| Common Name: | DRY GRAPHITE LUBE 03094 |
| Manufacturer: | CRC |
| SDS Revision Date: | 1/23/2014 |
| SDS Format: | ANSI-OSHA |
| Item Number(s): | 4JB39, 4JB59 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CRC(R*)
MATERIAL SAFETY DATA SHEET
| SECTION 1: PRODUCT & COMPANY IDENTIFICATION |  |
PRODUCT NAME: DRY GRAPHITE LUBE
PRODUCT NUMBER (S): 03094
PRODUCT USE: DRY FILM LUBRICANT
MANUFACTURER / SUPPLIER CONTACT INFORMATION:
IN UNITED STATES:
CRC INDUSTRIES, INC.
885 LOUIS DRIVE
WARMINSTER, PA 18974
WWW.CRCINDUSTRIES.COM
1-215-674-4300 (GENERAL)
(800) 521-3168 (TECHNICAL)
(800) 272-4620 (CUSTOMER SERVICE)
IN CANADA:
CRC CANADA CO.
2-1246 LORIMAR DRIVE
MISSISSAUGA, ONTARIO L5S 1R2
WWW.CRC-CANADA.CA
1-905-670-2291
IN MEXICO:
CRC INDUSTRIES MEXICO
AV. BENITO JUAREZ 4055 G
COLONIA ORQUIDEA
SAN LUIS POTOSI, SLP CP 78394
WWW.CRC-MEXICO.COM
52-444-824-1666
24-HR EMERGENCY - CHEMTREC: (800) 424-9300 OR (703) 527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
EXTREMELY FLAMMABLE. HARMFUL OR FATAL IF SWALLOWED.
VAPOR HARMFUL. EYE AND SKIN IRRITANT. CONTENTS UNDER PRESSURE.
APPEARANCE & ODOR: BLACK VISCOUS LIQUID, SOLVENT ODOR
POTENTIAL HEALTH EFFECTS:
ACUTE EFFECTS:
EYE:
MAY CAUSE EYE IRRITATION, INCLUDING REDNESS, ITCHING OR BURNING SENSATION.
SKIN:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION. SYMPTOMS OF
OVEREXPOSURE INCLUDE REDNESS, ITCHING AND BURNING OF SKIN.
INHALATION:
MAY CAUSE IRRITATION OF THE UPPER RESPIRATORY SYSTEM OR NERVOUS SYSTEM
DEPRESSION (HEADACHE, DIZZINESS, NAUSEA AND LOSS OF COORDINATION). EXTREME
OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH.
INGESTION: INGESTION OF AEROSOL PRODUCT IS NOT EXPECTED DURING NORMAL USE.
CHRONIC EFFECTS:
PROLONGED OVEREXPOSURE MAY CAUSE ADVERSE EFFECTS TO THE LIVER AND URINARY
SYSTEMS.
TARGET ORGANS: LIVER AND URINARY SYSTEMS
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: UNKNOWN
SEE SECTION 11 FOR TOXICOLOGY AND CARCINOGENICITY INFORMATION ON PRODUCT
INGREDIENTS.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS NUMBER % BY WT.
PROPANE 74-98-6 10 - 20
BUTANE 106-97-8 10 - 20
HEPTANE 142-82-5 40 - 50
TOLUENE 108-88-3 <2
2-PROPANOL 67-63-0 20 - 30
GRAPHITE 7782-42-5 <2
| SECTION 4: FIRST AID MEASURES | |
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. CALL A PHYSICIAN IF
IRRITATION PERSISTS.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND WASH AFFECTED AREA WITH SOAP AND WATER.
CALL A PHYSICIAN IF IRRITATION PERSISTS. WASH CONTAMINATED CLOTHING PRIOR
TO RE-USE.
INHALATION:
REMOVE PERSON TO FRESH AIR. KEEP PERSON CALM. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT GIVE OXYGEN. CALL A
PHYSICIAN.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
NOTE TO PHYSICIANS: TREAT SYMPTOMATICALLY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
FLAMMABLE PROPERTIES:
THIS PRODUCT IS EXTREMELY FLAMMABLE IN ACCORDANCE WITH AEROSOL FLAMMABILITY
DEFINITIONS. (SEE 16 CFR 1500.3(C)(6)).
FLASH POINT: <0 DEG. F / -17 DEG. C
AUTOIGNITION TEMPERATURE: ND
UPPER EXPLOSIVE LIMIT: ND
LOWER EXPLOSIVE LIMIT: ND
FIRE AND EXPLOSION DATA:
SUITABLE EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
PRODUCTS OF COMBUSTION: CARBON DIOXIDE AND CARBON MONOXIDE
EXPLOSION HAZARDS:
AEROSOL CONTAINERS, WHEN EXPOSED TO HEAT FROM FIRE, MAY BUILD PRESSURE AND
EXPLODE. VAPORS MAY ACCUMULATE IN A CONFINED SPACE AND CREATE A FLAMMABLE
ATMOSPHERE.
PROTECTION OF FIRE-FIGHTERS:
FIREFIGHTERS SHOULD WEAR SELF-CONTAINED, NIOSH-APPROVED BREATHING APPARATUS
FOR PROTECTION AGAINST SUFFOCATION AND POSSIBLE TOXIC DECOMPOSITION
PRODUCTS. PROPER EYE AND SKIN PROTECTION SHOULD BE PROVIDED. USE WATER
SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL AND TO KNOCK DOWN VAPORS WHICH
MAY RESULT FROM PRODUCT DECOMPOSITION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS: USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8.
ENVIRONMENTAL PRECAUTIONS:
TAKE PRECAUTIONS TO PREVENT CONTAMINATION OF GROUND AND SURFACE WATERS.
DO NOT FLUSH INTO SEWERS OR STORM DRAINS.
METHODS FOR CONTAINMENT & CLEAN-UP:
REMOVE ALL SOURCES OF IGNITION. DIKE AREA TO CONTAIN SPILL. VENTILATE THE
AREA WITH FRESH AIR. IF IN CONFINED SPACE OR LIMITED AIR CIRCULATION AREA,
CLEAN-UP WORKERS SHOULD WEAR APPROPRIATE RESPIRATORY PROTECTION. RECOVER OR
ABSORB SPILLED MATERIAL USING AN ABSORBENT DESIGNED FOR CHEMICAL SPILLS.
PLACE USED ABSORBENTS INTO PROPER WASTE CONTAINERS.
| SECTION 7: HANDLING AND STORAGE | |
HANDLING PROCEDURES:
KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. VAPORS WILL ACCUMULATE READILY
AND MAY IGNITE EXPLOSIVELY. DURING USE AND UNTIL ALL VAPORS ARE GONE:
KEEP AREA VENTILATE. DO NOT SMOKE. EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS. TURN OFF STOVES, ELECTRONIC TOOLS AND OTHER APPLIANCES, AND
ANY OTHER SOURCES OF IGNITION. USE CAUTION AROUND ENERGIZED EQUIPMENT. THE
METAL CONTAINER WILL CONDUCT ELECTRICITY IF IT CONTACTS A LIVE SOURCE. THIS
MAY RESULT IN INJURY TO THE USER FROM ELECTRICAL SHOCK AND/OR FLASH FIRE.
FOR PRODUCT USE INSTRUCTIONS, PLEASE SEE THE PRODUCT LABEL.
STORAGE PROCEDURES:
STORE IN A COOL DRY AREA OUT OF DIRECT SUNLIGHT. AEROSOL CANS MUST BE
MAINTAINED BELOW 120 DEG. F / 49 DEG. C TO PREVENT CANS FROM RUPTURING.
STORE OUT OF REACH OF CHILDREN
AEROSOL STORAGE LEVEL: III
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
COMPONENT OSHA ACGIH OTHER UNIT
TWA STEL TWA STEL TWA SOURCE
PROPANE 1000 NE 1000 NE NE PPM
BUTANE 800 NE 1000 NE NE PPM
HEPTANE 500 NE 400 500 NE PPM
TOLUENE 100 150 20 NE NE PPM
2-PROPANOL 400 NE 200 400 NE PPM
GRAPHITE 2.5 NE 2 NE NE MG/M3
N.E. - NOT ESTABLISHED
(C) - CEILING
(S) - SKIN
(V) - VACATED
CONTROLS AND PROTECTION:
ENGINEERING CONTROLS:
AREA SHOULD HAVE VENTILATION TO PROVIDE FRESH AIR. LOCAL EXHAUST
VENTILATION IS GENERALLY PREFERRED BECAUSE IT CAN CONTROL THE EMISSIONS OF
THE CONTAMINANT AT THE SOURCE, PREVENTING DISPERSION INTO THE GENERAL WORK
AREA. USE MECHANICAL MEANS IF NECESSARY TO MAINTAIN VAPOR LEVELS BELOW THE
EXPOSURE GUIDELINES. IF WORKING IN A CONFINED SPACE, FOLLOW APPLICABLE OSHA
REGULATIONS.
RESPIRATORY PROTECTION:
NONE REQUIRED FOR NORMAL WORK WHERE ADEQUATE VENTILATION IS PROVIDED. IF
ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE APPLICABLE
EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH ORGANIC
VAPOR CARTRIDGE. AIR MONITORING IS NEEDED TO DETERMINE ACTUAL EMPLOYEE
EXPOSURE LEVELS. USE A SELF-CONTAINED BREATHING APPARATUS IN CONFINED
SPACES AND FOR EMERGENCIES.
EYE/FACE PROTECTION:
FOR NORMAL CONDITIONS, WEAR SAFETY GLASSES. WHERE THERE IS REASONABLE
PROBABILITY OF LIQUID CONTACT, WEAR SPLASH-PROOF GOGGLES.
SKIN PROTECTION:
USE PROTECTIVE GLOVES SUCH AS NITRILE OR NEOPRENE. ALSO, USE FULL
PROTECTIVE CLOTHING IF THERE IS PROLONGED OR REPEATED CONTACT OF LIQUID
WITH SKIN.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: BLACK
ODOR: SOLVENT ODOR
ODOR THRESHOLD: ND
SPECIFIC GRAVITY: 0.66
INITIAL BOILING POINT: ND
FREEZING POINT: ND
VAPOR PRESSURE: ND
VAPOR DENSITY: >1 (AIR = 1)
EVAPORATION RATE: FAST
SOLUBILITY: ND
COEFFICIENT OF WATER/OIL DISTRIBUTION: NA
PH: NA
VOLATILE ORGANIC COMPOUNDS:
WT %: 98.8
G/L: 652.1
LBS./GAL: 5.43
| SECTION 10: STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: SOURCES OF IGNITION; TEMPERATURE EXTREMES
INCOMPATIBLE MATERIALS: NONE KNOWN
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON DIOXIDE AND CARBON MONOXIDE
POSSIBILITY OF HAZARDOUS REACTIONS: NO
| SECTION 11: TOXICOLOGICAL INFORMATION | |
LONG-TERM TOXICOLOGICAL STUDIES HAVE NOT BEEN CONDUCTED FOR THIS PRODUCT.
THE FOLLOWING INFORMATION IS AVAILABLE FOR COMPONENTS OF THIS PRODUCT.
ACUTE TOXICITY:
COMPONENT ORAL LD50 (RAT) DERMAL LD50 (RABBIT) INHALATION LC50 (RAT)
PROPANE NO DATA NO DATA NO DATA
BUTANE NO DATA NO DATA 658,000 MG/M3/4H
HEPTANE NO DATA NO DATA 103 G/M3/4H
TOLUENE 636 MG/KG 12,125 MG/KG 8000 PPM/4H
2-PROPANOL 4720 MG/KG 12,800 MG/KG 17,000 PPM/4H
GRAPHITE <10,000 MG/KG NO DATA NO DATA
CHRONIC TOXICITY:
COMPONENT OSHA IARC NTP IRRITANT SENSITIZER
CARCINOGEN CARCINOGEN CARCINOGEN
PROPANE NO NO NO NO NO
BUTANE NO NO NO NO NO
HEPTANE NO NO NO SKIN UNKNOWN
TOLUENE NO NO NO SKIN NO
2-PROPANOL NO NO NO EYE NO
GRAPHITE NO NO NO NO UNKNOWN
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE
TERATOGENICITY: NO INFORMATION AVAILABLE
MUTAGENICITY: NO INFORMATION AVAILABLE
SYNERGISTIC EFFECTS: NO INFORMATION AVAILABLE
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOLOGICAL STUDIES HAVE NOT BEEN CONDUCTED FOR THIS PRODUCT. THE FOLLOWING
INFORMATION IS AVAILABLE FOR COMPONENTS OF THIS PRODUCT.
ECOTOXICITY: NO INFORMATION AVAILABLE
PERSISTENCE / DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATION / ACCUMULATION: NO INFORMATION AVAILABLE
MOBILITY IN ENVIRONMENT: NO INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
WASTE CLASSIFICATION:
THE DISPENSED LIQUID PRODUCT IS A RCRA HAZARDOUS WASTE FOR THE
CHARACTERISTIC OF IGNITABILITY WITH A WASTE CODE OF D001. (SEE 40 CFR
PART 261.20 - 261.33)
AEROSOL CONTAINERS SHOULD BE FULLY EMPTIED AND DEPRESSURIZED BEFORE
DISPOSAL. EMPTY AEROSOL CONTAINERS MAY BE RECYCLED.
ALL DISPOSAL ACTIVITIES MUST COMPLY WITH FEDERAL, STATE, PROVINCIAL AND
LOCAL REGULATIONS. LOCAL REGULATIONS MAY BE MORE STRINGENT THAN STATE,
PROVINCIAL OR NATIONAL REQUIREMENTS.
| SECTION 14: TRANSPORT INFORMATION | |
US DOT (GROUND): UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY**
ICAO/IATA (AIR): UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY
IMO/IMDG (WATER): UN1950, AEROSOLS, 2.1, LIMITED QUANTITY
SPECIAL PROVISIONS:
**THIS PRODUCT CAN BE CLASSIFIED AND LABELED AS 'CONSUMER COMMODITY, ORM-D'
FOR DOMESTIC GROUND SHIPPING UNTIL DECEMBER 31, 2020.
IF SHIPPING AS LIMITED QUANTITY BY GROUND, NOTE THAT SHIPPING PAPERS ARE
NOT REQUIRED.
| SECTION 15: REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TOXIC SUBSTANCES CONTROL ACT (TSCA):
ALL INGREDIENTS ARE EITHER LISTED ON THE TSCA INVENTORY OR ARE EXEMPT.
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT
(CERCLA):
REPORTABLE QUANTITIES (RQ'S) EXIST FOR THE FOLLOWING INGREDIENTS:
TOLUENE (1,000 LBS)
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE
ITS RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
SUPERFUND AMENDMENTS REAUTHORIZATION ACT (SARA) TITLE III:
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (EHS): NONE
SECTION 311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
REACTIVE HAZARD: NO
RELEASE OF PRESSURE: YES
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: YES
SECTION 313 TOXIC CHEMICALS:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372: TOLUENE (1%)
CLEAN AIR ACT:
SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS): TOLUENE
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA):
THIS PRODUCT IS REGULATED UNDER THE HAZARD COMMUNICATION STANDARD.
U.S. STATE REGULATIONS:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROP 65):
THIS PRODUCT MAY CONTAIN THE FOLLOWING CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM:
TOLUENE
CONSUMER PRODUCTS VOC REGULATIONS: THIS PRODUCT IS NOT REGULATED.
STATE RIGHT TO KNOW:
NEW JERSEY: 74-98-6, 106-97-8, 142-82-5, 108-88-3, 67-63-0
PENNSYLVANIA: 74-98-6, 106-97-8, 142-82-5, 108-88-3, 67-63-0, 7782-42-5
MASSACHUSETTS: 74-98-6, 106-97-8, 142-82-5, 108-88-3, 67-63-0
RHODE ISLAND: 74-98-6, 106-97-8, 142-82-5, 108-88-3, 67-63-0, 7782-42-5
CANADIAN REGULATIONS:
CANADIAN DSL INVENTORY:
ALL INGREDIENTS ARE EITHER LISTED ON THE DSL INVENTORY OR ARE EXEMPT.
WHMIS HAZARD CLASS: A, B5, D2A, D2B
EUROPEAN UNION REGULATIONS:
ROHS COMPLIANCE:
THIS PRODUCT IS COMPLIANT WITH DIRECTIVE 2002/95/EC OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL OF 27 JANUARY 2003. THIS PRODUCT DOES NOT
CONTAIN ANY OF THE RESTRICTED SUBSTANCES AS LISTED IN ARTICLE 4(1) OF THE
ROHS DIRECTIVE.
ADDITIONAL REGULATORY INFORMATION: NONE
| SECTION 16: OTHER INFORMATION | |
HMIS(R*) (II):
HEALTH 2
FLAMMABILITY 4
REACTIVITY 0
PPE B
NFPA:
2
4
0
RATINGS RANGE FROM 0 (NO HAZARD) TO 4 (SEVERE HAZARD)
PREPARED BY: MICHELLE RUDNICK
CRC #: 03094
REVISION DATE: 01/23/2014
CHANGES SINCE LAST REVISION:
MSDS REFORMATTED TO MEET THE REQUIREMENTS OF THE CANADIAN CONTROLLED
PRODUCTS REGULATIONS.
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC INDUSTRIES' KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY
CRC TO BE ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND
DIRECTIONS ON THE LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION
CONTAINED ON THIS MSDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY
PROFESSIONAL, OR CRC INDUSTRIES.
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
CAS: CHEMICAL ABSTRACT SERVICE
CFR: CODE OF FEDERAL REGULATIONS
DOT: DEPARTMENT OF TRANSPORTATION
DSL: DOMESTIC SUBSTANCE LIST
G/L: GRAMS PER LITER
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
IMO: INTERNATIONAL MARITIME ORGANIZATION
LBS./GAL: POUNDS PER GALLON
LC: LETHAL CONCENTRATION
LD: LETHAL DOSE
NA: NOT APPLICABLE
ND: NOT DETERMINED
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY & HEALTH
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NTP: NATIONAL TOXICOLOGY PROGRAM
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PMCC: PENSKY-MARTENS CLOSED CUP
PPE: PERSONAL PROTECTION EQUIPMENT
PPM: PARTS PER MILLION
ROHS: RESTRICTION OF HAZARDOUS SUBSTANCES
STEL: SHORT TERM EXPOSURE LIMIT
TCC: TAG CLOSED CUP
TWA: TIME WEIGHTED AVERAGE
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM