| Common Name: | DYKEM TRANSPARENT STAIN BULK - STEEL BLUE, STEEL RED AND BLACK |
| Manufacturer: | ITW PROFESSIONAL BRANDS |
| SDS Revision Date: | 4/9/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 2C936, 2C945, 2C967, 2GKW1, 2GKW2, 2GKW3, 30E893, 30E901 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ITW PROFESSIONAL BRANDS
SAFETY DATA SHEET
ISSUING DATE: 09-APR-2014
REVISION DATE: 09-APR-2014
REVISION NUMBER: 0
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND THE COMPANY/UNDERTAKING
GHS PRODUCT IDENTIFIER:
PRODUCT NAME: DYKEM TRANSPARENT STAIN BULK - STEEL BLUE, STEEL RED AND BLACK
OTHER MEANS OF IDENTIFICATION:
PART NUMBER:
DK BLUE - STEEL BLUE (80200, 80300 80400, 80600, 80700), RED - STEEL RED
(80296, 80396, 80496, 80696), BLACK (81731)
FORMULA CODE:
DK BLUE - STEEL BLUE (8706), RED - STEEL RED (8705), BLACK (8749)
UN-NUMBER: UN1263
SYNONYMS: NONE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: STAINING COLORS
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER'S DETAILS:
SUPPLIER ADDRESS:
ITW PROFESSIONAL BRANDS
805 E. OLD 56 HIGHWAY
OLATHE, KS 66061
TEL: 1-800-443-9536
EMERGENCY TELEPHONE NUMBER:
EMERGENCY TELEPHONE NUMBER: 800-535-5053 INFOTRAC
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS ACCORDING TO THE OSHA HAZARD
COMMUNICATION STANDARD 2012 (29 CFR 1910.1200)
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
REPRODUCTIVE TOXICITY: CATEGORY 2
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE): CATEGORY 3
FLAMMABLE LIQUIDS: CATEGORY 2
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
EMERGENCY OVERVIEW:
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE DAMAGE
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
MAY CAUSE RESPIRATORY IRRITATION
MAY CAUSE DROWSINESS OR DIZZINESS
HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXCLAMATION MARK
HEALTH HAZARD
CORROSION
FLAME
APPEARANCE: RED, BLUE, BLACK, COLOR THIN VISCOSITY.
PHYSICAL STATE: LIQUID.
ODOR: SWEET, SOLVENT
PRECAUTIONARY STATEMENTS:
PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES - NO SMOKING
KEEP CONTAINER TIGHTLY CLOSED
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT
USE ONLY NON-SPARKING TOOLS
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
KEEP COOL
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
GENERAL ADVICE:
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION/ADVICE
SPECIFIC TREATMENT (SEE SUPPLEMENTAL FIRST AID INSTRUCTIONS ON THIS LABEL)
EYES:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
SKIN:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE.
INHALATION:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
FIRE:
IN CASE OF FIRE: USE CO2, DRY CHEMICAL, OR FOAM FOR EXTINCTION.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
HAZARD NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER INFORMATION: TOXIC TO AQUATIC LIFE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO WEIGHT % TRADE SECRET
ETHANOL 64-17-5 30-60 *
N-BUTYL ACETATE 123-86-4 30-60 *
N-BUTYL ALCOHOL 71-36-3 10-30 *
DIACETONE ALCOHOL 123-42-2 3-7 *
ISOPROPYL ALCOHOL 67-63-0 1-5 *
N-PROPYL ACETATE 109-60-4 1-5 *
MALACHITE GREEN OXALATE 2437-29-8 0.1-1 *
*THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD
AS A TRADE SECRET.
| 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST-AID MEASURES:
GENERAL ADVICE:
IMMEDIATE MEDICAL ATTENTION IS REQUIRED. SHOW THIS SAFETY DATA SHEET TO
THE DOCTOR IN ATTENDANCE. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. KEEP EYE WIDE OPEN WHILE RINSING. IMMEDIATE MEDICAL
ATTENTION IS REQUIRED.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH PLENTY OF WATER. REMOVE AND WASH CONTAMINATED
CLOTHING BEFORE RE-USE. IF SKIN IRRITATION PERSISTS, CALL A PHYSICIAN.
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
INGESTION:
IF LARGE QUANTITIES OF THIS MATERIAL ARE SWALLOWED, CALL A PHYSICIAN
IMMEDIATELY. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.
PROTECTION OF FIRST-AIDERS:
USE PERSONAL PROTECTIVE EQUIPMENT. REMOVE ALL SOURCES OF IGNITION.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MOST IMPORTANT SYMPTOMS/EFFECTS: NO INFORMATION AVAILABLE.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2). FOAM. DRY CHEMICAL. WATER FOG.
UNSUITABLE EXTINGUISHING MEDIA: NONE
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FLAMMABLE. MOST VAPORS ARE HEAVIER THAN AIR. THEY WILL SPREAD ALONG GROUND
AND COLLECT IN LOW OR CONFINED AREAS (SEWERS, BASEMENTS, TANKS). VAPORS MAY
TRAVEL TO SOURCE OF IGNITION AND FLASH BACK.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: YES.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR. USE WATER
SPRAY TO COOL SURROUNDING CONTAINERS.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
EVACUATE PERSONNEL TO SAFE AREAS. USE PERSONAL PROTECTIVE EQUIPMENT. ENSURE
ADEQUATE VENTILATION. REMOVE ALL SOURCES OF IGNITION. KEEP PEOPLE AWAY FROM
AND UPWIND OF SPILL/LEAK.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. PREVENT PRODUCT FROM
ENTERING DRAINS. DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
AVOID RELEASE TO THE ENVIRONMENT. DISPOSE OF CONTENTS/CONTAINER TO AN
APPROVED WASTE DISPOSAL PLANT. SEE SECTION 12 FOR ADDITIONAL ECOLOGICAL
INFORMATION
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
GROUND AND BOND CONTAINERS WHEN TRANSFERRING MATERIAL.
SMALL SPILLAGE:
TAKE UP WITH SAND, EARTH OR OTHER NONCOMBUSTIBLE ABSORBENT MATERIAL PICK UP
AND TRANSFER TO PROPERLY LABELED CONTAINERS.
LARGE SPILLAGE: PUMP ANY FREE LIQUID INTO AN APPROPRIATE CLOSED CONTAINER.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. USE ONLY IN AN AREA
CONTAINING FLAME PROOF EQUIPMENT. DO NOT BREATHE VAPORS OR SPRAY MIST.
ENSURE ADEQUATE VENTILATION. TO AVOID IGNITION OF VAPORS BY STATIC
ELECTRICITY DISCHARGE, ALL METAL PARTS OF THE EQUIPMENT MUST BE GROUNDED.
USE ONLY IN AREA PROVIDED WITH APPROPRIATE EXHAUST VENTILATION. DO NOT EAT,
DRINK OR SMOKE WHEN USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION. KEEP
IN PROPERLY LABELED CONTAINERS. KEEP CONTAINERS TIGHTLY CLOSED IN A COOL,
WELL-VENTILATED PLACE. KEEP OUT OF THE REACH OF CHILDREN.
INCOMPATIBLE PRODUCTS:
STRONG OXIDIZING AGENTS. STRONG ACIDS. STRONG REDUCING AGENTS. STRONG
ALKALIS.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
ETHANOL STEL: 1000 PPM TWA: 1000 PPM IDLH:
64-17-5 3300 PPM 10% LEL
TWA: 1900 MG/M3
TWA: 1000 PPM
(VACATED) TWA:
1000 PPM TWA: 1900 MG/M3
(VACATED) TWA:
1900 MG/M3
N-BUTYL ACETATE STEL: 200 PPM TWA: 150 PPM IDLH: 1700 PPM
123-86-4 TWA: 150 PPM TWA: 150 PPM
TWA: 710 MG/M3 TWA: 710 MG/M3
STEL: 200 PPM
(VACATED) TWA: STEL: 950 MG/M3
150 PPM
(VACATED) TWA:
710 MG/M3
(VACATED) STEL:
200 PPM
(VACATED) STEL:
950 MG/M3
N-BUTYL ALCOHOL TWA: 20 PPM TWA: 100 PPM IDLH: 1400 PPM
71-36-3 CEILING: 50 PPM
TWA:
300 MG/M3 CEILING:
(VACATED) S* 150 MG/M3
(VACATED) CEILING:
50 PPM
(VACATED) CEILING:
150 MG/M3
DIACETONE ALCOHOL TWA: 50 PPM TWA: 50 PPM IDLH: 1800 PPM
123-42-2 TWA: 50 PPM
TWA: 240 MG/M3 TWA: 240 MG/M3
(VACATED) TWA:
50 PPM
(VACATED) TWA:
240 MG/M3
ISOPROPYL ALCOHOL STEL: 400 PPM TWA: 400 PPM IDLH:
67-63-0 TWA: 200 PPM 2000 PPM 10% LEL
TWA: 980 MG/M3
TWA: 980 MG/M3
(VACATED) TWA: TWA: 400 PPM
400 PPM STEL: 500 PPM
STEL: 1225 MG/M3
(VACATED) TWA:
980 MG/M3
(VACATED) STEL:
500 PPM
(VACATED) STEL:
1225 MG/M3
N-PROPYL ACETATE STEL: 250 PPM TWA: 200 PPM IDLH: 1700 PPM
109-60-4 TWA: 200 PPM TWA: 200 PPM
TWA: 840 MG/M3 TWA: 840 MG/M3
STEL: 250 PPM
(VACATED) TWA: STEL: 1050 MG/M3
200 PPM
(VACATED) TWA:
840 MG/M3
(VACATED) STEL:
250 PPM
(VACATED) STEL:
1050 MG/M3
TRIPHENYL PHOSPHATE TWA: 3 MG/M3 TWA: 3 MG/M3 IDLH: 1000 MG/M3
115-86-6 TWA: 3 MG/M3
(VACATED) TWA:
3 MG/M3
IMMEDIATELY DANGEROUS TO LIFE OR HEALTH.
ACGIH TLV:
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS - THRESHOLD
LIMIT VALUE.
OSHA PEL:
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION - PERMISSIBLE EXPOSURE LIMITS.
NIOSH IDLH:
OTHER EXPOSURE GUIDELINES:
VACATED LIMITS REVOKED BY THE COURT OF APPEALS DECISION IN AFL-CIO V.
OSHA, 965 F.2D 962 (11TH CIR., 1992).
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
NONE REQUIRED UNDER NORMAL USAGE. IF SPLASHES ARE LIKELY TO OCCUR, WEAR:
CHEMICAL SPLASH GOGGLES.
SKIN AND BODY PROTECTION: CHEMICAL RESISTANT GLOVES
RESPIRATORY PROTECTION:
NONE REQUIRED UNDER NORMAL USAGE. IF EXPOSURE LIMITS ARE EXCEEDED OR
IRRITATION IS EXPERIENCED, NIOSH/MSHA APPROVED RESPIRATORY PROTECTION
SHOULD BE WORN.
HYGIENE MEASURES:
WHEN USING, DO NOT EAT, DRINK OR SMOKE. PROVIDE REGULAR CLEANING OF
EQUIPMENT, WORK AREA AND CLOTHING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE:
RED, BLUE, BLACK COLOR: THIN VISCOSITY
ODOR: SWEET, SOLVENT
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS / - METHOD
PH NO DATA AVAILABLE NONE KNOWN
MELTING POINT/RANGE NO DATA AVAILABLE NONE KNOWN
BOILING POINT/BOILING RANGE 76.667-125 DEG. C / NONE KNOWN
170-257 DEG. F
FLASH POINT 11.667 DEG. C / NONE KNOWN
53 DEG. F
EVAPORATION RATE <1 (BUAC = 1) BUAC = 1
FLAMMABILITY (SOLID, GAS) NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT 19.0
LOWER FLAMMABILITY LIMIT 1.40
VAPOR PRESSURE NO DATA AVAILABLE NONE KNOWN
VAPOR DENSITY >1 (AIR = 1) NONE KNOWN
SPECIFIC GRAVITY NO DATA AVAILABLE. NONE KNOWN
WATER SOLUBILITY NEGLIGIBLE NONE KNOWN
SOLUBILITY IN OTHER SOLVENTS NO DATA AVAILABLE NONE KNOWN
PARTITION COEFFICIENT NO DATA AVAILABLE NONE KNOWN
N-OCTANOL/WATER
AUTOIGNITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
DECOMPOSITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
VISCOSITY NO DATA AVAILABLE NONE KNOWN
FLAMMABLE PROPERTIES HIGHLY FLAMMABLE:
WILL BE EASILY
IGNITED BY HEAT,
SPARKS OR FLAMES.
EXPLOSIVE PROPERTIES NO DATA AVAILABLE
OXIDIZING PROPERTIES NO DATA AVAILABLE
OTHER INFORMATION:
VOC CONTENT (%) 8706 DK BLUE/STEEL
BLUE: 93.24%
8705 RED/STEEL RED:
92.46%
8749 BLACK: 87.21%
VOC (G/L) 8706 DK BLUE/STEEL
BLUE: 790 G/L
8705 RED/STEEL RED:
795 G/L
8749 BLACK: 753 G/L
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS. INCOMPATIBLE PRODUCTS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. STRONG ACIDS. STRONG REDUCING AGENTS. STRONG
ALKALIS.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE (CO). CARBON DIOXIDE (CO2). SOOT.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
INHALATION:
INHALATION OF VAPORS IN HIGH CONCENTRATION MAY CAUSE IRRITATION OF
RESPIRATORY SYSTEM. MAY CAUSE DROWSINESS AND DIZZINESS.
EYE CONTACT: IRRITATING TO EYES. CAUSES SERIOUS EYE DAMAGE.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED. INGESTION MAY CAUSE NAUSEA AND VOMITING.
CHEMICAL NAME LD50 ORAL LD50 DERMAL LC50 INHALATION
ETHANOL = 7060 MG/KG = 124.7 MG/L
(RAT) (RAT) 4 H
N-BUTYL ACETATE = 10768 MG/KG >17600 MG/KG = 391 PPM
(RAT) (RABBIT) (RAT) 4 H
N-BUTYL ALCOHOL = 790 MG/KG = 3400 MG/KG = 8000 PPM
(RAT) (RABBIT) (RAT) 4 H
DIACETONE ALCOHOL = 4 G/KG = 13500 MG/KG
(RAT) (RABBIT)
ISOPROPYL ALCOHOL = 4396 MG/KG 12800 MG/KG 72.6 MG/L
(RAT) (RAT) (RAT) 4 H
12870 MG/KG
(RABBIT)
N-PROPYL ACETATE = 9370 MG/KG >17760 MG/KG
(RAT) (RABBIT)
TRIPHENYL PHOSPHATE = 3500 MG/KG >7900 MG/KG
(RAT) (RABBIT)
MALACHITE GREEN OXALATE = 275 MG/KG
(RAT)
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND
LONG TERM EXPOSURE:
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE.
CARCINOGENICITY:
ETHANOL HAS BEEN SHOWN TO BE CARCINOGENIC IN LONG-TERM STUDIES ONLY WHEN
CONSUMED AND ABUSED AS AN ALCOHOLIC BEVERAGE. THE TABLE BELOW INDICATES
WHETHER EACH AGENCY HAS LISTED ANY INGREDIENT AS A CARCINOGEN.
CHEMICAL NAME ACGIH IARC NTP OSHA
ETHANOL A3 GROUP 1 KNOWN X
ISOPROPYL ALCOHOL GROUP 3 X
ACGIH: (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
A3 - ANIMAL CARCINOGEN
IARC: (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
GROUP 1: CARCINOGENIC TO HUMANS
GROUP 3: NOT CLASSIFIABLE AS TO ITS CARCINOGENICITY TO HUMANS
NTP: (NATIONAL TOXICITY PROGRAM)
KNOWN - KNOWN CARCINOGEN
OSHA: (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION)
X - PRESENT
REPRODUCTIVE TOXICITY: MAY DAMAGE FERTILITY OR THE UNBORN CHILD
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
CHRONIC TOXICITY:
AVOID REPEATED EXPOSURE. CONTAINS A KNOWN OR SUSPECTED REPRODUCTIVE TOXIN.
MAY CAUSE ADVERSE LIVER EFFECTS. ETHANOL HAS BEEN SHOWN TO BE A REPRODUCTIVE
TOXIN ONLY WHEN CONSUMED AS AN ALCOHOLIC BEVERAGE. ETHANOL HAS BEEN SHOWN
TO BE CARCINOGENIC IN LONG-TERM STUDIES ONLY WHEN CONSUMED AS ALCOHOLIC
BEVERAGE. MAY CAUSE ADVERSE EFFECTS ON THE BONE MARROW AND BLOOD-FORMING
SYSTEM.
TARGET ORGAN EFFECTS:
RESPIRATORY SYSTEM. EYES. SKIN CENTRAL NERVOUS SYSTEM (CNS).
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
NUMERICAL MEASURES OF TOXICITY - PRODUCT:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT:
LD50 ORAL: 2741 MG/KG; ACUTE TOXICITY ESTIMATE
LD50 DERMAL: 17753 MG/KG; ACUTE TOXICITY ESTIMATE
INHALATION:
DUST/MIST: 33.1 MG/L; ACUTE TOXICITY ESTIMATE
VAPOR: 133 3 MG/L; ACUTE TOXICITY ESTIMATE
| 12. ECOLOGICAL INFORMATION | |
THIS PRODUCT CONTAINS A CHEMICAL WHICH IS LISTED AS A SEVERE MARINE
POLLUTANT ACCORDING TO DOT.
ECOTOXICITY:
THE ENVIRONMENTAL IMPACT OF THIS PRODUCT HAS NOT BEEN FULLY INVESTIGATED.
CHEMICAL NAME TOXICITY TO ALGAE TOXICITY TO FISH
ETHANOL LC50 96 H:
64-17-5 12.0 - 16.0 ML/L
STATIC (ONCORHYNCHUS
MYKISS)
LC50 96 H:
>100 MG/L STATIC
(PIMEPHALES PROMELAS)
LC50 96 H:
13400 - 15100 MG/L
FLOW-THROUGH
(PIMEPHALES PROMELAS)
N-BUTYL ACETATE EC50 72 H: LC50 96 H:
123-86-4 = 674.7 MG/L 17 - 19 MG/L
(DESMODESMUS FLOW-THROUGH (PIMEPHALES
SUBSPICATUS) PROMELAS)
LC50 96 H:
= 100 MG/L STATIC
(LEPOMIS MACROCHIRUS)
LC50 96 H:
= 62 MG/L STATIC
(LEUCISCUS IDUS)
N-BUTYL ALCOHOL EC50 96 H: LC50 96 H:
71-36-3 >500 MG/L 1730 - 1910 MG/L STATIC
(DESMODESMUS (PIMEPHALES PROMELAS)
SUBSPICATUS)
LC50 96 H:
EC50 72 H: 1740 MG/L FLOW-THROUGH
>500 MG/L (PIMEPHALES PROMELAS)
(DESMODESMUS
SUBSPICATUS) LC50 96H:
100000-500000 (MICRO)G/L
STATIC (LEPOMIS
MACROCHIRUS)
LC50 96 H:
= 1910000 (MICRO)G/L
STATIC (PIMEPHALES
PROMELAS)
DIACETONE ALCOHOL LC50 96 H:
123-42-2 = 420 MG/L STATIC
(LEPOMIS MACROCHIRUS)
LC50 96 H:
= 420 MG/L
(LEPOMIS MACROCHIRUS)
ISOPROPYL ALCOHOL EC50 96 H: LC50 96 H:
67-63-0 >1000 MG/L = 11130 MG/L STATIC
(DESMODESMUS (PIMEPHALES PROMELAS)
SUBSPICATUS)
LC50 96 H:
EC50 72 H: = 9640 MG/L FLOW-THROUGH
>1000 MG/L (PIMEPHALES PROMELAS)
(DESMODESMUS
SUBSPICATUS) LC50 96 H:
>1400000 (MICRO)G/L
(LEPOMIS MACROCHIRUS)
N-PROPYL ACETATE LC50 96 H:
109-60-4 56-64 MG/L FLOW-THROUGH
(PIMEPHALES PROMELAS)
LC50 96 H:
56-64 MG/L STATIC
(PIMEPHALES PROMELAS)
TRIPHENYL PHOSPHATE EC50 96 H: LC50 96 H:
115-86-6 0.6 - 4 MG/L STATIC 0.28 - 0.5 MG/L STATIC
(PSEUDOKIRCHNERIELLA (ONCORHYNCHUS MYKISS)
SUBCAPITATA)
LC50 96 H:
0.81 - 0.94 MG/L
FLOW-THROUGH
(PIMEPHALES PROMELAS)
LC50 96 H:
0.53 - 0.8 MG/L STATIC
(PIMEPHALES PROMELAS)
LC50 96 H:
0.47 - 1.04 MG/L STATIC
(LEPOMIS MACROCHIRUS)
LC50 96 H:
= 1.2 MG/L STATIC
(ORYZIAS LATIPES)
CHEMICAL NAME TOXICITY TO MICROORGANISMS DAPHNIA MAGNA
(WATER FLEA)
ETHANOL EC50: = 34634 MG/L 30 MIN LC50 48 H:
EC50: = 35470 MG/L 5 MIN 9268 - 14221 MG/L
(DAPHNIA MAGNA)
EC50 24 H:
= 10800 MG/L
(DAPHNIA MAGNA)
EC50 48 H:
= 2 MG/L STATIC
(DAPHNIA MAGNA)
N-BUTYL ACETATE EC50: = 70.0 MG/L 5 MIN EC50 24 H:
EC50: = 82.2 MG/L 15 MIN = 72.8 MG/L
EC50: = 959 MG/L 18 H (DAPHNIA MAGNA)
EC50: = 98.9 MG/L 30 MIN
N-BUTYL ALCOHOL EC50: = 2041.4 MG/L 5 MIN EC50 48 H:
EC50: = 2186 MG/L 30 MIN = 1983 MG/L
EC50: = 3980 MG/L 24 H (DAPHNIA MAGNA)
EC50: = 4400 MG/L 17 H
EC50 48 H:
1897 - 2072 MG/L STATIC
(DAPHNIA MAGNA)
DIACETONE ALCOHOL EC50 24 H:
= 8750 MG/L
(DAPHNIA MAGNA)
ISOPROPYL ALCOHOL EC50 48 H:
= 13299 MG/L
(DAPHNIA MAGNA)
N-PROPYL ACETATE EC50 24 H:
= 318 MG/L
(DAPHNIA MAGNA)
TRIPHENYL EC50 48 H:
PHOSPHATE 0.86 - 1.2 MG/L
(DAPHNIA MAGNA)
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION:
CHEMICAL NAME LOG POW
ETHANOL -0.32
N-BUTYL ACETATE 1.81
N-BUTYL ALCOHOL 0.785
DIACETONE ALCOHOL 1.03
ISOPROPYL ALCOHOL 0.05
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHODS: DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
CONTAMINATED PACKAGING: DO NOT RE-USE EMPTY CONTAINERS.
US EPA WASTE NUMBER:
D001
U031
CHEMICAL NAME RCRA RCRA - BASIS RCRA - D RCRA - U
FOR LISTING SERIES WASTES SERIES WASTES
N-BUTYL ALCOHOL INCLUDED IN U031
71-36-3 WASTE STREAM:
F039
THIS PRODUCT CONTAINS ONE OR MORE SUBSTANCES THAT ARE LISTED WITH THE
STATE OF CALIFORNIA AS A HAZARDOUS WASTE.
CHEMICAL NAME CALIFORNIA HAZARDOUS WASTE
ETHANOL TOXIC
IGNITABLE
N-BUTYL ACETATE TOXIC
N-BUTYL ALCOHOL TOXIC
ISOPROPYL ALCOHOL TOXIC
IGNITABLE
NITROCELLULOSE IGNITABLE
REACTIVE
N-PROPYL ACETATE TOXIC
IGNITABLE
XANTHYLIUM,9-(2-CARBOXYPHENYL)- TOXIC
3,6-BIS(DIETHYL AMINO)-, CORROSIVE
HYDROGENBIS[3-[(4,5-DIHYDRO-3-METHYL-5 IGNITABLE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
REPORTABLE QUANTITY (RQ):
N-BUTYL ACETATE:
RQ KG: 5127.74
1-BUTANOL:
RQ KG: 13791.68
MARINE POLLUTANT:
THIS PRODUCT CONTAINS A CHEMICAL WHICH IS LISTED AS A SEVERE MARINE
POLLUTANT ACCORDING TO DOT.
DESCRIPTION: UN1263, PAINT, 3, II, RQ
EMERGENCY RESPONSE GUIDE NUMBER: 128
TDG:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
MARINE POLLUTANT:
THIS PRODUCT CONTAINS A CHEMICAL WHICH IS LISTED AS A SEVERE MARINE
POLLUTANT ACCORDING TO TDG.
DESCRIPTION: UN1263, PAINT, 3, II
MEX:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
DESCRIPTION: UN1263, PAINT, 3, II
ICAO:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
DESCRIPTION: UN1263, PAINT, 3, II
IATA:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
ERG CODE: 3L
DESCRIPTION: UN1263, PAINT, 3, II
IMDG/IMO:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
EMS NO.: F-E, S-E
MARINE POLLUTANT:
THIS PRODUCT CONTAINS A CHEMICAL WHICH IS LISTED AS A SEVERE MARINE
POLLUTANT ACCORDING TO IMDG/IMO
DESCRIPTION: UN1263, PAINT, 3, II, (11.667 DEG. C C.C.)
RID:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
CLASSIFICATION CODE: F1
DESCRIPTION: UN1263, PAINT, 3, II
ADR:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
CLASSIFICATION CODE: F1
TUNNEL RESTRICTION CODE: (D/E)
DESCRIPTION: UN1263, PAINT, 3, II, (D/E)
ADR/RID-LABELS: 3
ADN:
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
CLASSIFICATION CODE: F1
SPECIAL PROVISIONS: 163, 640C, 650
DESCRIPTION: UN1263, PAINT, 3, II
LIMITED QUANTITY: 5 L
VENTILATION: VE01
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: COMPLIES
LEGEND:
TSCA - UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL - CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
U.S. FEDERAL REGULATIONS:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT CONTAINS A CHEMICAL OR CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372:
CHEMICAL NAME CAS-NO WEIGHT % SARA 313 - THRESHOLD VALUES %
N-BUTYL ALCOHOL 71-36-3 16.4592 1.0
ISOPROPYL ALCOHOL 67-63-0 3.9715 1.0
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: YES
FIRE HAZARD: YES
SUDDEN RELEASE OF PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
CLEAN WATER ACT:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES WHICH ARE REGULATED
POLLUTANTS PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR
122.42):
CHEMICAL NAME CWA - CWA - CWA - CWA -
REPORTABLE TOXIC PRIORITY HAZARDOUS
QUANTITIES POLLUTANTS POLLUTANTS SUBSTANCES
N-BUTYL ACETATE 5000 LB X
CERCLA:
THIS MATERIAL, AS SUPPLIED, CONTAINS ONE OR MORE SUBSTANCES REGULATED AS
A HAZARDOUS SUBSTANCE UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302):
CHEMICAL NAME HAZARDOUS EXTREMELY HAZARDOUS RQ
SUBSTANCES RQS SUBSTANCES RQS
N-BUTYL ACETATE 5000 LB RQ: 5000 LB FINAL RQ
RQ: 2270 KG FINAL RQ
N-BUTYL ALCOHOL 5000 LB RQ: 5000 LB FINAL RQ
RQ: 2270 KG FINAL RQ
U.S. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS THE FOLLOWING PROPOSITION 65 CHEMICALS:
ETHYL ALCOHOL IS ONLY CONSIDERED A PROPOSITION 65 DEVELOPMENTAL HAZARD WHEN
IT IS INGESTED AS AN ALCOHOLIC BEVERAGE.
CHEMICAL NAME CAS-NO CALIFORNIA PROP. 65
ETHANOL 64-17-5 DEVELOPMENTAL
MICHLER'S KETONE 90-94-8 CARCINOGEN
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
"X" DESIGNATES THAT THE INGREDIENTS ARE LISTED ON THE STATE RIGHT TO
KNOW LIST.
CHEMICAL NAME NEW MASSACHUSETTS PENNSYLVANIA ILLINOIS RHODE
JERSEY ISLAND
ETHANOL X X X
N-BUTYL ACETATE X X X X
N-BUTYL ALCOHOL X X X X
DIACETONE ALCOHOL X X X X
ISOPROPYL ALCOHOL X X X X
NITROCELLULOSE X X X X
N-PROPYL ACETATE X X X X
TRIPHENYL PHOSPHATE X X X X
U.S. EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: NOT APPLICABLE
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARD 2
FLAMMABILITY 3
INSTABILITY 0
PHYSICAL AND CHEMICAL HAZARDS
HMIS:
HEALTH HAZARD 2
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
PREPARED BY:
PRODUCT STEWARDSHIP
23 BRITISH AMERICAN BLVD.
LATHAM, NY 12110
1-800-572-6501
ISSUING DATE: 09-APR-2014
REVISION DATE: 09-APR-2014
REVISION NOTE: INITIAL RELEASE.
GENERAL DISCLAIMER:
THE INFORMATION PROVIDED ON THIS SDS IS CORRECT TO THE BEST OF OUR
KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION. THE
INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT TO BE
CONSIDERED AS A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION RELATES
ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH
MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS,
UNLESS SPECIFIED IN THE TEXT.
WPS-ITW-025 - DYKEM TRANSPARENT STAIN BULK - STEEL BLUE, STEEL RED AND BLACK