| Common Name: | SIMPLE GREEN HAND CLEANER GEL |
| Manufacturer: | SUNSHINE MAKERS |
| SDS Revision Date: | 9/26/2014 |
| SDS Format: | No Format Specified |
| Item Number(s): | 19ZN58, 19ZN59 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
SIMPLE GREEN(R*) HAND CLEANER GEL
VERSION NO.: 42150-14C
ISSUE DATE: SEPTEMBER 26, 2014
SUPERSEDES DATE: MAY 5, 2014
OSHA HCS-2012 / GHS
| SECTION 1: IDENTIFICATION |  |
PRODUCT NAME: SIMPLE GREEN(R*) HAND CLEANER GEL
ADDITIONAL NAMES:
MANUFACTURER'S PART NUMBER: *PLEASE REFER TO SECTION 16
RECOMMENDED USE: CLEANER FOR REMOVING GREASE, DIRT AND GRIME FROM HANDS.
RESTRICTIONS ON USE: DO NOT USE FOR ANY OTHER APPLICATION.
COMPANY:
SUNSHINE MAKERS, INC.
15922 PACIFIC COAST HIGHWAY
HUNTINGTON BEACH, CA 92649
USA
TELEPHONE:
800-228-0709
562-795-6000 MON - FRI, 8AM - 5PM PST
FAX: 562-592-3830
EMAIL: INFO@SIMPLEGREEN.COM
EMERGENCY PHONE:
CHEM-TEL 24-HOUR EMERGENCY SERVICE: 800-255-3924
| SECTION 2: HAZARDS IDENTIFICATION | |
THIS PRODUCT IS CONSIDERED HAZARDOUS (EYE CORROSIVE/IRRITANT - CATEGORY 2B)
BY THE 2012 OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200)
OSHA HCS 2012:
LABEL ELEMENTS:
SIGNAL WORD: WARNING
HAZARD SYMBOL(S)/PICTOGRAM(S): NONE REQUIRED
HAZARD STATEMENTS:
H320: CAUSES EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN
OTHER INFORMATION: NONE KNOWN
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT CAS NUMBER PERCENT RANGE
WATER 7732-18-5 >87.5%
PUMICE 1332-09-8 <2%
ACRYLATES/C10-30 ALKYL ACRYLATE PROPRIETARY <1%
CROSSPOLYMER
DIISOPROPANOLAMINE 110-97-4 <1%
SODIUM CITRATE 68-04-2 <1%
ETHOXYLATED ALCOHOL 68439-46-3 <1%
ACETYLATED LANOLIN ALCOHOL 61788-49-6 <1%
SODIUM CARBONATE 497-19-8 <1%
CITRIC ACID 77-92-9 <1%
TETRASODIUM N,N-BIS(CARBOXYMETHYL)- 51981-21-6 <1%
L-GLUTAMATE
FRAGRANCE PROPRIETARY <1%
COLORANT PROPRIETARY <1%
BENZYL ALCOHOL 100-51-6 <0.5%
DEHYDROACETIC ACID 520-45-6 <0.5%
*SPECIFIC PERCENTAGES OF COMPOSITION ARE BEING WITHHELD AS A TRADE SECRET
| SECTION 4: FIRST-AID MEASURES | |
INHALATION:
NOT EXPECTED TO CAUSE RESPIRATORY IRRITATION. IF ADVERSE EFFECT OCCURS,
MOVE TO FRESH AIR.
SKIN CONTACT:
NOT EXPECTED TO CAUSE SKIN IRRITATION. IF ADVERSE EFFECT OCCURS, RINSE
SKIN WITH WATER.
EYE CONTACT: CAUSES EYE IRRITATION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
INGESTION:
MAY CAUSE UPSET STOMACH. DRINK PLENTY OF WATER TO DILUTE. SEE SECTION 11.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED: NONE KNOWN.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY: TREAT SYMPTOMATICALLY
| SECTION 5: FIRE-FIGHTING MEASURES | |
SUITABLE & UNSUITABLE EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, WATER SPRAY OR "ALCOHOL" FOAM. AVOID HIGH VOLUME JET
WATER.
SPECIFIC HAZARDS ARISING FROM CHEMICAL:
IN EVENT OF FIRE, FIRE CREATED CARBON OXIDES MAY BE FORMED.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS; WEAR FULL
PROTECTIVE CLOTHING.
THIS PRODUCT IS NON-FLAMMABLE. SEE SECTION 9 FOR PHYSICAL PROPERTIES.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY AND EMERGENCY PERSONNEL:
SEE SECTION 8 - PERSONAL PROTECTION. AVOID EYE CONTACT. WEAR SAFETY
GOGGLES.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW INTO OPEN WATERWAYS AND GROUND WATER SYSTEMS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEAN UP:
DIKE OR SOAK UP WITH INERT ABSORBENT MATERIAL. SEE SECTION 13 FOR DISPOSAL
CONSIDERATIONS.
| SECTION 7: HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ENSURE ADEQUATE VENTILATION. KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM
HEAT, SPARKS, OPEN FLAME AND DIRECT SUNLIGHT. DO NOT PIERCE ANY PART OF THE
CONTAINER. DO NOT MIX OR CONTAMINATE WITH ANY OTHER CHEMICAL. DO NOT EAT,
DRINK OR SMOKE WHILE USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE INCLUDING INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED. KEEP IN COOL DRY AREA. AVOID PROLONGED
EXPOSURE TO SUNLIGHT. DO NOT STORE AT TEMPERATURES ABOVE 109 DEG. F
(42.7 DEG. C). IF SEPARATION OCCURS, MIX THE PRODUCT FOR RECONSTITUTION.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE LIMIT VALUES:
NO COMPONENTS LISTED WITH TWA OR STEL VALUES UNDER OSHA OR ACGIH.
APPROPRIATE ENGINEERING CONTROLS:
SHOWERS, EYEWASH STATIONS, VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES / PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE CONTACT:
USE PROTECTIVE GLASSES OR SAFETY GOGGLES IF SPLASHING OR SPRAY-BACK IS
LIKELY.
RESPIRATORY:
USE IN WELL VENTILATED AREAS OR LOCAL EXHAUST VENTILATIONS WHEN CLEANING
SMALL SPACES.
SKIN CONTACT:
USE PROTECTIVE GLOVES (ANY MATERIAL) WHEN USED FOR PROLONGED PERIODS OR
DERMALLY SENSITIVE.
GENERAL HYGIENE CONSIDERATIONS:
WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: VISCOUS GREEN GEL
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT DETERMINED
ODOR: NO ADDED ODOR
AUTOIGNITION TEMPERATURE: NON-FLAMMABLE
ODOR THRESHOLD: NOT DETERMINED
DECOMPOSITION TEMPERATURE: 109 DEG. F
PH: 9.8 - 10.8
VISCOSITY: 7500 - 12000 CPS
FREEZING POINT: 0 DEG. C (32 DEG. F)
SPECIFIC GRAVITY: 0.95 - 1.05
BOILING POINT & RANGE: 101 DEG. C (213.8 DEG. F)
VOCS: **WATER & FRAGRANCE EXEMPTION IN CALCULATION
SCAQMD 304-91 / EPA 24: NOT TESTED
CARB METHOD 310**:
0.8 G/L
0.033 LB/GAL
0.08%
SCAQMD METHOD 313: NOT TESTED
FLASH POINT: >212 DEG. F
EVAPORATION RATE: NOT DETERMINED
FLAMMABILITY (SOLID, GAS): NOT DETERMINED
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT APPLICABLE
VOC COMPOSITE PARTIAL PRESSURE: NOT DETERMINED
VAPOR PRESSURE: NOT DETERMINED
RELATIVE DENSITY: 7.923 - 8.757 LB/GAL
VAPOR DENSITY: NOT DETERMINED
SOLUBILITY: 100% IN WATER
| SECTION 10: STABILITY AND REACTIVITY | |
REACTIVITY: NON-REACTIVE.
CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS 70 DEG. F (21 DEG. C) AND 14.7 PSIG
(760 MMHg).
POSSIBILITY OF HAZARDOUS REACTIONS: NONE KNOWN.
CONDITIONS TO AVOID: EXCESSIVE HEAT OR COLD.
INCOMPATIBLE MATERIALS:
DO NOT MIX WITH OXIDIZERS, ACIDS, BATHROOM CLEANERS, OR DISINFECTING
AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS: NORMAL PRODUCTS OF COMBUSTION - CO, CO2.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
LIKELY ROUTES OF EXPOSURE:
INHALATION: OVEREXPOSURE MAY CAUSE HEADACHE.
SKIN CONTACT:
NOT EXPECTED TO CAUSE IRRITATION, REPEATED CONTACT MAY CAUSE DRY SKIN.
EYE CONTACT: CAUSES EYE IRRITATION.
INGESTION: MAY CAUSE UPSET STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS: NO SYMPTOMS EXPECTED UNDER TYPICAL USE CONDITIONS.
DELAYED AND IMMEDIATE EFFECTS AND OR CHRONIC EFFECTS FROM SHORT TERM
EXPOSURE: NO SYMPTOMS EXPECTED UNDER TYPICAL USE CONDITIONS.
DELAYED AND IMMEDIATE EFFECTS AND OR CHRONIC EFFECTS FROM LONG TERM
EXPOSURE: HEADACHE, DRY SKIN, OR SKIN IRRITATION MAY OCCUR.
INTERACTIVE EFFECTS: NOT KNOWN.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY:
ORAL LD50 (RAT): >5 G/KG BODY WEIGHT
DERMAL LD50 (RABBIT): >5 G/KG BODY WEIGHT
CALCULATED VIA OSHA HCS 2012/GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION
AND LABELLING OF CHEMICALS
SKIN CORROSION/IRRITATION:
NON-IRRITANT PER DERMAL IRRITECTION(R*) ASSAY MODELING. NO ANIMAL TESTING
PERFORMED.
EYE DAMAGE/IRRITATION:
IRRITANT PER OCULAR IRRITECTION(R*) ASSAY MODELING. NO ANIMAL TESTING
PERFORMED.
GERM CELL MUTAGENICITY: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
CARCINOGENICITY:
NO INGREDIENTS TRIGGER OR CLASSIFY UNDER THIS CATEGORY UNDER NTP, IARC OR
OSHA.
REPRODUCTIVE TOXICITY: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
STOT-SINGLE EXPOSURE: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
STOT-REPEATED EXPOSURE: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
ASPIRATION HAZARD: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICITY:
VOLUME OF INGREDIENTS USED DOES NOT TRIGGER TOXICITY CLASSIFICATIONS UNDER
THE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF
CHEMICALS.
AQUATIC: NOT TESTED ON FINISHED FORMULATION.
TERRESTRIAL: NOT TESTED ON FINISHED FORMULATION.
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
UNUSED OR USED LIQUID:
MAY BE CONSIDERED HAZARDOUS IN YOUR AREA DEPENDING ON USAGE AND TONNAGE OF
DISPOSAL - CHECK WITH LOCAL, REGIONAL, AND OR NATIONAL REGULATIONS FOR
APPROPRIATE METHODS OF DISPOSAL.
EMPTY CONTAINERS: DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
NEVER DISPOSE OF USED DEGREASING RINSATES INTO LAKES, STREAMS, AND OPEN
BODIES OF WATER OR STORM DRAINS.
| SECTION 14: TRANSPORT INFORMATION | |
U.N. NUMBER: NOT APPLICABLE
TRANSPORT HAZARD CLASS(ES): NOT APPLICABLE
PACKING GROUP: NOT APPLICABLE
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
U.N. PROPER SHIPPING NAME:
SOAP, HAND IN CONTAINER FREESTANDING OR WITH PUMP
NMFC NUMBER: 59363
CLASS: 55
TRANSPORT IN BULK (ACCORDING TO ANNEX II OF MARPOL 73/78 AND IBC CODE):
UNKNOWN.
SPECIAL PRECAUTIONS WHICH USER NEEDS TO BE AWARE OF/COMPLY WITH, IN
CONNECTION WITH TRANSPORT OR CONVEYANCE EITHER WITHIN OR OUTSIDE THEIR
PREMISES: NONE KNOWN.
U.S. (DOT)/CANADIAN TDG: NOT REGULATED FOR SHIPPING.
IMO/IDMG: NOT CLASSIFIED AS HAZARDOUS
ICAO/IATA: NOT CLASSIFIED AS HAZARDOUS
ADR/RID: NOT CLASSIFIED AS HAZARDOUS
| SECTION 15: REGULATORY INFORMATION | |
ALL COMPONENTS ARE LISTED ON: TSCA AND DSL INVENTORY.
SARA TITLE III:
SECTIONS 311/312 HAZARD CATEGORIES: NOT APPLICABLE.
SECTIONS 313 SUPERFUNDS AMENDMENTS AND REAUTHORIZATIONS ACT OF 1986:
NOT APPLICABLE.
SECTIONS 302: NOT APPLICABLE.
CLEAN AIR ACT (CAA):
BENZYL ALCOHOL 100-51-6: GROUP III
CLEAN WATER ACT (CWA): NOT APPLICABLE
STATE RIGHT TO KNOW LISTS:
DIISOPROPANOLAMINE 110-97-4: MASSACHUSETTS, PENNSYLVANIA
BENZYL ALCOHOL 100-51-6: MASSACHUSETTS, PENNSYLVANIA
CALIFORNIA PROPOSITION 65: NO INGREDIENTS LISTED
TEXAS ESL:
ETHOXYLATED ALCOHOL 68439-46-3 60 (MICRO)G/M3 600 (MICRO)G/M3
LONG TERM SHORT TERM
SODIUM CITRATE 68-04-2 5 (MICRO)G/M3 50 (MICRO)G/M3
LONG TERM SHORT TERM
SODIUM CARBONATE 497-19-8 5 (MICRO)G/M3 50 (MICRO)G/M3
LONG TERM SHORT TERM
CITRIC ACID 77-92-9 10 (MICRO)G/M3 100 (MICRO)G/M3
LONG TERM SHORT TERM
PUMICE 1322-09-8 5 (MICRO)G/M3 50 (MICRO)G/M3
LONG TERM SHORT TERM
DIISOPROPANOLAMINE 110-97-4 46 (MICRO)G/M3 460 (MICRO)G/M3
LONG TERM SHORT TERM
BENZYL ALCOHOL 100-51-6 44 (MICRO)G/M3 440 (MICRO)G/M3
LONG TERM SHORT TERM
| SECTION 16: OTHER INFORMATION | |
SIZE ITEM NUMBER UPC
5 OZ. 0900000142150 043318421501
5 OZ. 0900200142150 043318000355
5 OZ., 12 PER CASE 0910001242150 043318421501
5 OZ., 12 PER CASE 0910201242150 043318000355
6.75 OZ. 0900000142675 043318426759
6.75 OZ,, 12 PER CASE 42675 & 0910001242675 043318426759
14 OZ. 0900000142014 043318420146
14 OZ,, 12 PER CASE 0910001242014 043318420146
1 GALLON 0900000142128 043318421280
1 GALLON, 4 PER CASE 0910000442128 043318421280
1 GALLON 0900200142128 043318000201
1 GALLON, 4 PER CASE 0910200442128 043318000201
55 GALLON 0900000142055 043318420559
USA ITEMS LISTED ONLY. NOT ALL ITEMS LISTED. USA ITEMS MAY NOT BE VALID FOR
INTERNATIONAL SALE.
CAGE CODE: 1Z575
GSA/FSS - CONTRACT NO. GS-07F0065J
NATIONAL STOCK NUMBERS:
42675 - NSN 8520-01-370-4284
0910200442128 - NSN 8520-01-370-2162
NFPA:
HEALTH 1 - EYE IRRITANT
FLAMMABILITY 0 - NON-FLAMMABLE
STABILITY 0 - STABLE
SPECIAL 0 - NONE
ACRONYMS:
NTP: NATIONAL TOXICOLOGY PROGRAM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
CPSC: CONSUMER PRODUCT SAFETY COMMISSION
TSCA: TOXIC SUBSTANCES CONTROL ACT
DSL: DOMESTIC SUBSTANCES LIST
PREPARED / REVISED BY: SUNSHINE MAKERS, INC., REGULATORY DEPARTMENT.
THIS SDS HAS BEEN REVISED IN THE FOLLOWING SECTIONS: REVISED SDS LAYOUT
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS GUIDANCE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT TO BE
CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION RELATES
ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH
MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS,
UNLESS SPECIFIED IN THE TEXT.