| Common Name: | SCRUBS SUN SKEETER INSECT REPELLENT + SUNSCREEN WIPE |
| Manufacturer: | ITW PROFESSIONAL BRANDS |
| SDS Revision Date: | 11/7/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 2FLN3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ITW PRO BRANDS
SAFETY DATA SHEET
ISSUING DATE: 22-OCT-2013
REVISION DATE: 07-NOV-2014
REVISION NUMBER: 1
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND THE COMPANY/UNDERTAKING
GHS PRODUCT IDENTIFIER:
PRODUCT NAME: SCRUBS(R*) SUN SKEETER(TM) INSECT REPELLENT + SUNSCREEN WIPE
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE(S): 91501
SYNONYMS: NONE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: INSECT REPELLANT, SUNSCREEN WIPES
USES ADVISED AGAINST: NONE REASONABLY FORESEEABLE
SUPPLIER'S DETAILS:
SUPPLIER ADDRESS:
ITW PRO BRANDS
805 E. OLD 56 HIGHWAY
OLATHE, KS 66061
TEL: 1-800-443-9536
EMERGENCY TELEPHONE NUMBER:
EMERGENCY TELEPHONE NUMBER: 800-535-5053 INFOTRAC
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS ACCORDING TO THE OSHA HAZARD
COMMUNICATION STANDARD 2012 (29 CFR 1910.1200)
SKIN CORROSION/IRRITATION: CATEGORY 2
SKIN SENSITIZATION: CATEGORY 1
FLAMMABLE LIQUIDS: CATEGORY 2
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
EMERGENCY OVERVIEW:
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION
MAY CAUSE AN ALLERGIC SKIN REACTION
HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXCLAMATION MARK
FLAME
APPEARANCE: COLORLESS
PHYSICAL STATE: LIQUID.
ODOR: ALCOHOL, FLORAL
PRECAUTIONARY STATEMENTS:
PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES - NO SMOKING
KEEP CONTAINER TIGHTLY CLOSED
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT
USE ONLY NON-SPARKING TOOLS
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
GENERAL ADVICE: NONE
SKIN:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
FIRE:
IN CASE OF FIRE: USE CO2, DRY CHEMICAL, OR FOAM FOR EXTINCTION.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
HAZARD NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER INFORMATION: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO WEIGHT % TRADE SECRET
ETHYL ALCOHOL 64-17-5 40-70 *
N,N-DIETHYL-M-TOLUAMIDE 134-62-3 10-30 *
*THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS
A TRADE SECRET.
| 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST-AID MEASURES:
EYE CONTACT:
RINSE THOROUGHLY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND CONSULT
A PHYSICIAN.
SKIN CONTACT:
NONE NORMALLY REQUIRED. IF SYMPTOMS ARISE, CALL A PHYSICIAN WASH SKIN WITH
SOAP AND WATER.
INHALATION:
NONE UNDER NORMAL USE. MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS
OCCUR.
INGESTION:
NONE UNDER NORMAL USE. IF LARGE QUANTITIES OF THIS MATERIAL ARE SWALLOWED,
CALL A PHYSICIAN IMMEDIATELY.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MOST IMPORTANT SYMPTOMS/EFFECTS: NO INFORMATION AVAILABLE.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA: DRY CHEMICAL. CARBON DIOXIDE (CO2). FOAM.
UNSUITABLE EXTINGUISHING MEDIA:
CAUTION: USE OF WATER SPRAY WHEN FIGHTING FIRE MAY BE INEFFICIENT.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
VAPORS MAY TRAVEL TO SOURCE OF IGNITION AND FLASH BACK. VAPORS MAY FORM
EXPLOSIVE MIXTURES WITH AIR.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE (CO2). FORMALDEHYDE. NITROUS OXIDE. SOOT.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: YES.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
GEAR. USE WATER SPRAY TO COOL SURROUNDING CONTAINERS.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
REMOVE ALL SOURCES OF IGNITION. AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
HIGH RISK OF SLIPPING DUE TO LEAKAGE/SPILLAGE OF PRODUCT.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. DISPOSE OF CONTENTS/CONTAINER TO AN
APPROVED WASTE DISPOSAL PLANT. COLLECT SPILLAGE. SEE SECTION 12 FOR
ADDITIONAL ECOLOGICAL INFORMATION
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
SMALL SPILLAGE: WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE).
LARGE SPILLAGE:
USE A NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND OR EARTH TO SOAK UP
THE PRODUCT AND PLACE INTO A CONTAINER FOR LATER DISPOSAL.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID CONTACT WITH EYES. WASH THOROUGHLY AFTER HANDLING. AVOID BREATHING
VAPORS OR MISTS. DO NOT TAKE INTERNALLY. DO NOT SMOKE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP AWAY FROM HEAT AND SOURCES OF
IGNITION. KEEP CONTAINERS TIGHTLY CLOSED IN A COOL, WELL-VENTILATED PLACE.
KEEP OUT OF THE REACH OF CHILDREN.
DO NOT CONTAMINATE FOOD OR FEED STUFFS.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZING AGENTS.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
ETHYL ALCOHOL TWA: 1000 PPM TWA: 1000 PPM IDLH: 3300 PPM 10% LEL
64-17-5 TWA: 1900 MG/M3 TWA: 1000 PPM
TWA: 1900 MG/M3
(VACATED) TWA:
1000 PPM
(VACATED) TWA:
1900 MG/M3
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED. AVOID CONTACT WITH EYES.
SKIN AND BODY PROTECTION: NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED.
RESPIRATORY PROTECTION:
NONE REQUIRED UNDER NORMAL USAGE. IF EXPOSURE LIMITS ARE EXCEEDED OR
IRRITATION IS EXPERIENCED, NIOSH/MSHA APPROVED RESPIRATORY PROTECTION
SHOULD BE WORN.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: COLORLESS
ODOR: ALCOHOL, FLORAL
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS/ - METHOD
PH 6.4 NONE KNOWN
MELTING POINT/RANGE NO DATA AVAILABLE NONE KNOWN
BOILING POINT/BOILING RANGE 82.222 DEG. C / 180 DEG. F NONE KNOWN
FLASH POINT 16.667 DEG. C / 62 DEG. F PMCC
EVAPORATION RATE NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY (SOLID, GAS) NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO DATA AVAILABLE
LOWER FLAMMABILITY LIMIT NO DATA AVAILABLE
VAPOR PRESSURE NO DATA AVAILABLE NONE KNOWN
VAPOR DENSITY >1 NONE KNOWN
RELATIVE DENSITY NO DATA AVAILABLE NONE KNOWN
SPECIFIC GRAVITY 0.885 NONE KNOWN
WATER SOLUBILITY MISCIBLE WITH WATER NONE KNOWN
SOLUBILITY IN OTHER SOLVENTS NO DATA AVAILABLE NONE KNOWN
PARTITION COEFFICIENT NO DATA AVAILABLE NONE KNOWN
N-OCTANOL/WATER
AUTOIGNITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
DECOMPOSITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
VISCOSITY NO DATA AVAILABLE NONE KNOWN
FLAMMABLE PROPERTIES NOT FLAMMABLE
EXPLOSIVE PROPERTIES NO DATA AVAILABLE
OXIDIZING PROPERTIES NO DATA AVAILABLE
OTHER INFORMATION:
VOC CONTENT (%) 55.5%
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: INCOMPATIBLE PRODUCTS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE (CO). CARBON DIOXIDE (CO2). NITROUS OXIDE. FORMALDEHYDE.
SMOKE. SOOT.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
INHALATION:
OVEREXPOSURE: MAY CAUSE IRRITATION OF RESPIRATORY TRACT.
EYE CONTACT: CONTACT WITH EYES MAY CAUSE IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND
LONG TERM EXPOSURE:
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE.
CARCINOGENICITY:
THE LIST BELOW INDICATES ANY INGREDIENT LISTED AS A CARCINOGEN:
ETHANOL HAS BEEN SHOWN TO BE CARCINOGENIC IN LONG-TERM STUDIES ONLY WHEN
CONSUMED AND ABUSED AS AN ALCOHOLIC BEVERAGE.
CHEMICAL NAME ACGIH IARC NTP OSHA
ETHYL ALCOHOL A3 GROUP 1 KNOWN X
ACGIH: (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
A3 - ANIMAL CARCINOGEN
IARC: (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
GROUP 1 - CARCINOGENIC TO HUMANS
NTP: (NATIONAL TOXICITY PROGRAM)
KNOWN - KNOWN CARCINOGEN
OSHA: (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION)
X - PRESENT
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE.
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
NUMERICAL MEASURES OF TOXICITY - PRODUCT:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT:
LD50 ORAL: 4306 MG/KG; ACUTE TOXICITY ESTIMATE
LD50 DERMAL: 5000 MG/KG; ACUTE TOXICITY ESTIMATE
INHALATION:
DUST/MIST: 124.7 MG/L; ACUTE TOXICITY ESTIMATE
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
CHEMICAL NAME TOXICITY TO ALGAE TOXICITY TO FISH
ETHYL ALCOHOL LC50 96 H:
64-17-5 12.0 - 16.0 ML/L
STATIC (ONCORHYNCHUS MYKISS)
LC50 96 H:
>100 MG/L
STATIC (PIMEPHALES PROMELAS)
LC50 96 H:
13400 - 15100 MG/L
FLOW-THROUGH (PIMEPHALES PROMELAS)
N,N-DIETHYL- LC50 96 H:
M-TOLUAMIDE 106-114 MG/L
134-62-3 FLOW-THROUGH (PIMEPHALES PROMELAS)
LC50 96 H:
=71.25 MG/L
STATIC (ONCORHYNCHUS MYKISS)
CHEMICAL NAME TOXICITY TO MICROORGANISMS DAPHNIA MAGNA (WATER FLEA)
ETHYL ALCOHOL EC50: 34634 MG/L 30 MIN LC50 48 H:
EC50: 35470 MG/L 5 MIN 9268 - 14221 MG/L
(DAPHNIA MAGNA)
EC50 24 H:
=10800 MG/L
(DAPHNIA MAGNA)
EC50 48 H:
=2 MG/L
STATIC (DAPHNIA MAGNA)
N,N-DIETHYL- EC50: 67.9 MG/L 5 MIN
M-TOLUAMIDE
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: NO INFORMATION AVAILABLE.
CHEMICAL NAME LOG POW
ETHYL ALCOHOL -0.32
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHODS:
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS
CONTAMINATED PACKAGING: DO NOT RE-USE EMPTY CONTAINERS.
THIS PRODUCT CONTAINS ONE OR MORE SUBSTANCES THAT ARE LISTED WITH THE
STATE OF CALIFORNIA AS A HAZARDOUS WASTE.
CHEMICAL NAME CALIFORNIA HAZARDOUS WASTE
ETHYL ALCOHOL TOXIC
IGNITABLE
| 14. TRANSPORT INFORMATION | |
DOT:
PROPER SHIPPING NAME: CONSUMER COMMODITY
HAZARD CLASS: ORM-D
DESCRIPTION: CONSUMER COMMODITY, ORM-D
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
LEGEND:
TSCA:
UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY. ALL
COMPONENTS OF THIS PRODUCT ARE EITHER LISTED OR ARE EXEMPT ON THE TSCA
INVENTORY.
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
U.S. FEDERAL REGULATIONS:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372.
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: YES
SUDDEN RELEASE OF PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
CLEAN WATER ACT:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42).
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED
AS HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL.
U.S. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS THE FOLLOWING PROPOSITION 65 CHEMICALS:
CHEMICAL NAME CAS-NO CALIFORNIA PROP. 65
ETHYL ALCOHOL 64-17-5 DEVELOPMENTAL
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
"X" DESIGNATES THAT THE INGREDIENTS ARE LISTED ON THE STATE RIGHT TO KNOW
LIST.
CHEMICAL NEW MASSACHUSETTS PENNSYLVANIA ILLINOIS RHODE
NAME JERSEY ISLAND
ETHYL ALCOHOL X X X
U.S. EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: 11694-112
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARD 1
FLAMMABILITY 3
INSTABILITY 0
PHYSICAL AND CHEMICAL HAZARDS
HMIS:
HEALTH HAZARD 1
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
PREPARED BY:
PRODUCT STEWARDSHIP
23 BRITISH AMERICAN BLVD.
LATHAM, NY 12110
1-800-572-6501
ISSUING DATE: 22-OCT-2013
REVISION DATE: 22-OCT-2013
REVISION NOTE: INITIAL RELEASE.
GENERAL DISCLAIMER:
THE INFORMATION PROVIDED ON THIS SDS IS CORRECT TO THE BEST OF OUR
KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT TO BE
CONSIDERED AS A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION RELATES
ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH
MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS,
UNLESS SPECIFIED IN THE TEXT.
WPS-ITW-011 - SCRUBS(R*) SUN SKEETER(TM) INSECT REPELLENT + SUNSCREEN WIPE