| Common Name: | FOOD GRADE SILICONE 03041, 03042 |
| Manufacturer: | CRC |
| SDS Revision Date: | 4/1/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 3APN3, 5VE47 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: FOOD GRADE SILICONE
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: 03041, 03042
RECOMMENDED USE: GENERAL PURPOSE SILICONE-BASED LUBRICANT
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY NAME: CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-HOUR EMERGENCY (CHEMTREC):
800-424-9300 (US)
703-527-3887 (INTERNATIONAL)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE LIQUIDS: CATEGORY 2
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
REPRODUCTIVE TOXICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 2
ASPIRATION HAZARD: CATEGORY 1
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, ACUTE HAZARD: CATEGORY 3
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 3
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY BE FATAL IF SWALLOWED AND ENTERS
AIRWAYS. CAUSES SKIN IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. MAY CAUSE DAMAGE TO
ORGANS (CENTRAL NERVOUS SYSTEM, UPPER RESPIRATORY TRACT, EYES) THROUGH
PROLONGED OR REPEATED EXPOSURE. HARMFUL TO AQUATIC LIFE. HARMFUL TO AQUATIC
LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. KEEP CONTAINER TIGHTLY CLOSED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT. USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. USE ONLY WITH
ADEQUATE VENTILATION; MAINTAIN VENTILATION DURING USE AND UNTIL ALL VAPORS
ARE GONE. OPEN DOORS AND WINDOWS OR USE OTHER MEANS TO ENSURE A FRESH AIR
SUPPLY DURING USE AND WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY
SYMPTOMS LISTED ON THIS LABEL, INCREASE VENTILATION OR LEAVE THE AREA.
DO NOT BREATHE MIST OR VAPOR. WASH THOROUGHLY AFTER HANDLING. WEAR
PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION. AVOID
RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE
REUSE.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IN CASE OF FIRE:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
STORAGE:
KEEP COOL. STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC):
STATIC ACCUMULATING FLAMMABLE LIQUID CAN BECOME ELECTROSTATICALLY CHARGED
EVEN IN BONDED AND GROUNDED EQUIPMENT. SPARKS MAY IGNITE LIQUID AND VAPOR.
MAY CAUSE FLASH FIRE OR EXPLOSION.
SUPPLEMENTAL INFORMATION:
93.12% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN ACUTE HAZARDS TO
THE AQUATIC ENVIRONMENT.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
NAPHTHA (PETROLEUM), 64742-49-0 70 - 80
HYDROTREATED LIGHT
2-METHYLPENTANE 107-83-5 10 - 20
N-HEXANE 110-54-3 3 - 5
POLYDIMETHYLSILOXANE 63148-62-9 3 - 5
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
RINSE SKIN WITH WATER/SHOWER. IF SKIN IRRITATION OCCURS: GET MEDICAL
ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. GET MEDICAL ATTENTION IF
IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. RINSE MOUTH. DO NOT
INDUCE VOMITING. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH CONTENT
DOESN'T GET INTO THE LUNGS. ASPIRATION MAY CAUSE PULMONARY EDEMA AND
PNEUMONITIS.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION. SYMPTOMS OF
OVEREXPOSURE MAY BE HEADACHE, DIZZINESS, TIREDNESS, NAUSEA AND VOMITING.
MAY CAUSE REDNESS AND PAIN. PROLONGED EXPOSURE MAY CAUSE CHRONIC EFFECTS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION: TAKE OFF ALL CONTAMINATED CLOTHING IMMEDIATELY.
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF
THE MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. CARBON DIOXIDE (CO2). DRY CHEMICAL POWDER, CARBON DIOXIDE,
SAND OR EARTH MAY BE USED FOR SMALL FIRES ONLY.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS MAY TRAVEL CONSIDERABLE
DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. THIS PRODUCT IS A POOR
CONDUCTOR OF ELECTRICITY AND CAN BECOME ELECTROSTATICALLY CHARGED. IF
SUFFICIENT CHARGE IS ACCUMULATED, IGNITION OF FLAMMABLE MIXTURES CAN OCCUR.
TO REDUCE POTENTIAL FOR STATIC DISCHARGE, USE PROPER BONDING AND GROUNDING
PROCEDURES. THIS LIQUID MAY ACCUMULATE STATIC ELECTRICITY WHEN FILLING
PROPERLY GROUNDED CONTAINERS. STATIC ELECTRICITY ACCUMULATION MAY BE
SIGNIFICANTLY INCREASED BY THE PRESENCE OF SMALL QUANTITIES OF WATER OR
OTHER CONTAMINANTS. MATERIAL WILL FLOAT AND MAY IGNITE ON SURFACE OF WATER.
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES. MOVE CONTAINERS FROM
FIRE AREA IF YOU CAN DO SO WITHOUT RISK.
GENERAL FIRE HAZARDS: HIGHLY FLAMMABLE LIQUID AND VAPOR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. ELIMINATE ALL IGNITION SOURCES (NO
SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE AREA). WEAR APPROPRIATE
PROTECTIVE EQUIPMENT AND CLOTHING DURING CLEAN-UP. DO NOT TOUCH DAMAGED
CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE
CLOTHING. DO NOT BREATHE MIST OR VAPOR. VENTILATE CLOSED SPACES BEFORE
ENTERING THEM. USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL
CONTAMINATION. TRANSFER BY MECHANICAL MEANS SUCH AS VACUUM TRUCK TO A
SALVAGE TANK OR OTHER SUITABLE CONTAINER FOR RECOVERY OR SAFE DISPOSAL.
LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED. FOR PERSONAL PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. USE
ONLY NON-SPARKING TOOLS. KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.)
AWAY FROM SPILLED MATERIAL.
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE THE SPILLED
MATERIAL, WHERE THIS IS POSSIBLE. COVER WITH PLASTIC SHEET TO PREVENT
SPREADING. USE A NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND OR EARTH
TO SOAK UP THE PRODUCT AND PLACE INTO A CONTAINER FOR LATER DISPOSAL.
PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS OR CONFINED AREAS. FOLLOWING
PRODUCT RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
ABSORB WITH EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND TRANSFER TO
CONTAINERS FOR LATER DISPOSAL. WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH,
FLEECE). CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. CONTACT LOCAL AUTHORITIES IN CASE OF
SPILLAGE TO DRAIN/AQUATIC ENVIRONMENT. PREVENT FURTHER LEAKAGE OR SPILLAGE
IF SAFE TO DO SO. DO NOT CONTAMINATE WATER. AVOID DISCHARGE INTO DRAINS,
WATER COURSES OR ONTO THE GROUND. USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. VAPORS MAY FORM EXPLOSIVE
MIXTURES WITH AIR. DO NOT HANDLE, STORE OR OPEN NEAR AN OPEN FLAME, SOURCES
OF HEAT OR SOURCES OF IGNITION. PROTECT MATERIAL FROM DIRECT SUNLIGHT.
MINIMIZE FIRE RISKS FROM FLAMMABLE AND COMBUSTIBLE MATERIALS (INCLUDING
COMBUSTIBLE DUST AND STATIC ACCUMULATING LIQUIDS) OR DANGEROUS REACTIONS
WITH INCOMPATIBLE MATERIALS. HANDLING OPERATIONS THAT CAN PROMOTE
ACCUMULATION OF STATIC CHARGES INCLUDE BUT ARE NOT LIMITED TO:
MIXING, FILTERING, PUMPING AT HIGH FLOW RATES, SPLASH FILLING, CREATING
MISTS OR SPRAYS, TANK AND CONTAINER FILLING, TANK CLEANING, SAMPLING,
GAUGING, SWITCH LOADING, VACUUM TRUCK OPERATIONS. TAKE PRECAUTIONARY
MEASURES AGAINST STATIC DISCHARGES. ALL EQUIPMENT USED WHEN HANDLING THE
PRODUCT MUST BE GROUNDED. USE NON-SPARKING TOOLS AND EXPLOSION-PROOF
EQUIPMENT. DO NOT BREATHE MIST OR VAPOR. AVOID CONTACT WITH EYES, SKIN, AND
CLOTHING. AVOID CONTACT DURING PREGNANCY/WHILE NURSING. WHEN USING, DO NOT
EAT, DRINK OR SMOKE. PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT. WASH HANDS THOROUGHLY AFTER HANDLING.
OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES. AVOID RELEASE TO THE
ENVIRONMENT. DO NOT EMPTY INTO DRAINS.
FOR ADDITIONAL INFORMATION ON EQUIPMENT BONDING AND GROUNDING, REFER TO THE
THE AMERICAN PETROLEUM INSTITUTE (API) RECOMMENDED PRACTICE 2003,
"PROTECTION AGAINST IGNITIONS ARISING OUT OF STATIC, LIGHTNING, AND STRAY
CURRENTS" OR NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) 77, "RECOMMENDED
PRACTICE ON STATIC ELECTRICITY" OR NATIONAL FIRE PROTECTION ASSOCIATION
(NFPA) 70, "NATIONAL ELECTRICAL CODE".
FOR PRODUCT USAGE INSTRUCTIONS, PLEASE SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. PREVENT ELECTROSTATIC CHARGE
BUILD-UP BY USING COMMON BONDING AND GROUNDING TECHNIQUES. AVOID SPARK
PROMOTERS. ELIMINATE SOURCES OF IGNITION. GROUND/BOND CONTAINER AND
EQUIPMENT. THESE ALONE MAY BE INSUFFICIENT TO REMOVE STATIC ELECTRICITY.
STORE IN ORIGINAL TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY PLACE OUT
OF DIRECT SUNLIGHT. STORE IN A WELL-VENTILATED PLACE. STORE AWAY FROM
INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS). KEEP IN AN AREA
EQUIPPED WITH SPRINKLERS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
N-HEXANE PEL 1800 MG/M3
(CAS 110-54-3) 500 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
2-METHYLPENTANE STEL 1000 PPM
(CAS 107-83-5) TWA 500 PPM
N-HEXANE TWA 50 PPM
(CAS 110-54-3)
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
2-METHYLPENTANE CEILING 1800 MG/M3
(CAS 107-83-5) 510 PPM
TWA 350 MG/M3
100 PPM
N-HEXANE TWA 180 MG/M3
(CAS 110-54-3) 50 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
N-HEXANE 0.4 MG/L 2,5-HEXANEDION, URINE *
(CAS 110-54-3) WITHOUT HYDROLYSIS
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US - CALIFORNIA OELS SKIN DESIGNATION
N-HEXANE (CAS 110-54-3) CAN BE ABSORBED THROUGH THE SKIN.
US ACGIH THRESHOLD LIMIT VALUES SKIN DESIGNATION
N-HEXANE (CAS 110-54-3) CAN BE ABSORBED THROUGH THE SKIN.
APPROPRIATE ENGINEERING CONTROLS:
EXPLOSION-PROOF GENERAL AND LOCAL EXHAUST VENTILATION. GOOD GENERAL
VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION
RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO
MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE
LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE
LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE AVAILABLE WHEN
HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS:
NITRILE. POLYVINYL CHLORIDE (PVC). VITON(R*).
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED.
RESPIRATORY PROTECTION:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA). AIR
MONITORING IS NEEDED TO DETERMINE ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING, DO NOT EAT, DRINK OR SMOKE. ALWAYS OBSERVE GOOD PERSONAL
HYGIENE MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE
EATING, DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND
PROTECTIVE EQUIPMENT TO REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: LIQUID.
COLOR: CLEAR. WATER-WHITE.
ODOR: MILD SOLVENT.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: -244.7 DEG. F (-153.7 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE: 118.4 DEG. F (48 DEG. C) ESTIMATED
FLASH POINT: <0 DEG. F (<-17.8 DEG. C) TAG CLOSED CUP
EVAPORATION RATE: FAST.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 1% ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 8% ESTIMATED
VAPOR PRESSURE: 294.2 HPA ESTIMATED
VAPOR DENSITY: >1 (AIR = 1)
RELATIVE DENSITY: 0.66
SOLUBILITY (WATER): NEGLIGIBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 437 DEG. F (225 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY (KINEMATIC): NOT AVAILABLE.
PERCENT VOLATILE: 97% ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. CONTACT WITH
INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS. CHLORINE.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
INHALATION:
MAY CAUSE DAMAGE TO ORGANS BY INHALATION. SYMPTOMS OF OVEREXPOSURE MAY BE
HEADACHE, DIZZINESS, TIREDNESS, NAUSEA AND VOMITING.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
MAY CAUSE REDNESS AND PAIN. SYMPTOMS OF OVEREXPOSURE MAY BE HEADACHE,
DIZZINESS, TIREDNESS, NAUSEA AND VOMITING.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. NARCOTIC EFFECTS.
PRODUCT SPECIES TEST RESULTS
FOOD GRADE SILICONE:
ACUTE:
DERMAL:
LD50 RABBIT 2486.1321 MG/KG ESTIMATED
INHALATION:
LC50 RAT 608.9773 MG/L, 4 HOURS ESTIMATED
ORAL:
LD50 RAT 14860.3066 MG/KG ESTIMATED
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION:
DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
RESPIRATORY SENSITIZATION: NOT AVAILABLE.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, ACGIH, NTP, OR
OSHA.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS OR DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, UPPER RESPIRATORY
TRACT, EYES) THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CHRONIC EFFECTS:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
OVEREXPOSURE TO N-HEXANE MAY CAUSE PROGRESSIVE AND POTENTIALLY IRREVERSIBLE
DAMAGE TO THE PERIPHERAL NERVOUS SYSTEM, PARTICULARLY IN THE ARMS AND LEGS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS. ACCUMULATION IN AQUATIC
ORGANISMS IS EXPECTED.
PRODUCT SPECIES TEST RESULTS
FOOD GRADE SILICONE:
AQUATIC:
FISH LC50 FISH 361.0246 MG/L, 96 HOURS ESTIMATED
COMPONENTS SPECIES TEST RESULTS
N-HEXANE (CAS 110-54-3):
AQUATIC:
FISH LC50 FATHEAD MINNOW 2.101 - 2.981 MG/L, 96 HOURS
(PIMEPHALES PROMELAS)
POLYDIMETHYLSILOXANE (CAS 63148-62-9):
AQUATIC:
FISH LC50 CHANNEL CATFISH 2.36 - 4.15 MG/L, 96 HOURS
(ICTALURUS PUNCTATUS)
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
2-METHYLPENTANE: 3.74
N-HEXANE: 3.9
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL OF WASTE FROM RESIDUES / UNUSED PRODUCTS:
IF DISCARDED, THIS PRODUCT IS CONSIDERED A RCRA IGNITABLE WASTE, D001.
CONSULT AUTHORITIES BEFORE DISPOSAL. DO NOT ALLOW THIS MATERIAL TO DRAIN
INTO SEWERS/WATER SUPPLIES. DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES
WITH CHEMICAL OR USED CONTAINER. DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS.
HAZARDOUS WASTE CODE:
D001: WASTE FLAMMABLE MATERIAL WITH A FLASH POINT <140 F
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1208
UN PROPER SHIPPING NAME: HEXANE MIXTURE
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK:
LABEL(S): 3
PACKING GROUP: II
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: IB2, T4, TP1
PACKAGING EXCEPTIONS: 150
PACKAGING NON BULK: 202
PACKAGING BULK: 242
IATA:
UN NUMBER: UN1208
UN PROPER SHIPPING NAME: HEXANE MIXTURE
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK:
PACKING GROUP: II
ENVIRONMENTAL HAZARDS: NO.
ERG CODE: 3H
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED.
CARGO AIRCRAFT ONLY: ALLOWED.
IMDG:
UN NUMBER: UN1208
UN PROPER SHIPPING NAME: HEXANE MIXTURE
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK:
PACKING GROUP: II
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO.
EMS: F-E, S-D
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
ALL COMPONENTS ARE ON THE U.S. EPA TSCA INVENTORY LIST.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL LISTED SUBSTANCE
N-HEXANE (CAS 110-54-3)
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
N-HEXANE (CAS 110-54-3)
CERCLA HAZARDOUS SUBSTANCES REPORTABLE QUANTITY
N-HEXANE (CAS 110-54-3) 5000 LBS
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS
RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
N-HEXANE (CAS 110-54-3)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SECTION 311/312 HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
US STATE REGULATIONS:
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
2-METHYLPENTANE (CAS 107-83-5)
N-HEXANE (CAS 110-54-3)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
2-METHYLPENTANE (CAS 107-83-5)
N-HEXANE (CAS 110-54-3)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
2-METHYLPENTANE (CAS 107-83-5)
N-HEXANE (CAS 110-54-3)
US. RHODE ISLAND RTK:
N-HEXANE (CAS 110-54-3)
US. CALIFORNIA PROPOSITION 65:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65):
THIS MATERIAL IS NOT KNOWN TO CONTAIN ANY CHEMICALS CURRENTLY LISTED AS
CARCINOGENS OR REPRODUCTIVE TOXINS.
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): 97%
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS:
THIS PRODUCT IS NOT FOR RETAIL SALE. IT IS FOR USE IN THE MANUFACTURING
PROCESS ONLY.
VOC CONTENT (CA): 97%
VOC CONTENT (OTC): 97%
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL YES
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING NO
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW NO
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS YES
AND CHEMICAL SUBSTANCES (PICCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 04-01-2014
PREPARED BY: ALLISON CHO
VERSION #: 01
FURTHER INFORMATION: CRC # 521A/C
HMIS(R*) RATINGS:
HEALTH 2*
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC INDUSTRIES' KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY
CRC TO BE ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND
DIRECTIONS ON THE LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION
CONTAINED ON THIS (M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY
PROFESSIONAL, OR CRC INDUSTRIES.
MATERIAL NAME: FOOD GRADE SILICONE
1321
SDS US