| Common Name: | LI-MN BUTTON CELL CR2032 |
| Manufacturer: | GUANGZHOU TIANQIU ENTERPRISE CHINA |
| SDS Revision Date: | 1/1/2013 |
| SDS Format: | ANSI-OSHA |
| Item Number(s): | 20UR47, 20UR48, 20UR51 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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TIANQIU(R*)
GUANGZHOU TIANQIU ENTERPRISE CO., LTD.
DOCUMENT REF. NO.: GZTQ/BAT-120210
MATERIAL SAFETY DATA SHEET
| 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: Li-Mn BUTTON CELL CR2032
MANUFACTURER: GUANGZHOU TIANQIU ENTERPRISE CO., LTD.
ADDRESS:
9/F
TIANQIU BUSINESS BUILDING NO. 16-30
HE YI RD
SAN YUAN LI AVE
GUANGZHOU
CHINA.
TELEPHONE: 8620-36322277
| 2. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENTS APPROX WT% CAS # EC #
IRON (Fe) 48.0 7439-89-6 231-096-4
MANGANESE DIOXIDE (MnO2) 34.8 1313-13-9 215-202-6
PERCHLORIC ACID, LITHIUM SALT 3.99 7791-03-9 232-237-2
(LiClO4)
POLYPROPYLENE ((C3H6)x) 3.43 9003-07-0
PROPYLENE CARBONATE (C4H6O3) 3.0 108-32-7 203-572-1
LITHIUM (Li) 1.9 7439-93-2 231-102-5
GRAPHITE (C) 1.7 7782-42-5 231-955-3
POLYTETRAFLUOROETHYLENE 1.7 9002-84-0
ETHYLENE GLYCOL DIMETHYL ETHER 1.48 110-71-4 203-794-9
(C4H10O2)
MERCURY (Hg) <0.0001 7439-97-6 231-106-7
CADMIUM (Cd) <0.001 7440-43-9 231-152-8
LEAD (Pb) <0.001 7439-92-1 231-100-4
| 3. HAZARDS IDENTIFICATION | |
ROUTES OF ENTRY: NOT APPLICABLE UNDER NORMAL CONDITIONS
HEALTH HAZARDS:
IN CASE OF LEAKAGE, WILL BE CAUSE ITCHY AND/OR CHEMICAL BURNS WHEN DIRECT
CONTACT WITH ELECTROLYTE
HAZARDS TO ENVIRONMENT: NOT APPLICABLE
FIRE AND EXPLOSION HAZARDS: NOT APPLICABLE
| 4. FIRST-AID MEASURES | |
SKIN CONTACT:
IF EXPOSED TO A LEAKING CELL, REMOVE CONTAMINATED CLOTHING. WASH EXPOSED
AREAS WITH PLENTY OF WATER AND SOAP. IF IRRITATION OCCURS, CONSULT A
PHYSICIAN.
EYES CONTACT:
IF A CELL IS LEAKAGE AND MATERIALS CONTACT EYES, FLUSH IMMEDIATELY WITH
RUNNING WATER FOR AT LEAST 15 MINUTES. CONSULT AN OPHTHALMOLOGIST AT ONCE.
INHALATION:
IF VAPOR FROM VENTED OR LEAKED CELLS ARE INHALATION, MOVE TO FRESH AIR AND
GET MEDICAL ATTENTION.
INGESTION:
GET IMMEDIATELY MEDICAL ATTENTION, DO NOT INDUCE VOMITING OR GIVE A LIQUID
TO UNCONSCIOUS PERSON.
| 5. FIRE FIGHTING MEASURES | |
HAZARD CHARACTERISTIC: NOT AVAILABLE
HAZARDS EXPOSE TO COMBUSTION PRODUCTS:
IN CASE OF FIRE, CARBON DIOXIDE, CARBON MONOXIDE AND OTHER TOXIC ORGANIC
SUBSTANCES WILL BE GENERATED. DO NOT INHALE FUMES AND SMOKE.
EXTINGUISHING MEDIA:
CLASS "D" FIRE EXTINGUISHER, LITH-X (GRAPHITE BASE), COPPER POWDER OR DRY
SAND.
SPECIAL FIRE FIGHTING PROCEDURES:
IN CASE OF FIRE IN AN ADJACENT AREA, USE WATER, CO2 OR DRY CHEMICAL
EXTINGUISHERS IF CELLS ARE PACKED IN THEIR ORIGINAL CONTAINER SINCE THE
FUEL OF THE FIRE IS BASICALLY PAPER PRODUCTS, FOR BURNING BULK QUANTITIES
OF UNPACKED CELLS USE CLASS "D" FIRE EXTINGUISHER, IN THIS CASE, DO NOT USE
WATER.
FIRE FIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS.
| 6. ACCIDENTAL RELEASE MEASURES | |
PRECAUTIONS:
AVOID DIRECT CONTACT WITH THE LEAKING OR RUPTURED CELLS. AVOID SHORT
CIRCUIT.
METHODS FOR CLEAN UP:
CARE FOR WELL-VENTILATED CONDITIONS. RECYCLE OR DISPOSE OF THE MATERIALS IN
AN APPROPRIATE WAY.
| 7. HANDLING AND STORAGE | |
PRECAUTION:
HANDING AND TRANSFER THE PRODUCTS CAREFULLY, MAKE SURE THE PACKING ALWAYS
IN GOOD CONDITION. DAMAGED PACKING MAY CAUSE CELLS CONTACT TOGETHER, IN
THIS CASE CELLS MAY SHORT CIRCUIT OR IMPROPERLY CONNECTED, IT CAUSE CELLS
VENTING, LEAKING OR EXPLODING.
STORAGE: STORE IN A DRY, COOL AND WELL-VENTILATED AREA.
| 8. EXPOSURE CONTROL/PERSONAL PROTECTION | |
EXPOSITION/TECHNICAL MEASURES:
ATMOSPHERIC VAPOR CONCENTRATIONS MUST BE MINIMIZED BY ADEQUATE VENTILATION.
PROTECTION OF HANDS, EYES, AND SKIN:
NO REQUIRED UNDER NORMAL USE CONDITIONS. WHEN HANDLING LEAKING CELLS, USE
GLOVES AND WEAR SAFETY GLASSES TO PROTECT HANDS, EYES AND SKIN.
GENERAL SAFETY AND HYGIENE MEASURES: USE ONLY AS DIRECTED.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE AND APPEARANCE: FLAT AND CIRCULAR
ODOR: ODORLESS
PH: N/A
MELTING POINT (DEG. C): N/A
SPECIFIC GRAVITY (H2O=1): N/A
BOILING POINT (DEG. C): N/A
VAPOR DENSITY (AIR=1): N/A
VAPOR PRESSURE (KPA): N/A
HEAT OF COMBUSTION (KJ/MOL): N/A
CRITICAL TEMPERATURE (DEG. C): N/A
CRITICAL PRESSURE (MPA): N/A
PARTITION COEFFICIENT: N/A
FLASH POINT (DEG. C): N/A
IGNITION TEMPERATURE (DEG. C): N/A
EXPLOSION LIMIT % (V/V): N/A
SOLUBILITY IN WATER: N/A
SOLUBILITY IN OTHER SOLVENTS: N/A
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
INCOMPATIBILITY: NONE
CONDITION TO AVOID: AVOID SHORTING, MECHANICAL & THERMAL ABUSE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
HAZARDOUS DECOMPOSITION: NONE
| 11. TOXICOLOGICAL INFORMATION | |
NOTE:
SINCE THE MATERIALS IN THIS CELL ARE SEALED IN THE CAN, THE POTENTIAL FOR
EXPOSURE TO THE COMPONENTS OF THE CELL IS NEGLIGIBLE, WHEN THE CELL IS USED
AS DIRECTED. HOWEVER TECHNICAL OR ELECTRICAL ABUSE OF THE CELL MAY RESULT
IN THE RELEASE OF CELL CONTENTS.
TOXICITY TO ANIMALS: NOT APPLICABLE
CHRONIC EFFECTS ON HUMAN: NOT APPLICABLE
| 12. ECOLOGICAL INFORMATION | |
THIS PRODUCT HAS NOT BEEN TESTED FOR ENVIRONMENTAL EFFECTS.
| 13. DISPOSAL CONSIDERATION | |
DISPOSE IN ACCORDANCE WITH FEDERAL, STATES AND LOCAL REGULATIONS
| 14. TRANSPORT INFORMATION | |
SHIPPING NAME: LITHIUM METAL CELLS
UN NUMBER: UN3090 (UN3091 FOR LITHIUM BATTERIES IN EQUIPMENT)
HAZARD CLASSIFICATION: CLASS 9 (MISCELLANEOUS)
ALL TIANQIU LITHIUM BATTERIES WHEN TRANSPORTED BY GROUND ARE NOT SUBJECT TO
THE REQUIREMENTS OF THE DEPARTMENT OF TRANSPORTATION (DOT) SUBCHAPTER C,
HAZARDOUS MATERIALS REGULATIONS IF THEY SHIPPED IN ACCORDANCE WITH ALL OF
THE APPLICABLE PROVISIONS OF SPECIAL PROVISION 188.
ALL TIANQIU LITHIUM BATTERIES ARE EXEMPT FROM THE OTHER REQUIREMENTS OF THE
INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) AND THE INTERNATIONAL AIR
TRANSPORT ASSOCIATION (IATA) DANGEROUS GOODS REGULATIONS IF THEY ARE
TRANSPORTED IN ACCORDANCE WITH ALL OF THE REQUIREMENTS SET OUT IN SECTION
II OF PACKING INSTRUCTION 968, 969 AND 970 UNDER THE CURRENT EDITION OF THE
IATA DANGEROUS GOODS REGULATIONS 54TH 2013.
ALL TIANQIU LITHIUM BATTERIES ARE EXEMPT FROM THE OTHER REQUIREMENTS OF THE
INTERNATIONAL MARITIME ORGANIZATION (IMO) DANGEROUS GOODS REGULATIONS IF
THEY ARE TRANSPORTED IN ACCORDANCE WITH ALL OF THE APPLICABLE REQUIREMENTS
OF SPECIAL PROVISIONS 188 AND 230.
FOR A LITHIUM METAL OR LITHIUM ALLOY CELL, THE LITHIUM CONTENT OR AGGREGATE
LITHIUM CONTENT IS NOT CONTAIN MORE THAN 1G.
FOR A LITHIUM METAL OR LITHIUM ALLOY BATTERY, THE LITHIUM CONTENT OR
AGGREGATE LITHIUM CONTENT IS NOT MORE THAN 2G.
EACH CELL OR BATTERY OF TIANQIU IS OF THE TYPE PROVEN TO MEET THE
REQUIREMENT OF EACH TEST IN THE UN MANUAL OF TESTS AND CRITERIA, PART III,
SUBSECTION 38.3.
IF YOU BUILD ANY OF OUR LITHIUM CELLS INTO A BATTERY PACK, YOU MUST ALSO
ASSURE THAT THEY ARE TESTED IN ACCORDANCE WITH THE UN MODEL REGULATIONS,
MANUAL OF TEST AND CRITERIA. PART III, SUBSECTION 38.3.
EFFECTIVE DECEMBER 29, 2004, THE DOT REQUIRES THAT THE OUTSIDE OF EACH
PACKAGE THAT CONTAINS PRIMARY LITHIUM BATTERIES, REGARDLESS OF SIZE OR
NUMBER OF BATTERIES, BE LABELED WITH THE FOLLOWING STATEMENT:
"PRIMARY LITHIUM BATTERIES- FORBIDDEN FOR TRANSPORT ABOARD PASSENGER
AIRCRAFT". THE LABELING REQUIREMENT COVERS SHIPMENTS VIA HIGHWAY, RAIL,
VESSEL OR CARGO-ONLY AIRCRAFT AND COVERS ALL SHIPMENTS INSIDE, INTO OR OUT
OF THE US. THE LABEL MUST BE IN CONTRASTING COLOR AND THE LETTERS MUST BE
12 MM (0.5 IN) IN HEIGHT FOR PACKAGES WEIGHING MORE THAN 30 KG AND 6 MM
(0.25 IN) IN HEIGHT FOR PACKAGES WEIGHTING LESS THAN 30 KG.
| 15. REGULATORY INFORMATION | |
SPECIAL REQUIREMENT BE ACCORDING TO THE LOCAL REGULATORIES.
| 16. OTHER INFORMATION | |
DO NOT HEAT OR DISPOSE OF IN FIRE. DO NOT RECHARGE OR DISASSEMBLE THE CELL.
NOTICE TO READER:
THE INFORMATION CONTAINED IN THIS MSDS WAS OBTAINED FROM CURRENT AND
RELIABLE SOURCES, HOWEVER, THE DATA IS PROVIDED WITHOUT ANY WARRANTY,
EXPRESSED OR IMPLIED, REGARDING ITS CORRECTNESS OR ACCURACY. SINCE THE
CONDITIONS OR HANDLING, STORAGE AND DISPOSAL OF THIS PRODUCT ARE BEYOND THE
CONTROL OF TIANQIU, TIANQIU WILL NOT BE RESPONSIBLE FOR LOSS, INJURY, OR
EXPENSE ARISING OUT OF THE PRODUCTS IMPROPER USE. NO WARRANTY, EXPRESSED OR
INFERRED, REGARDING THE PRODUCT DESCRIBED IN THIS MSDS SHALL BE CREATED OR
INFERRED BY ANY STATEMENT IN THIS MSDS. VARIOUS GOVERNMENT AGENCIES MAY
HAVE SPECIFIC REGULATIONS REGARDING THE TRANSPORTATION, HANDLING, STORAGE,
USE, OR DISPOSAL OF THIS PRODUCT, WHICH MAY NOT BE COVERED BY THIS MSDS.
THE USER IS RESPONSIBLE FOR FULL COMPLIANCE.
LITHIUM BUTTON CELL
DATE PREPARED: 2013/1/1