSSIBLE, SELECT PROTECTIVE CLOTHING DEPENDING ON OPERATIONS CONDUCTED,
PHYSICAL REQUIREMENTS AND OTHER SUBSTANCES IN THE WORKPLACE.
SUGGESTED MATERIALS FOR PROTECTIVE GLOVES INCLUDE:
4H (PE/EVAL), NITRILE RUBBER, SILVER SHIELD, VITON.
RESPIRATORY PROTECTION:
NO RESPIRATORY PROTECTION IS NORMALLY REQUIRED.
IF USER OPERATIONS GENERATE AN OIL MIST, DETERMINE IF AIRBORNE
CONCENTRATIONS ARE BELOW THE OCCUPATIONAL EXPOSURE LIMIT FOR MINERAL OIL
MIST, IF NOT, WEAR AN APPROVED RESPIRATOR THAT PROVIDES ADEQUATE PROTECTION
FROM THE MEASURED CONCENTRATIONS OF THIS MATERIAL. FOR AIR-PURIFYING
RESPIRATORS USE A PARTICULATE CARTRIDGE.
USE A POSITIVE PRESSURE AIR-SUPPLYING RESPIRATOR IN CIRCUMSTANCES WHERE
AIR-PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION.
OCCUPATIONAL EXPOSURE LIMITS:
COMPONENT AGENCY TWA STEL CEILING NOTATION
HIGHLY REFINED MINERAL OIL ACGIH 5 MG/M3 10 MG/M3
(C15 - C50)
HIGHLY REFINED MINERAL OIL OSHA Z-1 5 MG/M3
(C15 - C50)
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
ATTENTION:
THE DATA BELOW ARE TYPICAL VALUES AND DO NOT CONSTITUTE A SPECIFICATION.
COLOR: BROWN
PHYSICAL STATE: LIQUID
ODOR: PETROLEUM ODOR
PH: NOT APPLICABLE
VAPOR PRESSURE: <0.01 MMHg @ 37.8 DEG. C (100 DEG. F)
VAPOR DENSITY (AIR = 1): >1
BOILING POINT: >315.6 DEG. C (600 DEG. F)
SOLUBILITY: SOLUBLE IN HYDROCARBONS; INSOLUBLE IN WATER
FREEZING POINT: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
SPECIFIC GRAVITY:
0.87 - 0.9 @ 15.6 DEG. C (60.1 DEG. F) / 15.6 DEG. C (60.1 DEG. F)
VOLATILE ORGANIC:
COMPOUNDS (VOC): 1.1% WEIGHT
VISCOSITY: 6.6 CST - 18 CST @ 100 DEG. C (212 DEG. F) (MIN)
| SECTION 10 STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
THIS MATERIAL IS CONSIDERED STABLE UNDER NORMAL AMBIENT AND ANTICIPATED
STORAGE AND HANDLING CONDITIONS OF TEMPERATURE AND PRESSURE.
INCOMPATIBILITY WITH OTHER MATERIALS:
MAY REACT WITH STRONG ACIDS OR STRONG OXIDIZING AGENTS, SUCH AS CHLORATES,
NITRATES, PEROXIDES, ETC.
HAZARDOUS DECOMPOSITION PRODUCTS: HYDROGEN SULFIDE (ELEVATED TEMPERATURES)
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
| SECTION 11 TOXICOLOGICAL INFORMATION | |
IMMEDIATE HEALTH EFFECTS:
EYE IRRITATION:
THE EYE IRRITATION HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
SKIN IRRITATION:
THE SKIN IRRITATION HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
SKIN SENSITIZATION: NO PRODUCT TOXICOLOGY DATA AVAILABLE.
ACUTE DERMAL TOXICITY:
THE ACUTE DERMAL TOXICITY HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
ACUTE ORAL TOXICITY:
THE ACUTE ORAL TOXICITY HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
ACUTE INHALATION TOXICITY:
THE ACUTE INHALATION TOXICITY HAZARD IS BASED ON EVALUATION OF DATA FOR
SIMILAR MATERIALS OR PRODUCT COMPONENTS.
ADDITIONAL TOXICOLOGY INFORMATION:
THIS PRODUCT CONTAINS PETROLEUM BASE OILS WHICH MAY BE REFINED BY VARIOUS
PROCESSES INCLUDING SEVERE SOLVENT EXTRACTION, SEVERE HYDROCRACKING, OR
SEVERE HYDROTREATING. NONE OF THE OILS REQUIRES A CANCER WARNING UNDER THE
OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). THESE OILS HAVE NOT
BEEN LISTED IN THE NATIONAL TOXICOLOGY PROGRAM (NTP) ANNUAL REPORT NOR HAVE
THEY BEEN CLASSIFIED BY THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
(IARC) AS; CARCINOGENIC TO HUMANS (GROUP 1), PROBABLY CARCINOGENIC TO
HUMANS (GROUP 2A), OR POSSIBLY CARCINOGENIC TO HUMANS (GROUP 2B). THESE
OILS HAVE NOT BEEN CLASSIFIED BY THE AMERICAN CONFERENCE OF GOVERNMENTAL
INDUSTRIAL HYGIENISTS (ACGIH) AS:
CONFIRMED HUMAN CARCINOGEN (A1), SUSPECTED HUMAN CARCINOGEN (A2), OR
CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS (A3).
DURING USE IN ENGINES, CONTAMINATION OF OIL WITH LOW LEVELS OF
CANCER-CAUSING COMBUSTION PRODUCTS OCCURS. USED MOTOR OILS HAVE BEEN
SHOWN TO CAUSE SKIN CANCER IN MICE FOLLOWING REPEATED APPLICATION AND
CONTINUOUS EXPOSURE. BRIEF OR INTERMITTENT SKIN CONTACT WITH USED MOTOR
OIL IS NOT EXPECTED TO HAVE SERIOUS EFFECTS IN HUMANS IF THE OIL IS
THOROUGHLY REMOVED BY WASHING WITH SOAP AND WATER.
| SECTION 12 ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE TOXICITY OF THIS MATERIAL TO AQUATIC ORGANISMS HAS NOT BEEN EVALUATED.
CONSEQUENTLY, THIS MATERIAL SHOULD BE KEPT OUT OF SEWAGE AND DRAINAGE
SYSTEMS AND ALL BODIES OF WATER.
ENVIRONMENTAL FATE:
THIS MATERIAL IS NOT EXPECTED TO BE READILY BIODEGRADABLE.
| SECTION 13 DISPOSAL CONSIDERATIONS | |
USE MATERIAL FOR ITS INTENDED PURPOSE OR RECYCLE IF POSSIBLE. OIL
COLLECTION SERVICES ARE AVAILABLE FOR USED OIL RECYCLING OR DISPOSAL.
PLACE CONTAMINATED MATERIALS IN CONTAINERS AND DISPOSE OF IN A MANNER
CONSISTENT WITH APPLICABLE REGULATIONS. CONTACT YOUR SALES REPRESENTATIVE
OR LOCAL ENVIRONMENTAL OR HEALTH AUTHORITIES FOR APPROVED DISPOSAL OR
RECYCLING METHODS.
| SECTION 14 TRANSPORT INFORMATION | |
THE DESCRIPTION SHOWN MAY NOT APPLY TO ALL SHIPPING SITUATIONS. CONSULT
49CFR, OR APPROPRIATE DANGEROUS GOODS REGULATIONS, FOR ADDITIONAL
DESCRIPTION REQUIREMENTS (E.G., TECHNICAL NAME) AND MODE-SPECIFIC OR
QUANTITY-SPECIFIC SHIPPING REQUIREMENTS.
DOT SHIPPING DESCRIPTION: PETROLEUM LUBRICATING OIL
IMO/IMDG SHIPPING DESCRIPTION: PETROLEUM LUBRICATING OIL
| SECTION 15 REGULATORY INFORMATION | |
EPCRA 311/312 CATEGORIES:
1. IMMEDIATE (ACUTE) HEALTH EFFECTS: NO
2. DELAYED (CHRONIC) HEALTH EFFECTS: NO
3. FIRE HAZARD: NO
4. SUDDEN RELEASE OF PRESSURE HAZARD: NO
5. REACTIVITY HAZARD: NO
REGULATORY LISTS SEARCHED:
01-1=IARC GROUP 1
01-2A=IARC GROUP 2A
01-2B=IARC GROUP 2B
02=NTP CARCINOGEN
03=EPCRA 313
04=CA PROPOSITION 65
05=MA RTK
06=NJ RTK
07=PA RTK
THE FOLLOWING COMPONENTS OF THIS MATERIAL ARE FOUND ON THE REGULATORY
LISTS INDICATED.
ZINC ALKYL DITHLOPHOSPHATE 03, 06
CHEMICAL INVENTORIES:
ALL COMPONENTS COMPLY WITH THE FOLLOWING CHEMICAL INVENTORY REQUIREMENTS:
ENCS (JAPAN), IECSC (CHINA), PICCS (PHILIPPINES), TSCA (UNITED STATES).
ONE OR MORE COMPONENTS HAS BEEN NOTIFIED BUT MAY NOT BE LISTED IN THE
FOLLOWING CHEMICAL INVENTORIES:
DSL (CANADA). SECONDARY NOTIFICATION BY THE IMPORTER MAY BE REQUIRED.
ONE OR MORE COMPONENTS IS LISTED ON ELINCS (EUROPEAN UNION). SECONDARY
NOTIFICATION BY THE IMPORTER MAY BE REQUIRED.
ONE OR MORE COMPONENTS DOES NOT COMPLY WITH THE FOLLOWING CHEMICAL
INVENTORY REQUIREMENTS: AICS (AUSTRALIA), KECI (KOREA).
NEW JERSEY RTK CLASSIFICATION:
UNDER THE NEW JERSEY RIGHT-TO-KNOW ACT L. 1983 CHAPTER 315 N.J.S.A.
34:5A-1 ET. SEQ., THE PRODUCT IS TO BE IDENTIFIED AS FOLLOWS:
PETROLEUM OIL (MOTOR OIL)
WHMIS CLASSIFICATION:
THIS PRODUCT IS NOT CONSIDERED A CONTROLLED PRODUCT ACCORDING TO THE
CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS.
| SECTION 16 OTHER INFORMATION | |
NFPA RATINGS:
HEALTH 0
FLAMMABILITY 1
REACTIVITY 0
HMIS RATINGS:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
0-LEAST
1-SLIGHT
2-MODERATE
3-HIGH
4-EXTREME
PPE - PERSONAL PROTECTION EQUIPMENT INDEX RECOMMENDATION
* - CHRONIC EFFECT INDICATOR.
THESE VALUES ARE OBTAINED USING THE GUIDELINES OR PUBLISHED EVALUATIONS
PREPARED BY THE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) OR THE NATIONAL
PAINT AND COATING ASSOCIATION (FOR HMIS RATINGS).
REVISION STATEMENT:
THIS REVISION UPDATES THE FOLLOWING SECTIONS OF THIS MATERIAL SAFETY DATA
SHEET: 1-16
REVISION DATE: 06/22/2004
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - THRESHOLD LIMIT VALUE
TWA - TIME WEIGHTED AVERAGE
STEL - SHORT-TERM EXPOSURE LIMIT
PEL - PERMISSIBLE EXPOSURE LIMIT
CAS - CHEMICAL ABSTRACT SERVICE NUMBER
ACGIH - AMERICAN CONFERENCE OF GOVERNMENT INDUSTRIAL HYGIENISTS
IMO/IMDG - INTERNATIONAL MARITIME DANGEROUS GOODS CODE
API - AMERICAN PETROLEUM INSTITUTE
MSDS - MATERIAL SAFETY DATA SHEET
CVX - CHEVRON TEXACO
NFPA - NATIONAL FIRE PROTECTION ASSOCIATION (USA)
DOT - DEPARTMENT OF TRANSPORTATION (USA)
NTP - NATIONAL TOXICOLOGY PROGRAM (USA)
IARC - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
OSHA - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PREPARED ACCORDING TO THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND THE ANSI MSDS STANDARD (Z400.1) BY THE CHEVRON TEXACO
ENERGY RESEARCH & TECHNOLOGY COMPANY, 100 CHEVRON WAY, RICHMOND, CALIFORNIA
94802.
THE ABOVE INFORMATION IS BASED ON THE DATA OF WHICH WE ARE AWARE AND IS
BELIEVED TO BE CORRECT AS OF THE DATE HEREOF. SINCE THIS INFORMATION MAY
BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL AND WITH WHICH WE MAY BE
UNFAMILIAR AND SINCE DATA MADE AVAILABLE SUBSEQUENT TO THE DATE HEREOF
MAY SUGGEST MODIFICATIONS OF THE INFORMATION, WE DO NOT ASSUME ANY
RESPONSIBILITY FOR THE RESULTS OF ITS USE. THIS INFORMATION IS FURNISHED
UPON CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS OWN
DETERMINATION OF THE SUITABILITY OF THE MATERIAL FOR HIS PARTICULAR
PURPOSE.
REVISION NUMBER: 7
MSDS: 6711
MATERIAL SAFETY DATA SHEET
| SECTION 1 PRODUCT AND COMPANY IDENTIFICATION | |
CHEVRON HEAVY DUTY PREDILUTED 50/50 COOLANT/ANTIFREEZE PHOSPHATE FREE
(CONTAINS BITTERANT)
PRODUCT USE: ANTIFREEZE/COOLANT
PRODUCT NUMBER(S): CPS227045
COMPANY IDENTIFICATION:
CHEVRON PRODUCTS COMPANY
A DIVISION OF CHEVRON U.S.A. INC.
6001 BOLLINGER CANYON RD.
SAN RAMON, CA 94583
UNITED STATES OF AMERICA
WWW.CHEVRONLUBRICANTS.COM
TRANSPORTATION EMERGENCY RESPONSE:
CHEMTREC: (800) 424-9300 OR (703) 527-3887
HEALTH EMERGENCY:
CHEVRON EMERGENCY INFORMATION CENTER:
LOCATED IN THE USA. INTERNATIONAL COLLECT CALLS ACCEPTED.
(800) 231-0623 OR (510) 231-0623
PRODUCT INFORMATION:
EMAIL: LUBEMSDS@CHEVRON.COM
PRODUCT INFORMATION: (800) LUBE TEK
MSDS REQUESTS: (800) 414-6737
| SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS NUMBER AMOUNT
ETHYLENE GLYCOL 107-21-1 40 - 55% WEIGHT
DIETHYLENE GLYCOL 111-46-6 1 - 5% WEIGHT
| SECTION 3 HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
HARMFUL OR FATAL IF SWALLOWED
POSSIBLE BIRTH DEFECT HAZARD - CONTAINS MATERIAL THAT MAY CAUSE BIRTH
DEFECTS BASED ON ANIMAL DATA
CAUSES DAMAGE TO: KIDNEY
IMMEDIATE HEALTH EFFECTS:
EYE: NOT EXPECTED TO CAUSE PROLONGED OR SIGNIFICANT EYE IRRITATION.
SKIN:
CONTACT WITH THE SKIN IS NOT EXPECTED TO CAUSE PROLONGED OR SIGNIFICANT
IRRITATION. CONTACT WITH THE SKIN IS NOT EXPECTED TO CAUSE AN ALLERGIC SKIN
RESPONSE. NOT EXPECTED TO BE HARMFUL TO INTERNAL ORGANS IF ABSORBED THROUGH
THE SKIN.
INGESTION: TOXIC; MAY BE HARMFUL OR FATAL IF SWALLOWED.
INHALATION:
THE VAPOR OR FUMES FROM THIS MATERIAL MAY CAUSE RESPIRATORY IRRITATION.
SYMPTOMS OF RESPIRATORY IRRITATION MAY INCLUDE COUGHING AND DIFFICULTY
BREATHING. BREATHING THIS MATERIAL AT CONCENTRATIONS ABOVE THE RECOMMENDED
EXPOSURE LIMITS MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. CENTRAL NERVOUS
SYSTEM EFFECTS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA, VOMITING, WEAKNESS,
LOSS OF COORDINATION, BLURRED VISION, DROWSINESS, CONFUSION, OR
DISORIENTATION. AT EXTREME EXPOSURES, CENTRAL NERVOUS SYSTEM EFFECTS MAY
INCLUDE RESPIRATORY DEPRESSION, TREMORS OR CONVULSIONS, LOSS OF
CONSCIOUSNESS, COMA OR DEATH.
DELAYED OR OTHER HEALTH EFFECTS:
REPRODUCTION AND BIRTH DEFECTS:
CONTAINS MATERIAL THAT MAY CAUSE BIRTH DEFECTS BASED ON ANIMAL DATA.
TARGET ORGANS:
CONTAINS MATERIAL THAT CAUSES DAMAGE TO THE FOLLOWING ORGAN(S) IF
SWALLOWED: KIDNEY
SEE SECTION 11 FOR ADDITIONAL INFORMATION. RISK DEPENDS ON DURATION AND
LEVEL OF EXPOSURE.
| SECTION 4 FIRST AID MEASURES | |
EYE:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. AS A PRECAUTION, REMOVE
CONTACT LENSES, IF WORN, AND FLUSH EYES WITH WATER.
SKIN:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. AS A PRECAUTION, REMOVE
CLOTHING AND SHOES IF CONTAMINATED. TO REMOVE THE MATERIAL FROM SKIN, USE
SOAP AND WATER. DISCARD CONTAMINATED CLOTHING AND SHOES OR THOROUGHLY CLEAN
BEFORE REUSE.
INGESTION:
IF SWALLOWED, GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
INHALATION:
MOVE THE EXPOSED PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION
IF BREATHING DIFFICULTIES CONTINUE. MOVE THE EXPOSED PERSON TO FRESH AIR.
IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. GET MEDICAL ATTENTION IF BREATHING DIFFICULTIES CONTINUE OR IF
ANY OTHER SYMPTOMS DEVELOP.
| SECTION 5 FIRE FIGHTING MEASURES | |
FIRE CLASSIFICATION:
OSHA CLASSIFICATION (29 CFR 1910.1200):
NOT CLASSIFIED BY OSHA AS FLAMMABLE OR COMBUSTIBLE.
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 0
REACTIVITY 0
FLAMMABLE PROPERTIES:
FLASHPOINT: NOT APPLICABLE
AUTOIGNITION: NO DATA AVAILABLE
FLAMMABILITY (EXPLOSIVE) LIMITS (% BY VOLUME IN AIR):
LOWER: NOT APPLICABLE
UPPER: NOT APPLICABLE
EXTINGUISHING MEDIA:
DRY CHEMICAL, CO2, AFFF FOAM OR ALCOHOL RESISTANT FOAM.
PROTECTION OF FIRE FIGHTERS:
FIRE FIGHTING INSTRUCTIONS: THIS MATERIAL WILL NOT BURN.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
SPILL MANAGEMENT:
STOP THE SOURCE OF THE RELEASE IF YOU CAN DO IT WITHOUT RISK. CONTAIN
RELEASE TO PREVENT FURTHER CONTAMINATION OF SOIL, SURFACE WATER OR
GROUNDWATER. CLEAN UP SPILL AS SOON AS POSSIBLE, OBSERVING PRECAUTIONS IN
EXPOSURE CONTROLS/PERSONAL PROTECTION. USE APPROPRIATE TECHNIQUES SUCH AS
APPLYING NON-COMBUSTIBLE ABSORBENT MATERIALS OR PUMPING. WHERE FEASIBLE AND
APPROPRIATE, REMOVE CONTAMINATED SOIL. PLACE CONTAMINATED MATERIALS IN
DISPOSABLE CONTAINERS AND DISPOSE OF IN A MANNER CONSISTENT WITH APPLICABLE
REGULATIONS.
REPORTING:
REPORT SPILLS TO LOCAL AUTHORITIES AND/OR THE U.S. COAST GUARD'S NATIONAL
RESPONSE CENTER AT (800) 424-8802 AS APPROPRIATE OR REQUIRED.
| SECTION 7 HANDLING AND STORAGE | |
PRECAUTIONARY MEASURES:
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT TASTE OR SWALLOW.
DO NOT BREATHE VAPOR OR FUMES. WASH THOROUGHLY AFTER HANDLING.
GENERAL HANDLING INFORMATION:
DO NOT TASTE OR SWALLOW ANTIFREEZE OR SOLUTION. KEEP OUT OF THE REACH OF
CHILDREN AND ANIMALS.
GENERAL STORAGE INFORMATION: DO NOT STORE IN OPEN OR UNLABELED CONTAINERS.
CONTAINER WARNINGS:
CONTAINER IS NOT DESIGNED TO CONTAIN PRESSURE. DO NOT USE PRESSURE TO EMPTY
CONTAINER OR IT MAY RUPTURE WITH EXPLOSIVE FORCE. EMPTY CONTAINERS RETAIN
PRODUCT RESIDUE (SOLID, LIQUID, AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES
OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. EMPTY CONTAINERS
SHOULD BE COMPLETELY DRAINED, PROPERLY CLOSED, AND PROMPTLY RETURNED TO A
DRUM RECONDITIONER OR DISPOSED OF PROPERLY.
| SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
GENERAL CONSIDERATIONS:
CONSIDER THE POTENTIAL HAZARDS OF THIS MATERIAL (SEE SECTION 3), APPLICABLE
EXPOSURE LIMITS, JOB ACTIVITIES, AND OTHER SUBSTANCES IN THE WORK PLACE
WHEN DESIGNING ENGINEERING CONTROLS AND SELECTING PERSONAL PROTECTIVE
EQUIPMENT. IF ENGINEERING CONTROLS OR WORK PRACTICES ARE NOT ADEQUATE TO
PREVENT EXPOSURE TO HARMFUL LEVELS OF THIS MATERIAL, THE PERSONAL
PROTECTIVE EQUIPMENT LISTED BELOW IS RECOMMENDED. THE USER SHOULD READ
AND UNDERSTAND ALL INSTRUCTIONS AND LIMITATIONS SUPPLIED WITH THE EQUIPMENT
SINCE PROTECTION IS USUALLY PROVIDED FOR A LIMITED TIME OR UNDER CERTAIN
CIRCUMSTANCES.
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW THE RECOMMENDED EXPOSURE LIMITS.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
NO SPECIAL EYE PROTECTION IS NORMALLY REQUIRED. WHERE SPLASHING IS
POSSIBLE, WEAR SAFETY GLASSES WITH SIDE SHIELDS AS A GOOD SAFETY PRACTICE.
SKIN PROTECTION:
NO SPECIAL PROTECTIVE CLOTHING IS NORMALLY REQUIRED. WHERE SPLASHING IS
POSSIBLE, SELECT PROTECTIVE CLOTHING DEPENDING ON OPERATIONS CONDUCTED,
PHYSICAL REQUIREMENTS AND OTHER SUBSTANCES IN THE WORKPLACE.
SUGGESTED MATERIALS FOR PROTECTIVE GLOVES INCLUDE:
NATURAL RUBBER, NEOPRENE, NITRILE RUBBER, POLYVINYL CHLORIDE
(PVC OR VINYL).
RESPIRATORY PROTECTION:
DETERMINE IF AIRBORNE CONCENTRATIONS ARE BELOW THE RECOMMENDED
OCCUPATIONAL EXPOSURE LIMITS FOR JURISDICTION OF USE. IF AIRBORNE
CONCENTRATIONS ARE ABOVE THE ACCEPTABLE LIMITS, WEAR AN APPROVED
RESPIRATOR THAT PROVIDES ADEQUATE PROTECTION FROM THIS MATERIAL, SUCH AS:
AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS, DUSTS AND MISTS.
USE A POSITIVE PRESSURE AIR-SUPPLYING RESPIRATOR IN CIRCUMSTANCES WHERE
AIR-PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION.
OCCUPATIONAL EXPOSURE LIMITS:
COMPONENT AGENCY TWA STEL CEILING NOTATION
ETHYLENE GLYCOL ACGIH 100 MG/M3
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
ATTENTION:
THE DATA BELOW ARE TYPICAL VALUES AND DO NOT CONSTITUTE A SPECIFICATION.
COLOR: PURPLE
PHYSICAL STATE: LIQUID
ODOR: FAINT OR MILD
PH: 10 - 11
VAPOR PRESSURE: <0.1 MMHg @ 20 DEG. C (68 DEG. F)
VAPOR DENSITY (AIR = 1): 2.1 (TYPICAL)
BOILING POINT: 107.8 DEG. C (226 DEG. F)
SOLUBILITY: MISCIBLE
FREEZING POINT: -36.7 DEG. C (-34.1 DEG. F)
SPECIFIC GRAVITY:
1.08 @ 15.6 DEG. C (60.1 DEG. F) / 15.6 DEG. C (60.1 DEG. F)
VISCOSITY: NO DATA AVAILABLE
| SECTION 10 STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
THIS MATERIAL IS CONSIDERED STABLE UNDER NORMAL AMBIENT AND ANTICIPATED
STORAGE AND HANDLING CONDITIONS OF TEMPERATURE AND PRESSURE.
HAZARDOUS DECOMPOSITION PRODUCTS:
KETONES (ELEVATED TEMPERATURES), ALDEHYDES (ELEVATED TEMPERATURES)
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
| SECTION 11 TOXICOLOGICAL INFORMATION | |
IMMEDIATE HEALTH EFFECTS:
EYE IRRITATION:
THE EYE IRRITATION HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
SKIN IRRITATION:
THE SKIN IRRITATION HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
SKIN SENSITIZATION:
THE SKIN SENSITIZATION HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS. NO PRODUCT TOXICOLOGY DATA AVAILABLE.
ACUTE DERMAL TOXICITY:
THE ACUTE DERMAL TOXICITY HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
ACUTE ORAL TOXICITY:
THE ACUTE ORAL TOXICITY HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
ACUTE INHALATION TOXICITY:
THE ACUTE INHALATION TOXICITY HAZARD IS BASED ON EVALUATION OF DATA FOR
SIMILAR MATERIALS OR PRODUCT COMPONENTS.
ADDITIONAL TOXICOLOGY INFORMATION:
THIS PRODUCT CONTAINS DIETHYLENE GLYCOL (DEG). THE ESTIMATED ORAL LETHAL
DOSE IS ABOUT 50 CC (1.6 OZ) FOR AN ADULT HUMAN. DEG HAS CAUSED THE
FOLLOWING EFFECTS IN LABORATORY ANIMALS: LIVER ABNORMALITIES, KIDNEY DAMAGE
AND BLOOD ABNORMALITIES. IT HAS BEEN SUGGESTED AS A CAUSE OF THE FOLLOWING
EFFECTS IN HUMANS: LIVER ABNORMALITIES, KIDNEY DAMAGE, LUNG DAMAGE AND
CENTRAL NERVOUS SYSTEM DAMAGE.
THIS PRODUCT CONTAINS ETHYLENE GLYCOL (EG). THE TOXICITY OF EG VIA
INHALATION OR SKIN CONTACT IS EXPECTED TO BE SLIGHT AT ROOM TEMPERATURE.
THE ESTIMATED ORAL LETHAL DOSE IS ABOUT 100 CC (3.3 OZ.) FOR AN ADULT
HUMAN. ETHYLENE GLYCOL IS OXIDIZED TO OXALIC ACID WHICH RESULTS IN THE
DEPOSITION OF CALCIUM OXALATE CRYSTALS MAINLY IN THE BRAIN AND KIDNEYS.
EARLY SIGNS AND SYMPTOMS OF EG POISONING MAY RESEMBLE THOSE OF ALCOHOL
INTOXICATION. LATER, THE VICTIM MAY EXPERIENCE NAUSEA, VOMITING, WEAKNESS,
ABDOMINAL AND MUSCLE PAIN, DIFFICULTY IN BREATHING AND DECREASED URINE
OUTPUT. WHEN EG WAS HEATED ABOVE THE BOILING POINT OF WATER, VAPORS FORMED
WHICH REPORTEDLY CAUSED UNCONSCIOUSNESS, INCREASED LYMPHOCYTE COUNT, AND A
RAPID, JERKY MOVEMENT OF THE EYES IN PERSONS CHRONICALLY EXPOSED. WHEN EG
WAS ADMINISTERED ORALLY TO PREGNANT RATS AND MICE, THERE WAS AN INCREASE IN
FETAL DEATHS AND BIRTH DEFECTS. SOME OF THESE EFFECTS OCCURRED AT DOSES
THAT HAD NO TOXIC EFFECTS ON THE MOTHERS. WE ARE NOT AWARE OF ANY REPORTS
THAT EG CAUSES REPRODUCTIVE TOXICITY IN HUMAN BEINGS.
| SECTION 12 ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THIS MATERIAL IS NOT EXPECTED TO BE HARMFUL TO AQUATIC ORGANISMS. THE
ECOTOXICITY HAZARD IS BASED ON AN EVALUATION OF DATA FOR THE COMPONENTS OR
A SIMILAR MATERIAL.
ENVIRONMENTAL FATE:
READY BIODEGRADABILITY:
THIS MATERIAL IS NOT EXPECTED TO BE READILY BIODEGRADABLE. THE
BIODEGRADABILITY OF THIS MATERIAL IS BASED ON AN EVALUATION OF DATA FOR
THE COMPONENTS OR A SIMILAR MATERIAL.
| SECTION 13 DISPOSAL CONSIDERATIONS | |
USE MATERIAL FOR ITS INTENDED PURPOSE OR RECYCLE IF POSSIBLE. OIL
COLLECTION SERVICES ARE AVAILABLE FOR USED OIL RECYCLING OR DISPOSAL.
PLACE CONTAMINATED MATERIALS IN CONTAINERS AND DISPOSE OF IN A MANNER
CONSISTENT WITH APPLICABLE REGULATIONS. CONTACT YOUR SALES REPRESENTATIVE
OR LOCAL ENVIRONMENTAL OR HEALTH AUTHORITIES FOR APPROVED DISPOSAL OR
RECYCLING METHODS.
| SECTION 14 TRANSPORT INFORMATION | |
THE DESCRIPTION SHOWN MAY NOT APPLY TO ALL SHIPPING SITUATIONS. CONSULT
49CFR, OR APPROPRIATE DANGEROUS GOODS REGULATIONS, FOR ADDITIONAL
DESCRIPTION REQUIREMENTS (E.G., TECHNICAL NAME) AND MODE-SPECIFIC OR
QUANTITY-SPECIFIC SHIPPING REQUIREMENTS.
DOT SHIPPING DESCRIPTION: ANTI-FREEZE PREPARATIONS, PROPRIETARY
ADDITIONAL INFORMATION:
BULK SHIPMENTS WITH A REPORTABLE QUANTITY (5000 POUNDS) OF ETHYLENE GLYCOL
ARE A HAZARDOUS MATERIAL. THE PROPER SHIPPING NAME IS:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ETHYLENE GLYCOL), 9,
UN3082, III, RQ (ETHYLENE GLYCOL).
IMO/IMDG SHIPPING DESCRIPTION:
MAY BE REGULATED AS DANGEROUS GOODS FOR TRANSPORTATION UNDER THE IMDG CODE
ICAO/IATA SHIPPING DESCRIPTION:
ANTI-FREEZE PREPARATIONS, PROPRIETARY; NOT REGULATED AS DANGEROUS GOODS FOR
TRANSPORT UNDER ICAO
| SECTION 15 REGULATORY INFORMATION | |
EPCRA 311/312 CATEGORIES:
1. IMMEDIATE (ACUTE) HEALTH EFFECTS: YES
2. DELAYED (CHRONIC) HEALTH EFFECTS: YES
3. FIRE HAZARD: NO
4. SUDDEN RELEASE OF PRESSURE HAZARD: NO
5. REACTIVITY HAZARD: NO
REGULATORY LISTS SEARCHED:
01-1=IARC GROUP 1
01-2A=IARC GROUP 2A
01-2B=IARC GROUP 2B
02=NTP CARCINOGEN
03=EPCRA 313
04=CA PROPOSITION 65
05=MA RTK
06=NJ RTK
07=PA RTK
THE FOLLOWING COMPONENTS OF THIS MATERIAL ARE FOUND ON THE REGULATORY
LISTS INDICATED.
DIETHYLENE GLYCOL: 07
ETHYLENE GLYCOL: 03, 05, 06, 07
CHEMICAL INVENTORIES:
ALL COMPONENTS COMPLY WITH THE FOLLOWING CHEMICAL INVENTORY REQUIREMENTS:
AICS (AUSTRALIA), DSL (CANADA), EINECS (EUROPEAN UNION), IECSC (CHINA),
TSCA (UNITED STATES).
ONE OR MORE COMPONENTS DOES NOT COMPLY WITH THE FOLLOWING CHEMICAL
INVENTORY REQUIREMENTS: ENCS (JAPAN), KECI (KOREA), PICCS (PHILIPPINES).
NEW JERSEY RTK CLASSIFICATION: REFER TO COMPONENTS LISTED IN SECTION 2.
WHMIS CLASSIFICATION:
CLASS D, DIVISION 1, SUBDIVISION B: TOXIC MATERIAL
ACUTE LETHALITY
CLASS D, DIVISION 2, SUBDIVISION A: VERY TOXIC MATERIAL
TERATOGENICITY AND EMBRYOTOXICITY
| SECTION 16 OTHER INFORMATION | |
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 0
REACTIVITY 0
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 0
REACTIVITY 0
0-LEAST
1-SLIGHT
2-MODERATE
3-HIGH
4-EXTREME
PPE - PERSONAL PROTECTION EQUIPMENT INDEX RECOMMENDATION
* - CHRONIC EFFECT INDICATOR.
THESE VALUES ARE OBTAINED USING THE GUIDELINES OR PUBLISHED EVALUATIONS
PREPARED BY THE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) OR THE NATIONAL
PAINT AND COATING ASSOCIATION (FOR HMIS RATINGS).
LABEL RECOMMENDATION:
LABEL CATEGORY: ANTIFREEZE/COOLANT 1 - AFC1
REVISION STATEMENT:
THIS REVISION UPDATES THE FOLLOWING SECTIONS OF THIS MATERIAL SAFETY DATA
SHEET: 12, 16
REVISION DATE: APRIL 22, 2009
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - THRESHOLD LIMIT VALUE
TWA - TIME WEIGHTED AVERAGE
STEL - SHORT-TERM EXPOSURE LIMIT
PEL - PERMISSIBLE EXPOSURE LIMIT
CAS - CHEMICAL ABSTRACT SERVICE NUMBER
ACGIH - AMERICAN CONFERENCE OF GOVERNMENT INDUSTRIAL HYGIENISTS
IMO/IMDG - INTERNATIONAL MARITIME DANGEROUS GOODS CODE
API - AMERICAN PETROLEUM INSTITUTE
MSDS - MATERIAL SAFETY DATA SHEET
CVX - CHEVRON
NFPA - NATIONAL FIRE PROTECTION ASSOCIATION (USA)
DOT - DEPARTMENT OF TRANSPORTATION (USA)
NTP - NATIONAL TOXICOLOGY PROGRAM (USA)
IARC - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
OSHA - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PREPARED ACCORDING TO THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND THE ANSI MSDS STANDARD (Z400.1) BY THE CHEVRON ENERGY
TECHNOLOGY COMPANY, 100 CHEVRON WAY, RICHMOND, CALIFORNIA 94802.
THE ABOVE INFORMATION IS BASED ON THE DATA OF WHICH WE ARE AWARE AND IS
BELIEVED TO BE CORRECT AS OF THE DATE HEREOF. SINCE THIS INFORMATION MAY
BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL AND WITH WHICH WE MAY BE
UNFAMILIAR AND SINCE DATA MADE AVAILABLE SUBSEQUENT TO THE DATE HEREOF MAY
SUGGEST MODIFICATIONS OF THE INFORMATION, WE DO NOT ASSUME ANY
RESPONSIBILITY FOR THE RESULTS OF ITS USE. THIS INFORMATION IS FURNISHED
UPON CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS OWN
DETERMINATION OF THE SUITABILITY OF THE MATERIAL FOR HIS PARTICULAR
PURPOSE.
MATERIAL SAFETY DATA SHEET
| SECTION 1 PRODUCT AND COMPANY IDENTIFICATION | |
CHEVRON RANDO(R*) HD PREMIUM OIL MV
PRODUCT USE: HYDRAULIC OIL
PRODUCT NUMBER(S): CPS277314
COMPANY IDENTIFICATION:
CHEVRON PRODUCTS COMPANY
A DIVISION OF CHEVRON U.S.A. INC.
6001 BOLLINGER CANYON RD.
SAN RAMON, CA 94583
UNITED STATES OF AMERICA
WWW.CHEVRONLUBRICANTS.COM
TRANSPORTATION EMERGENCY RESPONSE:
CHEMTREC: (800) 424-9300 OR (703) 527-3887
HEALTH EMERGENCY:
CHEVRON EMERGENCY INFORMATION CENTER:
LOCATED IN THE USA. INTERNATIONAL COLLECT CALLS ACCEPTED.
(800) 231-0623 OR (510) 231-0623
PRODUCT INFORMATION:
EMAIL: LUBEMSDS@CHEVRON.COM
PRODUCT INFORMATION: (800) LUBE TEK
MSDS REQUESTS: (800) 414-6737
| SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS NUMBER AMOUNT
HIGHLY REFINED MINERAL OIL (C15 - C50) MIXTURE 60 - 100% WEIGHT
| SECTION 3 HAZARDS IDENTIFICATION | |
IMMEDIATE HEALTH EFFECTS:
EYE: NOT EXPECTED TO CAUSE PROLONGED OR SIGNIFICANT EYE IRRITATION.
SKIN:
CONTACT WITH THE SKIN IS NOT EXPECTED TO CAUSE PROLONGED OR SIGNIFICANT
IRRITATION. NOT EXPECTED TO BE HARMFUL TO INTERNAL ORGANS IF ABSORBED
THROUGH THE SKIN. HIGH-PRESSURE EQUIPMENT INFORMATION:
ACCIDENTAL HIGH-VELOCITY INJECTION UNDER THE SKIN OF MATERIALS OF THIS
TYPE MAY RESULT IN SERIOUS INJURY. SEEK MEDICAL ATTENTION AT ONCE SHOULD
AN ACCIDENT LIKE THIS OCCUR. THE INITIAL WOUND AT THE INJECTION SITE MAY
NOT APPEAR TO BE SERIOUS AT FIRST; BUT, IF LEFT UNTREATED, COULD RESULT IN
DISFIGUREMENT OR AMPUTATION OF THE AFFECTED PART.
INGESTION: NOT EXPECTED TO BE HARMFUL IF SWALLOWED.
INHALATION:
NOT EXPECTED TO BE HARMFUL IF INHALED. CONTAINS A PETROLEUM-BASED MINERAL
OIL. MAY CAUSE RESPIRATORY IRRITATION OR OTHER PULMONARY EFFECTS FOLLOWING
PROLONGED OR REPEATED INHALATION OF OIL MIST AT AIRBORNE LEVELS ABOVE THE
RECOMMENDED MINERAL OIL MIST EXPOSURE LIMIT SYMPTOMS OF RESPIRATORY
IRRITATION MAY INCLUDE COUGHING AND DIFFICULTY BREATHING.
| SECTION 4 FIRST AID MEASURES | |
EYE:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. AS A PRECAUTION, REMOVE
CONTACT LENSES, IF WORN, AND FLUSH EYES WITH WATER.
SKIN:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. AS A PRECAUTION, REMOVE
CLOTHING AND SHOES IF CONTAMINATED. TO REMOVE THE MATERIAL FROM SKIN, USE
SOAP AND WATER. DISCARD CONTAMINATED CLOTHING AND SHOES OR THOROUGHLY CLEAN
BEFORE REUSE.
INGESTION:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. DO NOT INDUCE VOMITING. AS A
PRECAUTION, GET MEDICAL ADVICE.
INHALATION:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. IF EXPOSED TO EXCESSIVE LEVELS
OF MATERIAL IN THE AIR, MOVE THE EXPOSED PERSON TO FRESH AIR. GET MEDICAL
ATTENTION IF COUGHING OR RESPIRATORY DISCOMFORT OCCURS.
NOTE TO PHYSICIANS:
IN AN ACCIDENT INVOLVING HIGH-PRESSURE EQUIPMENT, THIS PRODUCT MAY BE
INJECTED UNDER THE SKIN. SUCH AN ACCIDENT MAY RESULT IN A SMALL, SOMETIMES
BLOODLESS, PUNCTURE WOUND. HOWEVER, BECAUSE OF ITS DRIVING FORCE, MATERIAL
INJECTED INTO A FINGERTIP CAN BE DEPOSITED INTO THE PALM OF THE HAND.
WITHIN 24 HOURS, THERE IS USUALLY A GREAT DEAL OF SWELLING, DISCOLORATION,
AND INTENSE THROBBING PAIN. IMMEDIATE TREATMENT AT A SURGICAL EMERGENCY
CENTER IS RECOMMENDED.
| SECTION 5 FIRE FIGHTING MEASURES | |
LEAKS/RUPTURES IN HIGH PRESSURE SYSTEM USING MATERIALS OF THIS TYPE CAN
CREATE A FIRE HAZARD WHEN IN THE VICINITY OF IGNITION SOURCES (EG. OPEN
FLAME, PILOT LIGHTS, SPARKS, OR ELECTRIC ARCS).
FIRE CLASSIFICATION:
OSHA CLASSIFICATION (29 CFR 1910.1200):
NOT CLASSIFIED BY OSHA AS FLAMMABLE OR COMBUSTIBLE.
NFPA RATINGS:
HEALTH 0
FLAMMABILITY 1
REACTIVITY 0
FLAMMABLE PROPERTIES:
FLASHPOINT (CLEVELAND OPEN CUP): 170 DEG. C (338 DEG. F) MINIMUM
AUTOIGNITION: NO DATA AVAILABLE
FLAMMABILITY (EXPLOSIVE) LIMITS (% BY VOLUME IN AIR):
LOWER: NO DATA AVAILABLE
UPPER: NO DATA AVAILABLE
EXTINGUISHING MEDIA:
USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE (CO2) TO EXTINGUISH
FLAMES.
PROTECTION OF FIRE FIGHTERS:
FIRE FIGHTING INSTRUCTIONS:
THIS MATERIAL WILL BURN ALTHOUGH IT IS NOT EASILY IGNITED. FOR FIRES
INVOLVING THIS MATERIAL, DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE SPACE
WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING SELF-CONTAINED BREATHING
APPARATUS.
COMBUSTION PRODUCTS:
HIGHLY DEPENDENT ON COMBUSTION CONDITIONS. A COMPLEX MIXTURE OF AIRBORNE
SOLIDS, LIQUIDS, AND GASES INCLUDING CARBON MONOXIDE, CARBON DIOXIDE, AND
UNIDENTIFIED ORGANIC COMPOUNDS WILL BE EVOLVED WHEN THIS MATERIAL UNDERGOES
COMBUSTION.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
PROTECTIVE MEASURES:
ELIMINATE ALL SOURCES OF IGNITION IN VICINITY OF SPILLED MATERIAL.
SPILL MANAGEMENT:
STOP THE SOURCE OF THE RELEASE IF YOU CAN DO IT WITHOUT RISK. CONTAIN
RELEASE TO PREVENT FURTHER CONTAMINATION OF SOIL, SURFACE WATER OR
GROUNDWATER. CLEAN UP SPILL AS SOON AS POSSIBLE, OBSERVING PRECAUTIONS IN
EXPOSURE CONTROLS/PERSONAL PROTECTION. USE APPROPRIATE TECHNIQUES SUCH AS
APPLYING NON-COMBUSTIBLE ABSORBENT MATERIALS OR PUMPING. WHERE FEASIBLE AND
APPROPRIATE, REMOVE CONTAMINATED SOIL. PLACE CONTAMINATED MATERIALS IN
DISPOSABLE CONTAINERS AND DISPOSE OF IN A MANNER CONSISTENT WITH APPLICABLE
REGULATIONS.
REPORTING:
REPORT SPILLS TO LOCAL AUTHORITIES AND/OR THE U.S. COAST GUARD'S NATIONAL
RESPONSE CENTER AT (800) 424-8802 AS APPROPRIATE OR REQUIRED.
| SECTION 7 HANDLING AND STORAGE | |
PRECAUTIONARY MEASURES:
DO NOT USE IN HIGH PRESSURE SYSTEMS IN THE VICINITY OF FLAMES, SPARKS AND
HOT SURFACES. USE ONLY IN WELL VENTILATED AREAS. KEEP CONTAINER CLOSED.
GENERAL HANDLING INFORMATION:
AVOID CONTAMINATING SOIL OR RELEASING THIS MATERIAL INTO SEWAGE AND
DRAINAGE SYSTEMS AND BODIES OF WATER.
STATIC HAZARD:
ELECTROSTATIC CHARGE MAY ACCUMULATE AND CREATE A HAZARDOUS CONDITION WHEN
HANDLING THIS MATERIAL, TO MINIMIZE THIS HAZARD, BONDING AND GROUNDING MAY
BE NECESSARY BUT MAY NOT, BY THEMSELVES, BE SUFFICIENT REVIEW ALL
OPERATIONS WHICH HAVE THE POTENTIAL OF GENERATING AND ACCUMULATING AN
ELECTROSTATIC CHARGE AND/OR A FLAMMABLE ATMOSPHERE (INCLUDING TANK AND
CONTAINER FILLING, SPLASH FILLING, TANK CLEANING, SAMPLING, GAUGING, SWITCH
LOADING, FILTERING, MIXING, AGITATION, AND VACUUM TRUCK OPERATIONS) AND USE
APPROPRIATE MITIGATING PROCEDURES. FOR MORE INFORMATION, REFER TO OSHA
STANDARD 29 CFR 1910.106, 'FLAMMABLE AND COMBUSTIBLE LIQUIDS', NATIONAL
FIRE PROTECTION ASSOCIATION (NFPA 77, 'RECOMMENDED PRACTICE ON STATIC
ELECTRICITY', AND/OR THE AMERICAN PETROLEUM INSTITUTE (API) RECOMMENDED
PRACTICE 2003, 'PROTECTION AGAINST IGNITIONS ARISING OUT OF STATIC,
LIGHTNING, AND STRAY CURRENTS'.
CONTAINER WARNINGS:
CONTAINER IS NOT DESIGNED TO CONTAIN PRESSURE. DO NOT USE PRESSURE TO EMPTY
CONTAINER OR IT MAY RUPTURE WITH EXPLOSIVE FORCE. EMPTY CONTAINERS RETAIN
PRODUCT RESIDUE (SOLID, LIQUID, AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES
OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. EMPTY CONTAINERS
SHOULD BE COMPLETELY DRAINED, PROPERLY CLOSED, AND PROMPTLY RETURNED TO A
DRUM RECONDITIONER OR DISPOSED OF PROPERLY.
| SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
GENERAL CONSIDERATIONS:
CONSIDER THE POTENTIAL HAZARDS OF THIS MATERIAL {SEE SECTION 3), APPLICABLE
EXPOSURE LIMITS, JOB ACTIVITIES, AND OTHER SUBSTANCES IN THE WORK PLACE
WHEN DESIGNING ENGINEERING CONTROLS AND SELECTING PERSONAL PROTECTIVE
EQUIPMENT. IF ENGINEERING CONTROLS OR WORK PRACTICES ARE NOT ADEQUATE TO
PREVENT EXPOSURE TO HARMFUL LEVELS OF THIS MATERIAL, THE PERSONAL
PROTECTIVE EQUIPMENT LISTED BELOW IS RECOMMENDED. THE USER SHOULD READ AND
UNDERSTAND ALL INSTRUCTIONS AND LIMITATIONS SUPPLIED WITH THE EQUIPMENT
SINCE PROTECTION IS USUALLY PROVIDED FOR A LIMITED TIME OR UNDER CERTAIN
CIRCUMSTANCES.
ENGINEERING CONTROLS: USE IN A WELL-VENTILATED AREA.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
NO SPECIAL EYE PROTECTION IS NORMALLY REQUIRED, WHERE SPLASHING IS
POSSIBLE, WEAR SAFETY GLASSES WITH SIDE SHIELDS AS A GOOD SAFETY PRACTICE.
SKIN PROTECTION:
NO SPECIAL PROTECTIVE CLOTHING IS NORMALLY REQUIRED. WHERE SPLASHING IS
POSSIBLE, SELECT PROTECTIVE CLOTHING DEPENDING ON OPERATIONS CONDUCTED,
PHYSICAL REQUIREMENTS AND OTHER SUBSTANCES IN THE WORKPLACE. SUGGESTED
MATERIALS FOR PROTECTIVE GLOVES INCLUDE:
4H (PE/EVAL), VITON, NITRILE RUBBER, SILVER SHIELD.
RESPIRATORY PROTECTION:
NO RESPIRATORY PROTECTION IS NORMALLY REQUIRED.
IF USER OPERATIONS GENERATE AN OIL MIST, DETERMINE IF AIRBORNE
CONCENTRATIONS ARE BELOW THE OCCUPATIONAL EXPOSURE LIMIT FOR MINERAL OIL
MIST, IF NOT, WEAR AN APPROVED RESPIRATOR THAT PROVIDES ADEQUATE PROTECTION
FROM THE MEASURED CONCENTRATIONS OF THIS MATERIAL. FOR AIR-PURIFYING
RESPIRATORS USE A PARTICULATE CARTRIDGE.
USE A POSITIVE PRESSURE AIR-SUPPLYING RESPIRATOR IN CIRCUMSTANCES WHERE
AIR-PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION.
OCCUPATIONAL EXPOSURE LIMITS:
COMPONENT AGENCY TWA STEL CEILING NOTATION
HIGHLY REFINED MINERAL OIL ACGIH 5 MG/M3 10 MG/M3
(C15 - C50)
HIGHLY REFINED MINERAL OIL OSHA Z-1 5 MG/M3
(C15 - C50)
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
ATTENTION:
THE DATA BELOW ARE TYPICAL VALUES AND DO NOT CONSTITUTE A SPECIFICATION.
COLOR: YELLOW
PHYSICAL STATE: LIQUID
ODOR: PETROLEUM ODOR
PH: NOT APPLICABLE
VAPOR PRESSURE: <0.01 MMHg @ 37.8 DEG. C (100 DEG. F)
VAPOR DENSITY (AIR = 1): >1 (TYPICAL)
BOILING POINT: >315 DEG. C (599 DEG. F) MINIMUM
SOLUBILITY: SOLUBLE IN HYDROCARBON SOLVENTS; INSOLUBLE IN WATER.
FREEZING POINT:
NO DATA AVAILABLE @ 15.6 DEG. C (60.1 DEG. F) / 15.6 DEG. C (60.1 DEG. F)
DENSITY: 0.86 KG/L - 0.9 KG/L @ 15 DEG. C (59 DEG. F)
VOLATILE ORGANIC:
COMPOUNDS (VOC): <2.1% WEIGHT
VISCOSITY: 28.8 CST @ 40 DEG. C (104 DEG. F) MINIMUM
| SECTION 10 STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
THIS MATERIAL IS CONSIDERED STABLE UNDER NORMAL AMBIENT AND ANTICIPATED
STORAGE AND HANDLING CONDITIONS OF TEMPERATURE AND PRESSURE.
INCOMPATIBILITY WITH OTHER MATERIALS:
MAY REACT WITH STRONG ACIDS OR STRONG OXIDIZING AGENTS, SUCH AS CHLORATES,
NITRATES, PEROXIDES, ETC.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN (NONE EXPECTED)
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
| SECTION 11 TOXICOLOGICAL INFORMATION | |
IMMEDIATE HEALTH EFFECTS:
EYE IRRITATION:
THE EYE IRRITATION HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
SKIN IRRITATION:
THE SKIN IRRITATION HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
SKIN SENSITIZATION:
THE SKIN SENSITIZATION HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
ACUTE DERMAL TOXICITY:
THE ACUTE DERMAL TOXICITY HAZARD IS BASED ON EVALUATION OF DATA FOR
SIMILAR MATERIALS OR PRODUCT COMPONENTS.
ACUTE ORAL TOXICITY:
THE ACUTE ORAL TOXICITY HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
ACUTE INHALATION TOXICITY:
THE ACUTE INHALATION TOXICITY HAZARD IS BASED ON EVALUATION OF DATA FOR
SIMILAR MATERIALS OR PRODUCT COMPONENTS.
ADDITIONAL TOXICOLOGY INFORMATION:
THIS PRODUCT CONTAINS PETROLEUM BASE OILS WHICH MAY BE REFINED BY VARIOUS
PROCESSES INCLUDING SEVERE SOLVENT EXTRACTION, SEVERE HYDROCRACKING, OR
SEVERE HYDROTREATING. NONE OF THE OILS REQUIRES A CANCER WARNING UNDER THE
OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). THESE OILS HAVE NOT
BEEN LISTED IN THE NATIONAL TOXICOLOGY PROGRAM (NTP) ANNUAL REPORT NOR HAVE
THEY BEEN CLASSIFIED BY THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
(IARC) AS; CARCINOGENIC TO HUMANS (GROUP 1), PROBABLY CARCINOGENIC TO
HUMANS (GROUP 2A), OR POSSIBLY CARCINOGENIC TO HUMANS (GROUP 2B). THESE
OILS HAVE NOT BEEN CLASSIFIED BY THE AMERICAN CONFERENCE OF GOVERNMENTAL
INDUSTRIAL HYGIENISTS (ACGIH) AS: CONFIRMED HUMAN CARCINOGEN (A1),
SUSPECTED HUMAN CARCINOGEN (A2), OR CONFIRMED ANIMAL CARCINOGEN WITH
UNKNOWN RELEVANCE TO HUMANS (A3).
| SECTION 12 ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THIS MATERIAL IS NOT EXPECTED TO BE HARMFUL TO AQUATIC ORGANISMS. THE
ECOTOXICITY HAZARD IS BASED ON AN EVALUATION OF DATA FOR THE COMPONENTS
OR A SIMILAR MATERIAL.
ENVIRONMENTAL FATE:
READY BIODEGRADABILITY:
THIS MATERIAL IS NOT EXPECTED TO BE READILY BIODEGRADABLE. THE
BIODEGRADABILITY OF THIS MATERIAL IS BASED ON AN EVALUATION OF DATA FOR
THE COMPONENTS OR A SIMILAR MATERIAL.
| SECTION 13 DISPOSAL CONSIDERATIONS | |
USE MATERIAL FOR ITS INTENDED PURPOSE OR RECYCLE IF POSSIBLE. OIL
COLLECTION SERVICES ARE AVAILABLE FOR USED OIL RECYCLING OR DISPOSAL.
PLACE CONTAMINATED MATERIALS IN CONTAINERS AND DISPOSE OF IN A MANNER
CONSISTENT WITH APPLICABLE REGULATIONS. CONTACT YOUR SALES REPRESENTATIVE
OR LOCAL ENVIRONMENTAL OR HEALTH AUTHORITIES FOR APPROVED DISPOSAL OR
RECYCLING METHODS.
| SECTION 14 TRANSPORT INFORMATION | |
THE DESCRIPTION SHOWN MAY NOT APPLY TO ALL SHIPPING SITUATIONS. CONSULT
49CFR, OR APPROPRIATE DANGEROUS GOODS REGULATIONS, FOR ADDITIONAL
DESCRIPTION REQUIREMENTS (E.G., TECHNICAL NAME) AND MODE-SPECIFIC OR
QUANTITY-SPECIFIC SHIPPING REQUIREMENTS.
DOT SHIPPING DESCRIPTION:
PETROLEUM LUBRICATING OIL, NOT REGULATED AS A HAZARDOUS MATERIAL FOR
TRANSPORTATION UNDER 49 CFR
ADDITIONAL INFORMATION:
NOT HAZARDOUS BY U.S. DOT. ADR/RID HAZARD CLASS NOT APPLICABLE.
IMO/IMDG SHIPPING DESCRIPTION:
PETROLEUM LUBRICATING OIL; NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT
UNDER THE IMDG CODE
ICAO/IATA SHIPPING DESCRIPTION:
PETROLEUM LUBRICATING OIL; NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT
UNDER ICAO TI OR IATA DGR
| SECTION 15 REGULATORY INFORMATION | |
EPCRA 311/312 CATEGORIES:
1. IMMEDIATE (ACUTE) HEALTH EFFECTS: NO
2. DELAYED (CHRONIC) HEALTH EFFECTS: NO
3. FIRE HAZARD: NO
4. SUDDEN RELEASE OF PRESSURE HAZARD: NO
5. REACTIVITY HAZARD: NO
REGULATORY LISTS SEARCHED:
01-1=IARC GROUP 1
01-2A=IARC GROUP 2A
01-2B=IARC GROUP 2B
02=NTP CARCINOGEN
03=EPCRA 313
04=CA PROPOSITION 65
05=MA RTK
06=NJ RTK
07=PA RTK
NO COMPONENTS OF THIS MATERIAL WERE FOUND ON THE REGULATORY LISTS ABOVE.
CHEMICAL INVENTORIES:
ALL COMPONENTS COMPLY WITH THE FOLLOWING CHEMICAL INVENTORY REQUIREMENTS:
AICS (AUSTRALIA), DSL (CANADA), EINECS (EUROPEAN UNION), ENCS (JAPAN),
IECSC (CHINA), KECI (KOREA), PICCS (PHILIPPINES), TSCA (UNITED STATES).
NEW JERSEY RTK CLASSIFICATION:
UNDER THE NEW JERSEY RIGHT-TO-KNOW ACT L. 1983 CHAPTER 315 N.J.S.A.
34:5A-1 ET. SEQ., THE PRODUCT IS TO BE IDENTIFIED AS FOLLOWS:
PETROLEUM OIL (HYDRAULIC OIL)
WHMIS CLASSIFICATION:
THIS PRODUCT IS NOT CONSIDERED A CONTROLLED PRODUCT ACCORDING TO THE
CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS.
| SECTION 16 OTHER INFORMATION | |
NFPA RATINGS:
HEALTH 0
FLAMMABILITY 1
REACTIVITY 0
HMIS RATINGS:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
0-LEAST
1-SLIGHT
2-MODERATE
3-HIGH
4-EXTREME
PPE - PERSONAL PROTECTION EQUIPMENT INDEX RECOMMENDATION
* - CHRONIC EFFECT INDICATOR.
THESE VALUES ARE OBTAINED USING THE GUIDELINES OR PUBLISHED EVALUATIONS
PREPARED BY THE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) OR THE NATIONAL
PAINT AND COATING ASSOCIATION (FOR HMIS RATINGS).
LABEL RECOMMENDATION:
LABEL CATEGORY: INDUSTRIAL OIL 1 - IND1
REVISION STATEMENT:
THIS REVISION UPDATES THE FOLLOWING SECTIONS OF THIS MATERIAL SAFETY DATA
SHEET: 2, 9, 16
REVISION DATE: OCTOBER 30, 2008
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - THRESHOLD LIMIT VALUE
TWA - TIME WEIGHTED AVERAGE
STEL - SHORT-TERM EXPOSURE LIMIT
PEL - PERMISSIBLE EXPOSURE LIMIT
CAS - CHEMICAL ABSTRACT SERVICE NUMBER
ACGIH - AMERICAN CONFERENCE OF GOVERNMENT INDUSTRIAL HYGIENISTS
IMO/IMDG - INTERNATIONAL MARITIME DANGEROUS GOODS CODE
API - AMERICAN PETROLEUM INSTITUTE
MSDS - MATERIAL SAFETY DATA SHEET
CVX - CHEVRON
NFPA - NATIONAL FIRE PROTECTION ASSOCIATION (USA)
DOT - DEPARTMENT OF TRANSPORTATION (USA)
NTP - NATIONAL TOXICOLOGY PROGRAM (USA)
IARC - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
OSHA - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PREPARED ACCORDING TO THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND THE ANSI MSDS STANDARD (Z400.1) BY THE CHEVRON ENERGY
TECHNOLOGY COMPANY, 100 CHEVRON WAY, RICHMOND, CALIFORNIA 94802.
THE ABOVE INFORMATION IS BASED ON THE DATA OF WHICH WE ARE AWARE AND IS
BELIEVED TO BE CORRECT AS OF THE DATE HEREOF. SINCE THIS INFORMATION MAY
BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL AND WITH WHICH WE MAY BE
UNFAMILIAR AND SINCE DATA MADE AVAILABLE SUBSEQUENT TO THE DATE HEREOF
MAY SUGGEST MODIFICATIONS OF THE INFORMATION, WE DO NOT ASSUME ANY
RESPONSIBILITY FOR THE RESULTS OF ITS USE. THIS INFORMATION IS FURNISHED
UPON CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS OWN
DETERMINATION OF THE SUITABILITY OF THE MATERIAL FOR HIS PARTICULAR
PURPOSE.
MATERIAL SAFETY DATA SHEET
| SECTION 1 PRODUCT AND COMPANY IDENTIFICATION | |
CHEVRON ULTRA-DUTY GREASE EP
PRODUCT USE: GREASE
PRODUCT NUMBER(S): CPS238011, CPS238012, CPS238013
SYNONYMS:
CHEVRON ULTRA-DUTY GREASE EP NLGI 0, CHEVRON ULTRA-DUTY GREASE EP NLGI 1,
CHEVRON ULTRA-DUTY GREASE EP NLGI 2
COMPANY IDENTIFICATION:
CHEVRON PRODUCTS COMPANY
A DIVISION OF CHEVRON U.S.A. INC.
6001 BOILINGER CANYON RD.
SAN RAMON, CA 94583
UNITED STATES OF AMERICA
WWW.CHEVRONLUBRICANTS.COM
TRANSPORTATION EMERGENCY RESPONSE:
CHEMTREC: (800) 424-9300 OR (703) 527-3887
HEALTH EMERGENCY:
CHEVRON EMERGENCY INFORMATION CENTER:
LOCATED IN THE USA. INTERNATIONAL COLLECT CALLS ACCEPTED.
(800) 231-0623 OR (510) 231-0623
PRODUCT INFORMATION:
EMAIL: LUBEMSDS@CHEVRON.COM
PRODUCT INFORMATION: (800) LUBE TEK
MSDS REQUESTS: (800) 414-6737
| SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS | |
COMPONENTS CAS NUMBER AMOUNT
HIGHLY REFINED MINERAL OIL (C15 - C50) MIXTURE 60 - 100 %WT/WT
ZINC DIALKYLDITHIOPHOSPHATE 68649-42-3 1 - 5 %WT/WT
| SECTION 3 HAZARDS IDENTIFICATION | |
IMMEDIATE HEALTH EFFECTS:
EYE: NOT EXPECTED TO CAUSE PROLONGED OR SIGNIFICANT EYE IRRITATION.
SKIN:
CONTACT WITH THE SKIN IS NOT EXPECTED TO CAUSE PROLONGED OR SIGNIFICANT
IRRITATION. NOT EXPECTED TO BE HARMFUL TO INTERNAL ORGANS IF ABSORBED
THROUGH THE SKIN. HIGH-PRESSURE EQUIPMENT INFORMATION:
ACCIDENTAL HIGH-VELOCITY INJECTION UNDER THE SKIN OF MATERIALS OF THIS
TYPE MAY RESULT IN SERIOUS INJURY. SEEK MEDICAL ATTENTION AT ONCE SHOULD AN
ACCIDENT LIKE THIS OCCUR. THE INITIAL WOUND AT THE INJECTION SITE MAY NOT
APPEAR TO BE SERIOUS AT FIRST; BUT, IF LEFT UNTREATED, COULD RESULT IN
DISFIGUREMENT OR AMPUTATION OF THE AFFECTED PART.
INGESTION: NOT EXPECTED TO BE HARMFUL IF SWALLOWED.
INHALATION:
NOT EXPECTED TO BE HARMFUL IF INHALED. CONTAINS A PETROLEUM-BASED MINERAL
OIL. MAY CAUSE RESPIRATORY IRRITATION OR OTHER PULMONARY EFFECTS FOLLOWING
PROLONGED OR REPEATED INHALATION OF OIL MIST AT AIRBORNE LEVELS ABOVE THE
RECOMMENDED MINERAL OIL MIST EXPOSURE LIMIT. SYMPTOMS OF RESPIRATORY
IRRITATION MAY INCLUDE COUGHING AND DIFFICULTY BREATHING.
| SECTION 4 FIRST AID MEASURES | |
EYE:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. AS A PRECAUTION, REMOVE
CONTACT LENSES, IF WORN, AND FLUSH EYES WITH WATER.
SKIN:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. AS A PRECAUTION, REMOVE
CLOTHING AND SHOES IF CONTAMINATED. TO REMOVE THE MATERIAL FROM SKIN,
APPLY A WATERLESS HAND CLEANER, MINERAL OIL, OR PETROLEUM JELLY. THEN WASH
WITH SOAP AND WATER. DISCARD CONTAMINATED CLOTHING AND SHOES OR THOROUGHLY
CLEAN BEFORE REUSE.
INGESTION:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. DO NOT INDUCE VOMITING. AS
A PRECAUTION, GET MEDICAL ADVICE.
INHALATION:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. IF EXPOSED TO EXCESSIVE LEVELS
OF MATERIAL IN THE AIR, MOVE THE EXPOSED PERSON TO FRESH AIR. GET MEDICAL
ATTENTION IF COUGHING OR RESPIRATORY DISCOMFORT OCCURS.
NOTE TO PHYSICIANS:
IN AN ACCIDENT INVOLVING HIGH-PRESSURE EQUIPMENT, THIS PRODUCT MAY BE
INJECTED UNDER THE SKIN. SUCH AN ACCIDENT MAY RESULT IN A SMALL, SOMETIMES
BLOODLESS, PUNCTURE WOUND. HOWEVER, BECAUSE OF ITS DRIVING FORCE, MATERIAL
INJECTED INTO A FINGERTIP CAN BE DEPOSITED INTO THE PALM OF THE HAND.
WITHIN 24 HOURS, THERE IS USUALLY A GREAT DEAL OF SWELLING, DISCOLORATION,
AND INTENSE THROBBING PAIN. IMMEDIATE TREATMENT AT A SURGICAL EMERGENCY
CENTER IS RECOMMENDED.
| SECTION 5 FIRE FIGHTING MEASURES | |
FIRE CLASSIFICATION:
OSHA CLASSIFICATION (29 CFR 1910.1200):
NOT CLASSIFIED BY OSHA AS FLAMMABLE OR COMBUSTIBLE.
NFPA RATINGS:
HEALTH 0
FLAMMABILITY 1
REACTIVITY 0
FLAMMABLE PROPERTIES:
FLASHPOINT: 274 DEG. C (525 DEG. F) MINIMUM
AUTOIGNITION: NO DATA AVAILABLE
FLAMMABILITY (EXPLOSIVE) LIMITS (% BY VOLUME IN AIR):
LOWER: NOT APPLICABLE
UPPER: NOT APPLICABLE
EXTINGUISHING MEDIA:
USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE (CO2) TO EXTINGUISH
FLAMES.
PROTECTION OF FIRE FIGHTERS:
FIRE FIGHTING INSTRUCTIONS:
THIS MATERIAL WILL BURN ALTHOUGH IT IS NOT EASILY IGNITED. FOR FIRES
INVOLVING THIS MATERIAL, DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE SPACE
WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING SELF-CONTAINED BREATHING
APPARATUS.
COMBUSTION PRODUCTS:
HIGHLY DEPENDENT ON COMBUSTION CONDITIONS. A COMPLEX MIXTURE OF AIRBORNE
SOLIDS, LIQUIDS, AND GASES INCLUDING CARBON MONOXIDE, CARBON DIOXIDE, AND
UNIDENTIFIED ORGANIC COMPOUNDS WILL BE EVOLVED WHEN THIS MATERIAL UNDERGOES
COMBUSTION.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
PROTECTIVE MEASURES:
ELIMINATE ALL SOURCES OF IGNITION IN VICINITY OF SPILLED MATERIAL.
SPILL MANAGEMENT:
CLEAN UP SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS IN EXPOSURE
CONTROLS/PERSONAL PROTECTION SECTION. STOP THE SOURCE OF THE RELEASE IF YOU
CAN DO IT WITHOUT RISK. CONTAIN RELEASE TO PREVENT FURTHER CONTAMINATION
OF SOIL, SURFACE WATER OR GROUNDWATER. CLEAN UP SPILL AS SOON AS POSSIBLE,
OBSERVING PRECAUTIONS IN EXPOSURE CONTROLS/PERSONAL PROTECTION. USE
APPROPRIATE TECHNIQUES SUCH AS APPLYING NON-COMBUSTIBLE ABSORBENT MATERIALS
OR PUMPING. WHERE FEASIBLE AND APPROPRIATE, REMOVE CONTAMINATED SOIL. PLACE
CONTAMINATED MATERIALS IN DISPOSABLE CONTAINERS AND DISPOSE OF IN A MANNER
CONSISTENT WITH APPLICABLE REGULATIONS.
REPORTING:
REPORT SPILLS TO LOCAL AUTHORITIES AND/OR THE U.S. COAST GUARD'S NATIONAL
RESPONSE CENTER AT (800) 424-8802 AS APPROPRIATE OR REQUIRED.
| SECTION 7 HANDLING AND STORAGE | |
PRECAUTIONARY MEASURES: KEEP OUT OF THE REACH OF CHILDREN.
GENERAL HANDLING INFORMATION:
AVOID CONTAMINATING SOIL OR RELEASING THIS MATERIAL INTO SEWAGE AND
DRAINAGE SYSTEMS AND BODIES OF WATER.
STATIC HAZARD:
ELECTROSTATIC CHARGE MAY ACCUMULATE AND CREATE A HAZARDOUS CONDITION WHEN
HANDLING THIS MATERIAL. TO MINIMIZE THIS HAZARD, BONDING AND GROUNDING MAY
BE NECESSARY BUT MAY NOT, BY THEMSELVES, BE SUFFICIENT. REVIEW ALL
OPERATIONS WHICH HAVE THE POTENTIAL OF GENERATING AND ACCUMULATING AN
ELECTROSTATIC CHARGE AND/OR A FLAMMABLE ATMOSPHERE (INCLUDING TANK AND
CONTAINER FILLING, SPLASH FILLING, TANK CLEANING, SAMPLING, GAUGING, SWITCH
LOADING, FILTERING, MIXING, AGITATION, AND VACUUM TRUCK OPERATIONS) AND USE
APPROPRIATE MITIGATING PROCEDURES. FOR MORE INFORMATION, REFER TO OSHA
STANDARD 29 CFR 1910.106, 'FLAMMABLE AND COMBUSTIBLE LIQUIDS', NATIONAL
FIRE PROTECTION ASSOCIATION (NFPA 77, 'RECOMMENDED PRACTICE ON STATIC
ELECTRICITY', AND/OR THE AMERICAN PETROLEUM INSTITUTE (API) RECOMMENDED
PRACTICE 2003, 'PROTECTION AGAINST IGNITIONS ARISING OUT OF STATIC,
LIGHTNING, AND STRAY CURRENTS'.
CONTAINER WARNINGS:
CONTAINER IS NOT DESIGNED TO CONTAIN PRESSURE. DO NOT USE PRESSURE TO EMPTY
CONTAINER OR IT MAY RUPTURE WITH EXPLOSIVE FORCE. EMPTY CONTAINERS RETAIN
PRODUCT RESIDUE (SOLID, LIQUID, AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES
OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. EMPTY CONTAINERS
SHOULD BE COMPLETELY DRAINED, PROPERLY CLOSED, AND PROMPTLY RETURNED TO
A DRUM RECONDITIONER OR DISPOSED OF PROPERLY.
| SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
GENERAL CONSIDERATIONS:
CONSIDER THE POTENTIAL HAZARDS OF THIS MATERIAL {SEE SECTION 3), APPLICABLE
EXPOSURE LIMITS, JOB ACTIVITIES, AND OTHER SUBSTANCES IN THE WORK PLACE
WHEN DESIGNING ENGINEERING CONTROLS AND SELECTING PERSONAL PROTECTIVE
EQUIPMENT. IF ENGINEERING CONTROLS OR WORK PRACTICES ARE NOT ADEQUATE TO
PREVENT EXPOSURE TO HARMFUL LEVELS OF THIS MATERIAL, THE PERSONAL
PROTECTIVE EQUIPMENT LISTED BELOW IS RECOMMENDED. THE USER SHOULD READ AND
UNDERSTAND AIL INSTRUCTIONS AND LIMITATIONS SUPPLIED WITH THE EQUIPMENT
SINCE PROTECTION IS USUALLY PROVIDED FOR A LIMITED TIME OR UNDER CERTAIN
CIRCUMSTANCES.
ENGINEERING CONTROLS: USE IN A WELL-VENTILATED AREA.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
NO SPECIAL EYE PROTECTION IS NORMALLY REQUIRED. WHERE SPLASHING IS
POSSIBLE, WEAR SAFETY GLASSES WITH SIDE SHIELDS AS A GOOD SAFETY PRACTICE.
SKIN PROTECTION:
NO SPECIAL PROTECTIVE CLOTHING IS NORMALLY REQUIRED. WHERE SPLASHING IS
POSSIBLE, SELECT PROTECTIVE CLOTHING DEPENDING ON OPERATIONS CONDUCTED,
PHYSICAL REQUIREMENTS AND OTHER SUBSTANCES IN THE WORKPLACE.
SUGGESTED MATERIALS FOR PROTECTIVE GLOVES INCLUDE:
NEOPRENE, NITRILE RUBBER, SILVER SHIELD, VITON.
RESPIRATORY PROTECTION: NO RESPIRATORY PROTECTION IS NORMALLY REQUIRED.
IF USER OPERATIONS GENERATE AN OIL MIST, DETERMINE IF AIRBORNE
CONCENTRATIONS ARE BELOW THE OCCUPATIONAL EXPOSURE LIMIT FOR MINERAL OIL
MIST. IF NOT, WEAR AN APPROVED RESPIRATOR THAT PROVIDES ADEQUATE PROTECTION
FROM THE MEASURED CONCENTRATIONS OF THIS MATERIAL. FOR AIR-PURIFYING
RESPIRATORS USE A PARTICULATE CARTRIDGE.
USE A POSITIVE PRESSURE AIR-SUPPLYING RESPIRATOR IN CIRCUMSTANCES WHERE
AIR-PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION.
OCCUPATIONAL EXPOSURE LIMITS:
COMPONENT AGENCY TWA STEL CEILING NOTATION
HIGHLY REFINED MINERAL ACGIH 5 MG/M3 10 MG/M3
OIL (C15 - C50)
HIGHLY REFINED MINERAL OSHA Z-1 5 MG/M3
OIL (C15 - C50)
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
ATTENTION:
THE DATA BELOW ARE TYPICAL VALUES AND DO NOT CONSTITUTE A SPECIFICATION.
COLOR: RED
PHYSICAL STATE: SEMI-SOLID
ODOR: PETROLEUM ODOR
PH: NOT APPLICABLE
VAPOR PRESSURE: <0.01 MMHg MAXIMUM @ 100 DEG. C (212 DF)
VAPOR DENSITY (AIR = 1): >1 MINIMUM
BOILING POINT: >260 DEG. C (500 DEG. F) MINIMUM
SOLUBILITY: SOLUBLE IN HYDROCARBONS; INSOLUBLE IN WATER
MELTING POINT: 165 DEG. C (329 DEG. F) (MIN)
DENSITY: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
EVAPORATION RATE: NO DATA AVAILABLE
| SECTION 10 STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
THIS MATERIAL IS CONSIDERED STABLE UNDER NORMAL AMBIENT AND ANTICIPATED
STORAGE AND HANDLING CONDITIONS OF TEMPERATURE AND PRESSURE.
INCOMPATIBILITY WITH OTHER MATERIALS:
MAY REACT WITH STRONG ACIDS OR STRONG OXIDIZING AGENTS, SUCH AS CHLORATES,
NITRATES, PEROXIDES, ETC.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN (NONE EXPECTED)
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
| SECTION 11 TOXICOLOGICAL INFORMATION | |
IMMEDIATE HEALTH EFFECTS:
EYE IRRITATION:
THE DRAIZE EYE IRRITATION MEAN SCORE IN RABBITS FOR A 24-HOUR EXPOSURE
WAS: 6.7/110.
SKIN IRRITATION:
FOR A 24-HOUR EXPOSURE, THE PRIMARY IRRITATION SCORE (PIS) IN RABBITS IS:
0.6/8.0.
SKIN SENSITIZATION: NO PRODUCT TOXICOLOGY DATA AVAILABLE.
ACUTE DERMAL TOXICITY:
LD50: >2G/KG (RAT).
ACUTE ORAL TOXICITY:
THE ACUTE ORAL TOXICITY HAZARD IS BASED ON EVALUATION OF DATA FOR SIMILAR
MATERIALS OR PRODUCT COMPONENTS.
ACUTE INHALATION TOXICITY:
THE ACUTE INHALATION TOXICITY HAZARD IS BASED ON EVALUATION OF DATA FOR
SIMILAR MATERIALS OR PRODUCT COMPONENTS.
ADDITIONAL TOXICOLOGY INFORMATION:
THIS PRODUCT CONTAINS PETROLEUM BASE OILS WHICH MAY BE REFINED BY VARIOUS
PROCESSES INCLUDING SEVERE SOLVENT EXTRACTION, SEVERE HYDROCRACKING, OR
SEVERE HYDROTREATING. NONE OF THE OILS REQUIRES A CANCER WARNING UNDER THE
OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). THESE OILS HAVE NOT
BEEN LISTED IN THE NATIONAL TOXICOLOGY PROGRAM (NTP) ANNUAL REPORT NOR HAVE
THEY BEEN CLASSIFIED BY THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
(IARC) AS; CARCINOGENIC TO HUMANS (GROUP 1), PROBABLY CARCINOGENIC TO
HUMANS (GROUP 2A), OR POSSIBLY CARCINOGENIC TO HUMANS (GROUP 2B). THESE
OILS HAVE NOT BEEN CLASSIFIED BY THE AMERICAN CONFERENCE OF GOVERNMENTAL
INDUSTRIAL HYGIENISTS (ACGIH) AS: CONFIRMED HUMAN CARCINOGEN (A1),
SUSPECTED HUMAN CARCINOGEN (A2), OR CONFIRMED ANIMAL CARCINOGEN WITH
UNKNOWN RELEVANCE TO HUMANS (A3).
| SECTION 12 ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE TOXICITY OF THIS MATERIAL TO AQUATIC ORGANISMS HAS NOT BEEN EVALUATED.
CONSEQUENTLY, THIS MATERIAL SHOULD BE KEPT OUT OF SEWAGE AND DRAINAGE
SYSTEMS AND ALL BODIES OF WATER.
ENVIRONMENTAL FATE:
READY BIODEGRADABILITY:
THIS MATERIAL IS NOT EXPECTED TO BE READILY BIODEGRADABLE. THE
BIODEGRADABILITY OF THIS MATERIAL IS BASED ON AN EVALUATION OF DATA FOR
THE COMPONENTS OR A SIMILAR MATERIAL.
| SECTION 13 DISPOSAL CONSIDERATIONS | |
USE MATERIAL FOR ITS INTENDED PURPOSE OR RECYCLE IF POSSIBLE. OIL
COLLECTION SERVICES ARE AVAILABLE FOR USED OIL RECYCLING OR DISPOSAL. PLACE
CONTAMINATED MATERIALS IN CONTAINERS AND DISPOSE OF IN A MANNER CONSISTENT
WITH APPLICABLE REGULATIONS. CONTACT YOUR SALES REPRESENTATIVE OR LOCAL
ENVIRONMENTAL OR HEALTH AUTHORITIES FOR APPROVED DISPOSAL OR RECYCLING
METHODS.
| SECTION 14 TRANSPORT INFORMATION | |
THE DESCRIPTION SHOWN MAY NOT APPLY TO ALL SHIPPING SITUATIONS. CONSULT
49 CFR, OR APPROPRIATE DANGEROUS GOODS REGULATIONS, FOR ADDITIONAL
DESCRIPTION REQUIREMENTS (E.G., TECHNICAL NAME) AND MODE-SPECIFIC OR
QUANTITY-SPECIFIC SHIPPING REQUIREMENTS.
DOT SHIPPING DESCRIPTION:
PETROLEUM LUBRICATING GREASE; NOT REGULATED AS A HAZARDOUS MATERIAL FOR
TRANSPORTATION UNDER 49 CFR
ADDITIONAL INFORMATION:
NOT HAZARDOUS BY U.S. DOT. ADR/RID HAZARD CLASS NOT APPLICABLE.
IMO/IMDG SHIPPING DESCRIPTION:
PETROLEUM LUBRICATING GREASE; MAY BE REGULATED AS DANGEROUS GOODS FOR
TRANSPORT UNDER THE IMDG CODE
ICAO/IATA SHIPPING DESCRIPTION:
PETROLEUM LUBRICATING GREASE; NOT REGULATED AS DANGEROUS GOODS FOR
TRANSPORT UNDER ICAO
| SECTION 15 REGULATORY INFORMATION | |
EPCRA 311/312 CATEGORIES:
1. IMMEDIATE (ACUTE) HEALTH EFFECTS: NO
2. DELAYED (CHRONIC) HEALTH EFFECTS: NO
3. FIRE HAZARD: NO
4. SUDDEN RELEASE OF PRESSURE HAZARD: NO
5. REACTIVITY HAZARD: NO
REGULATORY LISTS SEARCHED:
01-1=IARC GROUP 1
01-2A=IARC GROUP 2A
01-2B=IARC GROUP 2B
02=NTP CARCINOGEN
03=EPCRA 313
04=CA PROPOSITION 65
05=MA RTK
06=NJ RTK
07=PA RTK
THE FOLLOWING COMPONENTS OF THIS MATERIAL ARE FOUND ON THE REGULATORY
LISTS INDICATED.
ZINC DIALKYLDITHIOPHOSPHATE: 03, 06
CHEMICAL INVENTORIES:
ALL COMPONENTS COMPLY WITH THE FOLLOWING CHEMICAL INVENTORY REQUIREMENTS:
AICS (AUSTRALIA), DSL (CANADA), EINECS (EUROPEAN UNION), ENCS (JAPAN),
IECSC (CHINA), PICCS (PHILIPPINES), TSCA (UNITED STATES).
ONE OR MORE COMPONENTS DOES NOT COMPLY WITH THE FOLLOWING CHEMICAL
INVENTORY REQUIREMENTS: KECI (KOREA).
NEW JERSEY RTK CLASSIFICATION:
UNDER THE NEW JERSEY RIGHT-TO-KNOW ACT L. 1983 CHAPTER 315 N.J.S.A.
34:5A-1 ET. SEQ., THE PRODUCT IS TO BE IDENTIFIED AS FOLLOWS:
PETROLEUM OIL (GREASE)
WHMIS CLASSIFICATION:
THIS PRODUCT IS NOT CONSIDERED A CONTROLLED PRODUCT ACCORDING TO THE
CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS.
| SECTION 16 OTHER INFORMATION | |
NFPA RATINGS:
HEALTH 0
FLAMMABILITY 1
REACTIVITY 0
HMIS RATINGS:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
0-LEAST
1-SLIGHT
2-MODERATE
3-HIGH
4-EXTREME
PPE-PERSONAL PROTECTION EQUIPMENT INDEX RECOMMENDATION
*-CHRONIC EFFECT INDICATOR.
THESE VALUES ARE OBTAINED USING THE GUIDELINES OR PUBLISHED EVALUATIONS
PREPARED BY THE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) OR THE
NATIONAL PAINT AND COATING ASSOCIATION (FOR HMIS RATINGS).
LABEL RECOMMENDATION:
LABEL CATEGORY: GREASE 1 - GRS1
REVISION STATEMENT:
THIS REVISION UPDATES THE FOLLOWING SECTIONS OF THIS: 2, 16
REVISION DATE: FEBRUARY 26, 2009
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - THRESHOLD LIMIT VALUE
TWA - TIME WEIGHTED AVERAGE
STEL - SHORT-TERM EXPOSURE LIMIT
PEL - PERMISSIBLE EXPOSURE LIMIT
CAS - CHEMICAL ABSTRACT SERVICE NUMBER
ACGIH - AMERICAN CONFERENCE OF GOVERNMENT INDUSTRIAL HYGIENISTS
IMO/IMDG - INTERNATIONAL MARITIME DANGEROUS GOODS CODE
API - AMERICAN PETROLEUM INSTITUTE
MSDS - MATERIAL SAFETY DATA SHEET
CVX - CHEVRON
NFPA - NATIONAL FIRE PROTECTION ASSOCIATION (USA)
DOT - DEPARTMENT OF TRANSPORTATION (USA)
NTP - NATIONAL TOXICOLOGY PROGRAM (USA)
IARC - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
OSHA - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PREPARED ACCORDING TO THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND THE ANSI MSDS STANDARD (Z400.1) BY THE CHEVRON ENERGY
TECHNOLOGY COMPANY, 100 CHEVRON WAY, RICHMOND, CALIFORNIA 94802.
THE ABOVE INFORMATION IS BASED ON THE DATA OF WHICH WE ARE AWARE AND IS
BELIEVED TO BE CORRECT AS OF THE DATE HEREOF. SINCE THIS INFORMATION MAY
BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL AND WITH WHICH WE MAY BE
UNFAMILIAR AND SINCE DATA MADE AVAILABLE SUBSEQUENT TO THE DATE HEREOF
MAY SUGGEST MODIFICATIONS OF THE INFORMATION, WE DO NOT ASSUME ANY
RESPONSIBILITY FOR THE RESULTS OF ITS USE. THIS INFORMATION IS FURNISHED
UPON CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS OWN
DETERMINATION OF THE SUITABILITY OF THE MATERIAL FOR HIS PARTICULAR
PURPOSE.
BP
MATERIAL SAFETY DATA SHEET
| 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: ECD ULTRA LOW SULFUR DIESEL
MSDS #: 0000000795
HISTORIC MSDS #: NONE.
CODE: 0000000795
PRODUCT USE: FUEL.
SUPPLIER:
BP PRODUCTS NORTH AMERICA INC.
150 WEST WARRENVILLE ROAD
NAPERVILLE, ILLINOIS 60563-8460
USA
EMERGENCY HEALTH INFORMATION: 1 (800) 447-8735
OUTSIDE THE US: +1 703-527-3887 (CHEMTREC)
EMERGENCY SPILL INFORMATION: 1 (800) 424-9300 CHEMTREC (USA)
OTHER PRODUCT INFORMATION:
1 (866) 4 BP - MSDS
(866-427-6737 TOLL FREE - NORTH AMERICA)
EMAIL: BPCARES@BP.COM
| 2. COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT NAME CAS # % BY WEIGHT
PETROLEUM DISTILLATES 8008-20-6 100
| 3. HAZARDS IDENTIFICATION | |
PHYSICAL STATE: LIQUID.
COLOR: AMBER, TO VARIOUS COLORS, (MAY BE DYED RED.)
EMERGENCY OVERVIEW:
WARNING!
COMBUSTIBLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FLASH FIRE.
HARMFUL IF SWALLOWED.
ASPIRATION HAZARD.
HARMFUL OR FATAL IF LIQUID IS ASPIRATED INTO LUNGS.
CAUSES SKIN IRRITATION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
INHALATION CAUSES HEADACHES, DIZZINESS, DROWSINESS, AND NAUSEA, AND
MAY LEAD TO UNCONSCIOUSNESS.
DO NOT INGEST. IF INGESTED DO NOT INDUCE VOMITING. AVOID CONTACT WITH
EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR OR MIST. KEEP AWAY FROM HEAT,
SPARKS AND FLAME. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. USE
ONLY WITH ADEQUATE VENTILATION WASH THOROUGHLY AFTER HANDLING.
ROUTES OF ENTRY: DERMAL CONTACT. EYE CONTACT. INHALATION. INGESTION.
POTENTIAL HEALTH EFFECTS:
EYES: SLIGHTLY IRRITATING TO THE EYES.
SKIN: CAUSES SKIN IRRITATION.
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. INHALATION CAUSES HEADACHES,
DIZZINESS, DROWSINESS, AND NAUSEA, AND MAY LEAD TO UNCONSCIOUSNESS. SEE
TOXICOLOGICAL INFORMATION (SECTION 11).
INGESTION:
HARMFUL IF SWALLOWED. ASPIRATION HAZARD IF SWALLOWED - HARMFUL OR FATAL IF
LIQUID IS ASPIRATED INTO LUNGS. SEE TOXICOLOGICAL INFORMATION (SECTION 11).
MEDICAL CONDITIONS AGGRAVATED BY OVER-EXPOSURE: NONE IDENTIFIED.
SEE TOXICOLOGICAL INFORMATION (SECTION 11).
| 4. FIRST AID MEASURES | |
EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION OCCURS.
SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH
CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE. GET MEDICAL
ATTENTION IMMEDIATELY.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND
CAUSE DAMAGE. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
FLAMMABILITY OF THE PRODUCT: COMBUSTIBLE LIQUID.
FLASH POINT: 51.667 DEG. C (CLOSED CUP) TAGLIABUE.
EXPLOSION LIMITS:
LOWER: 0.6%
UPPER: 7.5%
PRODUCTS OF COMBUSTION:
THESE PRODUCTS ARE CARBON OXIDES (CO, CO2) (CARBON MONOXIDE, CARBON
DIOXIDE).
UNUSUAL FIRE/EXPLOSION HAZARDS:
COMBUSTIBLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE. VAPORS MAY
ACCUMULATE IN LOW OR CONFINED AREAS, TRAVEL CONSIDERABLE DISTANCE TO
SOURCE OF IGNITION AND FLASH BACK. RUNOFF TO SEWER MAY CREATE FIRE OR
EXPLOSION HAZARD.
EXPLOSIVE IN THE PRESENCE OF THE FOLLOWING MATERIALS OR CONDITIONS:
OPEN FLAMES, SPARKS AND STATIC DISCHARGE AND HEAT.
FIRE-FIGHTING MEDIA AND INSTRUCTIONS:
IN CASE OF FIRE, USE WATER FOG, FOAM, DRY CHEMICALS, OR CARBON DIOXIDE. DO
NOT FIGHT FIRE WHEN IT REACHES MATERIAL. WITHDRAW FROM FIRE AND LET IT
BURN. PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY
OF THE INCIDENT IF THERE IS A FIRE. FIRST MOVE PEOPLE OUT OF LINE-OF-SIGHT
OF THE SCENE AND AWAY FROM WINDOWS. COOL CONTAINING VESSELS WITH WATER JET
IN ORDER TO PREVENT PRESSURE BUILD-UP, AUTOIGNITION OR EXPLOSION.
PROTECTIVE CLOTHING (FIRE):
FIRE-FIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS (SCBA) AND FULL TURNOUT GEAR.
SPECIAL REMARKS ON FIRE HAZARDS: DO NOT USE WATER JET.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
IMMEDIATELY CONTACT EMERGENCY PERSONNEL. ELIMINATE ALL IGNITION SOURCES.
KEEP UNNECESSARY PERSONNEL AWAY. USE SUITABLE PROTECTIVE EQUIPMENT
(SEE SECTION: "EXPOSURE CONTROLS/PERSONAL PROTECTION"). FOLLOW ALL FIRE
FIGHTING PROCEDURES (SEE SECTION: "FIRE-FIGHTING MEASURES"). DO NOT TOUCH
OR WALK THROUGH SPILLED MATERIAL.
ENVIRONMENTAL PRECAUTIONS AND CLEAN-UP METHODS:
IF EMERGENCY PERSONNEL ARE UNAVAILABLE, CONTAIN SPILLED MATERIAL. FOR SMALL
SPILLS ADD ABSORBENT (SOIL MAY BE USED IN THE ABSENCE OF OTHER SUITABLE
MATERIALS) AND USE A NON-SPARKING OR EXPLOSION PROOF MEANS TO TRANSFER
MATERIAL TO A SEALED, APPROPRIATE CONTAINER FOR DISPOSAL. FOR LARGE SPILLS
DIKE SPILLED MATERIAL OR OTHERWISE CONTAIN MATERIAL TO ENSURE RUNOFF DOES
NOT REACH A WATERWAY. PLACE SPILLED MATERIAL IN AN APPROPRIATE CONTAINER
FOR DISPOSAL. AVOID CONTACT OF SPILLED MATERIAL WITH SOIL AND PREVENT
RUNOFF ENTERING SURFACE WATERWAYS. SEE SECTION 13 FOR WASTE DISPOSAL
INFORMATION.
PERSONAL PROTECTION IN CASE OF A LARGE SPILL:
SPLASH GOGGLES. CHEMICAL RESISTANT PROTECTIVE SUIT. VAPOR RESPIRATOR.
BOOTS. GLOVES.
CAUTION:
THE PROTECTION PROVIDED BY AIR-PURIFYING RESPIRATORS IS LIMITED. USE A
POSITIVE PRESSURE AIR-SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR
AN UNCONTROLLED RELEASE, IF EXPOSURE LEVELS ARE NOT KNOWN, OR IF
CONCENTRATIONS EXCEED THE PROTECTION LIMITS OF AIR-PURIFYING RESPIRATOR.
SUGGESTED PROTECTIVE CLOTHING MIGHT NOT BE SUFFICIENT; CONSULT A SPECIALIST
BEFORE HANDLING THIS PRODUCT.
| 7. HANDLING AND STORAGE | |
HANDLING:
ASPIRATION HAZARD IF SWALLOWED- CAN ENTER LUNGS AND CAUSE DAMAGE. NEVER
SIPHON BY MOUTH. DO NOT INGEST. IF INGESTED DO NOT INDUCE VOMITING. WHEN
USING DO NOT EAT, DRINK OR SMOKE. AVOID CONTACT WITH SKIN AND CLOTHING.
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. AVOID CONTACT WITH EYES.
USE ONLY WITH ADEQUATE VENTILATION AVOID BREATHING VAPOR OR MIST. KEEP AWAY
FROM HEAT, SPARKS AND FLAME. TO AVOID FIRE OR EXPLOSION, DISSIPATE STATIC
ELECTRICITY DURING TRANSFER BY GROUNDING AND BONDING CONTAINERS AND
EQUIPMENT BEFORE TRANSFERRING MATERIAL. USE EXPLOSION-PROOF ELECTRICAL
(VENTILATING, LIGHTING AND MATERIAL HANDLING) EQUIPMENT. WASH THOROUGHLY
AFTER HANDLING. EMPTY CONTAINERS MAY CONTAIN HARMFUL, FLAMMABLE/COMBUSTIBLE
OR EXPLOSIVE RESIDUE OR VAPORS. DO NOT CUT, GRIND, DRILL, WELD, REUSE OR
DISPOSE OF CONTAINERS UNLESS ADEQUATE PRECAUTIONS ARE TAKEN AGAINST THESE
HAZARDS.
STORAGE:
STORE IN A SEGREGATED AND APPROVED AREA. KEEP CONTAINER IN A COOL,
WELL-VENTILATED AREA. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY
FOR USE. AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME). STORE AND
USE ONLY IN EQUIPMENT/CONTAINERS DESIGNED FOR USE WITH THIS PRODUCT.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME OCCUPATIONAL EXPOSURE LIMITS
PETROLEUM DISTILLATES ACGIH TLV (UNITED STATES, 1/2006). SKIN
TWA: 200 MG/M3 8 HOUR(S).
CONTROL MEASURES:
PROVIDE EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP THE
RELEVANT AIRBORNE CONCENTRATIONS BELOW THEIR RESPECTIVE OCCUPATIONAL
EXPOSURE LIMITS. IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY WORK
PRACTICES, AIRBORNE EXPOSURES SHOULD BE CONTROLLED TO THE LOWEST EXTENT
PRACTICABLE.
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD.
PERSONAL PROTECTION:
EYES: AVOID CONTACT WITH EYES. SAFETY GLASSES WITH SIDE SHIELDS.
SKIN AND BODY:
AVOID CONTACT WITH SKIN AND CLOTHING. WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY:
USE ONLY WITH ADEQUATE VENTILATION DO NOT BREATHE VAPOR OR MIST. IF
VENTILATION IS INADEQUATE, USE A NIOSH CERTIFIED RESPIRATOR WITH AN ORGANIC
VAPOR CARTRIDGE AND P95 PARTICULATE FILTER.
CAUTION:
THE PROTECTION PROVIDED BY AIR-PURIFYING RESPIRATORS IS LIMITED. USE A
POSITIVE PRESSURE AIR-SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR
AN UNCONTROLLED RELEASE, IF EXPOSURE LEVELS ARE NOT KNOWN, OR IF
CONCENTRATIONS EXCEED THE PROTECTION LIMITS OF AIR-PURIFYING RESPIRATOR.
HANDS: WEAR GLOVES THAT CANNOT BE PENETRATED BY CHEMICALS OR OIL.
THE CORRECT CHOICE OF PROTECTIVE GLOVES DEPENDS UPON THE CHEMICALS BEING
HANDLED, THE CONDITIONS OF WORK AND USE, AND THE CONDITION OF THE GLOVES
(EVEN THE BEST CHEMICALLY RESISTANT GLOVE WILL BREAK DOWN AFTER REPEATED
CHEMICAL EXPOSURES). MOST GLOVES PROVIDE ONLY A SHORT TIME OF PROTECTION
BEFORE THEY MUST BE DISCARDED AND REPLACED. BECAUSE SPECIFIC WORK
ENVIRONMENTS AND MATERIAL HANDLING PRACTICES VARY, SAFETY PROCEDURES
SHOULD BE DEVELOPED FOR EACH INTENDED APPLICATION. GLOVES SHOULD THEREFORE
BE CHOSEN IN CONSULTATION WITH THE SUPPLIER/MANUFACTURER AND WITH A FULL
ASSESSMENT OF THE WORKING CONDITIONS.
CONSULT YOUR SUPERVISOR OR S.O.P. FOR SPECIAL HANDLING DIRECTIONS
CONSULT LOCAL AUTHORITIES FOR ACCEPTABLE EXPOSURE LIMITS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID.
ODOR: PETROLEUM
COLOR: AMBER, TO VARIOUS COLORS, (MAY BE DYED RED.)
HEAT OF COMBUSTION: NOT AVAILABLE.
BOILING POINT / RANGE: 171.11 TO 357.22 DEG. C
SPECIFIC GRAVITY: <1 (WATER = 1)
SOLUBILITY: NEGLIGIBLE <0.1%
VISCOSITY:
KINEMATIC: 1.8 TO 3.6 MM2/S (1.8 TO 3.6 CST) AT 37.778 DEG. C
| 10. STABILITY AND REACTIVITY | |
STABILITY AND REACTIVITY:
STABLE UNDER RECOMMENDED STORAGE AND HANDLING CONDITIONS
(SEE SECTION: "HANDLING AND STORAGE").
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, SPARKS AND FLAME. AVOID ALL POSSIBLE SOURCES OF
IGNITION (SPARK OR FLAME).
INCOMPATIBILITY WITH VARIOUS SUBSTANCES:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS:
OXIDIZING MATERIALS, ACIDS AND ALKALIS. HALOGENATED COMPOUNDS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THESE PRODUCTS ARE CARBON OXIDES (CO, CO2) (CARBON MONOXIDE, CARBON
DIOXIDE)
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
ASPIRATION OF THIS PRODUCT INTO THE LUNGS CAN CAUSE CHEMICAL PNEUMONIA AND
CAN BE FATAL. ASPIRATION INTO THE LUNGS CAN OCCUR WHILE VOMITING AFTER
INGESTION OF THIS PRODUCT DO NOT SIPHON BY MOUTH.
CHRONIC TOXICITY:
CARCINOGENIC EFFECTS:
NO COMPONENT OF THIS PRODUCT AT LEVELS GREATER THAN 0.1 % IS IDENTIFIED AS
A CARCINOGEN BY ACGIH OR THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
(IARC). NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN 0.1% IS
IDENTIFIED AS A CARCINOGEN BY THE U.S. NATIONAL TOXICOLOGY PROGRAM (NTP)
OR THE U.S. OCCUPATIONAL SAFETY AND HEALTH ACT (OSHA).
OTHER CHRONIC TOXICITY DATA:
MIDDLE DISTILLATE:
FROM SKIN-PAINTING STUDIES OF PETROLEUM DISTILLATES OF SIMILAR COMPOSITION
AND DISTILLATE RANGE, IT HAS BEEN SHOWN THAT THESE TYPES OF MATERIALS OFTEN
POSSESS WEAK CARCINOGENIC ACTIVITY IN LABORATORY ANIMALS. IN THESE TESTS,
THE MATERIAL IS PAINTED ON THE SHAVED BACKS OF MICE TWICE A WEEK FOR THEIR
LIFETIME. THE MATERIAL IS NOT WASHED OFF BETWEEN APPLICATIONS. THEREFORE,
THERE MAY BE A POTENTIAL RISK OF SKIN CANCER FROM PROLONGED OR REPEATED
SKIN CONTACT WITH THIS PRODUCT IN THE ABSENCE OF GOOD PERSONAL HYGIENE.
THIS PARTICULAR PRODUCT HAS NOT BEEN TESTED FOR CARCINOGENIC ACTIVITY, BUT
WE HAVE CHOSEN TO BE CAUTIOUS IN LIGHT OF THE FINDINGS WITH OTHER
DISTILLATE STREAMS.
OCCASIONAL SKIN CONTACT WITH THIS PRODUCT IS NOT EXPECTED TO HAVE SERIOUS
EFFECTS, BUT GOOD PERSONAL HYGIENE SHOULD BE PRACTICED AND REPEATED SKIN
CONTACT AVOIDED. THIS PRODUCT CAN ALSO BE EXPECTED TO PRODUCE SKIN
IRRITATION UPON PROLONGED OR REPEATED SKIN CONTACT. PERSONAL HYGIENE
MEASURES TAKEN TO PREVENT SKIN IRRITATION ARE EXPECTED TO BE ADEQUATE TO
PREVENT RISK OF SKIN CANCER.
DIESEL EXHAUST PARTICULATES HAVE BEEN CLASSIFIED BY THE NATIONAL
TOXICOLOGICAL PROGRAM (NTP) TO BE A REASONABLY ANTICIPATED HUMAN
CARCINOGEN. EXPOSURE SHOULD BE MINIMIZED TO REDUCE POTENTIAL RISK.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
TOXIC TO AQUATIC ORGANISMS. MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
MOBILITY:
SPILLAGES MAY PENETRATE THE SOIL CAUSING GROUND WATER CONTAMINATION.
BIOACCUMULATIVE POTENTIAL:
THIS PRODUCT IS NOT EXPECTED TO BIOACCUMULATE THROUGH FOOD CHAINS IN THE
ENVIRONMENT.
OTHER ECOLOGICAL INFORMATION:
SPILLS MAY FORM A FILM ON WATER SURFACES CAUSING PHYSICAL DAMAGE TO
ORGANISMS. OXYGEN TRANSFER COULD ALSO BE IMPAIRED.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE INFORMATION:
AVOID CONTACT OF SPILLED MATERIAL AND RUNOFF WITH SOIL AND SURFACE
WATERWAYS. CONSULT AN ENVIRONMENTAL PROFESSIONAL TO DETERMINE IF LOCAL,
REGIONAL OR NATIONAL REGULATIONS WOULD CLASSIFY SPILLED OR CONTAMINATED
MATERIALS AS HAZARDOUS WASTE. USE ONLY APPROVED TRANSPORTERS, RECYCLERS,
TREATMENT, STORAGE OR DISPOSAL FACILITIES. DISPOSE OF IN ACCORDANCE WITH
ALL APPLICABLE LOCAL AND NATIONAL REGULATIONS.
CONSULT YOUR LOCAL OR REGIONAL AUTHORITIES.
| 14. TRANSPORT INFORMATION | |
INTERNATIONAL TRANSPORT REGULATIONS:
REGULATORY INFORMATION UN NUMBER PROPER SHIPPING NAME CLASS
DOT CLASSIFICATION NA1993 DIESEL FUEL COMBUSTIBLE
LIQUID.
TDG CLASSIFICATION UN1202 GAS OIL 3
IMDG CLASSIFICATION UN1202 GAS OIL 3
IATA CLASSIFICATION UN1202 GAS OIL 3
REGULATORY INFORMATION PACKING GROUP LABEL ADDITIONAL INFORMATION
DOT CLASSIFICATION III REPORTABLE QUANTITY:
100 LBS. (45.36 KG)
TDG CLASSIFICATION III CLASS 3, NOT DETERMINED.
FLAMMABLE
LIQUIDS
IMDG CLASSIFICATION III CLASS 3 - NOT DETERMINED.
FLAMMABLE
LIQUIDS
IATA CLASSIFICATION III CLASS 3, NOT DETERMINED.
FLAMMABLE
LIQUIDS
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
US INVENTORY (TSCA): IN COMPLIANCE.
TSCA 12(B) ONE-TIME EXPORT NOTIFICATION: NAPHTHALENE
THIS PRODUCT IS NOT REGULATED UNDER SECTION 302 OF SARA AND 40 CFR PART
355.
SARA 311/312 MSDS DISTRIBUTION - CHEMICAL INVENTORY - HAZARD
IDENTIFICATION:
ECD ULTRA LOW SULFUR DIESEL:
FIRE HAZARD, IMMEDIATE (ACUTE) HEALTH HAZARD, DELAYED (CHRONIC) HEALTH
HAZARD
SARA 313:
FORM R - REPORTING REQUIREMENTS:
THIS PRODUCT DOES NOT CONTAIN ANY HAZARDOUS INGREDIENTS AT OR ABOVE
REGULATED THRESHOLDS.
SUPPLIER NOTIFICATION:
THIS PRODUCT DOES NOT CONTAIN ANY HAZARDOUS INGREDIENTS AT OR ABOVE
REGULATED THRESHOLDS.
CERCLA SECTIONS 102A/103 HAZARDOUS SUBSTANCES (40 CFR PART 302.4):
O-XYLENE: 1000 LBS. (453.6 KG)
NAPHTHALENE: 100 LBS. (45.36 KG)
XYLENE: 100 LBS. (45.36 KG)
ETHYLBENZENE: 1000 LBS. (453.6 KG)
XYLENE: 100 LBS. (45.36 KG)
CUMENE: 5000 LBS. (2268 KG)
XYLENE: 100 LBS. (45.36 KG)
STATE REGULATIONS:
MASSACHUSETTS RTK: STRAIGHT RUN KEROSINE; 1,2,4-TRIMETHYLBENZENE
NEW JERSEY: STRAIGHT RUN KEROSINE; 1,2,4-TRIMETHYLBENZENE
PENNSYLVANIA RTK:
STRAIGHT RUN KEROSINE (GENERIC ENVIRONMENTAL HAZARD);
1,2,4-TRIMETHYLBENZENE (ENVIRONMENTAL HAZARD, GENERIC ENVIRONMENTAL HAZARD)
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER. NAPHTHALENE; ETHYLBENZENE
PROP 65 CHEMICALS WILL RESULT UNDER CERTAIN CONDITIONS FROM THE USE OF
THIS MATERIAL. FOR EXAMPLE, BURNING FUELS PRODUCES COMBUSTION PRODUCTS
INCLUDING DIESEL EXHAUST, A PROP 65 CARCINOGEN, AND CARBON MONOXIDE, A
PROP 65 REPRODUCTIVE TOXIN.
INVENTORIES:
AUSTRALIAN INVENTORY (AICS): NOT DETERMINED.
CANADA INVENTORY (DSL): IN COMPLIANCE.
CHINA INVENTORY (IECS): NOT DETERMINED.
EC INVENTORY (EINECS/ELINCS): NOT DETERMINED.
JAPAN INVENTORY (ENCS): NOT DETERMINED.
KOREA INVENTORY (ECL): NOT DETERMINED.
PHILIPPINE INVENTORY (PICCS): NOT DETERMINED.
| 16. OTHER INFORMATION | |
LABEL REQUIREMENTS:
WARNING!
COMBUSTIBLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FLASH FIRE.
HARMFUL IF SWALLOWED.
ASPIRATION HAZARD.
HARMFUL OR FATAL IF LIQUID IS ASPIRATED INTO LUNGS.
CAUSES SKIN IRRITATION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
INHALATION CAUSES HEADACHES, DIZZINESS, DROWSINESS, AND NAUSEA, AND MAY
LEAD TO UNCONSCIOUSNESS.
HMIS(R*) RATING:
HEALTH 0*
FLAMMABILITY 2
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 0
FIRE HAZARD 2
INSTABILITY 0
SPECIFIC HAZARD
HISTORY:
DATE OF ISSUE: 07/05/2006.
DATE OF PREVIOUS ISSUE: NO PREVIOUS VALIDATION.
PREPARED BY: PRODUCT STEWARDSHIP
NOTICE TO READER:
NOTICE:
THIS MATERIAL SAFETY DATA SHEET IS BASED UPON DATA CONSIDERED TO BE
ACCURATE AT THE TIME OF ITS PREPARATION. DESPITE OUR EFFORTS, IT MAY NOT
BE UP TO DATE OR APPLICABLE TO THE CIRCUMSTANCES OF ANY PARTICULAR CASE.
WE ARE NOT RESPONSIBLE FOR ANY DAMAGE OR INJURY RESULTING FROM ABNORMAL
USE, FROM ANY FAILURE TO FOLLOW APPROPRIATE PRACTICES OR FROM HAZARDS
INHERENT IN THE NATURE OF THE PRODUCT.
PRODUCT CODE: 0000000795
VERSION: 1
FORMAT: US-COMP
LANGUAGE: ENGLISH. (ENGLISH)
BUILD: 4.2.8
LOCTITE(R*)
MATERIAL SAFETY DATA SHEET
HENKEL TECHNOLOGIES
REVISION DATE: 10/20/2003
ISSUE DATE: 10/20/2003
| 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: 242(R*) THREADLOCKER
ITEM NUMBER: 24231
PRODUCT TYPE: ANAEROBIC SEALANT
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL LOCTITE CORPORATION
1001 TROUT BROOK CROSSING
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: 860.571.5100
EMERGENCY TELEPHONE: 860.571.5100
INTERNET: WWW.LOCTITE.COM
| 2. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENTS % ACGIH TLV OSHA PEL OTHER
POLYGLYCOL DIMETHACRYLATE 60-100 NONE NONE
POLYGLYCOL OLEATE 10-30 NONE NONE NONE
9004-96-0
ALKYLENE GLYCOL 1-5 NONE NONE NONE
CUMENE HYDROPEROXIDE 1-5 NONE NONE 1 PPM (6 MG/M3)
80-15-9 SKIN (WEEL)
| 3. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
PHYSICAL STATE: LIQUID
COLOR: BLUE
ODOR: MILD
WARNING:
CAUSES EYE IRRITATION.
MAY CAUSE SKIN IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
HMIS:
HEALTH 1*
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION SEE SECTION 8
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS:
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION.
SKIN CONTACT: MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE SKIN IRRITATION.
EYE CONTACT: CONTACT WITH EYES WILL CAUSE IRRITATION.
INGESTION: NOT EXPECTED TO BE HARMFUL BY INGESTION.
EXISTING CONDITIONS AGGRAVATED BY EXPOSURE: SKIN DISORDERS.
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 4. FIRST AID MEASURES | |
INHALATION:
REMOVE TO FRESH AIR. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH
CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
EYE CONTACT:
FLUSH WITH COPIOUS AMOUNTS OF WATER, PREFERABLY, LUKEWARM WATER FOR AT
LEAST 15 MINUTES, HOLDING EYELIDS OPEN ALL THE TIME. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM. OBTAIN MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
FLASH POINT: GREATER THAN 93 DEG. C (200 DEG. F) TAGLIABUE CLOSED CUP
AUTOIGNITION TEMPERATURE: NOT AVAILABLE
FLAMMABLE/EXPLOSIVE LIMITS-LOWER %: NOT AVAILABLE
FLAMMABLE/EXPLOSIVE LIMITS-UPPER %: NOT AVAILABLE
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIRE FIGHTING PROCEDURES: NONE
UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SULFUR. OXIDES OF NITROGEN. IRRITATING ORGANIC
VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
ENVIRONMENTAL PRECAUTIONS:
PREVENT PRODUCT FROM ENTERING DRAINS OR OPEN WATERS.
CLEAN-UP METHODS:
SOAK UP WITH INERT ABSORBENT. STORE IN A PARTLY FILLED, CLOSED CONTAINER
UNTIL DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING: AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE: FOR SAFE STORAGE, STORE AT OR BELOW 38 DEG. C (100 DEG. F).
INCOMPATIBLE PRODUCTS: REFER TO SECTION 10.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL LOCTITE CUSTOMER
SERVICE AT (800) 243-4874.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
NO SPECIFIC VENTILATION REQUIREMENTS NOTED, BUT FORCED VENTILATION MAY
STILL BE REQUIRED IF CONCENTRATIONS EXCEED OCCUPATIONAL EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT. NEOPRENE GLOVES. BUTYL RUBBER GLOVES. NATURAL RUBBER GLOVES.
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SEE SECTION 2 FOR EXPOSURE LIMITS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: BLUE
ODOR: MILD
VAPOR PRESSURE: LESS THAN 5 MMHg AT 27 DEG. C (80 DEG. F)
PH: NOT APPLICABLE
BOILING POINT/RANGE: GREATER THAN 149 DEG. C (300 DEG. F)
MELTING POINT/RANGE: NOT AVAILABLE
SPECIFIC GRAVITY: 1.1
VAPOR DENSITY: NOT AVAILABLE
EVAPORATION RATE: NOT AVAILABLE
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE
VOC CONTENT: 4.48%; 49.3 GRAMS/LITER (EPA METHOD 24}
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SULFUR. OXIDES OF NITROGEN. IRRITATING ORGANIC
VAPORS.
INCOMPATABILITY: STRONG OXIDIZERS.
CONDITIONS TO AVOID:
SEE "HANDLING AND STORAGE" (SECTION 7) AND "INCOMPATABILITY" (SECTION 10).
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT TOXICITY DATA:
ACUTE ORAL LD50 GREATER THAN 10, 000 MG/KG (RAT).
ACUTE DERMAL LD50 GREATER THAN 5000 MG/KG (RABBIT).
CARCINOGEN STATUS:
HAZARDOUS COMPONENTS NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
POLYGLYCOL NO NO NO
DIMETHACRYLATE
POLYGLYCOL OLEATE NO NO NO
ALKYLENE GLYCOL NO NO NO
CUMENE HYDROPEROXIDE NO NO NO
LITERATURE REFERENCED TARGET ORGAN & OTHER HEALTH EFFECTS:
HAZARDOUS COMPONENTS HEALTH EFFECTS/TARGET ORGANS
POLYGLYCOL DIMETHACRYLATE ALLERGEN, IRRITANT
POLYGLYCOL OLEATE IRRITANT
ALKYLENE GLYCOL IRRITANT
CUMENE HYDROPEROXIDE ALLERGEN, CENTRAL NERVOUS SYSTEM,
CORROSIVE, IRRITANT, MUTAGEN
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL GOVERNMENTAL REGULATIONS.
EPA HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: UNRESTRICTED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: UNRESTRICTED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: UNRESTRICTED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
MARINE POLLUTANT: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE.
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMUS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH HAZARD, DELAYED HEALTH HAZARD
CERCLA/SARA 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). CUMENE HYDROPEROXIDE
(CAS# 80-15-9).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. 1,4-DIOXANE
(CAS# 123-91-1). ETHYLENE OXIDE (CAS# 75-21-8). SILICA, QUARTZ
(CAS# 14808-60-7). ARSENIC (CAS# 7440-38-2). LEAD (CAS# 7439-92-1).
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE DOMESTIC
SUBSTANCES LIST.
WHMIS HAZARD CLASS: D.2.A, D.2.B
| 16. OTHER INFORMATION | |
THIS MATERIAL SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION
IN SECTIONS: NEW MATERIAL SAFETY DATA SHEET FORMAT.
PREPARED BY: STEPHEN REPETTO, SENIOR HEALTH & REGULATORY AFFAIRS SPECIALIST
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL LOCTITE CORPORATION DOES NOT
ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY PERSONS OVER WHOSE
METHODS HENKEL LOCTITE CORPORATION HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL LOCTITE'S PRODUCTS OR
ANY PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO
ADOPT SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY
AND PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND
USE OF ANY OF HENKEL LOCTITE CORPORATION'S PRODUCTS. IN LIGHT OF THE
FOREGOING, HENKEL LOCTITE CORPORATION SPECIFICALLY DISCLAIMS ALL
WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY AND
FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR USE OF HENKEL
LOCTITE CORPORATION'S PRODUCTS. HENKEL LOCTITE CORPORATION FURTHER
DISCLAIMS ANY LIABILITY FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY
KIND, INCLUDING LOST PROFITS.
LOCTITE(R*)
MATERIAL SAFETY DATA SHEET
HENKEL TECHNOLOGIES
REVISION DATE: 11/05/2003
ISSUE DATE: 11/05/2003
| 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: 567 THREAD SEALANT PST(R*) PIPE SEALANT WITH PTFE
ITEM NUMBER: 56747
PRODUCT TYPE: ANAEROBIC SEALANT
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL LOCTITE CORPORATION
1001 TROUT BROOK CROSSING
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: 860.571.5100
EMERGENCY TELEPHONE: 860.571.5100
INTERNET: WWW.LOCTITE.COM
| 2. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENTS % ACGIH TLV OSHA PEL OTHER
FUMARATE RESIN 30-60 NONE NONE NONE
POLYGLYCOL LAURATE 10-30 NONE NONE NONE
POLYGLYCOL DIMETHACRYLATE 10-30 NONE NONE
CUMENE HYDROPEROXIDE 1-5 NONE NONE 1 PPM (6 MG/M3)
80-15-9 SKIN (WEEL)
| 3. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
PHYSICAL STATE: PASTE
COLOR: WHITE
ODOR: MILD
WARNING:
CAUSES EYE IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
HMIS:
HEALTH 1*
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION SEE SECTION 8
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS:
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION.
SKIN CONTACT: MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CONTACT WITH EYES WILL CAUSE IRRITATION.
INGESTION: NOT EXPECTED TO BE HARMFUL BY INGESTION.
EXISTING CONDITIONS AGGRAVATED BY EXPOSURE: NONE KNOWN
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 4. FIRST AID MEASURES | |
INHALATION:
REMOVE TO FRESH AIR. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH
CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
EYE CONTACT:
FLUSH WITH COPIOUS AMOUNTS OF WATER, PREFERABLY, LUKEWARM WATER FOR AT
LEAST 15 MINUTES, HOLDING EYELIDS OPEN ALL THE TIME. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM. OBTAIN MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
FLASH POINT: GREATER THAN 93 DEG. C (200 DEG. F) TAGLIABUE CLOSED CUP
AUTOIGNITION TEMPERATURE: NOT AVAILABLE
FLAMMABLE/EXPLOSIVE LIMITS-LOWER %: NOT AVAILABLE
FLAMMABLE/EXPLOSIVE LIMITS-UPPER %: NOT AVAILABLE
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIRE FIGHTING PROCEDURES: NONE
UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SULFUR. OXIDES OF NITROGEN. TOXIC FLUORINE
COMPOUNDS. IRRITATING ORGANIC VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
ENVIRONMENTAL PRECAUTIONS:
PREVENT PRODUCT FROM ENTERING DRAINS OR OPEN WATERS.
CLEAN-UP METHODS:
SOAK UP WITH INERT ABSORBENT. STORE IN A PARTLY FILLED, CLOSED CONTAINER
UNTIL DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING: AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE: FOR SAFE STORAGE, STORE AT OR BELOW 38 DEG. C (100 DEG. F).
INCOMPATIBLE PRODUCTS: REFER TO SECTION 10.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL LOCTITE CUSTOMER
SERVICE AT (800) 243-4874.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
NO SPECIFIC VENTILATION REQUIREMENTS NOTED, BUT FORCED VENTILATION MAY
STILL BE REQUIRED IF CONCENTRATIONS EXCEED OCCUPATIONAL EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SEE SECTION 2 FOR EXPOSURE LIMITS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: WHITE
ODOR: MILD
VAPOR PRESSURE: LESS THAN 5 MMHg AT 27 DEG. C (80 DEG. F)
PH: NOT APPLICABLE
BOILING POINT/RANGE: GREATER THAN 149 DEG. C (300 DEG. F)
MELTING POINT/RANGE: NOT AVAILABLE
SPECIFIC GRAVITY: 1.14
VAPOR DENSITY: NOT AVAILABLE
EVAPORATION RATE: NOT AVAILABLE
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE
VOC CONTENT: 8.6%; 98.04 GRAMS/LITER (EPA METHOD 24)
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SULFUR. OXIDES OF NITROGEN. TOXIC FLUORINE
COMPOUNDS. IRRITATING ORGANIC VAPORS.
INCOMPATABILITY: STRONG OXIDIZERS.
CONDITIONS TO AVOID:
SEE "HANDLING AND STORAGE" (SECTION 7) AND "INCOMPATABILITY" (SECTION 10).
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT TOXICITY DATA:
ACUTE ORAL LD50 GREATER THAN 10, 000 MG/KG (RAT).
ACUTE DERMAL LD50 GREATER THAN 2000 MG/KG (RABBIT) (ESTIMATED).
CARCINOGEN STATUS:
HAZARDOUS COMPONENTS NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
FUMARATE RESIN NO NO NO
POLYGLYCOL LAURATE NO NO NO
POLYGLYCOL DIMETHACRYLATE NO NO NO
CUMENE HYDROPEROXIDE NO NO NO
LITERATURE REFERENCED TARGET ORGAN & OTHER HEALTH EFFECTS:
HAZARDOUS COMPONENTS HEALTH EFFECTS/TARGET ORGANS
FUMARATE RESIN ALLERGEN, IRRITANT
POLYGLYCOL LAURATE ALLERGEN, IRRITANT
POLYGLYCOL DIMETHACRYLATE ALLERGEN, IRRITANT
CUMENE HYDROPEROXIDE ALLERGEN, CENTRAL NERVOUS SYSTEM, CORROSIVE,
IRRITANT, MUTAGEN
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL GOVERNMENTAL REGULATIONS.
EPA HAZARDOUS WASTE NUMBER: NOT HAZARDOUS
| 14. TRANSPORT INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: UNRESTRICTED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: UNRESTRICTED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: UNRESTRICTED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
MARINE POLLUTANT: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION:
BISPHENOL A DIGLYCIDYL ETHER (CAS# 1675-54-3).
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMUS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH HAZARD, DELAYED HEALTH HAZARD
CERCLA/SARA 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). CUMENE HYDROPEROXIDE
(CAS# 80-15-9).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. EPICHLOROHYDRIN
(CAS# 106-89-8). 1,4-DIOXANE (CAS# 123-91-1). BENZENE (CAS# 71-43-2).
ACETALDEHYDE (CAS# 75-07-0). ETHYLENE OXIDE (CAS# 75-21-8). O-TOLUIDINE
(CAS# 95-53-4).
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE DOMESTIC
SUBSTANCES LIST.
WHMIS HAZARD CLASS: D.2.A, D.2.B
| 16. OTHER INFORMATION | |
THIS MATERIAL SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION
IN SECTIONS: NEW MATERIAL SAFETY DATA SHEET FORMAT.
PREPARED BY: STEPHEN REPETTO, SENIOR HEALTH & REGULATORY AFFAIRS SPECIALIST
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL LOCTITE CORPORATION DOES NOT
ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY PERSONS OVER WHOSE
METHODS HENKEL LOCTITE CORPORATION HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL LOCTITE'S PRODUCTS OR
ANY PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO
ADOPT SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY
AND PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND
USE OF ANY OF HENKEL LOCTITE CORPORATION'S PRODUCTS. IN LIGHT OF THE
FOREGOING, HENKEL LOCTITE CORPORATION SPECIFICALLY DISCLAIMS ALL
WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY AND
FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR USE OF HENKEL
LOCTITE CORPORATION'S PRODUCTS. HENKEL LOCTITE CORPORATION FURTHER
DISCLAIMS ANY LIABILITY FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY
KIND, INCLUDING LOST PROFITS.
TROJAN(R*)
BATTERY COMPANY
TROJAN BATTERY COMPANY
LEAD / ACID BATTERY
MATERIAL SAFETY DATA SHEET
HAZARD RATING:
H 3
F 1
R 2
COR
| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |
MANUFACTURER'S NAME: TROJAN BATTERY COMPANY
ADDRESS:
12380 CLARK ST.
SANTA FE SPRINGS, CA 90670
EMERGENCY TELEPHONE NO.:
CHEMTREC: (800) 424-9300
INTERNATIONAL: (703) 527-3887
OTHER INFORMATION CALLS:
562-236-3000
800-423-6569
PERSON RESPONSIBLE FOR PREPARATION:
ISMAEL PEDROZA, JR. DIRECTOR OF EH&S
REVISION DATE: MAY 13, 2010
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
C.A.S. PRINCIPAL HAZARDOUS COMPONENT(S) HAZARD CATEGORY %
(CHEMICAL & COMMON NAME(S)
7439-92-1 LEAD/LEAD OXIDE/LEAD SULFATE ACUTE-CHRONIC 60 - 97%
7440-36-0 ANTIMONY CHRONIC 1.5 - 4%
7440-38-2 ARSENIC ACUTE-CHRONIC <1%
7664-93-9 SULFURIC ACID REACTIVE-OXIDIZER 10 - 38%
(BATTERY ELECTROLYTE) ACUTE-CHRONIC
7440-70-2 CALCIUM REACTIVE <0.15%
7440-31-5 TIN CHRONIC <0.3%
PRINCIPAL HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL-TWA
(CHEMICAL & COMMON NAME(S)
LEAD/LEAD OXIDE/LEAD SULFATE 0.05 MG/M3 0.05 MG/M3
ANTIMONY 0.5 MG/M3 0.5 MG/M3
ARSENIC 0.01 MG/M3 0.01 MG/M3
SULFURIC ACID (BATTERY ELECTROLYTE) 1.0 MG/M3 1.0 MG/M3
CALCIUM NOT ESTABLISHED NOT ESTABLISHED
TIN 2.0 MG/M3 NOT ESTABLISHED
NOTE:
PEL'S FOR INDIVIDUAL STATES MAY DIFFER FROM OSHA PEL'S. CHECK WITH LOCAL
AUTHORITIES FOR THE APPLICABLE STATE PEL'S.
OSHA - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
NIOSH - NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH.
COMMON NAME:
(USED ON LABEL) (TRADE NAME & SYNONYMS): LEAD/ACID STORAGE BATTERY
CHEMICAL FAMILY: TOXIC AND CORROSIVE MATERIAL MIXTURE
CHEMICAL NAME: LEAD/ACID STORAGE BATTERY
FORMULA: LEAD AND ACID (ELECTROLYTE)
| SECTION 3 - HAZARD IDENTIFICATION | |
SIGNS AND SYMPTOMS OF EXPOSURE:
1. ACUTE HAZARDS:
DO NOT OPEN BATTERY. AVOID CONTACT WITH INTERNAL COMPONENTS. INTERNAL
COMPONENTS INCLUDE LEAD AND LIQUID ELECTROLYTE.
ELECTROLYTE:
ELECTROLYTE IS CORROSIVE AND CONTACT MAY CAUSE SKIN IRRITATION AND CHEMICAL
BURNS. ELECTROLYTE CAUSES SEVERE IRRITATION AND BURNS OF EYES, NOSE AND
THROAT. INGESTION CAN CAUSE SEVERE BURNS AND VOMITING.
LEAD:
DIRECT SKIN OR EYE CONTACT MAY CAUSE LOCAL IRRITATION. INHALATION OR
INGESTION OF LEAD DUST OR FUMES MAY RESULT IN HEADACHE, NAUSEA, VOMITING,
ABDOMINAL SPASMS, FATIGUE, SLEEP DISTURBANCES, WEIGHT LOSS, ANEMIA AND LEG,
ARM AND JOINT PAIN.
2. SUBCHRONIC AND CHRONIC HEALTH EFFECTS:
ELECTROLYTE:
REPEATED CONTACT WITH SULFURIC ACID BATTERY ELECTROLYTE FLUID MAY CAUSE
DRYING OF THE SKIN WHICH MAY RESULT IN IRRITATION, DERMATITIS, AND SKIN
BURNS. REPEATED EXPOSURE TO SULFURIC ACID MIST MAY CAUSE EROSION OF TEETH,
CHRONIC EYE IRRITATION AND/OR CHRONIC INFLAMMATION OF THE NOSE, THROAT AND
LUNGS.
LEAD:
PROLONGED EXPOSURE MAY CAUSE CENTRAL NERVOUS SYSTEM DAMAGE,
GASTROINTESTINAL DISTURBANCES, ANEMIA, WRIST-DROP AND KIDNEY DYSFUNCTION.
PREGNANT WOMEN SHOULD BE PROTECTED FROM EXCESSIVE EXPOSURE TO PREVENT LEAD
FROM CROSSING THE PLACENTAL BARRIER AND CAUSING INFANT NEUROLOGICAL
DISORDERS.
CALIFORNIA PROPOSITION 65 WARNING:
BATTERY POSTS, TERMINALS, AND RELATED ACCESSORIES CONTAIN LEAD AND LEAD
COMPOUNDS, CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND
REPRODUCTIVE HARM, AND DURING CHARGING, STRONG INORGANIC ACID MISTS
CONTAINING SULFURIC ACID ARE EVOLVED, A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER. WASH HANDS AFTER HANDLING.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
IF BATTERY IS BROKEN OR MATERIAL IS SPILLED, THEN PERSONS WITH THE
FOLLOWING MEDICAL CONDITIONS MUST TAKE PRECAUTIONS:
PULMONARY EDEMA, BRONCHITIS, EMPHYSEMA, DENTAL EROSION AND
TRACHEOBRONCHITIS.
ROUTES OF ENTRY:
INHALATION: YES
INGESTION: YES
EYE CONTACT: YES
SKIN CONTACT: YES
CHEMICAL(S) LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN:
PROPOSITION 65: YES
NATIONAL TOXICOLOGY PROGRAM: YES
I.A.R.C. MONOGRAPHS: YES
OSHA: NO
EPA CAG: YES
NIOSH: YES
| SECTION 4 - FIRST AID MEASURES | |
EMERGENCY AND FIRST AID PROCEDURES:
CONTACT WITH INTERNAL COMPONENTS IF BATTERY IS OPENED, BROKEN OR SPILLED.
1. INHALATION:
REMOVE TO FRESH AIR AND PROVIDE MEDICAL OXYGEN/CPR IF NEEDED.
OBTAIN MEDICAL ATTENTION.
2. EYES:
IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES, HOLD EYELIDS OPEN.
OBTAIN MEDICAL ATTENTION.
3. SKIN:
FLUSH CONTACTED AREA WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING AND OBTAIN MEDICAL ATTENTION IF NECESSARY.
4. INGESTION:
DO NOT INDUCE VOMITING. IF CONSCIOUS DRINK LARGE AMOUNTS OF WATER/MILK.
OBTAIN MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.
| SECTION 5 - FIREFIGHTING MEASURES | |
FLASH POINT: NOT APPLICABLE
FLAMMABLE LIMITS IN AIR % BY VOLUME (WHEN CHARGING):
HYDROGEN (H2)
LOWER: 4.1%
UPPER: 74.2%
EXTINGUISHER MEDIA: CLASS ABC, CO2, HALON
AUTO-IGNITION TEMPERATURE: POLYPROPYLENE 675 DEG. F
SPECIAL FIRE FIGHTING PROCEDURES:
LEAD-ACID BATTERIES DO NOT BURN OR BURN WITH DIFFICULTY. DO NOT USE WATER
ON FIRES WHERE MOLTEN METAL IS PRESENT. EXTINGUISH FIRE WITH AGENT SUITABLE
FOR SURROUNDING COMBUSTIBLE MATERIALS. COOL EXTERIOR OF BATTERY IF EXPOSED
TO FIRE TO PREVENT RUPTURE. THE ACID MIST AND VAPORS GENERATED BY HEAT OR
FIRE ARE CORROSIVE. USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS
(SCBA) AND FULL PROTECTIVE EQUIPMENT OPERATED IN POSITIVE-PRESSURE MODE.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
HYDROGEN GAS AND SULFURIC ACID VAPORS ARE GENERATED UPON OVERCHARGE AND
POLYPROPYLENE CASE FAILURE. VENTILATE CHARGING AREAS AS PER ACGIH
INDUSTRIAL VENTILATION:
A MANUAL OF RECOMMENDED PRACTICE AND NATIONAL FIRE CODE, 1980 VOL. 1, P.
12, B-9, 10. HYDROGEN GAS MAY BE FLAMMABLE OR EXPLOSIVE WHEN MIXED WITH
AIR, OXYGEN, CHLORINE. AVOID OPEN FLAMES/SPARKS/OTHER SOURCES OF IGNITION
NEAR BATTERY. TO AVOID RISK OF FIRE OR EXPLOSION, KEEP SPARKS OR OTHER
SOURCES OF IGNITION AWAY FROM BATTERIES AND DO NOT ALLOW METALLIC MATERIALS
TO SIMULTANEOUSLY CONTACT NEGATIVE AND POSITIVE TERMINALS OF CELLS AND
BATTERIES. SULFURIC ACID REACTS VIOLENTLY WITH WATER/ORGANICS.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PROCEDURES FOR CLEANUP:
STOP RELEASE, IF POSSIBLE. AVOID CONTACT WITH ANY SPILLED MATERIAL. CONTAIN
SPILL, ISOLATE HAZARD AREA, AND DENY ENTRY. LIMIT SITE ACCESS TO EMERGENCY
RESPONDERS. NEUTRALIZE WITH SODIUM BICARBONATE, SODA ASH, LIME OR OTHER
NEUTRALIZING AGENT. PLACE BATTERY IN SUITABLE CONTAINER FOR DISPOSAL.
DISPOSE OF CONTAMINATED MATERIAL IN ACCORDANCE WITH APPLICABLE LOCAL, STATE
AND FEDERAL REGULATIONS. SODIUM BICARBONATE, SODA ASH, SAND, LIME OR OTHER
NEUTRALIZING AGENT SHOULD BE KEPT ON-SITE FOR SPILL REMEDIATION.
PERSONAL PRECAUTIONS:
ACID RESISTANT APRONS, BOOTS AND PROTECTIVE CLOTHING. ANSI APPROVED SAFETY
GLASSES WITH SIDE SHIELDS/FACE SHIELD RECOMMENDED. VENTILATE ENCLOSED
AREAS.
ENVIRONMENTAL PRECAUTIONS:
LEAD AND ITS COMPOUNDS AND SULFURIC ACID CAN POSE A SEVERE THREAT TO THE
ENVIRONMENT. CONTAMINATION OF WATER, SOIL, AND AIR SHOULD BE PREVENTED.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
KEEP AWAY FROM FLAMES DURING AND IMMEDIATELY AFTER CHARGING. COMBUSTION OR
OVERCHARGING MAY CREATE OR LIBERATE TOXIC AND HAZARDOUS GASES AND LIQUIDS
INCLUDING HYDROGEN, SULFURIC ACID MIST, SULFUR DIOXIDE, SULFUR TRIOXIDE,
STIBINE, ARSINE AND SULFURIC ACID. STORE BATTERIES IN COOL, DRY, WELL
VENTILATED AREA. DO NOT SHORT CIRCUIT BATTERY TERMINALS, OR REMOVE VENT
CAPS DURING STORAGE OR RECHARGING. PROTECT BATTERY FROM PHYSICAL DAMAGE.
OTHER PRECAUTIONS:
GOOD PERSONAL HYGIENE AND WORK PRACTICES ARE MANDATORY. REFRAIN FROM
EATING, DRINKING OR SMOKING IN WORK AREAS. THOROUGHLY WASH HANDS, FACE,
NECK, AND ARMS BEFORE EATING, DRINKING OR SMOKING. LAUNDER SOILED CLOTHING
BEFORE REUSE. EMPTIED BATTERIES CONTAIN HAZARDOUS SULFURIC ACID RESIDUE.
| SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
RESPIRATORY PROTECTION (SPECIFY TYPE):
ACID/GAS NIOSH APPROVED RESPIRATOR IS REQUIRED WHEN THE PEL IS EXCEEDED OR
EMPLOYEE EXPERIENCES RESPIRATORY IRRITATION. WHEN EXPOSURE LEVELS ARE
UNKNOWN OR WHEN FIREFIGHTING, WEAR A SELF-CONTAINED BREATHING APPARATUS
WITH A FULL FACEPIECE OPERATED IN A POSITIVE PRESSURE MODE.
VENTILATION:
MUST BE PROVIDED WHEN CHARGING IN AN ENCLOSED AREA. CHANGE AIR EVERY
15 MIN.
LOCAL EXHAUST: WHEN PEL IS EXCEEDED.
MECHANICAL (GENERAL):
NORMAL MECHANICAL VENTILATION RECOMMENDED FOR STATIONARY APPLICATIONS.
PROTECTIVE GLOVES:
WEAR RUBBER OR PLASTIC ACID RESISTANT GLOVES WITH ELBOW LENGTH GAUNTLET
WHEN FILLING BATTERIES.
EYE PROTECTION:
ANSI APPROVED SAFETY GLASSES WITH SIDE SHIELDS/FACE SHIELD RECOMMENDED.
SAFETY GOGGLES.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
VENTILATION AS DESCRIBED IN THE INDUSTRIAL VENTILATION MANUAL PRODUCED BY
THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS, SHALL BE
PROVIDED IN AREAS WHERE EXPOSURES ARE ABOVE THE PEL OR TLV SPECIFIED BY
OSHA OR OTHER LOCAL, STATE AND FEDERAL REGULATIONS.
ACID-RESISTANT RUBBER OR PLASTIC APRON, BOOTS AND PROTECTIVE CLOTHING.
SAFETY SHOWER AND EYEWASH.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT: ELECTROLYTE APPROX. 235 DEG. F
VAPOR PRESSURE: ELECTROLYTE 1 MMHg @ 145.8 DEG. F
SPECIFIC GRAVITY: ELECTROLYTE (H2O=1) 1.250 - 1.320
PH: <2
MELTING POINT: POLYPROPYLENE <320 DEG. F
PERCENT VOLATILE BY VOLUME (%): NOT APPLICABLE
VAPOR DENSITY:
HYDROGEN (AIR=1): 0.069
ELECTROLYTE (AIR=1): 3.4 AT STP
EVAPORATION RATE: NOT APPLICABLE
SOLUBILITY IN WATER:
ELECTROLYTE: 100% SOLUBLE
REACTIVITY IN WATER: ELECTROLYTE-WATER REACTIVE (1)
APPEARANCE AND ODOR:
BATTERY: POLYPROPYLENE OR HARD RUBBER CASE, SOLID.
LEAD: GRAY, METALLIC, SOLID
ELECTROLYTE:
LIQUID, COLORLESS, OILY FLUID; NUISANCE ODOR WHEN HOT OR CHARGING BATTERY.
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY:
UNSTABLE ( )
STABLE (X)
CONDITIONS TO AVOID:
HIGH TEMPERATURES - CASES DECOMPOSE AT <320 DEG. F.
AVOID OVERCHARGING AND SMOKING, OR SPARKS NEAR BATTERY SURFACE AND RAPID
OVERCHARGE.
INCOMPATIBILITY (MATERIALS TO AVOID):
SPARKS, OPEN FLAMES, KEEP BATTERY CASE AWAY FROM STRONG OXIDIZERS.
HAZARDOUS DECOMPOSITION PRODUCTS:
AN EXPLOSIVE HYDROGEN/OXYGEN MIXTURE WITHIN THE BATTERY MAY OCCUR DURING
CHARGING. COMBUSTION CAN PRODUCE CARBON DIOXIDE (CO2) AND CARBON MONOXIDE
(CO). MOLTEN METALS PRODUCE FUMES AND/OR VAPOR THAT MAY BE TOXIC OR
RESPIRATORY IRRITANTS.
HAZARDOUS POLYMERIZATION:
MAY OCCUR ( )
WILL NOT OCCUR (X)
DO NOT OVERCHARGE.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
GENERAL:
THE PRIMARY ROUTES OF EXPOSURE TO LEAD ARE INGESTION OR INHALATION OF DUST
AND FUMES.
ACUTE:
INGESTION/INHALATION:
EXPOSURE TO LEAD AND ITS COMPOUNDS MAY CAUSE HEADACHE, NAUSEA, VOMITING,
ABDOMINAL SPASMS, FATIGUE, SLEEP DISTURBANCES, WEIGHT LOSS, ANEMIA, AND
PAIN IN THE LEGS, ARMS AND JOINTS. KIDNEY DAMAGE, AS WELL AS ANEMIA, CAN
OCCUR FROM ACUTE EXPOSURE.
CHRONIC:
INHALATION/INGESTION:
PROLONGED EXPOSURE TO LEAD AND ITS COMPOUNDS MAY PRODUCE MANY OF THE
SYMPTOMS OF SHORT-TERM EXPOSURE AND MAY ALSO CAUSE CENTRAL NERVOUS SYSTEM
DAMAGE, GASTROINTESTINAL DISTURBANCES, ANEMIA, AND WRIST DROP. SYMPTOMS OF
CENTRAL NERVOUS SYSTEM DAMAGE INCLUDE FATIGUE, HEADACHES, TREMORS,
HYPERTENSION, HALLUCINATIONS, CONVULSIONS AND DELIRIUM. KIDNEY DYSFUNCTION
AND POSSIBLE INJURY HAS ALSO BEEN ASSOCIATED WITH CHRONIC LEAD POISONING.
CHRONIC OVER-EXPOSURE TO LEAD HAS BEEN IMPLICATED AS A CAUSATIVE AGENT FOR
THE IMPAIRMENT OF MALE AND FEMALE REPRODUCTIVE CAPACITY, BUT THERE IS, AT
PRESENT, NO SUBSTANTIATION OF THE IMPLICATION. PREGNANT WOMEN SHOULD BE
PROTECTED FROM EXCESSIVE EXPOSURE. LEAD CAN CROSS THE PLACENTAL BARRIER AND
UNBORN CHILDREN MAY SUFFER NEUROLOGICAL DAMAGE OR DEVELOPMENTAL PROBLEMS
DUE TO EXCESSIVE LEAD EXPOSURE IN PREGNANT WOMEN.
| SECTION 12 - ECOLOGICAL INFORMATION | |
IN MOST SURFACE WATER AND GROUNDWATER, LEAD FORMS COMPOUNDS WITH ANIONS
SUCH AS HYDROXIDES, CARBONATES, SULFATES, AND PHOSPHATES AND PRECIPITATES
OUT OF THE WATER COLUMN. LEAD MAY OCCUR AS SORBED IONS OR SURFACE COATINGS
ON SEDIMENT MINERAL PARTICLES OR MAY BE CARRIED IN COLLOIDAL PARTICLES IN
SURFACE WATER. MOST LEAD IS STRONGLY RETAINED IN SOIL, RESULTING IN LITTLE
MOBILITY. LEAD MAY BE IMMOBILIZED BY ION EXCHANGE WITH HYDROUS OXIDES OR
CLAYS OR BY CHELATION WITH HUMIC OR FULVIC ACIDS IN THE SOIL. LEAD (WHEN IN
THE DISSOLVED PHASE) IS BIO-ACCUMULATED BY PLANTS AND ANIMALS, BOTH AQUATIC
AND TERRESTRIAL.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHODS:
LEAD-ACID BATTERIES ARE COMPLETELY RECYCLABLE. RETURN WHOLE SCRAP BATTERIES
TO DISTRIBUTOR, MANUFACTURER OR LEAD SMELTER FOR RECYCLING.
FOR INFORMATION ON RETURNING BATTERIES TO TROJAN BATTERY COMPANY FOR
RECYCLING CALL 800-423-6569. FOR NEUTRALIZED SPILLS, PLACE RESIDUE IN
ACID-RESISTANT CONTAINERS WITH SORBENT MATERIAL, SAND OR EARTH AND DISPOSE
OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS FOR ACID AND
LEAD COMPOUNDS. CONTACT LOCAL AND/OR STATE ENVIRONMENTAL OFFICIALS
REGARDING DISPOSAL INFORMATION.
| SECTION 14 - TRANSPORT INFORMATION | |
U.S. DOT PROPER SHIPPING NAME: BATTERIES, WET, FILLED WITH ACID
U.S. DOT HAZARD CLASS: 8
U.S. DOT ID NUMBER: UN 2794
U.S. DOT PACKING GROUP: III
U.S. DOT LABEL: CORROSIVE
IMO PROPER SHIPPING NAME: BATTERIES, WET, FILLED WITH ACID
IMO REGULATION PAGE NUMBER: 8120
IMO U.N. CLASS: 8
IMO U.N. NUMBER: UN 2794
IMO PACKING GROUP: III
IMO LABEL: CORROSIVE
IMO VESSEL STOWAGE: A
IATA PROPER SHIPPING NAME: BATTERIES, WET, FILLED WITH ACID
IATA U.N. CLASS: 8
IATA U.N. NUMBER: UN 2794
IATA PACKING GROUP: III
IATA LABEL: CORROSIVE
| SECTION 15 - REGULATORY INFORMATION | |
U.S. HAZARDOUS UNDER HAZARD COMMUNICATION STANDARD:
LEAD: YES
SULFURIC ACID: YES
ANTIMONY: YES
ARSENIC: YES
INGREDIENTS LISTED ON TSCA INVENTORY: YES
CERCLA SECTION 304 HAZARDOUS SUBSTANCES:
LEAD: YES
RQ: NA*
SULFURIC ACID: YES
RQ: 1000 POUNDS
ANTIMONY: YES
RQ: 5000 POUNDS
ARSENIC: YES
RQ: 1 POUND
*REPORTING NOT REQUIRED WHEN DIAMETER OF THE PIECES OF SOLID METAL RELEASED
IS EQUAL TO OR EXCEEDS 100 MICROMETERS.
EPCRA SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE:
SULFURIC ACID: YES
EPCRA SECTION 313 TOXIC RELEASE INVENTORY:
LEAD:
CAS NO: 7439-92-1
SULFURIC ACID:
CAS NO: 7664-93-9
ANTIMONY:
CAS NO: 7440-36-0
ARSENIC:
CAS NO: 7440-38-2
| SECTION 16 - OTHER INFORMATION | |
THE INFORMATION ABOVE IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST
INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, TROJAN BATTERY COMPANY
MAKES NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR
IMPLIED, WITH RESPECT TO SUCH INFORMATION, AND WE ASSUME NO LIABILITY
RESULTING FROM ITS USE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO
DETERMINE THE SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES.
ALTHOUGH REASONABLE PRECAUTIONS HAVE BEEN TAKEN IN THE PREPARATION OF THE
DATA CONTAINED HEREIN, IT IS OFFERED SOLELY FOR YOUR INFORMATION,
CONSIDERATION AND INVESTIGATION. THIS MATERIAL SAFETY DATA SHEET PROVIDES
GUIDELINES FOR THE SAFE HANDLING AND USE OF THIS PRODUCT; IT DOES NOT AND
CANNOT ADVISE ON ALL POSSIBLE SITUATIONS, THEREFORE, YOUR SPECIFIC USE OF
THIS PRODUCT SHOULD BE EVALUATED TO DETERMINE IF ADDITIONAL PRECAUTIONS ARE
REQUIRED.
FORM MSDS REV.: MAY 13, 2010
NYOGEL 760G
PRODUCT: 760G
REVISION DATE: 2003/02/10
| SECTION 1: PRODUCT AND COMPANY IDENTIFICATION | |
MANUFACTURER: NYE LUBRICANTS, INC.
MANUFACTURER EMERGENCY PHONE NUMBER:
CHEMTREC:
800-424-9300.
508-996-6721 (8:00AM - 5:00PM ET WEEKDAYS).
PRODUCT NAME: NYOGEL 760G.
CHEMICAL FAMILY: LUBRICATING GREASE.
HMIS:
H 1
F 1
R 0
PPE SEC. 8
| SECTION 2: INGREDIENT INFORMATION | |
C.A.S. CONC % INGREDIENT OSHA-PEL OSHA-PEL ACGIH-TLV ACGIH-TLV
WGT/WGT NAME TWA STEL TWA STEL
OIL MIST 5 MG/M3 NOT 5 MG/M3 NOT
AVAILABLE AVAILABLE
INGREDIENT NAME NIOSH REL TWA NIOSH REL STEL NIOSH IDL
OIL MIST 5 MG/M3 10 MG/M3 2500 MG/M3
| SECTION 2A: ADDITIONAL INGREDIENT INFORMATION | |
NOTE: PRODUCT FORMULATION IS PROPRIETARY.
NO INGREDIENTS ARE KNOWN TO BE HAZARDOUS UNDER NORMAL USAGE.
| SECTION 3: HAZARD IDENTIFICATION | |
EMERGENCY OVERVIEW:
MAY IRRITATE EYES. PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE IRRITATION.
INHALATION OF OIL MIST OR VAPORS FROM MATERIAL AT HIGH TEMPERATURES MAY
IRRITATE RESPIRATORY PASSAGES.
ROUTE OF ENTRY: SKIN CONTACT, EYE CONTACT, INHALATION AND INGESTION.
EFFECTS OF ACUTE EXPOSURE:
EYE CONTACT: MAY CAUSE IRRITATION.
SKIN CONTACT: MAY CAUSE IRRITATION ON PROLONGED OR REPEATED CONTACT.
INHALATION:
OIL MIST AND VAPORS AT HIGH TEMPERATURES MAY IRRITATE RESPIRATORY PASSAGES.
INGESTION: MAY CAUSE GASTRO-INTESTINAL IRRITATION.
EFFECTS OF CHRONIC EXPOSURE: SEE EFFECTS OF ACUTE EXPOSURE.
CARCINOGENIC EFFECTS:
IARC, NTP, AND OSHA DO NOT LIST THIS PRODUCT OR ITS INGREDIENTS AS
CARCINOGENS.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE KNOWN.
TARGET ORGANS: RESPIRATORY PASSAGES AT HIGH TEMPERATURES, EYES, SKIN.
| SECTION 4: FIRST AID MEASURES | |
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING.
WASH THOROUGHLY WITH SOAP AND WATER.
SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS.
EYE CONTACT:
FLUSH WITH WATER FOR AT LEAST 15 MINUTES.
OBTAIN IMMEDIATE MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR. IF NOT BREATHING, QUALIFIED PERSONNEL SHOULD
ADMINISTER ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN.
INGESTION:
OBTAIN IMMEDIATE MEDICAL ATTENTION.
DO NOT INDUCE VOMITING, UNLESS DIRECTED TO DO SO BY A PHYSICIAN.
| SECTION 5: FIRE FIGHTING MEASURES | |
FLAMMABILITY: NOT FLAMMABLE.
CONDITIONS OF FLAMMABILITY: AT TEMPERATURES AT OR ABOVE FLASH POINT.
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM. WATER SPRAY.
SPECIAL PROCEDURES:
SELF-CONTAINED BREATHING APPARATUS REQUIRED.
FIREFIGHTERS SHOULD WEAR THE USUAL PROTECTIVE GEAR.
DO NOT LET FIREFIGHTING WATER RUNOFF ENTER A SEWER.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
FLASH POINT (DEG. C), METHOD:
CLOSED CUP.
ASTM D-93.
>400 DEG. F (204 DEG. C).
LOWER FLAMMABILITY LIMIT (% VOL): NOT AVAILABLE.
UPPER FLAMMABILITY LIMIT (% VOL): NOT AVAILABLE.
EXPLOSION DATA:
SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE.
SENSITIVITY TO MECHANICAL IMPACT: NOT AVAILABLE.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON MONOXIDE (CO).
TRACES OF OTHER TOXIC FUMES.
RATE OF BURNING: NOT AVAILABLE.
EXPLOSIVE POWER: NOT AVAILABLE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
LEAK/SPILL:
CONTAIN THE SPILL.
PREVENT ENTRY INTO DRAINS, SEWERS, AND OTHER WATERWAYS.
AREA WILL BE SLIPPERY UNTIL CLEANED.
WEAR APPROPRIATE PROTECTIVE EQUIPMENT.
WIPE OR SCRAPE UP SPILLED MATERIAL.
WASH SPILL AREA AFTER MATERIAL PICK UP IS COMPLETE.
TRANSFER TO AN APPROVED CONTAINER FOR DISPOSAL OR RECOVERY.
OBSERVE PRECAUTIONS FROM OTHER SECTIONS.
FOLLOW APPLICABLE OSHA (29 CFR 1910.120), STATE AND LOCAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
HANDLING PROCEDURES AND EQUIPMENT:
WASH THOROUGHLY AFTER USING, PARTICULARLY BEFORE EATING OR SMOKING.
DO NOT EAT, DRINK OR SMOKE IN HANDLING AREA.
AVOID CONTAMINATION OF CIGARETTES OR OTHER TOBACCO PRODUCTS.
LAUNDER CONTAMINATED CLOTHING PRIOR TO REUSE.
USERS SHOULD BE ALERT TO THE POSSIBILITY THAT VERY SMALL PERCENTAGES OF THE
POPULATION MAY DISPLAY UNEXPECTED ALLERGIC REACTIONS TO OTHERWISE INNOCUOUS
INDUSTRIAL LUBRICANTS AND RAW MATERIALS.
STORAGE REQUIREMENTS:
STORE AWAY FROM INCOMPATIBLE MATERIALS.
DO NOT STORE IN OPEN OR UNLABELLED CONTAINERS.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
PRECAUTIONARY MEASURES:
GLOVES/TYPE:
CHEMICAL RESISTANT GLOVES.
AVOID SKIN CONTACT.
RESPIRATORY/TYPE:
NONE REQUIRED UNDER NORMAL USE.
IF EXPOSURE LIMIT IS EXCEEDED, WEAR A NIOSH APPROVED RESPIRATOR.
AVOID BREATHING OIL MIST.
EYE/TYPE:
AVOID EYE CONTACT.
SAFETY GLASSES, GOGGLES OR FACE SHIELD.
IN ACCORDANCE WITH OSHA 29 CFR 1910.133.
FOOTWEAR/TYPE: SAFETY SHOES PER LOCAL REGULATIONS.
CLOTHING/TYPE:
WEAR ADEQUATE PROTECTIVE CLOTHES.
APRON
OTHER/TYPE:
EYE WASH FACILITY SHOULD BE IN CLOSE PROXIMITY.
EMERGENCY SHOWER SHOULD BE IN CLOSE PROXIMITY.
VENTILATION REQUIREMENTS:
LOCAL VENTILATION IS GENERALLY NOT NECESSARY UNDER NORMAL CONDITIONS OF
USE WITH ADEQUATE GENERAL VENTILATION. VENTILATION AND OTHER FORMS OF
ENGINEERING CONTROLS ARE THE PREFERRED MEANS FOR CONTROLLING CHEMICAL
EXPOSURES.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SEMI-SOLID.
APPEARANCE & ODOR:
SLIGHT ODOUR.
CLEAR TO LIGHT YELLOW.
SMOOTH GREASE.
ODOR THRESHOLD (PPM): NOT AVAILABLE.
VAPOUR PRESSURE (MMHg): NEGLIGIBLE.
VAPOUR DENSITY (AIR=1): NOT AVAILABLE.
VOLATILES (%): NONE
EVAPORATION RATE (BUTYL ACETATE = 1): NOT AVAILABLE.
BOILING POINT (DEG. C): NOT VOLATILE.
FREEZING POINT (DEG. C): NON-MELTING.
PH: NOT AVAILABLE.
SPECIFIC GRAVITY @ 20 DEG. C: (WATER = 1, @ 4 DEG. C). 0.91 @ 25 DEG. C
SOLUBILITY IN WATER (%): INSOLUBLE.
COEFFICIENT OF WATER\OIL DIST.: NOT AVAILABLE.
VOC: NONE
| SECTION 10: STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
CONDITIONS OF INSTABILITY: PYROLYSIS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
INCOMPATIBLE SUBSTANCES: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS: SEE HAZARDOUS COMBUSTION PRODUCTS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
SENSITIZATION TO PRODUCT: NOT AVAILABLE.
REPRODUCTIVE EFFECTS: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
SYNERGISTIC MATERIALS: NOT AVAILABLE.
| SECTION 12: ECOLOGICAL INFORMATION | |
ENVIRONMENTAL TOXICITY: NO DATA AT THIS TIME.
ENVIRONMENTAL FATE: NO DATA AT THIS TIME.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL:
CONTACT A LICENSED WASTE - DISPOSAL CONTRACTOR FOR DETAILED
RECOMMENDATIONS.
MANY STATES CLASSIFY WASTE LUBRICANTS AS "HAZARDOUS", WHICH MEANS DISPOSAL
CAN ONLY BE A LICENSED FIRM. FOLLOW APPLICABLE FEDERAL, STATE, AND LOCAL
REGULATIONS.
| SECTION 14: TRANSPORT INFORMATION | |
DOT: NOT REGULATED.
| SECTION 15: REGULATORY INFORMATION | |
USA REGULATORY INFORMATION:
SARA HAZARD CATEGORIES SECTIONS 311/312:
IMMEDIATE (ACUTE) HEALTH HAZARD: NO.
DELAYED (CHRONIC) HEALTH HAZARD: NO.
FIRE HAZARD: NO.
SUDDEN RELEASE OF PRESSURE: NO.
REACTIVE: NO.
SARA SECTION 313: NOT REGULATED.
TSCA INVENTORY:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY.
| SECTION 16: OTHER INFORMATION | |
SUPPLIER MSDS DATE: 2003/02/10
DATA PREPARED BY: GSM
DISCLAIMER:
WHILE THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN ARE BELIEVED TO
BE ACCURATE AS OF THE DATE HEREOF, NYE LUBRICANTS, INC. MAKES NO WARRANTY
WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY WITH RESPECT THEREON.
MATERIAL SAFETY DATA SHEET
SCOTCHKOTE BRAND ELECTRICAL COATING
02/06/2009
3M
MATERIAL SAFETY DATA SHEET
COPYRIGHT, 2009, 3M COMPANY. ALL RIGHTS RESERVED. COPYING AND/OR
DOWNLOADING OF THIS INFORMATION FOR THE PURPOSE OF PROPERLY UTILIZING 3M
PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
| SECTION 1: PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: SCOTCHKOTE BRAND ELECTRICAL COATING
MANUFACTURER: 3M
DIVISION: ELECTRICAL MARKETS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
ISSUE DATE: 02/06/2009
SUPERCEDES DATE: 02/06/2009
DOCUMENT GROUP: 10-2644-2
PRODUCT USE:
INTENDED USE: MOISTURE PROOFING FOR WIRE CONNECTIONS
| SECTION 2: INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
ACETONE 67-64-1 40 - 45
METHYL ETHYL KETONE 78-93-3 10 - 15
ACRYLONITRILE-BUTADIENE POLYMER 9003-18-3 10 - 15
TOLUENE 108-88-3 10 - 15
PHENOL-FORMALDEHYDE RESIN 25085-50-1 5 - 10
GLYCEROL ESTERS OF ROSIN ACIDS 8050-31-5 5 - 10
ZINC OXIDE 1314-13-2 1 - 2
SALICYLIC ACID 69-72-7 1 - 2
ANTIOXIDANT 68411-46-1 0.1 - 1
MINUTE QUANTITIES OF THE SUBSTANCES LISTED BELOW MAY BE EMITTED DURING
NORMAL USE:
SUBSTANCE CONDITION
HYDROCARBONS NORMAL USE
| SECTION 3: HAZARDS IDENTIFICATION | |
3.1 EMERGENCY OVERVIEW:
ODOR, COLOR, GRADE: BROWN, SOLVENT ODOR
GENERAL PHYSICAL FORM: LIQUID
IMMEDIATE HEALTH, PHYSICAL, AND ENVIRONMENTAL HAZARDS:
FLAMMABLE LIQUID AND VAPOR. CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY
BUILD PRESSURE AND EXPLODE. VAPORS MAY TRAVEL LONG DISTANCES ALONG THE
GROUND OR FLOOR TO AN IGNITION SOURCE AND FLASH BACK. MAY CAUSE TARGET
ORGAN EFFECTS. CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH
DEFECTS OR OTHER REPRODUCTIVE HARM.
3.2 POTENTIAL HEALTH EFFECTS:
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED OR
HAZY VISION.
SKIN CONTACT:
MODERATE SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
MAY BE ABSORBED THROUGH SKIN AND CAUSE TARGET ORGAN EFFECTS.
INHALATION: MAY BE HARMFUL IF INHALED.
UPPER RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY BE ABSORBED FOLLOWING INHALATION AND CAUSE TARGET ORGAN EFFECTS.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, NAUSEA, DIARRHEA AND VOMITING.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY BE ABSORBED FOLLOWING INGESTION AND CAUSE TARGET ORGAN EFFECTS.
TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE:
LIVER EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE LOSS OF APPETITE, WEIGHT LOSS, FATIGUE,
WEAKNESS, ABDOMINAL TENDERNESS AND JAUNDICE.
CENTRAL NEUROPATHY:
SIGNS/SYMPTOMS MAY INCLUDE IRRITABILITY, MEMORY IMPAIRMENT, PERSONALITY
CHANGES, SLEEP DISORDERS, AND DECREASED ABILITY TO CONCENTRATE.
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS AND
TREMORS.
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
| SECTION 4: FIRST AID MEASURES | |
4.1 FIRST AID PROCEDURES:
THE FOLLOWING FIRST AID RECOMMENDATIONS ARE BASED ON AN ASSUMPTION THAT
APPROPRIATE PERSONAL AND INDUSTRIAL HYGIENE PRACTICES ARE FOLLOWED.
EYE CONTACT:
FLUSH EYES WITH LARGE AMOUNTS OF WATER. IF SIGNS/SYMPTOMS PERSIST, GET
MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND SHOES. IMMEDIATELY FLUSH SKIN WITH LARGE
AMOUNTS OF WATER. GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING AND
CLEAN SHOES BEFORE REUSE.
INHALATION:
REMOVE PERSON TO FRESH AIR. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL
ATTENTION.
IF SWALLOWED:
DO NOT INDUCE VOMITING. GIVE VICTIM TWO GLASSES OF WATER. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET IMMEDIATE MEDICAL
ATTENTION.
| SECTION 5: FIRE FIGHTING MEASURES | |
5.1 FLAMMABLE PROPERTIES:
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
FLASH POINT: 0.0 DEG. F [TEST METHOD: CLOSED CUP] [DETAILS: MITS DATA]
OSHA FLAMMABILITY CLASSIFICATION: CLASS IB FLAMMABLE LIQUID
5.2 EXTINGUISHING MEDIA:
USE FIRE EXTINGUISHERS WITH CLASS B EXTINGUISHING AGENTS (E.G., DRY
CHEMICAL, CARBON DIOXIDE).
5.3 PROTECTION OF FIRE FIGHTERS:
SPECIAL FIRE FIGHTING PROCEDURES:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE. WEAR FULL PROTECTIVE EQUIPMENT (BUNKER GEAR) AND A SELF-CONTAINED
BREATHING APPARATUS (SCBA).
UNUSUAL FIRE AND EXPLOSION HAZARDS:
FLAMMABLE LIQUID AND VAPOR. CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY
BUILD PRESSURE AND EXPLODE. EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS
MAY TRAVEL LONG DISTANCES ALONG THE GROUND OR FLOOR TO AN IGNITION SOURCE
AND FLASH BACK.
NOTE:
SEE STABILITY AND REACTIVITY (SECTION 10) FOR HAZARDOUS COMBUSTION AND
THERMAL DECOMPOSITION INFORMATION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
ACCIDENTAL RELEASE MEASURES:
REFER TO OTHER SECTIONS OF THIS MSDS FOR INFORMATION REGARDING PHYSICAL
AND HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL
PROTECTIVE EQUIPMENT. CALL 3M-HELPS LINE (1-800-364-3577) FOR MORE
INFORMATION ON HANDLING AND MANAGING THE SPILL. EVACUATE UNPROTECTED AND
UNTRAINED PERSONNEL FROM HAZARD AREA. THE SPILL SHOULD BE CLEANED UP BY
QUALIFIED PERSONNEL. REMOVE ALL IGNITION SOURCES SUCH AS FLAMES, SMOKING
MATERIALS, AND ELECTRICAL SPARK SOURCES. USE ONLY NON-SPARKING TOOLS.
VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR SPILLS IN CONFINED
SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN
ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. CONTAIN SPILL. FOR LARGER
SPILLS, COVER DRAINS AND BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS
OR BODIES OF WATER. COVER SPILL AREA WITH A FIRE-EXTINGUISHING FOAM. AN
AQUEOUS FILM FORMING FOAM (AFFF) IS RECOMMENDED. WORKING FROM AROUND THE
EDGES OF THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR
COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT
ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL
DOES NOT REMOVE A TOXIC, CORROSIVITY OR FLAMMABILITY HAZARD. COLLECT AS
MUCH OF THE SPILLED MATERIAL AS POSSIBLE USING NON-SPARKING TOOLS. CLEAN
UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND
AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW
SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND MSDS. COLLECT THE RESULTING
RESIDUE CONTAINING SOLUTION. PLACE IN A METAL CONTAINER APPROVED FOR
TRANSPORTATION BY APPROPRIATE AUTHORITIES. SEAL THE CONTAINER. DISPOSE
OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
IN THE EVENT OF A RELEASE OF THIS MATERIAL, THE USER SHOULD DETERMINE IF
THE RELEASE QUALIFIES AS REPORTABLE ACCORDING TO LOCAL, STATE, AND FEDERAL
REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1 HANDLING:
AVOID EYE CONTACT. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH EXPOSED AREAS THOROUGHLY WITH SOAP AND WATER. CONTENTS MAY BE UNDER
PRESSURE, OPEN CAREFULLY. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME, PILOT
LIGHTS AND OTHER SOURCES OF IGNITION. GROUND CONTAINERS SECURELY WHEN
TRANSFERRING CONTENTS. WEAR LOW STATIC OR PROPERLY GROUNDED SHOES. DO NOT
PIERCE OR BURN CONTAINER, EVEN AFTER USE. NO SMOKING WHILE HANDLING THIS
MATERIAL. DO NOT SPRAY NEAR FLAMES OR SOURCES OF IGNITION. AVOID BREATHING
OF VAPORS, MISTS OR SPRAY. AVOID PROLONGED OR REPEATED SKIN CONTACT. AVOID
STATIC DISCHARGE. AVOID EYE CONTACT WITH VAPORS, MISTS, OR SPRAY. KEEP OUT
OF THE REACH OF CHILDREN. BE SURE THAT ANY PEOPLE IN THE AREA FOLLOW THE
PRECAUTIONS. ATTACH A COPY OF THE PRECAUTIONS TO ANY OTHER CONTAINER TO
WHICH THIS PRODUCT MAY BY TRANSFERRED. AVOID PROLONGED BREATHING OF VAPORS.
AVOID EYE AND SKIN CONTACT. KEEP CONTAINER CLOSED WHEN NOT IN USE. IF WORK
AREA CONDITIONS PREVENT COMPLIANCE WITH ANY OF THE ABOVE PRECAUTIONS, DO
NOT USE THE PRODUCT. KEEP OUT OF THE REACH OF CHILDREN. AVOID CONTACT WITH
OXIDIZING AGENTS.
7.2 STORAGE:
STORE IN A COOL PLACE. STORE AWAY FROM ACIDS. STORE AWAY FROM HEAT.
STORE OUT OF DIRECT SUNLIGHT. KEEP CONTAINER IN WELL-VENTILATED AREA.
KEEP CONTAINER TIGHTLY CLOSED. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 ENGINEERING CONTROLS:
PROVIDE LOCAL EXHAUST VENTILATION AT TRANSFER POINTS. PROVIDE APPROPRIATE
LOCAL EXHAUST VENTILATION ON OPEN CONTAINERS. USE GENERAL DILUTION
VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE EXPOSURES
TO BELOW OCCUPATIONAL EXPOSURE LIMITS AND/OR CONTROL MIST, VAPOR, OR SPRAY.
IF VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE):
8.2.1 EYE/FACE PROTECTION:
AVOID EYE CONTACT WITH VAPORS, MISTS, OR SPRAY.
THE FOLLOWING EYE PROTECTION(S) ARE RECOMMENDED: INDIRECT VENTED GOGGLES.
8.2.2 SKIN PROTECTION:
AVOID SKIN CONTACT.
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT
BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. CONSULT WITH YOUR GLOVE
AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR SELECTION OF APPROPRIATE
COMPATIBLE MATERIALS.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
FLUOROELASTOMER (VITON).
8.2.3 RESPIRATORY PROTECTION:
AVOID BREATHING OF VAPORS, MISTS OR SPRAY.
SELECT ONE OF THE FOLLOWING NIOSH APPROVED RESPIRATORS BASED ON AIRBORNE
CONCENTRATION OF CONTAMINANTS AND IN ACCORDANCE WITH OSHA REGULATIONS:
HALF FACEPIECE OR FULLFACE AIR-PURIFYING RESPIRATOR WITH ORGANIC VAPOR
CARTRIDGES AND P95 PARTICULATE PREFILTERS. CONSULT THE CURRENT 3M
RESPIRATORY SELECTION GUIDE FOR ADDITIONAL INFORMATION OR CALL
1-800-243-4630 FOR 3M TECHNICAL ASSISTANCE.
8.2.4 PREVENTION OF SWALLOWING:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH EXPOSED AREAS
THOROUGHLY WITH SOAP AND WATER.
8.3 EXPOSURE GUIDELINES:
INGREDIENT AUTHORITY TYPE LIMIT ADDITIONAL
INFORMATION
ACETONE ACGIH TWA 500 PPM TABLE A4
ACETONE ACGIH STEL 750 PPM TABLE A4
ACETONE OSHA TWA, VACATED 750 PPM
ACETONE OSHA TWA 1000 PPM TABLE Z-1
ACETONE OSHA STEL, VACATED 1000 PPM
METHYL ETHYL KETONE ACGIH TWA 200 PPM
METHYL ETHYL KETONE ACGIH STEL 300 PPM
METHYL ETHYL KETONE OSHA TWA 200 PPM TABLE Z-1 A
METHYL ETHYL KETONE OSHA STEL 300 PPM TABLE Z-1 A
TOLUENE ACGIH TWA 20 PPM TABLE A4
TOLUENE CMRG STEL 75 PPM SKIN NOTATION*
TOLUENE OSHA TWA, VACATED 100 PPM
TOLUENE OSHA STEL, VACATED 150 PPM
TOLUENE OSHA TWA 200 PPM TABLE Z-2
TOLUENE OSHA CEIL 300 PPM TABLE Z-2
ZINC OXIDE ACGIH TWA, RESPIRABLE 2 MG/M3
ZINC OXIDE ACGIH STEL 10 MG/M3
ZINC OXIDE OSHA TWA, AS FUME 5 MG/M3 TABLE Z-1
ZINC OXIDE OSHA TWA, RESPIRABLE 5 MG/M3 TABLE Z-1
ZINC OXIDE OSHA STEL, VACATED, 10 MG/M3
AS FUME
ZINC OXIDE OSHA TWA, VACATED, 10 MG/M3
AS DUST
ZINC OXIDE OSHA TWA, AS 15 MG/M3 TABLE Z-1
TOTAL DUST
* SUBSTANCE(S) REFER TO THE POTENTIAL CONTRIBUTION TO THE OVERALL EXPOSURE
BY THE CUTANEOUS ROUTE INCLUDING MUCOUS MEMBRANE AND EYE, EITHER BY
AIRBORNE OR, MORE PARTICULARLY, BY DIRECT CONTACT WITH THE SUBSTANCE.
VEHICLES CAN ALTER SKIN ABSORPTION.
VAC VACATED PEL:
VACATED PERMISSIBLE EXPOSURE LIMITS [PEL] ARE ENFORCED AS THE OSHA PEL IN
SOME STATES. CHECK WITH YOUR LOCAL REGULATORY AGENCY.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
CMRG: CHEMICAL MANUFACTURER RECOMMENDED GUIDELINE
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
AIHA:
AMERICAN INDUSTRIAL HYGIENE ASSOCIATION WORKPLACE ENVIRONMENTAL EXPOSURE
LEVEL (WEEL)
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
ODOR, COLOR, GRADE: BROWN, SOLVENT ODOR
GENERAL PHYSICAL FORM: LIQUID
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
FLASH POINT: 0.0 DEG. F [TEST METHOD: CLOSED CUP] [DETAILS: MITS DATA]
BOILING POINT: >=95 DEG. F [DETAILS: MITS DATA]
VAPOR PRESSURE: <=27 PSIA [@ 131.0000000000 DEG. F] [DETAILS: MITS DATA]
SPECIFIC GRAVITY: 0.88 [DETAILS: MITS DATA]
PH: NOT APPLICABLE
MELTING POINT: NO DATA AVAILABLE
EVAPORATION RATE: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
APPROXIMATELY 2.1 LB/GAL [DETAILS: SPECIFIC METHOD: CALCD. PER 3M]
PERCENT VOLATILE: 30 [DETAILS: CONDITIONS: 75]
VOC LESS H2O & EXEMPT SOLVENTS:
APPROXIMATELY 251 G/L [DETAILS: SPECIFIC METHOD: CALCD. PER 3M]
VISCOSITY: 325 CENTIPOISE [@ 73.4000000000 DEG. F] [DETAILS: MITS DATA]
| SECTION 10: STABILITY AND REACTIVITY | |
STABILITY: STABLE.
MATERIALS AND CONDITIONS TO AVOID: NONE KNOWN
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
AMINE COMPOUNDS NOT SPECIFIED
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
| SECTION 11: TOXICOLOGICAL INFORMATION | |
PLEASE CONTACT THE ADDRESS LISTED IN SECTION 1 OF THIS MSDS FOR
TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION: NOT DETERMINED.
CHEMICAL FATE INFORMATION: NOT DETERMINED.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
INCINERATE IN A PERMITTED HAZARDOUS WASTE INCINERATOR. AS A DISPOSAL
ALTERNATIVE, DISPOSE OF WASTE PRODUCT IN A PERMITTED HAZARDOUS WASTE
FACILITY.
EPA HAZARDOUS WASTE NUMBER (RCRA):
D001 (IGNITABLE), D035 (METHYL ETHYL KETONE)
SINCE REGULATIONS VARY, CONSULT APPLICABLE REGULATIONS OR AUTHORITIES
BEFORE DISPOSAL.
| SECTION 14: TRANSPORT INFORMATION | |
PLEASE CONTACT THE EMERGENCY NUMBERS LISTED IN SECTION 1 OF THIS MSDS
FOR TRANSPORTATION INFORMATION FOR THIS MATERIAL.
| SECTION 15: REGULATORY INFORMATION | |
US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
ZINC OXIDE (ZINC COMPOUNDS) 1314-13-2 1 - 2
TOLUENE 108-88-3 10 - 15
METHYL ETHYL KETONE 78-93-3 30 - 15
STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
TOLUENE 108-88-3 *DEVELOPMENTAL TOXIN
* WARNING:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
ALL APPLICABLE CHEMICAL INGREDIENTS IN THIS MATERIAL ARE LISTED ON THE
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES (EINECS), OR ARE EXEMPT
POLYMERS WHOSE MONOMERS ARE LISTED ON EINECS.
CONTACT 3M FOR MORE INFORMATION.
ADDITIONAL INFORMATION: ALL INGREDIENTS ON TSCA; EINECS; CDSL
INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS MSDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 3
REACTIVITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
REASON FOR REISSUE:
THE MSDS HAS BEEN REVISED BECAUSE 3M HAS ADOPTED THE 16-SECTION ANSI/ISO
FORMAT. THE POTENTIAL HAZARDS OF THE PRODUCT HAVE NOT CHANGED. WE ENCOURAGE
YOU TO REREAD THE MSDS AND REVIEW THE INFORMATION.
REVISION CHANGES:
SECTION 1:
PRODUCT USE INFORMATION WAS MODIFIED.
COPYRIGHT WAS MODIFIED.
SECTION 3: POTENTIAL EFFECTS FROM INHALATION INFORMATION WAS MODIFIED.
SECTION 3: POTENTIAL EFFECTS FROM INGESTION INFORMATION WAS MODIFIED.
SECTION 3: OTHER HEALTH EFFECTS INFORMATION WAS MODIFIED.
SECTION 2: INGREDIENT TABLE WAS ADDED.
SECTION 15: EPCRA 313 INFORMATION WAS ADDED.
SECTION 15: EPCRA 313 TEXT WAS ADDED.
SECTION 8: EXPOSURE GUIDELINES INGREDIENT INFORMATION WAS ADDED.
SECTION 8: EXPOSURE GUIDELINES LEGEND WAS ADDED.
SECTION 8: EXPOSURE GUIDELINE NOTE WAS ADDED.
SECTION 8: EXPOSURE GUIDELINES DATA SOURCE LEGEND WAS ADDED.
SECTION 15: CALIFORNIA PROPOSITION 65 INGREDIENT INFORMATION WAS ADDED.
SECTION 15: CALIFORNIA PROPOSITION 65 HEADING WAS ADDED.
DISCLAIMER:
THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET (MSDS) IS BELIEVED TO
BE CORRECT AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER
THE 3M PRODUCT IS FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S
METHOD OF USE OR APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT
THE USE AND APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN
THE USER'S KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE
THE 3M PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE MSDS AVAILABLE DIRECTLY FROM 3M.
3M MSDSS ARE AVAILABLE AT WWW.3M.COM
MATERIAL SAFETY DATA SHEET
F63B21
05 00
DATE OF PREPARATION: SEP 8, 2008
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NUMBER: F63B21
PRODUCT NAME: POLANE(R*) S PLUS POLYURETHANE COATING (PART A), BLACK
MANUFACTURER'S NAME:
THE SHERWIN-WILLIAMS COMPANY
101 PROSPECT AVENUE N.W.
CLEVELAND, OH 44115
TELEPHONE NUMBERS AND WEBSITES:
REGULATORY INFORMATION: (216) 566-2902
MEDICAL EMERGENCY: (216) 566-2917
TRANSPORTATION EMERGENCY*: (800) 424-9300
*FOR CHEMICAL EMERGENCY ONLY (SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT)
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
% BY WEIGHT CAS NUMBER INGREDIENT UNITS VAPOR
PRESSURE
24 110-43-0 METHYL N-AMYL KETONE 3.855 MM
ACGIH TLV: 50 PPM
OSHA PEL: 100 PPM
1 88230-35-7 OXO-HEXYL ACETATE 0.7 MM
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
3 14807-96-6 TALC
ACGIH TLV: 2 MG/M3 AS RESP. DUST
OSHA PEL: 2 MG/M3 AS RESP. DUST
1 1333-86-4 CARBON BLACK
ACGIH TLV: 3.5 MG/M3
OSHA PEL: 3.5 MG/M3
| SECTION 3 - HAZARDS IDENTIFICATION | |
HMIS CODES:
HEALTH 2*
FLAMMABILITY 2
REACTIVITY 0
ROUTES OF EXPOSURE:
INHALATION OF VAPOR OR SPRAY MIST.
EYE OR SKIN CONTACT WITH THE PRODUCT, VAPOR OR SPRAY MIST.
EFFECTS OF OVEREXPOSURE:
EYES: IRRITATION.
SKIN: PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION.
INHALATION: IRRITATION OF THE UPPER RESPIRATORY SYSTEM.
MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN
UNCONSCIOUSNESS AND POSSIBLY DEATH.
PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS IN SECTION 2 MAY CAUSE
ADVERSE EFFECTS TO THE LIVER AND URINARY SYSTEMS.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS.
REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN
EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
MAY CAUSE ALLERGIC RESPIRATORY AND/OR SKIN REACTION IN SUSCEPTIBLE PERSONS
OR SENSITIZATION. THIS EFFECT MAY BE DELAYED SEVERAL HOURS AFTER EXPOSURE.
PERSONS SENSITIVE TO ISOCYANATES WILL EXPERIENCE INCREASED ALLERGIC
REACTION ON REPEATED EXPOSURE.
CANCER INFORMATION:
FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11.
| SECTION 4 - FIRST AID MEASURES | |
EYES:
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL
ATTENTION.
SKIN:
WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
INHALATION:
IF ANY BREATHING PROBLEMS OCCUR DURING USE, LEAVE THE AREA AND GET FRESH
AIR. IF PROBLEMS REMAIN OR OCCUR LATER, IMMEDIATELY GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT: 102 DEG. F PMCC
LEL: 1.0
UEL: 8.0
FLAMMABILITY CLASSIFICATION:
COMBUSTIBLE, FLASH ABOVE 99 AND BELOW 200 DEG. F
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.
DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY
CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN
MEDICAL ATTENTION.
SPECIAL FIRE FIGHTING PROCEDURES:
FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS
SHOULD BE USED.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE
BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME
HEAT.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA.
REMOVE WITH INERT ABSORBENT.
| SECTION 7 - HANDLING AND STORAGE | |
STORAGE CATEGORY: DOL STORAGE CLASS II
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
CONTENTS ARE COMBUSTIBLE. KEEP AWAY FROM HEAT AND OPEN FLAME.
CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING PROCEDURES.
KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED CONTAINERS
WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF
THE REACH OF CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRECAUTIONS TO BE TAKEN IN USE:
NO PERSON SHOULD USE THIS PRODUCT, OR BE IN THE AREA WHERE IT IS BEING
USED, IF THEY HAVE CHRONIC (LONG-TERM) LUNG OR BREATHING PROBLEMS OR IF
THEY EVER HAD A REACTION TO ISOCYANATES.
USE ONLY WITH ADEQUATE VENTILATION.
AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR AND SPRAY MIST.
WASH HANDS AFTER USING.
THIS COATING MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES
(LISTED "AS DUST" IN SECTION 2) WHICH MAY BE PRESENT AT HAZARDOUS LEVELS
ONLY DURING SANDING OR ABRADING OF THE DRIED FILM. IF NO SPECIFIC DUSTS ARE
LISTED IN SECTION 2, THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE
ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION),
OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION).
VENTILATION:
LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO
MATERIALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION:
WHERE OVERSPRAY IS PRESENT, A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR
(TC19C NIOSH/MSHA APPROVED) SHOULD BE WARN. IF UNAVAILABLE, A PROPERLY
FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR
PROTECTION AGAINST MATERIALS IN SECTION 2 MAY BE EFFECTIVE. FOLLOW
RESPIRATOR MANUFACTURERS DIRECTIONS FOR USE. WEAR THE RESPIRATOR FOR THE
WHOLE TIME OF SPRAYING AND UNTIL ALL VAPORS AND MISTS ARE GONE. NO PERSONS
SHOULD BE ALLOWED IN THE AREA WHERE THIS PRODUCT IS BEING USED UNLESS
EQUIPPED WITH THE SAME RESPIRATOR PROTECTION RECOMMENDED FOR THE PAINTERS.
WHEN SANDING OR ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR
APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT,
UNDERLYING PAINT, OR THE ABRASIVE.
PROTECTIVE GLOVES:
TO PREVENT SKIN CONTACT, WEAR GLOVES WHICH ARE RECOMMENDED BY GLOVE
SUPPLIER FOR PROTECTION AGAINST MATERIALS IN SECTION 2.
EYE PROTECTION: WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
OTHER PROTECTIVE EQUIPMENT: USE BARRIER CREAM ON EXPOSED SKIN.
OTHER PRECAUTIONS:
THIS PRODUCT MUST BE MIXED WITH OTHER COMPONENTS BEFORE USE. BEFORE OPENING
THE PACKAGES, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
CAN BE HARMFUL OR FATAL.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
PRODUCT WEIGHT:
11.56 LB/GAL
1384 G/L
SPECIFIC GRAVITY: 1.39
BOILING POINT:
297 - 349 DEG. F
147 - 176 DEG. C
MELTING POINT: NOT AVAILABLE
VOLATILE VOLUME: 44%
EVAPORATION RATE: SLOWER THAN ETHER
VAPOR DENSITY: HEAVIER THAN AIR
SOLUBILITY IN WATER: N.A.
VOLATILE ORGANIC COMPOUNDS (VOC THEORETICAL - AS PACKAGED):
3.00 LB/GAL 359 G/L LESS WATER AND FEDERALLY EXEMPT SOLVENTS
3.00 LB/GAL 359 G/L EMITTED VOC
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBILITY: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
CHRONIC HEALTH HAZARDS:
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
CARBON BLACK IS CLASSIFIED BY IARC AS POSSIBLY CARCINOGENIC TO HUMANS
(GROUP 2B) BASED ON EXPERIMENTAL ANIMAL DATA, HOWEVER, THERE IS
INSUFFICIENT EVIDENCE IN HUMANS FOR ITS CARCINOGENICITY.
TOXICOLOGY DATA:
CAS NO. INGREDIENT NAME
110-43-0 METHYL N-AMYL KETONE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 1670 MG/KG
88230-35-7 OXO-HEXYL ACETATE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
14807-96-6 TALC
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
1333-86-4 CARBON BLACK
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261.
WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA
HAZARDOUS WASTE NUMBERS.
INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINER.
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL, AND LOCAL
REGULATIONS REGARDING POLLUTION.
| SECTION 14 - TRANSPORT INFORMATION | |
US GROUND (DOT):
MAY BE CLASSED AS A COMBUSTIBLE LIQUID FOR U.S. GROUND.
UN1263, PAINT, 3, PG III, (ERG#128)
BULK CONTAINERS MAY BE SHIPPED AS:
UN1263, PAINT, COMBUSTIBLE LIQUID, PG III, (ERG#128)
CANADA (TDG):
MAY BE CLASSED AS A COMBUSTIBLE LIQUID FOR CANADIAN GROUND.
UN1263, PAINT, CLASS 3, PG III, (ERG#128)
IMO: UN1263, PAINT, CLASS 3, PG III, (39 C C.C.), EMS F-E, S-E
| SECTION 15 - REGULATORY INFORMATION | |
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION:
CAS NO. CHEMICAL/COMPOUND % BY WT % ELEMENT
NO INGREDIENTS IN THIS PRODUCT ARE SUBJECT TO SARA 313 (40 CFR 372.65C)
SUPPLIER NOTIFICATION.
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
TSCA CERTIFICATION:
ALL CHEMICALS IN THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON
THE TSCA INVENTORY.
| SECTION 16 - OTHER INFORMATION | |
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS
ALL OF THE INFORMATION REQUIRED BY THE CPR.
THE ABOVE INFORMATION PERTAINS TO THIS PRODUCT AS CURRENTLY FORMULATED, AND
IS BASED ON THE INFORMATION AVAILABLE AT THIS TIME. ADDITION OF REDUCERS OR
OTHER ADDITIVES TO THIS PRODUCT MAY SUBSTANTIALLY ALTER THE COMPOSITION AND
HAZARDS OF THE PRODUCT. SINCE CONDITIONS OF USE ARE OUTSIDE OUR CONTROL, WE
MAKE NO WARRANTIES, EXPRESS OR IMPLIED, AND ASSUME NO LIABILITY IN
CONNECTION WITH ANY USE OF THIS INFORMATION.
MATERIAL SAFETY DATA SHEET
E61AC149
03 00
DATE OF PREPARATION: JAN 13, 2010
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NUMBER: E61AC149
PRODUCT NAME: 3.5 VOC EPOXY PRIMER (PART A), GRAY
MANUFACTURER'S NAME:
THE SHERWIN-WILLIAMS COMPANY
101 PROSPECT AVENUE N.W.
CLEVELAND, OH 44115
TELEPHONE NUMBERS AND WEBSITES:
REGULATORY INFORMATION: (216) 566-2902
MEDICAL EMERGENCY: (216) 566-2917
TRANSPORTATION EMERGENCY*: (800) 424-9300
*FOR CHEMICAL EMERGENCY ONLY (SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT)
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
% BY WEIGHT CAS NUMBER INGREDIENT UNITS VAPOR
PRESSURE
0.1 100-41-4 ETHYLBENZENE 7.1 MM
ACGIH TLV: 100 PPM
ACGIH TLV: 125 PPM STEL
OSHA PEL: 100 PPM
OSHA PEL: 125 PPM STEL
3 107-87-9 METHYL N-PROPYL KETONE 27.8 MM
ACGIH TLV: 150 PPM STEL
OSHA PEL: 200 PPM
OSHA PEL: 250 PPM STEL
1 108-10-1 METHYL ISOBUTYL KETONE 16 MM
ACGIH TLV: 50 PPM
ACGIH TLV: 75 PPM STEL
OSHA PEL: 50 PPM
OSHA PEL: 75 PPM STEL
12 110-43-0 METHYL N-AMYL KETONE 3.855 MM
ACGIH TLV: 50 PPM
OSHA PEL: 100 PPM
2 763-69-9 ETHYL 3-ETHOXYPROPIONATE 1.11 MM
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
3 108-65-6 1-METHOXY-2-PROPANOL ACETATE 1.8 MM
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
4 PROPRIETARY EPOXY POLYMER
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
2 25036-25-3 EPOXY POLYMER
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
2 25068-38-6 EPOXY POLYMER
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
4 25085-99-8 EPOXY POLYMER
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
1 2530-83-8 ORGANOSILANE ESTER
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
0.1 14808-60-7 QUARTZ
ACGIH TLV: 0.025 MG/M3 AS RESP. DUST
OSHA PEL: 0.1 MG/M3 AS RESP. DUST
10 14807-96-6 TALC
ACGIH TLV: 2 MG/M3 AS RESP. DUST
OSHA PEL: 2 MG/M3 AS RESP. DUST
16 7727-43-7 BARIUM SULFATE
ACGIH TLV: 10 MG/M3 AS DUST
OSHA PEL: 10 MG/M3 TOTAL DUST
OSHA PEL: 5 MG/M3 RESPIRABLE
FRACTION
10 13463-67-7 TITANIUM DIOXIDE
ACGIH TLV: 10 MG/M3 AS DUST
OSHA PEL: 10 MG/M3 TOTAL DUST
OSHA PEL: 5 MG/M3 RESPIRABLE
FRACTION
| SECTION 3 - HAZARDS IDENTIFICATION | |
HMIS CODES:
HEALTH 3*
FLAMMABILITY 3
REACTIVITY 1
ROUTES OF EXPOSURE:
INHALATION OF VAPOR OR SPRAY MIST.
EYE OR SKIN CONTACT WITH THE PRODUCT, VAPOR OR SPRAY MIST.
EFFECTS OF OVEREXPOSURE:
EYES: IRRITATION.
SKIN: PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION.
INHALATION: IRRITATION OF THE UPPER RESPIRATORY SYSTEM.
MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN
UNCONSCIOUSNESS AND POSSIBLY DEATH.
PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS IN SECTION 2 MAY CAUSE
ADVERSE EFFECTS TO THE LIVER, URINARY AND BLOOD FORMING SYSTEMS.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS.
REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN
EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
MAY CAUSE ALLERGIC SKIN REACTION IN SUSCEPTIBLE PERSONS OR SKIN
SENSITIZATION.
CANCER INFORMATION:
FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11.
| SECTION 4 - FIRST AID MEASURES | |
EYES:
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL
ATTENTION.
SKIN:
WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
IF IRRITATION PERSISTS OR OCCURS LATER, GET MEDICAL ATTENTION.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
INHALATION:
IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT: 76 DEG. F PMCC
LEL: 1.0
UEL: 13.1
FLAMMABILITY CLASSIFICATION:
RED LABEL - FLAMMABLE, FLASH BELOW 100 DEG. F (38 DEG. C)
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.
DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY
CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN
MEDICAL ATTENTION.
SPECIAL FIRE FIGHTING PROCEDURES:
FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS
SHOULD BE USED.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE
BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME
HEAT.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA.
REMOVE WITH INERT ABSORBENT.
| SECTION 7 - HANDLING AND STORAGE | |
STORAGE CATEGORY: DOL STORAGE CLASS IC
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
CONTENTS ARE FLAMMABLE. KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.
DURING USE AND UNTIL ALL VAPORS ARE GONE:
KEEP AREA VENTILATED - DO NOT SMOKE - EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS - TURN OFF STOVES, ELECTRIC TOOLS AND APPLIANCES, AND ANY OTHER
SOURCES OF IGNITION.
CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING PROCEDURES.
KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED CONTAINERS
WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF
THE REACH OF CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRECAUTIONS TO BE TAKEN IN USE:
USE ONLY WITH ADEQUATE VENTILATION.
AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR AND SPRAY MIST.
WASH HANDS AFTER USING.
THIS COATING MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES
(LISTED "AS DUST" IN SECTION 2) WHICH MAY BE PRESENT AT HAZARDOUS LEVELS
ONLY DURING SANDING OR ABRADING OF THE DRIED FILM. IF NO SPECIFIC DUSTS ARE
LISTED IN SECTION 2, THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE
ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION),
OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION).
VENTILATION:
LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO
MATERIALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION:
IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY
VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR
APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS IN SECTION 2.
WHEN SANDING OR ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR
APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT,
UNDERLYING PAINT, OR THE ABRASIVE.
PROTECTIVE GLOVES:
WEAR GLOVES WHICH ARE RECOMMENDED BY GLOVE SUPPLIER FOR PROTECTION AGAINST
MATERIALS IN SECTION 2.
EYE PROTECTION: WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
OTHER PROTECTIVE EQUIPMENT:
USE OF BARRIER CREAM ON EXPOSED SKIN IS RECOMMENDED.
OTHER PRECAUTIONS:
THIS PRODUCT MUST BE MIXED WITH OTHER COMPONENTS BEFORE USE. BEFORE OPENING
THE PACKAGES, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
CAN BE HARMFUL OR FATAL.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
PRODUCT WEIGHT:
13.81 LB/GAL
1655 G/L
SPECIFIC GRAVITY: 1.66
BOILING POINT:
217 - 342 DEG. F
102 - 172 DEG. C
MELTING POINT: NOT AVAILABLE
VOLATILE VOLUME: 44%
EVAPORATION RATE: SLOWER THAN ETHER
VAPOR DENSITY: HEAVIER THAN AIR
SOLUBILITY IN WATER: N.A.
VOLATILE ORGANIC COMPOUNDS (VOC THEORETICAL - AS PACKAGED):
3.10 LB/GAL 372 G/L LESS WATER AND FEDERALLY EXEMPT SOLVENTS
3.10 LB/GAL 372 G/L EMITTED VOC
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBILITY: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
BY FIRE:
CARBON DIOXIDE, CARBON MONOXIDE, PHOSPHORIC ACID FUMES, OXIDES OF
PHOSPHORUS
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
CHRONIC HEALTH HAZARDS:
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
ETHYLBENZENE IS CLASSIFIED BY IARC AS POSSIBLY CARCINOGENIC TO HUMANS (2B)
BASED ON INADEQUATE EVIDENCE IN HUMANS AND SUFFICIENT EVIDENCE IN
LABORATORY ANIMALS. LIFETIME INHALATION EXPOSURE OF RATS AND MICE TO HIGH
ETHYLBENZENE CONCENTRATIONS RESULTED IN INCREASES IN CERTAIN TYPES OF
CANCER, INCLUDING KIDNEY TUMORS IN RATS AND LUNG AND LIVER TUMORS IN MICE.
THESE EFFECTS WERE NOT OBSERVED IN ANIMALS EXPOSED TO LOWER CONCENTRATIONS.
THERE IS NO EVIDENCE THAT ETHYLBENZENE CAUSES CANCER IN HUMANS.
CRYSTALLINE SILICA (QUARTZ, CRISTOBALITE) IS LISTED BY IARC AND NTP. LONG
TERM EXPOSURE TO HIGH LEVELS OF SILICA DUST, WHICH CAN OCCUR ONLY WHEN
SANDING OR ABRADING THE DRY FILM, MAY CAUSE LUNG DAMAGE (SILICOSIS) AND
POSSIBLY CANCER.
IARC'S MONOGRAPH NO. 93 REPORTS THERE IS SUFFICIENT EVIDENCE OF
CARCINOGENICITY IN EXPERIMENTAL RATS EXPOSED TO TITANIUM DIOXIDE BUT
INADEQUATE EVIDENCE FOR CARCINOGENICITY IN HUMANS AND HAS ASSIGNED A GROUP
2B RATING. IN ADDITION, THE IARC SUMMARY CONCLUDES, "NO SIGNIFICANT
EXPOSURE TO TITANIUM DIOXIDE IS THOUGHT TO OCCUR DURING THE USE OF PRODUCTS
IN WHICH TITANIUM IS BOUND TO OTHER MATERIALS, SUCH AS PAINT."
TOXICOLOGY DATA:
CAS NO. INGREDIENT NAME
100-41-4 ETHYLBENZENE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 3500 MG/KG
107-87-9 METHYL N-PROPYL KETONE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 1600 MG/KG
108-10-1 METHYL ISOBUTYL KETONE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 2080 MG/KG
110-43-0 METHYL N-AMYL KETONE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 1670 MG/KG
763-69-9 ETHYL 3-ETHOXYPROPIONATE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 5000 MG/KG
108-65-6 1-METHOXY-2-PROPANOL ACETATE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 8500 MG/KG
PROPRIETARY EPOXY POLYMER
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
25036-25-3 EPOXY POLYMER
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
25068-38-6 EPOXY POLYMER
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
25085-99-8 EPOXY POLYMER
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
2530-83-8 ORGANOSILANE ESTER
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
14808-60-7 QUARTZ
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
14807-96-6 TALC
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
7727-43-7 BARIUM SULFATE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
13463-67-7 TITANIUM DIOXIDE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261.
WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA
HAZARDOUS WASTE NUMBERS.
INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINER.
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL, AND LOCAL
REGULATIONS REGARDING POLLUTION.
| SECTION 14 - TRANSPORT INFORMATION | |
US GROUND (DOT):
1 GALLON AND LESS MAY BE CLASSED AS CONSUMER COMMODITY, ORM-D
LARGER CONTAINERS ARE REGULATED AS: UN1263, PAINT, 3, PG III, (ERG#128)
DOT (DEPT OF TRANSPORTATION) HAZARDOUS SUBSTANCES & REPORTABLE QUANTITIES:
XYLENES (ISOMERS AND MIXTURE): 100 LB RQ
BULK CONTAINERS MAY BE SHIPPED AS (CHECK REPORTABLE QUANTITIES):
UN1263, PAINT, 3, PG III, (ERG#128)
CANADA (TDG): UN1263, PAINT, CLASS 3, PG III, LIMITED QUANTITY, (ERG#128)
IMO: UN1263, PAINT, CLASS 3, PG III, (24 C C.C.), EMS F-E, S-E, ADR (D/E)
| SECTION 15 - REGULATORY INFORMATION | |
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION:
CAS NO. CHEMICAL/COMPOUND % BY WT % ELEMENT
100-41-4 ETHYLBENZENE 0.1
108-10-1 METHYL ISOBUTYL KETONE 1
ZINC COMPOUND 5 2.4
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
TSCA CERTIFICATION:
ALL CHEMICALS IN THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON
THE TSCA INVENTORY.
| SECTION 16 - OTHER INFORMATION | |
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS
ALL OF THE INFORMATION REQUIRED BY THE CPR.
THE ABOVE INFORMATION PERTAINS TO THIS PRODUCT AS CURRENTLY FORMULATED, AND
IS BASED ON THE INFORMATION AVAILABLE AT THIS TIME. ADDITION OF REDUCERS OR
OTHER ADDITIVES TO THIS PRODUCT MAY SUBSTANTIALLY ALTER THE COMPOSITION AND
HAZARDS OF THE PRODUCT. SINCE CONDITIONS OF USE ARE OUTSIDE OUR CONTROL, WE
MAKE NO WARRANTIES, EXPRESS OR IMPLIED, AND ASSUME NO LIABILITY IN
CONNECTION WITH ANY USE OF THIS INFORMATION.
MATERIAL SAFETY DATA SHEET
V66VC248
01 00
DATE OF PREPARATION: JAN 5, 2010
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NUMBER: V66VC248
PRODUCT NAME: AMINE HARDENER (PART B)
MANUFACTURER'S NAME:
THE SHERWIN-WILLIAMS COMPANY
101 PROSPECT AVENUE N.W.
CLEVELAND, OH 44115
TELEPHONE NUMBERS AND WEBSITES:
REGULATORY INFORMATION: (216) 566-2902
MEDICAL EMERGENCY: (216) 566-2917
TRANSPORTATION EMERGENCY*: (800) 424-9300
*FOR CHEMICAL EMERGENCY ONLY (SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT)
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
% BY WEIGHT CAS NUMBER INGREDIENT UNITS VAPOR
PRESSURE
60 71-36-3 1-BUTANOL 5.5 MM
ACGIH TLV: 20 PPM
OSHA PEL: 50 PPM (SKIN) CEILING
7 100-51-6 PHENYLMETHANOL 0.15 MM
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
2 90-72-2 TRI(DIMETHYLAMINOMETHYL)PHENOL
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
2 PROPRIETARY MODIFIED ALIPHATIC AMINE
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
1 1477-55-0 1,3-BENZENEDIMETHANAMINE
ACGIH TLV: 0.1 PPM (SKIN) CEILING
OSHA PEL: 0.1 PPM (SKIN) CEILING
2 1761-71-3 METHYLENEDICYCLOHEXYLAMINE
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
17 PROPRIETARY POLYAMIDE
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
7 PROPRIETARY AMINO POLYMER
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
| SECTION 3 - HAZARDS IDENTIFICATION | |
HMIS CODES:
HEALTH 3*
FLAMMABILITY 3
REACTIVITY 0
ROUTES OF EXPOSURE:
INHALATION OF VAPOR OR SPRAY MIST.
EYE OR SKIN CONTACT WITH THE PRODUCT, VAPOR OR SPRAY MIST.
EFFECTS OF OVEREXPOSURE:
EYES: CAUSES BURNS.
SKIN: CAUSES BURNS.
INHALATION: CAUSES BURNS OF THE UPPER RESPIRATORY SYSTEM.
MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN
UNCONSCIOUSNESS AND POSSIBLY DEATH.
PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS IN SECTION 2 MAY CAUSE
ADVERSE EFFECTS TO THE LIVER, URINARY AND NERVOUS SYSTEMS.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS.
REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN
EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
MAY CAUSE ALLERGIC SKIN REACTION IN SUSCEPTIBLE PERSONS OR SKIN
SENSITIZATION.
CANCER INFORMATION:
FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11.
| SECTION 4 - FIRST AID MEASURES | |
EYES:
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL
ATTENTION IMMEDIATELY.
SKIN:
WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
IF IRRITATION PERSISTS OR OCCURS LATER, GET MEDICAL ATTENTION.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
INHALATION:
IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT: 95 DEG. F PMCC
LEL: 1.4
UEL: 11.2
FLAMMABILITY CLASSIFICATION:
RED LABEL - FLAMMABLE, FLASH BELOW 100 DEG. F (38 DEG. C)
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.
DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY
CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN
MEDICAL ATTENTION.
SPECIAL FIRE FIGHTING PROCEDURES:
FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS
SHOULD BE USED.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE
BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME
HEAT.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA.
REMOVE WITH INERT ABSORBENT.
| SECTION 7 - HANDLING AND STORAGE | |
STORAGE CATEGORY: DOL STORAGE CLASS IC
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
CONTENTS ARE FLAMMABLE. KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.
DURING USE AND UNTIL AIL VAPORS ARE GONE:
KEEP AREA VENTILATED - DO NOT SMOKE - EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS - TURN OFF STOVES, ELECTRIC TOOLS AND APPLIANCES, AND ANY OTHER
SOURCES OF IGNITION.
CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING PROCEDURES.
KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED CONTAINERS
WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF
THE REACH OF CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRECAUTIONS TO BE TAKEN IN USE:
USE ONLY WITH ADEQUATE VENTILATION.
DO NOT GET IN EYES, OR ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR OR SPRAY
MIST.
WASH HANDS AFTER USING.
THIS COATING MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES
(LISTED "AS DUST" IN SECTION 2) WHICH MAY BE PRESENT AT HAZARDOUS LEVELS
ONLY DURING SANDING OR ABRADING OF THE DRIED FILM. IF NO SPECIFIC DUSTS ARE
LISTED IN SECTION 2, THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE
ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION),
OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION).
VENTILATION:
LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO
MATERIALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION:
IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY
VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR
APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS IN SECTION 2.
WHEN SANDING OR ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR
APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT,
UNDERLYING PAINT, OR THE ABRASIVE.
PROTECTIVE GLOVES:
TO PREVENT SKIN CONTACT, WEAR GLOVES WHICH ARE RECOMMENDED BY GLOVE
SUPPLIER FOR PROTECTION AGAINST MATERIALS IN SECTION 2.
EYE PROTECTION:
TO PREVENT EYE CONTACT, WEAR SAFETY SPECTACLES WITH IMPERFORATED
SIDESHIELDS.
OTHER PROTECTIVE EQUIPMENT: USE BARRIER CREAM ON EXPOSED SKIN.
OTHER PRECAUTIONS:
THIS PRODUCT MUST BE MIXED WITH OTHER COMPONENTS BEFORE USE. BEFORE OPENING
THE PACKAGES, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
CAN BE HARMFUL OR FATAL.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
PRODUCT WEIGHT:
7.34 LB/GAL
879 G/L
SPECIFIC GRAVITY: 0.88
BOILING POINT:
243 - 405 DEG. F
117 - 207 DEG. C
MELTING POINT: NOT AVAILABLE
VOLATILE VOLUME: 72%
EVAPORATION RATE: SLOWER THAN ETHER
VAPOR DENSITY: HEAVIER THAN AIR
SOLUBILITY IN WATER: N.A.
VOLATILE ORGANIC COMPOUNDS (VOC THEORETICAL - AS PACKAGED):
4.98 LB/GAL 597 G/L LESS WATER AND FEDERALLY EXEMPT SOLVENTS
4.98 LB/GAL 597 G/L EMITTED VOC
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBILITY: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
CHRONIC HEALTH HAZARDS:
NO INGREDIENT IN THIS PRODUCT IS AN IARC, NTP OR OSHA LISTED CARCINOGEN.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
TOXICOLOGY DATA:
CAS NO. INGREDIENT NAME
71-36-3 1-BUTANOL
LC50 RAT 4HR: 8000 PPM
LD50 RAT: 790 MG/KG
100-51-6 PHENYLMETHANOL
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
90-72-2 TRI(DIMETHYLAMINOMETHYL)PHENOL
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 1653 MG/KG
PROPRIETARY MODIFIED ALIPHATIC AMINE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
1477-55-0 1,3-BENZENEDIMETHANAMINE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
1761-71-3 METHYLENEDICYCLOHEXYLAMINE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
PROPRIETARY POLYAMIDE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
PROPRIETARY AMINO POLYMER
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261.
WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA
HAZARDOUS WASTE NUMBERS.
INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINER.
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL, AND LOCAL
REGULATIONS REGARDING POLLUTION.
| SECTION 14 - TRANSPORT INFORMATION | |
US GROUND (DOT):
1 GALLON AND LESS MAY BE CLASSED AS CONSUMER COMMODITY, ORM-D
LARGER CONTAINERS ARE REGULATED AS:
UN3469, PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE, 3 (6), PG III,
(ERG#132)
DOT (DEPT OF TRANSPORTATION) HAZARDOUS SUBSTANCES & REPORTABLE QUANTITIES:
1-BUTANOL: 5000 LB RQ
BULK CONTAINERS MAY BE SHIPPED AS (CHECK REPORTABLE QUANTITIES):
UN3469, PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE, 3 (8), PG III,
(ERG#132)
CANADA (TDG):
UN3469, PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE, CLASS 3 (8),
PG III, LIMITED QUANTITY, (ERG#132)
IMO:
UN3469, PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE, CLASS 3, (8),
PG III, (35 C C.C.), EMS F-E, S-C, ADR (D/E)
| SECTION 15 - REGULATORY INFORMATION | |
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION:
CAS NO. CHEMICAL/COMPOUND % BY WT % ELEMENT
71-36-3 1-BUTANOL 60
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
TSCA CERTIFICATION:
ALL CHEMICALS IN THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON
THE TSCA INVENTORY.
| SECTION 16 - OTHER INFORMATION | |
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS
ALL OF THE INFORMATION REQUIRED BY THE CPR.
THE ABOVE INFORMATION PERTAINS TO THIS PRODUCT AS CURRENTLY FORMULATED, AND
IS BASED ON THE INFORMATION AVAILABLE AT THIS TIME. ADDITION OF REDUCERS OR
OTHER ADDITIVES TO THIS PRODUCT MAY SUBSTANTIALLY ALTER THE COMPOSITION AND
HAZARDS OF THE PRODUCT. SINCE CONDITIONS OF USE ARE OUTSIDE OUR CONTROL, WE
MAKE NO WARRANTIES, EXPRESS OR IMPLIED, AND ASSUME NO LIABILITY IN
CONNECTION WITH ANY USE OF THIS INFORMATION.
MATERIAL SAFETY DATA SHEET
F63RXW13761-4373
00 01
DATE OF PREPARATION: JUN 1, 2009
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NUMBER: F63RXW13761-4373
PRODUCT NAME: POLANE * S PLUS POLYURETHANE ENAMEL, NEW TEREX WHITE 60
MANUFACTURER'S NAME:
THE SHERWIN-WILLIAMS COMPANY
101 PROSPECT AVENUE N.W.
CLEVELAND, OH 44115
TELEPHONE NUMBERS AND WEBSITES:
REGULATORY INFORMATION: (216) 566-2902
MEDICAL EMERGENCY: (216) 566-2917
TRANSPORTATION EMERGENCY*: (800) 424-9300
* FOR CHEMICAL EMERGENCY ONLY (SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT)
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
% BY WEIGHT CAS NUMBER INGREDIENT UNITS VAPOR
PRESSURE
21 110-43-0 METHYL N-AMYL KETONE 3.855 MM
ACGIH TLV: 50 PPM
OSHA PEL: 100 PPM
2 14807-96-6 TALC
ACGIH TLV: 2 MG/M3 AS RESP. DUST
OSHA PEL: 2 MG/M3 AS RESP. DUST
30 13463-67-7 TITANIUM DIOXIDE
ACGIH TLV: 10 MG/M3 AS DUST
OSHA PEL: 15 MG/M3 TOTAL DUST
OSHA PEL: 5 MG/M3 RESPIRABLE
FRACTION
| SECTION 3 - HAZARDS IDENTIFICATION | |
HMIS CODES:
HEALTH 2*
FLAMMABILITY 2
REACTIVITY 0
ROUTES OF EXPOSURE:
INHALATION OF VAPOR OR SPRAY MIST.
EYE OR SKIN CONTACT WITH THE PRODUCT, VAPOR OR SPRAY MIST.
EFFECTS OF OVEREXPOSURE:
EYES: IRRITATION.
SKIN: PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION.
INHALATION: IRRITATION OF THE UPPER RESPIRATORY SYSTEM.
MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN
UNCONSCIOUSNESS AND POSSIBLY DEATH.
PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS IN SECTION 2 MAY CAUSE
ADVERSE EFFECTS TO THE LIVER AND URINARY SYSTEMS.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS.
REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN
EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
MAY CAUSE ALLERGIC RESPIRATORY AND/OR SKIN REACTION IN SUSCEPTIBLE PERSONS
OR SENSITIZATION. THIS EFFECT MAY BE DELAYED SEVERAL HOURS AFTER EXPOSURE.
PERSONS SENSITIVE TO ISOCYANATES WILL EXPERIENCE INCREASED ALLERGIC
REACTION ON REPEATED EXPOSURE.
CANCER INFORMATION:
FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11.
| SECTION 4 - FIRST AID MEASURES | |
EYES:
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL
ATTENTION.
SKIN:
WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
INHALATION:
IF ANY BREATHING PROBLEMS OCCUR DURING USE, LEAVE THE AREA AND GET FRESH
AIR. IF PROBLEMS REMAIN OR OCCUR LATER, IMMEDIATELY GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT: 100 DEG. F TCC
LEL: 1.1
UEL: 7.9
FLAMMABILITY CLASSIFICATION:
COMBUSTIBLE, FLASH ABOVE 99 AND BELOW 200 DEG. F
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.
DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY
CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN
MEDICAL ATTENTION.
SPECIAL FIRE FIGHTING PROCEDURES:
FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS
SHOULD BE USED.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE
BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME
HEAT.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA.
REMOVE WITH INERT ABSORBENT.
| SECTION 7 - HANDLING AND STORAGE | |
STORAGE CATEGORY: DOL STORAGE CLASS II
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
CONTENTS ARE COMBUSTIBLE. KEEP AWAY FROM HEAT AND OPEN FLAME.
CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING PROCEDURES.
KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED CONTAINERS
WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF
THE REACH OF CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRECAUTIONS TO BE TAKEN IN USE:
NO PERSON SHOULD USE THIS PRODUCT, OR BE IN THE AREA WHERE IT IS BEING
USED, IF THEY HAVE CHRONIC (LONG-TERM) LUNG OR BREATHING PROBLEMS OR IF
THEY EVER HAD A REACTION TO ISOCYANATES.
USE ONLY WITH ADEQUATE VENTILATION.
AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR AND SPRAY MIST.
WASH HANDS AFTER USING.
THIS COATING MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES
(LISTED "AS DUST" IN SECTION 2) WHICH MAY BE PRESENT AT HAZARDOUS LEVELS
ONLY DURING SANDING OR ABRADING OF THE DRIED FILM. IF NO SPECIFIC DUSTS ARE
LISTED IN SECTION 2, THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE
ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION),
OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION).
VENTILATION:
LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO
MATERIALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION:
WHERE OVERSPRAY IS PRESENT, A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR
(TC19C NIOSH/MSHA APPROVED) SHOULD BE WORN. IF UNAVAILABLE, A PROPERLY
FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR
PROTECTION AGAINST MATERIALS IN SECTION 2 MAY BE EFFECTIVE. FOLLOW
RESPIRATOR MANUFACTURERS DIRECTIONS FOR USE. WEAR THE RESPIRATOR FOR THE
WHOLE TIME OF SPRAYING AND UNTIL ALL VAPORS AND MISTS ARE GONE. NO PERSONS
SHOULD BE ALLOWED IN THE AREA WHERE THIS PRODUCT IS BEING USED UNLESS
EQUIPPED WITH THE SAME RESPIRATOR PROTECTION RECOMMENDED FOR THE PAINTERS.
WHEN SANDING OR ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR
APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT,
UNDERLYING PAINT, OR THE ABRASIVE.
PROTECTIVE GLOVES:
TO PREVENT SKIN CONTACT, WEAR GLOVES WHICH ARE RECOMMENDED BY GLOVE
SUPPLIER FOR PROTECTION AGAINST MATERIALS IN SECTION 2.
EYE PROTECTION: WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
OTHER PROTECTIVE EQUIPMENT: USE BARRIER CREAM ON EXPOSED SKIN.
OTHER PRECAUTIONS:
THIS PRODUCT MUST BE MIXED WITH OTHER COMPONENTS BEFORE USE. BEFORE OPENING
THE PACKAGES, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
CAN BE HARMFUL OR FATAL.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
PRODUCT WEIGHT:
12.76 LB/GAL
1529 G/L
SPECIFIC GRAVITY: 1.54
BOILING POINT:
297 - 308 DEG. F
147 - 153 DEG. C
MELTING POINT: NOT AVAILABLE
VOLATILE VOLUME: 42%
EVAPORATION RATE: SLOWER THAN ETHER
VAPOR DENSITY: HEAVIER THAN AIR
SOLUBILITY IN WATER: N.A.
VOLATILE ORGANIC COMPOUNDS (VOC THEORETICAL - AS PACKAGED):
2.91 LB/GAL 349 G/L LESS WATER AND FEDERALLY EXEMPT SOLVENTS
2.91 LB/GAL 349 G/L EMITTED VOC
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBILITY: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
CHRONIC HEALTH HAZARDS:
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
IARC'S MONOGRAPH NO. 93 REPORTS THERE IS SUFFICIENT EVIDENCE OF
CARCINOGENICITY IN EXPERIMENTAL RATS EXPOSED TO TITANIUM DIOXIDE BUT
INADEQUATE EVIDENCE FOR CARCINOGENICITY IN HUMANS AND HAS ASSIGNED A GROUP
2B RATING. IN ADDITION, THE IARC SUMMARY CONCLUDES, "NO SIGNIFICANT
EXPOSURE TO TITANIUM DIOXIDE IS THOUGHT TO OCCUR DURING THE USE OF PRODUCTS
IN WHICH TITANIUM IS BOUND TO OTHER MATERIALS, SUCH AS PAINT."
TOXICOLOGY DATA:
CAS NO. INGREDIENT NAME
110-43-0 METHYL N-AMYL KETONE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 1670 MG/KG
14807-96-6 TALC
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
13463-67-7 TITANIUM DIOXIDE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261.
WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA
HAZARDOUS WASTE NUMBERS.
INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINER.
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL, AND LOCAL
REGULATIONS REGARDING POLLUTION.
| SECTION 14 - TRANSPORT INFORMATION | |
US GROUND (DOT):
MAY BE CLASSED AS A COMBUSTIBLE LIQUID FOR U.S. GROUND.
UN1263, PAINT, 3, PG III, (ERG#128)
BULK CONTAINERS MAY BE SHIPPED AS:
UN1263, PAINT, COMBUSTIBLE LIQUID, PG III, (ERG#128)
CANADA (TDG):
MAY BE CLASSED AS A COMBUSTIBLE LIQUID FOR CANADIAN GROUND.
UN1263, PAINT, CLASS 3, PG III, (ERG#128)
IMO: UN1263, PAINT, CLASS 3, PG III, (38 C C.C.), EMS F-E, S-E
| SECTION 15 - REGULATORY INFORMATION | |
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION:
CAS NO. CHEMICAL/COMPOUND % BY WT % ELEMENT
NO INGREDIENTS IN THIS PRODUCT ARE SUBJECT TO SARA 313 (40 CFR 372.65C)
SUPPLIER NOTIFICATION.
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
TSCA CERTIFICATION:
ALL CHEMICALS IN THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON
THE TSCA INVENTORY.
| SECTION 16 - OTHER INFORMATION | |
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS
ALL OF THE INFORMATION REQUIRED BY THE CPR.
THE ABOVE INFORMATION PERTAINS TO THIS PRODUCT AS CURRENTLY FORMULATED, AND
IS BASED ON THE INFORMATION AVAILABLE AT THIS TIME. ADDITION OF REDUCERS OR
OTHER ADDITIVES TO THIS PRODUCT MAY SUBSTANTIALLY ALTER THE COMPOSITION AND
HAZARDS OF THE PRODUCT. SINCE CONDITIONS OF USE ARE OUTSIDE OUR CONTROL, WE
MAKE NO WARRANTIES, EXPRESS OR IMPLIED, AND ASSUME NO LIABILITY IN
CONNECTION WITH ANY USE OF THIS INFORMATION.
OSRAM SYLVANIA
PRODUCT SAFETY DATA SHEET
PSDS NO.: 1.5.1
METAL HALIDE LAMPS
LEAD - FREE
SYLVANIA BRAND METAL HALIDE LAMPS, MANUFACTURED BY OSRAM SYLVANIA PRODUCTS
INC., ARE EXEMPTED FROM THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200) BECAUSE THEY ARE "ARTICLES." THE FOLLOWING
INFORMATION IS PROVIDED BY OSRAM SYLVANIA AS A COURTESY TO ITS CUSTOMERS.
| I. PRODUCT IDENTIFICATION | |
TRADE NAME (AS LABELED):
SYLVANIA METALARC(R*) AND METALARC PRO-TECH(R*) LAMPS
(LEAD-FREE METAL HALIDE LAMPS FOR GENERAL LIGHTING)
THIS DATA SHEET COVERS PAR 38 MEDIUM-BASED LAMPS AND ALL MOGUL BASED
LAMPS EXCEPT MP-175, MP-250, MP-320/350, MP-350/400, MP-360, MI-400,
& MP-1000
MANUFACTURER:
OSRAM SYLVANIA PRODUCTS INC.
655 SOUTH WILLOW STREET
MANCHESTER, NH 03103-5705
(603) 669-5350
| II. HAZARDOUS INGREDIENTS | |
THERE ARE NO KNOWN HEALTH HAZARDS FROM EXPOSURE TO LAMPS THAT ARE INTACT.
IF A LAMP IS BROKEN, THE FOLLOWING MATERIALS MAY BE RELEASED:
CHEMICAL NAME CAS NUMBER % BY WT. EXPOSURE LIMITS IN AIR (MG/CUBIC M)
ACGIH (TLV) OSHA (PEL)
BARIUM PEROXIDE 1304-29-6 0-<0.6 0.5
(1,2) MERCURY 7439-97-6 <0.1 0.025 0.1 CEILING
SODIUM 7440-23-5 <0.01
QUARTZ, FUSED 60676-86-0 10-30 0.1 RESP. 0.1
DUST
GLASS (TUNGSTEN- 50-75 10(3) 15(3)
SEALING
BOROSILICATE)
YTTRIUM 13566-12-6 0-<0.5 1.0 1.0
VANADATE
ALUMINUM OXIDE 1344-28-1 0-<0.03 10(3) 15(3)
(1) THIS CHEMICAL IS SUBJECT TO THE REPORTING REQUIREMENTS OR SECTION 313
OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
AND 40 CFR PART 372.
(2) THE MERCURY IN THIS PRODUCT IS ONE OF THE SUBSTANCES KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY IF INGESTED. [CALIFORNIA SAFE
DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65).]
(3) LIMITS AS NUISANCE PARTICULATE.
| III. PHYSICAL PROPERTIES | |
NOT APPLICABLE TO INTACT LAMP.
| IV. FIRE & EXPLOSION HAZARDS | |
FLAMMABILITY: NON-COMBUSTIBLE.
FIRE EXTINGUISHING MATERIALS:
USE EXTINGUISHING AGENTS SUITABLE FOR SURROUNDING FIRE.
SPECIAL FIREFIGHTING PROCEDURE:
USE A SELF-CONTAINED BREATHING APPARATUS TO PREVENT INHALATION OF DUST
AND/OR FUMES THAT MAY BE GENERATED FROM BROKEN LAMPS DURING FIREFIGHTING
ACTIVITIES.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
WHEN EXPOSED TO HIGH TEMPERATURE, TOXIC FUMES MAY BE RELEASED FROM BROKEN
LAMPS.
| V. HEALTH HAZARDS | |
A. OPERATING LAMPS:
CONSULT THE OSRAM SYLVANIA PRODUCT CATALOG OR RELEVANT TECHNICAL DATA
SHEETS FOR COMPLETE WARNINGS, OPERATING AND INSTALLATION GUIDES FOR
SPECIFIC LAMP TYPES.
WARNING:
METAL HALIDE ARE-TUBES OPERATE AT HIGH PRESSURE AND HIGH TEMPERATURE AND
MAY UNEXPECTEDLY RUPTURE.
IF THE OUTER JACKET IS BROKEN AND THE LAMP CONTINUES TO OPERATE,
ULTRAVIOLET RADIATION WHICH MAY CAUSE SKIN AND EYE IRRITATION WITH
PROLONGED EXPOSURE MAY BE EMITTED. IMMEDIATELY SHUT POWER OFF AND REPLACE
LAMP.
METAL HALIDE LAMPS MUST BE OPERATED ONLY IN SUITABLE DESIGNED MIXTURES.
B. LAMP MATERIALS:
THERE ARE NO KNOWN HEALTH HAZARDS FROM EXPOSURE TO LAMPS THAT ARE INTACT,
NO ADVERSE EFFECTS ARE EXPECTED FROM OCCASIONAL EXPOSURE TO BROKEN LAMPS.
AS A MATTER OF GOOD PRACTICE, AVOID PROLONGED OR FREQUENT EXPOSURE TO
BROKEN LAMPS UNLESS THERE IS ADEQUATE VENTILATION. THE MAJOR HAZARD FROM
BROKEN LAMPS IS THE POSSIBILITY OF SUSTAINING GLASS CUTS.
NIOSH/OSHA OCCUPATIONAL HEALTH GUIDELINES FOR CHEMICAL HAZARDS AND/OR
NIOSH POCKET GUIDE TO CHEMICAL HAZARDS LISTS THE FOLLOWING EFFECTS OF
OVEREXPOSURE TO THE CHEMICALS/MATERIALS TABULATED BELOW WHEN THEY ARE
INHALED, INGESTED, OR CONTACTED WITH SKIN OR EYE:
MERCURY:
EXPOSURE TO HIGH CONCENTRATIONS OF VAPORS FOR BRIEF PERIODS CAN CAUSE ACUTE
SYMPTOMS SUCH AS PNEUMONITIS. CHEST PAINS, SHORTNESS OF BREATH, COUGHING,
GINGIVITIS, SALIVATION AND POSSIBLY STOMATITIS. MAY CAUSE REDNESS AND
IRRITATION AS A RESULT OF CONTACT WITH SKIN AND/OR EYES.
BARIUM PEROXIDE:
MAY BE FATAL IF SWALLOWED. HARMFUL DUST, AVOID SKIN AND EYE CONTACT.
QUARTZ, FUSED:
FIBROSIS OF THE LUNGS CAUSING SHORTNESS OF BREATH AND COUGHING HAS BEEN
ASSOCIATED WITH SILICA EXPOSURE.
SODIUM:
SKIN CONTACT CAN CAUSE THERMAL AND/OR ALKALI BURNS. FUMES FROM BURNING
SODIUM ARE HIGHLY IRRITATING TO SKIN, EYES AND MUCOUS MEMBRANES.
GLASS:
GLASS DUST IS CONSIDERED TO BE PHYSIOLOGICALLY INERT AND AS SUCH, HAS AN
OSHA EXPOSURE LIMIT OF 15 MG/CUBIC METER FOR TOTAL DUST END 5 MG/CUBIC
METER FOR RESPIRABLE DUST. THE ACGIH TLVS FOR PARTICULATES NOT OTHERWISE
CLASSIFIED ARE 10 MG/CUBIC METER FOR TOTAL DUST AND 3 MG/CUBIC METER FOR
RESPIRABLE DUST.
YTTRIUM VANADATE:
INHALATION OF VANADIUM COMPOUNDS CAN CAUSE IRRITATION OF THE NOSE, THROAT,
AND RESPIRATORY TRACT EYE CONTACT AND PROLONGED, REPEATED SKIN CONTACT MAY
ALSO CAUSE IRRITATION. STUDIES OF WORKERS EXPOSED TO THIS MATERIAL SHOWED
NO EVIDENCE OF CHRONIC OR SYSTEMIC EFFECTS.
ALUMINUM OXIDE (ALUMINA):
ALUMINA IS A NON-TOXIC MATERIAL WHICH IS VERY LOW IN FREE-SILICA CONTENT.
SHARP-EDGED PARTICLES CAN IRRITATE THE EYES, PERHAPS THE SKIN, AND
DEFINITELY THE MUCOUS MEMBRANES OF THE RESPIRATORY TRACT.
EMERGENCY AND FIRST AID PROCEDURES:
GLASS CUTS:
PERFORM NORMAL FIRST AID PROCEDURES. SEEK MEDICAL ATTENTION AS REQUIRED.
INHALATION:
IF DISCOMFORT, IRRITATION OR SYMPTOMS OF PULMONARY INVOLVEMENT DEVELOP,
REMOVE FROM EXPOSURE AND SEEK MEDICAL ATTENTION.
INGESTION: SEEK MEDICAL ATTENTION.
CONTACT, SKIN:
THOROUGHLY WASH AFFECTED AREA WITH MILD SOAP OR DETERGENT AND WATER AND
PREVENT FURTHER CONTACT. SEEK MEDICAL ATTENTION IF IRRITATION OCCURS.
CONTACT, EYE:
WASH EYES, INCLUDING UNDER EYELIDS, IMMEDIATELY WITH COPIOUS AMOUNTS OF
WATER FOR 15 MINUTES. SEEK MEDICAL ATTENTION.
CARCINOGENIC ASSESSMENT (NTP ANNUAL REPORT, IARC MONOGRAPHS, OTHER): NONE
| VI. REACTIVITY DATA | |
STABILITY: STABLE
CONDITIONS TO AVOID: NONE FOR INTACT LAMPS.
INCOMPATIBILITY (MATERIALS TO AVOID): NONE FOR INTACT LAMPS.
HAZARDOUS DECOMPOSITION PRODUCT (INCLUDING COMBUSTION PRODUCTS):
NONE FOR INTACT LAMPS.
HAZARDOUS POLYMERIZATION PRODUCTS: WILL NOT OCCUR.
| VII. PROCEDURES FOR DISPOSAL OF LAMPS | |
OSRAM SYLVANIA RECOMMENDS THAT ALL MERCURY-CONTAINING LAMPS BE RECYCLED.
FOR A LIST OF LAMP RECYCLERS AND TO OBTAIN STATE REGULATORY DISPOSAL
INFORMATION, LOG ONTO WWW.LAMPRECYCLE.ORG.
IF LAMPS ARE BROKEN, VENTILATE AREA WHERE BREAKAGE OCCURRED. CLEAN-UP WITH
A SPECIAL MERCURY VACUUM CLEANER (NOT A STANDARD VACUUM CLEANER) OR OTHER
SUITABLE MEANS THAT AVOIDS DUST AND MERCURY VAPOR GENERATION. TAKE USUAL
PRECAUTIONS FOR COLLECTION OF BROKEN GLASS. PLACE MATERIALS IN CLOSED
CONTAINERS TO AVOID GENERATING DUST AND MERCURY VAPOR.
IT IS THE RESPONSIBILITY OF THE WASTE GENERATOR TO ENSURE PROPER
CLASSIFICATION AND DISPOSAL OF WASTE PRODUCTS. TO THAT END, TCLP TESTS
SHOULD BE CONDUCTED ON ALL WASTE PRODUCTS, INCLUDING THIS ONE, TO DETERMINE
THE ULTIMATE DISPOSITION IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND
LOCAL REGULATIONS. SOME STATES HAVE SPECIFIC DISPOSAL REQUIREMENTS FOR
LAMPS CONTAINING MERCURY.
LAMPS WHICH PASS THE EPA'S TCLP TEST ARE CONSIDERED NON-HAZARDOUS WASTE IN
MOST STATES. ALWAYS REVIEW YOUR LOCAL AND STATE REGULATIONS WHICH CAN VARY.
BASED UPON THE NEMA* STANDARD LL 3 (PROCEDURES FOR HIGH INTENSIVE
DISCHARGE LAMP SAMPLE PREPARATION AND THE TCLP) TESTING PROTOCOL, THE
METALARC PRO-TECH(R*) PAR 3B/ECO(TM) LAMP PASSES THE TCLP TEST.
*NEMA (NATIONAL ELECTRICAL MANUFACTURERS ASSOCIATION) STANDARD MAY BE
OBTAINED FROM NEMA, 1300 NORTH 17TH STREET, SUITE 184; ROSSLYN, VA 22209.
| VIII. SPECIAL HANDLING INFORMATION - FOR BROKEN LAMPS | |
VENTILATION:
USE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION TO MAINTAIN EXPOSURE
LEVELS BELOW THE PEL OR TLV LIMITS. IF SUCH VENTILATION IS UNAVAILABLE,
USE RESPIRATORS AS SPECIFIED BELOW.
RESPIRATORY PROTECTION:
USE APPROPRIATE NIOSH APPROVED RESPIRATOR IF AIRBORNE DUST CONCENTRATIONS
EXCEED THE PERTINENT PEL OR TLV LIMITS. ALL APPROPRIATE SET FORTH IN 29
CFR 1910.134 SHOULD BE MET.
EYE PROTECTION:
OSHA SPECIFIED SAFETY GLASSES, GOGGLES OR FACE SHIELD ARE RECOMMENDED IF
LAMPS ARE BEING BROKEN. IN THE EVENT AN OUTER JACKET IS BROKEN, THE LAMP
SHOULD BE SHUT OFF IMMEDIATELY AND REPLACED TO AVOID EXPOSURE TO
ULTRAVIOLET RADIATION.
PROTECTIVE CLOTHING:
OSHA SPECIFIED CUT AND PUNCTURE-RESISTANT GLOVES ARE RECOMMENDED FOR
DEALING WITH BROKEN LAMPS.
HYGIENIC PRACTICES:
AFTER HANDLING BROKEN LAMPS, WISH THOROUGHLY BEFORE EATING, SMOKING OR
HANDLING TOBACCO PRODUCTS, APPLYING COSMETICS, OR USING TOILET FACILITIES.
ALTHOUGH OSRAM SYLVANIA PRODUCTS INC. ATTEMPTS TO PROVIDE CURRENT AND
ACCURATE INFORMATION HEREIN. IT MAKES NO REPRESENTATIONS REGARDING THE
ACCURACY OR COMPLETENESS OF THE INFORMATION AND ASSUMES NO LIABILITY FOR
ANY LOSS, DAMAGE OR INJURY OF ANY KIND WHICH MAY RESULT FROM, OR ARISE OUT
OF, THE USE OF/OR RELIANCE ON THE INFORMATION BY ANY PERSON.
ISSUE DATE: JUNE 8, 2005 REV B
SUPERSEDES: JULY 10, 2001
IN CASE OF QUESTIONS, PLEASE CALL:
OSRAM SYLVANIA PRODUCTS INC.
ENVIRONMENTAL/SAFETY ENGINEER
(603) 669-5350
071001
PRODUCT SAFETY DATA SHEET FOR SYLVANIA BRAND, LEAD-FREE METALARE(R*) &
METALARE PRO-TECH(R*) LAMPS
TROJAN(R*)
BATTERY COMPANY
TROJAN BATTERY COMPANY
LEAD / ACID BATTERY
MATERIAL SAFETY DATA SHEET
HAZARD RATING:
H 3
F 1
R 2
COR
| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |
MANUFACTURER S NAME: TROJAN BATTERY COMPANY
ADDRESS:
12380 CLARK ST.
SANTA FE SPRINGS, CA 90670
EMERGENCY TELEPHONE NO:
CHEMTREC: 800-424-9300
OTHER INFORMATION CALLS:
562-236-3000
800-423-6569
PERSON RESPONSIBLE FOR PREPARATION: ISMAEL PEDROZA. JR
REVISION DATE: NOVEMBER 07, 2007
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
CAS PRINCIPAL HAZARDOUS HAZARD CATEGORY % ACGIH OSHA
COMPONENT(S) TLV PEL-TWA
(CHEMICAL & COMMON
NAME(S))
7439-92-1 LEAD/LEAD OXIDE/LEAD ACUTE-CHRONIC 60-97% 0.05 0.05
SULFATE MG/M3 MG/M3
7440-36-0 ANTIMONY CHRONIC 1.5-4% 0.5 0.5
MG/M3 MG/M3
7440-38-2 ARSENIC ACUTE-CHRONIC <1% 0.01 0.01
MG/M3 MG/M3
7664-93-9 SULFURIC ACID REACTIVE- 10-38% 1.0 1.0
(BATTERY OXIDIZER MG/M3 MG/M3
ELECTROLYTE) ACUTE-CHRONIC
7440-70-2 CALCIUM REACTIVE <0.15% NOT NOT
ESTAB- ESTAB-
LISHED LISHED
7440-31-5 TIN CHRONIC <0.3% 2.0 NOT
MG/M3 ESTAB-
LISHED
NOTE:
PEL'S FOR INDIVIDUAL STATES "MAY DIFFER FROM OSHA PEL'S. CHECK WITH LOCAL
AUTHORITIES FOR THE APPLICABLE STATE PEL'S.
OSHA - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
NIOSH - NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH.
COMMON NAME:
(USED ON LABEL) TRADE NAME & SYNONYMS: LEAD/ACID STORAGE BATTERY
CHEMICAL FAMILY: TOXIC AND CORROSIVE MATERIAL MIXTURE
CHEMICAL NAME: LEAD/ACID STORAGE BATTERY
FORMULA: LEAD AND ACID (ELECTROLYTE)
| SECTION 3 - HAZARD IDENTIFICATION | |
SIGNS AND SYMPTOMS OF EXPOSURE:
1. ACUTE HAZARDS:
DO NOT OPEN BATTERY. AVOID CONTACT WITH INTERNAL COMPONENTS. INTERNAL
COMPONENTS INCLUDE LEAD AND LIQUID ELECTROLYTE
ELECTROLYTE:
ELECTROLYTE IS CORROSIVE AND CONTACT MAY CAUSE SKIN IRRITATION AND
CHEMICAL BURNS ELECTROLYTE CAUSES SEVERE IRRITATION AND BURNS OF EYES, NOSE
AND THROAT. INGESTION CAN CAUSE SEVERE BURNS AND VOMITING.
LEAD:
DIRECT SKIN OR EYE CONTACT MAY CAUSE LOCAL IRRITATION. INHALATION OR
INGESTION OF LEAD OUST OR FUMES MAY RESULT IN HEADACHE, NAUSEA, VOMITING,
ABDOMINAL SPASMS, FATIGUE, SLEEP DISTURBANCES, WEIGHT LOSS, ANEMIA AND
LEG, ARM AND JOINT PAIN.
2. SUBCHRONIC AND CHRONIC HEALTH EFFECTS:
ELECTROLYTE:
REPEATED CONTACT WITH SULFURIC ACID BATTERY ELECTROLYTE FLUID MAY CAUSE
DRYING OF THE SKIN WHICH MAY RESULT IN IRRITATION, DERMATITIS, AND SKIN
BURNS. REPEATED EXPOSURE TO SULFURIC ACID MIST MAY CAUSE EROSION OF TEETH,
CHRONIC EYE IRRITATION AND/OR CHRONIC INFLAMMATION OF THE NOSE, THROAT AND
LUNGS.
LEAD:
PROLONGED EXPOSURE MAY CAUSE CENTRAL NERVOUS SYSTEM DAMAGE,
GASTROINTESTINAL DISTURBANCES ANEMIA, WRIST-DROP AND KIDNEY DYSFUNCTION.
PREGNANT WOMEN SHOULD BE PROTECTED FROM EXCESSIVE EXPOSURE TO PREVENT LEAD
FROM CROSSING THE PLACENTAL BARRIER AND CAUSING INFANT NEUROLOGICAL
DISORDERS.
CALIFORNIA PROPOSITION 65 WARNING:
BATTERY POSTS, TERMINALS AND RELATED ACCESSORIES CONTAIN LEAD AND LEAD
COMPOUNDS, CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND
REPRODUCTIVE HARM, AND DURING CHARGING, STRONG INORGANIC ACID MISTS
CONTAINING SULFURIC ACID ARE EVOLVED, A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER. WASH HANDS AFTER HANDLING.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
IF BATTERY IS BROKEN OR MATERIAL IS SPILLED THEN PERSONS WITH THE FOLLOWING
MEDICAL CONDITIONS MUST TAKE PRECAUTIONS:
PULMONARY EDEMA BRONCHITIS, EMPHYSEMA, DENTAL EROSION AND TRACHEOBRONCHITIS
ROUTES OF ENTRY:
INHALATION: YES
INGESTION: YES
EYE CONTACT: YES
SKIN CONTACT: YES
CHEMICAL(S) LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN:
PROPOSITION 65: YES
NATIONAL TOXICOLOGY PROGRAM: YES
IARC MONOGRAPHS: YES
OSHA: NO
EPA CAG: YES
NIOSH: YES
| SECTION 4 - FIRST AID MEASURES | |
EMERGENCY AND FIRST AID PROCEDURES:
CONTACT WITH INTERNAL COMPONENTS IF BATTERY IS OPENED, BROKEN OR SPILLED.
1 INHALATION:
REMOVE TO FRESH AIR AND PROVIDE MEDICAL OXYGEN/CPR IF NEEDED. OBTAIN
MEDICAL ATTENTION.
2 EYES:
IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES, HOLD EYELIDS OPEN.
OBTAIN MEDICAL ATTENTION.
3 SKIN:
FLUSH CONTACTED AREA WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING AND OBTAIN MEDICAL ATTENTION IF NECESSARY.
4 INGESTION:
DO NOT INDUCE VOMITING. IF CONSCIOUS DRINK LARGE AMOUNTS OF WATER/MILK.
OBTAIN MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.
| SECTION 5 - FIREFIGHTING MEASURES | |
FLASH POINT: NOT APPLICABLE
FLAMMABLE LIMITS IN AIR % BY VOLUME (WHEN CHARGING):
HYDROGEN (H2)
LOWER: 4.1%
UPPER: 74.2%
EXTINGUISHER MEDIA: CLASS ABC, CO2 HALON
AUTO-IGNITION TEMPERATURE: POLYPROPYLENE 675 DEG. F
SPECIAL FIRE FIGHTING PROCEDURES:
LEAD-ACID BATTERIES DO NOT BURN OR BURN WITH DIFFICULTY. DO NOT USE WAFER
ON FIRES WHERE MOLTEN METAL IS PRESENT. EXTINGUISH FIRE WITH AGENT SUITABLE
FOR SURROUNDING COMBUSTIBLE MATERIALS. COOL EXTERIOR OF BATTERY IF EXPOSED
TO FIRE TO PREVENT RUPTURE. THE ACID MIST AND VAPORS GENERATED BY HEAT OR
FIRE ARE CORROSIVE. USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS
(SCBA) AND FULL PROTECTIVE EQUIPMENT OPERATED IN POSITIVE-PRESSURE MODE.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
HYDROGEN GAS AND SULFURIC ACID VAPORS ARE GENERATED UPON OVERCHARGE AND
POLYPROPYLENE CASE FAILURE. VENTILATE CHARGING AREAS AS PER ACGIH
INDUSTRIAL VENTILATION:
A MANUAL OF RECOMMENDED PRACTICE AND NATIONAL FIRE CODE. 1980 VOL. 1, P 12,
B-9, 10. HYDROGEN GAS MAY BE FLAMMABLE OR EXPLOSIVE WHEN MIXED WITH AIR.
OXYGEN, CHLORINE. AVOID OPEN FLAMES/SPARKS/OTHER SOURCES OF IGNITION NEAR
BATTERY. TO AVOID RISK OF FIRE OR EXPLOSION, KEEP SPARKS OR OTHER SOURCES
OF IGNITION AWAY FROM BATTERIES AND DO NOT ALLOW METALLIC MATERIALS TO
SIMULTANEOUSLY CONTACT NEGATIVE AND POSITIVE TERMINALS OF CELLS AND
BATTERIES SULFURIC ACID REACTS VIOLENTLY WITH WATER/ORGANICS.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PROCEDURES FOR CLEANUP:
STOP RELEASE IF POSSIBLE. AVOID CONTACT WITH ANY SPILLED MATERIAL. CONTAIN
SPILL, ISOLATE HAZARD AREA, AND DENY ENTRY. LIMIT SITE ACCESS TO EMERGENCY
RESPONDERS. NEUTRALIZE WITH SODIUM BICARBONATE, SODA ASH, LIME OR OTHER
NEUTRALIZING AGENT. PLACE BATTERY IN SUITABLE CONTAINER FOR DISPOSAL.
DISPOSE OF CONTAMINATED MATERIAL IN ACCORDANCE WITH APPLICABLE LOCAL, STATE
AND FEDERAL REGULATIONS. SODIUM BICARBONATE, SODA ASH, SAND, LIME OR OTHER
NEUTRALIZING AGENT SHOULD BE KEPT ON SITE FOR SPILL REMEDIATION.
PERSONAL PRECAUTIONS:
ACID RESISTANT APRONS, BOOTS AND PROTECTIVE CLOTHING ANSI APPROVED SAFETY
GLASSES WITH SIDE SHIELDS/FACE SHIELD RECOMMENDED. VENTILATE ENCLOSED
AREAS.
ENVIRONMENTAL PRECAUTIONS:
LEAD AND ITS COMPOUNDS AND SULFURIC ACID CAN POSE A SEVERE THREAT TO THE
ENVIRONMENT. CONTAMINATION OF WATER, SOIL, AND AIR SHOULD BE PREVENTED.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
KEEP AWAY FROM FLAMES DURING AND IMMEDIATELY AFTER CHARGING COMBUSTION OR
OVERCHARGING MAY CREATE OR LIBERATE TOXIC AND HAZARDOUS GASES ANA LIQUIDS
INCLUDING HYDROGEN, SULFURIC ACID MIST, SULFUR DIOXIDE, SULFUR TRIOXIDE.
STIBINE. ARSINE AND SULFURIC ACID. STORE BATTERIES IN COOL, DRY, WELL
VENTILATED AREA. DO NOT SHORT CIRCUIT BATTERY TERMINALS, OR REMOVE VENT
CAPS DURING STORAGE OR RECHARGING. PROTECT BATTERY FROM PHYSICAL DAMAGE.
OTHER PRECAUTIONS:
GOOD PERSONAL HYGIENE AND WORK PRACTICES ARE MANDATORY. REFRAIN FROM
EATING, DRINKING OR SMOKING IN WORK AREA. THOROUGHLY WASH HANDS, FACE, NECK
AND ARMS BEFORE EATING, DRINKING OR SMOKING. LAUNDER SOILED CLOTHING BEFORE
REUSE. EMPTIED BATTERIES CONTAIN HAZARDOUS SULFURIC ACID RESIDUE.
| SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
RESPIRATORY PROTECTION (SPECIFY TYPE):
ACID/GAS NIOSH APPROVED RESPIRATOR IS REQUIRED WHEN THE PEL IS EXCEEDED OR
EMPLOYEE EXPERIENCES RESPIRATORY IRRITATION. WHEN EXPOSURE LEVELS ARE
UNKNOWN OR WHEN FIREFIGHTING. WEAR A SELF-CONTAINED BREATHING APPARATUS
WITH A FULL FACEPIECE OPERATED IN A POSITIVE PRESSURE MODE.
VENTILATION:
MUST BE PROVIDED WHEN CHARGING IN AN ENCLOSED AREA. CHANGE AN EVERY 15 MIN
LOCAL EXHAUST: WHEN PEL IS EXCEEDED
MECHANICAL (GENERAL):
NORMAL MECHANICAL VENTILATION RECOMMENDED FOR STATIONARY APPLICATIONS.
PROTECTIVE GLOVES:
WEAR RUBBER OR PLASTIC ACID RESISTANT GLOVES WITH ELBOW LENGTH GAUNTLET
WHEN FILLING BATTERIES
EYE PROTECTION:
ANSI APPROVED SAFETY GLASSES WITH SIDE SHIELD/FACE SHIELD RECOMMENCED.
SAFETY GOGGLES
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
VENTILATION AS DESCRIBED IN THE INDUSTRIAL VENTILATION MANUAL PRODUCED BY
THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS SHALL BE
PROVIDED IN AREAS WHERE EXPOSURES ARE ABOVE THE PEL OR TLV SPECIFIED BY
OSHA OR OTHER LOCAL, STATE AND FEDERAL REGULATIONS. ACID-RESISTANT RUBBER
OR PLASTIC APRON BOOTS AND PROTECTIVE CLOTHING SAFETY SHOWER AND EYEWASH
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT:
ELECTROLYTE: APPROX 235 DEG. F
VAPOR PRESSURE:
ELECTROLYTE: 1 MMHg @ 145.8 DEG. F
SPECIFIC GRAVITY:
ELECTROLYTE (H2O=1): 1.250 - 1.320
PH: <2
MELTING POINT:
POLYPROPYLENE: <320 DEG. F
PERCENT VOLATILE BY VOLUME (%): NOT APPLICABLE
VAPOR DENSITY:
HYDROGEN (AIR = 1): 0.069
ELECTROLYTE (AIR = 1): 3.4 AT STP
EVAPORATION RATE: NOT APPLICABLE
SOLUBILITY IN WATER: ELECTROLYTE 100% SOLUBLE
REACTIVITY IN WATER:
ELECTROLYTE: WATER REACTIVE (1)
APPEARANCE AND ODOR:
BATTERY: POLYPROPYLENE OR HARD RUBBER CASE, SOLID.
LEAD: GRAY, METALLIC, SOLID
ELECTROLYTE:
LIQUID, COLORLESS, OILY FLUID, NUISANCE ODOR WHEN HOT OR CHARGING BATTERY.
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY:
UNSTABLE ( )
STABLE (X)
CONDITIONS TO AVOID:
HIGH TEMPERATURES. CASES DECOMPOSE AT <320 F.
AVOID OVERCHARGING AND SMOKING, OR SPARKS NEAT BATTERY SURFACE AND RAPID
OVERCHARGE
INCOMPATIBILITY (MATERIALS TO AVOID):
SPARKS OPEN FLAMES. KEEP BATTERY CASE AWAY FROM STRONG OXIDIZERS
HAZARDOUS DECOMPOSITION PRODUCTS:
AN EXPLOSIVE HYDROGEN/OXYGEN MIXTURE WITHIN THE BATTERY MAY OCCUR DURING
CHARGING. COMBUSTION CAN PRODUCE CARBON DIOXIDE (CO2) AND CARBON MONOXIDE
(CO) MOLTEN METALS PRODUCE FUMES AND/OR VAPOR THAT MAY BE TOXIC OR
RESPIRATORY IRRITANTS.
HAZARDOUS POLYMERIZATION:
MAY OCCUR ( )
WILL NOT OCCUR (X)
DO NOT OVERCHARGE
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
GENERAL:
THE PRIMARY ROUTES OF EXPOSURE TO LEAD ARE INGESTION OR INHALATION OF DUST
AND FUMES.
ACUTE:
INGESTION/INHALATION:
EXPOSURE TO LEAD AND ITS COMPOUNDS MAY CAUSE HEADACHE, NAUSEA, VOMITING,
ABDOMINAL SPASMS, FATIGUE SLEEP DISTURBANCES, WEIGHT LOSS, ANEMIA, AND PAIN
IN THE LEGS, ARMS AND JOINTS. KIDNEY DAMAGE, AS WELL AS ANEMIA, CAN OCCUR
FROM ACUTE EXPOSURE.
CHRONIC:
INHALATION/INGESTION:
PROLONGED EXPOSURE TO LEAD AND ITS COMPOUNDS MAY PRODUCE MANY OF THE
SYMPTOMS OF SHORT-TERM EXPOSURE AND MAY ALSO CAUSE CENTRAL NERVOUS SYSTEM
DAMAGE GASTROINTESTINAL DISTURBANCES ANEMIA, AND WRIST DROP. SYMPTOMS OF
CENTRAL NERVOUS SYSTEM DAMAGE INCLUDE FATIGUE HEADACHES, TREMORS,
HYPERTENSION, HALLUCINATIONS, CONVULSIONS AND DELIRIUM. KIDNEY DYSFUNCTION
AND POSSIBLE INJURY HAS ALSO BEEN ASSOCIATED WITH CHRONIC LEAD POISONING.
CHRONIC OVER-EXPOSURE TO LEAD HAS BEEN IMPLICATED AS A CAUSATIVE AGENT FOR
THE IMPAIRMENT OF MALE AND FEMALE REPRODUCTIVE CAPACITY, BUT THERE IS, AT
PRESENT, NO SUBSTANTIATION OF THE IMPLICATION. PREGNANT WOMEN SHOULD BE
PROTECTED FROM EXCESSIVE EXPOSURE. LEAD CAN CROSS THE PLACENTAL BARRIER AND
UNBORN CHILDREN MAY SUFFER NEUROLOGICAL DAMAGE OR DEVELOPMENTAL PROBLEMS
DUE TO EXCESSIVE LEAD EXPOSURE IN PREGNANT WOMEN.
| SECTION 12 - ECOLOGICAL INFORMATION | |
IN MOST SURFACE WATER AND GROUNDWATER, LEAD FORMS COMPOUNDS WITH ANIONS
SUCH AS HYDROXIDES, CARBONATES, SULFATES, AND PHOSPHATES AND PRECIPITATES
OUT OF THE WATER COLUMN. LEAD MAY OCCUR AS SORBED IONS OR SURFACE COATINGS
ON SEDIMENT MINERAL PARTICLES OR MAY BE CARRIED IN COLLOIDAL PARTICLES IN
SURFACE WATER MOST LEAD IS STRONGLY RETAINED IN SOIL, RESULTING IN LITTLE
MOBILITY. LEAD MAY BE IMMOBILIZED BY ION EXCHANGE WITH HYDROUS OXIDES OR
CLAYS OR BY CHELATION WITH HUMIC OR FULVIC ACIDS IN THE SOIL. LEAD (WHEN IN
THE DISSOLVED PHASE) IS BIO-ACCUMULATED BY PLANTS AND ANIMALS, BOTH AQUATIC
AND TERRESTRIAL.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHODS:
LEAD-ACID BATTERIES ARE COMPLETELY RECYCLABLE RETURN WHOLE SCRAP BATTERIES
TO DISTRIBUTOR, MANUFACTURER OR LEAD SMELLER FOR RECYCLING FOR INFORMATION
ON RETURNING BATTERIES TO TROJAN BATTERY COMPANY FOR RECYCLING CALL
800-423-6569 FOR NEUTRALIZED SPILLS, PLACE RESIDUE IN ACID-RESISTANT
CONTAINERS WITH SORBENT MATERIAL, SAND OR EARTH AND DISPOSE OF IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS FOR ACID AND LEAD
COMPOUNDS CONTACT LOCAL AND/OR SLATE ENVIRONMENTAL OFFICIALS REGARDING
DISPOSAL INFORMATION.
| SECTION 14 - TRANSPORT INFORMATION | |
U.S. DOT PROPER SHIPPING NAME: BATTERIES, WET, FILLED WITH ACID
U.S. DOT HAZARD CLASS: 8
U.S. DOT ID NUMBER UN: 2794
U.S. DOT PACKING GROUP: III
U.S. DOT LABEL: CORROSIVE
IMO PROPER SHIPPING NAME: BATTERIES, WET, FILLED WITH ACID
IMO REGULATION PAGE NUMBER: 8120
IMO U.N. CLASS: 8
IMO U.N. NUMBER: UN 2794
IMO PACKING GROUP: III
IMO LABEL: CORROSIVE
IMO VESSEL STOWAGE: A
IATA PROPER SHIPPING NAME: BATTERIES, WET. FILLED WITH ACID
IATA U.N. CLASS: 8
IATA U.N. NUMBER: UN 2794
IATA PACKING GROUP: III
IATA LABEL: CORROSIVE
| SECTION 15 - REGULATORY INFORMATION | |
U.S. HAZARDOUS UNDER HAZARD COMMUNICATION STANDARD:
LEAD: YES
SULFURIC ACID: YES
ANTIMONY: YES
ARSENIC: YES
INGREDIENTS LISTED ON TSCA INVENTORY: YES
CERCLA SECTION 304 HAZARDOUS SUBSTANCES:
LEAD: YES
RQ: NA*
SULFURIC ACID: YES
RQ: 1000 POUNDS
ANTIMONY: YES
RQ: 5000 POUNDS
ARSENIC: YES
RQ: 1 POUND
*REPORTING NOT REQUIRED WHEN DIAMETER OF THE PIECES OF SOLID METAL RELEASED
IS EQUAL TO OR EXCEEDS 100 MICROMETERS
EPCRA SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE:
SULFURIC ACID: YES
EPCRA SECTION 313 TOXIC RELEASE INVENTORY:
LEAD:
CAS NO: 7439-92-1
SULFURIC ACID:
CAS NO: 7664-93-9
ANTIMONY:
CAS NO: 7440-36-0
ARSENIC:
CAS NO: 7440-38-2
| SECTION 16 - OTHER INFORMATION | |
THE INFORMATION ABOVE IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST
INFORMATION CURRENTLY AVAILABLE TO US HOWEVER. TROJAN BATTERY COMPANY MAKES
NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED,
WITH RESPECT TO SUCH INFORMATION. AND WE ASSUME NO LIABILITY RESULTING FROM
ITS USE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE
SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES ALTHOUGH
REASONABLE PRECAUTIONS HAVE BEEN TAKEN IN THE PREPARATION OF THE DATA
CONTAINED HEREIN. IT IS OFFERED SOLELY FOR YOUR INFORMATION CONSIDERATION
AND INVESTIGATION THIS MATERIAL SAFETY DATA SHEET PROVIDES GUIDELINES FOR
THE SAFE HANDLING AND USE OF THIS PRODUCT, IT DOES NOT AND CANNOT ADVISE ON
ALL POSSIBLE SITUATIONS, THEREFORE. YOUR SPECIFIC USE OF THIS PRODUCT
SHOULD BE EVALUATED TO DETERMINE IF ADDITIONAL PRECAUTIONS ARE REQUIRED.
FORM MSDS REV: 11/07/07