| Common Name: | AS5400 SYSTEM SAFETY YELLOW, AS5444402 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 9/3/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 2FP54 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
DATE PRINTED: 9/3/2014
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: AS5400 SYSTEM SAFETY YELLOW
PRODUCT IDENTIFIER: AS5444402
PRODUCT USE/CLASS: ANTI-SLIP/EPOXY FLOOR COATING
REVISION DATE: 9/3/2014
SUPERCEDES DATE: NEW SDS
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
EMERGENCY OVERVIEW:
HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION. FLAMMABLE LIQUID AND VAPOR.
CAUSES NOSE AND THROAT IRRITATION. HARMFUL IF INHALED. MAY AFFECT THE BRAIN
OR NERVOUS SYSTEM CAUSING DIZZINESS HEADACHE OR NAUSEA. VAPOR HARMFUL.
CAUSES EYE, SKIN, NOSE, AND THROAT IRRITATION. MAY CAUSE EYE, SKIN, OR
RESPIRATORY TRACT IRRITATION. KEEP OUT OF REACH OF CHILDREN. HARMFUL IF
INHALED. USE VENTILATION NECESSARY TO KEEP EXPOSURES BELOW RECOMMENDED
EXPOSURE LIMITS, IF ANY.
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
EXCLAMATION MARK
FLAME
HEALTH HAZARD
SIGNAL WORD: DANGER
GHS HAZARD STATEMENTS:
FLAMMABLE LIQUID, CATEGORY 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
ACUTE TOXICITY, ORAL, CATEGORY 5:
H303: MAY BE HARMFUL IF SWALLOWED.
ACUTE TOXICITY, DERMAL, CATEGORY 5:
H313: MAY BE HARMFUL IN CONTACT WITH SKIN.
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRITATION, CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
ACUTE TOXICITY, INHALATION, CATEGORY 4:
H332: HARMFUL IF INHALED.
STOT, SINGLE EXPOSURE, CATEGORY 3, RTI:
H335: MAY CAUSE RESPIRATORY IRRITATION.
STOT, SINGLE EXPOSURE, CATEGORY 3, NE:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
ORGANIC PEROXIDE, CATEGORIES C, D:
H242: HEATING MAY CAUSE A FIRE.
ASPIRATION HAZARD, CATEGORY 2:
H305: MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS.
EYE IRRITATION, CATEGORY 2B:
H320: CAUSES EYE IRRITATION.
GHS PRECAUTIONARY STATEMENTS:
P102: KEEP OUT OF REACH OF CHILDREN.
P103: READ LABEL BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P234: KEEP ONLY IN ORIGINAL CONTAINER.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P262: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
P264: WASH ... THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P285: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P351: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
P374: FIGHT FIRE WITH NORMAL PRECAUTIONS FROM A REASONABLE DISTANCE.
P402: STORE IN A DRY PLACE.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/.../ EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P370+P378:
IN CASE OF FIRE: USE ... FOR EXTINCTION.
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P501: DISPOSE OF CONTENTS/CONTAINER TO ...
P321: SPECIFIC TREATMENT (SEE ... ON THIS LABEL).
P352: WASH WITH PLENTY OF SOAP AND WATER.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P304+P340:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P405: STORE LOCKED UP.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P220: KEEP/STORE AWAY FROM CLOTHING/.../COMBUSTIBLE MATERIALS.
P410: PROTECT FROM SUNLIGHT.
P420: STORE AWAY FROM OTHER MATERIALS.
P411+P235:
STORE AT TEMPERATURES NOT EXCEEDING ... DEG. C/... DEG. F. KEEP COOL.
P302+P350:
IF ON SKIN: GENTLY WASH WITH PLENTY OF SOAP AND WATER.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
CRYSTALLINE SILICA 14808-60-7 10-25 GHS07 H302
XYLENE 1330-20-7 10-25 GHS02 H226
ALUMINUM OXIDE 1344-28-1 10-25
ETHYLBENZENE 100-41-4 2.5-10 GHS02-GHS07 H225-332
PROPYLENE GLYCOL 107-98-2 1.0-2.5 GHS02-GHS06 H226-310
MONOMETHYL ETHER
CARBON BLACK 1333-86-4 0.1-1.0 GHS02 H251
TITANIUM DIOXIDE 13463-67-7 0.1-1.0
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"16. OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN
ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION. IF SWALLOWED, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND, WATER
FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME. VAPORS CAN
TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. VAPORS MAY FORM EXPLOSIVE
MIXTURES WITH AIR. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILDUP OF
STEAM. KEEP CONTAINERS TIGHTLY CLOSED.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP AND
POSSIBLE AUTOIGNITION OR EXPLOSION. EVACUATE AREA AND FIGHT FIRE FROM A
SAFE DISTANCE. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
CONTAINERS MAY EXPLODE WHEN HEATED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. ELIMINATE ALL IGNITION SOURCES; USE EXPLOSION-PROOF
EQUIPMENT. PLACE MATERIAL IN A CONTAINER AND DISPOSE OF ACCORDING TO
LOCAL, PROVINCIAL, STATE AND FEDERAL REGULATIONS. REMOVE ALL SOURCES OF
IGNITION, VENTILATE AREA AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING
TOOLS. DISPOSE OF ACCORDING TO LOCAL, STATE (PROVINCIAL) AND FEDERAL
REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS. VENTILATE AREA, ISOLATE
SPILLED MATERIAL, AND REMOVE WITH INERT ABSORBENT. DISPOSE OF CONTAMINATED
ABSORBENT, CONTAINER, AND UNUSED CONTENTS IN ACCORDANCE WITH LOCAL, STATE,
AND FEDERAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. USE ONLY WITH
ADEQUATE VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER
CONTAINER IS EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. KEEP AWAY FROM HEAT, SPARKS, FLAME AND SOURCES OF
IGNITION. KEEP CONTAINER CLOSED WHEN NOT IN USE. PRODUCT SHOULD BE STORED
IN TIGHTLY SEALED CONTAINERS AND PROTECTED FROM HEAT, MOISTURE, AND FOREIGN
MATERIALS. STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE. AVOID EXCESS HEAT. DO NOT STORE ABOVE 120 DEG. F.
STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF
NFPA CLASS II COMBUSTIBLE LIQUIDS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
CRYSTALLINE SILICA 14808-60-7 20.0
XYLENE 1330-20-7 20.0
ALUMINUM OXIDE 1344-28-1 15.0
ETHYLBENZENE 100-41-4 5.0
PROPYLENE GLYCOL MONOMETHYL ETHER 107-98-2 5.0
CARBON BLACK 1333-86-4 1.0
TITANIUM DIOXIDE 13463-67-7 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
CRYSTALLINE SILICA 0.025 MG/M3 N.E. 0.1 MG/M3 N.E.
[RESPIRABLE [RESPIRABLE
DUST] DUST]
XYLENE 100 PPM 150 PPM 100 PPM N.E.
ALUMINUM OXIDE 1 MG/M3 N.E. 5 MG/M3 N.E.
[RESPIRABLE] [RESPIRABLE]
ETHYLBENZENE 20 PPM 125 PPM 100 PPM N.E.
PROPYLENE GLYCOL 100 PPM 150 PPM N.E. N.E.
MONOMETHYL ETHER
CARBON BLACK 3 MG/M3 N.E. 3.5 MG/M3 N.E.
(INHALABLE
DUST)
TITANIUM DIOXIDE 10 MG/M3 N.E. 15 MG/M3 N.E.
[TOTAL DUST]
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH AN
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED
EXPOSURE LIMITS.
PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE
PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR IN ANY OTHER
CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION. USE GLOVES TO PREVENT PROLONGED SKIN CONTACT.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION. REFER TO
SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE REGARDING
TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
PHYSICAL STATE: LIQUID
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.574
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: NEGLIGIBLE
PARTITION COEFFICIENT, N-OCTANOL/WATER: NO INFORMATION
DECOMPOSITION TEMP., DEG. C: NO INFORMATION
BOILING RANGE, DEG. C: 212 - 279
EXPLOSIVE LIMITS, VOL%: 1.0 - 10.9
FLAMMABILITY: SUPPORTS COMBUSTION
FLASH POINT, DEG. C: 26
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: NO INFORMATION
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION. AVOID TEMPERATURES ABOVE
120 DEG. F. AVOID CONTACT WITH STRONG ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO
DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES. CONTAINS SOLVENTS
WHICH MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND FORMALDEHYDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES SERIOUS EYE IRRITATION
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE IRRITATION. CAUSES SKIN
IRRITATION. ALLERGIC REACTIONS ARE POSSIBLE.
EFFECTS OF OVEREXPOSURE - INHALATION:
HARMFUL IF INHALED. AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. MAY
CAUSE HEADACHES AND DIZZINESS. HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO
THE EYES, NOSE, THROAT AND LUNGS. HIGH GAS, VAPOR, MIST OR DUST
CONCENTRATIONS MAY BE HARMFUL IF INHALED. PROLONGED OR EXCESSIVE INHALATION
MAY CAUSE RESPIRATORY TRACT IRRITATION.
EFFECTS OF OVEREXPOSURE - INGESTION:
HARMFUL IF SWALLOWED. ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND
CAUSE DAMAGE.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
IARC LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B).
OVEREXPOSURE TO XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH LIVER
ABNORMALITIES, KIDNEY, LUNG, SPLEEN, EYE AND BLOOD DAMAGE AS WELL AS
REPRODUCTIVE DISORDERS. EFFECTS IN HUMANS, DUE TO CHRONIC OVEREXPOSURE,
HAVE INCLUDED LIVER, CARDIAC ABNORMALITIES AND NERVOUS SYSTEM DAMAGE.
CONTAINS TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP
2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY IARC. NO SIGNIFICANT EXPOSURE TO
TITANIUM DIOXIDE IS THOUGHT TO OCCUR DURING THE USE OF PRODUCTS IN WHICH
TITANIUM DIOXIDE IS BOUND TO OTHER MATERIALS, SUCH AS IN PAINTS DURING
BRUSH APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND
LEVEL OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST
AND THE ACTUAL CONCENTRATION OF TITANIUM DIOXIDE IN THE FORMULA. (REF: IARC
MONOGRAPH, VOL. 93, 2010)CONTAINS CARBON BLACK. CHRONIC INFLAMMATION, LUNG
FIBROSIS, AND LUNG TUMORS HAVE BEEN OBSERVED IN SOME RATS EXPERIMENTALLY
EXPOSED FOR LONG PERIODS OF TIME TO EXCESSIVE CONCENTRATIONS OF CARBON
BLACK AND SEVERAL INSOLUBLE FINE DUST PARTICLES. TUMORS HAVE NOT BEEN
OBSERVED IN OTHER ANIMAL SPECIES (I.E., MOUSE AND HAMSTER) UNDER SIMILAR
CIRCUMSTANCES AND STUDY CONDITIONS. EPIDEMIOLOGICAL STUDIES OF NORTH
AMERICAN WORKERS SHOW NO EVIDENCE OF CLINICALLY SIGNIFICANT ADVERSE HEALTH
EFFECTS DUE TO OCCUPATIONAL EXPOSURE TO CARBON BLACK.
CARBON BLACK IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY
IARC AND IS PROPOSED TO BE LISTED AS A4- "NOT CLASSIFIED AS A HUMAN
CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND THE
ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA. REPORTS HAVE
ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. HIGH CONCENTRATIONS MAY
LEAD TO CENTRAL NERVOUS SYSTEM EFFECTS (DROWSINESS, DIZZINESS, NAUSEA,
HEADACHES, PARALYSIS, AND BLURRED VISION) AND/OR DAMAGE.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
14808-60-7 CRYSTALLINE SILICA 500 MG/KG N.I. N.I.
RAT
1330-20-7 XYLENE 4300 MG/KG N.I. 47635 MG/L
RAT RAT
1344-28-1 ALUMINUM OXIDE >5000 MG/KG N.I. N.I.
RAT
100-41-4 ETHYLBENZENE 3500 MG/KG 15354 MG/KG 17.2 MG/L
RAT RABBIT RAT
107-98-2 PROPYLENE GLYCOL 5200 MG/KG 13 G/KG 54.6 MG/L RAT
MONOMETHYL ETHER RAT RABBIT
13463-67-7 TITANIUM DIOXIDE >10000 MG/KG N.I. N.I.
RAT
N.I. - NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
PRODUCT IS A MIXTURE OF LISTED COMPONENTS. PRODUCT IS A MIXTURE OF LISTED
COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(US DOT) (IMDG)
UN NUMBER N.A. 1263 1263 N.A.
PROPER SHIPPING PAINT PRODUCTS PAINT PAINT PAINT PRODUCTS
NAME IN LIMITED IN LIMITED
QUANTITIES QUANTITIES
HAZARD CLASS N.A. 3 3 N.A.
PACKING GROUP N.A. III III N.A.
LIMITED QUANTITY YES YES YES YES
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FIRE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
XYLENE 1330-20-7
ALUMINUM OXIDE 1344-28-1
ETHYLBENZENE 100-41-4
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA COMPONENTS EXIST IN THIS PRODUCT.
INVENTORY INFORMATION:
COUNTRY VALUE
USA (TSCA) NO INFORMATION
CANADA (DSL) NO INFORMATION
MEXICO (INSQ) NO INFORMATION
EUROPE (EINECS) NO INFORMATION
JAPAN (ENCS) NO INFORMATION
PHILIPPINES (PICCS) NO INFORMATION
CHINA (IECSC) NO INFORMATION
AUSTRALIA (AICS) NO INFORMATION
KOREA (KECI) NO INFORMATION
NEW ZEALAND (NZIOC) NO INFORMATION
NO INFORMATION
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCTS CONTAINS A SUBSTANCE KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.
CHEMICAL NAME CAS-NO.
CRYSTALLINE SILICA 14808-60-7
ETHYLBENZENE 100-41-4
CARBON BLACK 1333-86-4
TITANIUM DIOXIDE 13463-67-7
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS:
WARNING:
THIS PRODUCT CONTAINS A SUBSTANCE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CHEMICAL NAME CAS-NO.
TOLUENE 108-88-3
INTERNATIONAL REGULATIONS:
CANADIAN WHMIS:
THIS SDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
CANADIAN WHMIS CLASS:
B2
D2A
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 438
MSDS REVISION DATE: 9/3/2014
REASON FOR REVISION: NO INFORMATION
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H226: FLAMMABLE LIQUID AND VAPOUR.
H251:
SELF-HEATING: MAY CATCH FIRE.
H302: HARMFUL IF SWALLOWED.
H310: FATAL IN CONTACT WITH SKIN.
H332: HARMFUL IF INHALED.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS02: FLAME
GHS06: SKULLS AND CROSSBONES
GHS07: EXCLAMATION MARK
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.