| Common Name: | RIM HANGER NO PDCB EVERGREEN 1.76OZ(50G)12 PC |
| Manufacturer: | GRAINGER GLOBAL SOURCING |
| SDS Revision Date: | 11/14/2014 |
| SDS Format: | GHS-EU |
| Item Number(s): | 2ZXE8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
ACC. TO OSHA HCS
PRINTING DATE: 11/18/2014
REVIEWED ON: 11/14/2014
| 1 IDENTIFICATION |  |
PRODUCT IDENTIFIER: 2ZXE8
TRADE NAME: RIM HANGER NO PDCB GRAINGER EVERGREEN 1.76OZ(50G)12 PC
ARTICLE NUMBER: (779) (67)
APPLICATION OF THE SUBSTANCE / THE MIXTURE: AIR FRESHENER
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
GRAINGER GLOBAL SOURCING
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045
USA
847-535-1000
INFORMATION DEPARTMENT: GRAINGER TECHNICAL SUPPORT
EMERGENCY TELEPHONE NUMBER:
GRAINGER TECHNICAL SUPPORT AT 1-800-356-2501
IN THE CASE OF POISONING, CONTACT CHEMTREC:
1-800-424-9300 (TOLL-FREE)
00 + 1-703-527-3887 (NON-US)
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS07: EXCLAMATION MARK
ACUTE TOX. 4:
H302: HARMFUL IF SWALLOWED.
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR DIRECTIVE 1999/45/EC:
HARMFUL
HARMFUL IF SWALLOWED.
INFORMATION CONCERNING PARTICULAR HAZARDS FOR HUMAN AND ENVIRONMENT:
THE PRODUCT HAS TO BE LABELED DUE TO THE CALCULATION PROCEDURE OF
INTERNATIONAL GUIDELINES.
CLASSIFICATION SYSTEM:
THE CLASSIFICATION WAS MADE ACCORDING TO THE LATEST EDITIONS OF
INTERNATIONAL SUBSTANCES LISTS, AND EXPANDED UPON FROM COMPANY AND
LITERATURE DATA.
LABEL ELEMENTS:
LABELLING ACCORDING TO EU GUIDELINES:
THE PRODUCT HAS BEEN CLASSIFIED AND MARKED IN ACCORDANCE WITH DIRECTIVES
ON HAZARDOUS MATERIALS.
CODE LETTER AND HAZARD DESIGNATION OF PRODUCT: HARMFUL
HAZARD-DETERMINING COMPONENTS OF LABELING:
SODIUM DODECYLBENZENESULPHONATE, PURE
RISK PHRASES: HARMFUL IF SWALLOWED.
SAFETY PHRASES:
KEEP OUT OF THE REACH OF CHILDREN.
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS.
IF SWALLOWED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THIS CONTAINER OR
LABEL.
DISPOSE OF THIS MATERIAL AND ITS CONTAINER TO HAZARDOUS OR SPECIAL WASTE
COLLECTION POINT.
CLASSIFICATION SYSTEM:
NFPA RATINGS (SCALE 0 - 4):
HEALTH 2
FIRE 1
REACTIVITY 0
HMIS-RATINGS (SCALE 0 - 4):
HEALTH 2
FIRE 1
REACTIVITY 0
OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
DESCRIPTION:
MIXTURE OF THE SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS.
DANGEROUS COMPONENTS:
25155-30-0 SODIUM DODECYLBENZENESULPHONATE, PURE 25-50%
POLYETHYLENE GLYCOL 2.5-<10%
FRAGRANCE TRADE SECRET (779) 2.5-<10%
112926-00-8 PRECIPITATED SILICA (SILICA-AMORPHOUS) 1-</=2.5%
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE MEDICAL
OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT.
AFTER INHALATION: SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
AFTER SKIN CONTACT: GENERALLY THE PRODUCT DOES NOT IRRITATE THE SKIN.
AFTER EYE CONTACT:
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER.
AFTER SWALLOWING: IMMEDIATELY CALL A DOCTOR.
INFORMATION FOR DOCTOR:
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
USE FIRE FIGHTING MEASURES THAT SUIT THE ENVIRONMENT.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT: NO SPECIAL MEASURES REQUIRED.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
NOT REQUIRED.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/SURFACE OR GROUND WATER.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
NO SPECIAL PRECAUTIONS ARE NECESSARY IF USED CORRECTLY.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
NO SPECIAL MEASURES REQUIRED.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
NO SPECIAL REQUIREMENTS.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY: NOT REQUIRED.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS: NONE.
SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL SYSTEMS:
NO FURTHER DATA; SEE ITEM 7.
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
POLYETHYLENE GLYCOL:
WEEL:
LONG-TERM VALUE: 10 MG/M3 (H); MW >200
112926-00-8 PRECIPITATED SILICA (SILICA-AMORPHOUS):
PEL: 20 MPPCF OR 80 MG/M3 / %SiO2
REL:
LONG-TERM VALUE: 6 MG/M3
SEE POCKET GUIDE APP. C
TLV: TLV WITHDRAWN
ADDITIONAL INFORMATION:
THE LISTS THAT WERE VALID DURING THE CREATION WERE USED AS BASIS.
EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
BREATHING EQUIPMENT: NOT REQUIRED.
PROTECTION OF HANDS:
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/THE
SUBSTANCE/THE PREPARATION. DUE TO MISSING TESTS NO RECOMMENDATION TO THE
GLOVE MATERIAL CAN BE GIVEN FOR THE PRODUCT/THE PREPARATION/THE CHEMICAL
MIXTURE.
SELECTION OF THE GLOVE MATERIAL ON CONSIDERATION OF THE PENETRATION TIMES,
RATES OF DIFFUSION AND THE DEGRADATION
MATERIAL OF GLOVES:
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER. AS THE PRODUCT IS A PREPARATION OF SEVERAL SUBSTANCES, THE
RESISTANCE OF THE GLOVE MATERIAL CAN NOT BE CALCULATED IN ADVANCE AND HAS
THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF
THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: NOT REQUIRED.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL INFORMATION:
APPEARANCE:
FORM: SOLID
COLOR: ACCORDING TO PRODUCT SPECIFICATION
ODOR: CHARACTERISTIC
ODOUR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT APPLICABLE.
CHANGE IN CONDITION:
MELTING POINT/MELTING RANGE: UNDETERMINED.
BOILING POINT/BOILING RANGE: UNDETERMINED.
FLASH POINT: 301 DEG. C (574 DEG. F)
FLAMMABILITY (SOLID, GASEOUS): NOT DETERMINED.
IGNITION TEMPERATURE:
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
AUTO IGNITING: PRODUCT IS NOT SELFIGNITING.
DANGER OF EXPLOSION: PRODUCT DOES NOT PRESENT AN EXPLOSION HAZARD.
EXPLOSION LIMITS:
LOWER: NOT DETERMINED.
UPPER: NOT DETERMINED.
VAPOR PRESSURE: NOT APPLICABLE.
DENSITY: NOT DETERMINED.
RELATIVE DENSITY: NOT DETERMINED.
VAPOUR DENSITY: NOT APPLICABLE.
EVAPORATION RATE: NOT APPLICABLE.
SOLUBILITY IN / MISCIBILITY WITH WATER: SOLUBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT APPLICABLE.
KINEMATIC: NOT APPLICABLE.
SOLVENT CONTENT:
ORGANIC SOLVENTS: 0.0%
VOC CONTENT: <0.50%
SOLIDS CONTENT: 95.1%
OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY:
CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED ACCORDING TO SPECIFICATIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NO DANGEROUS REACTIONS KNOWN.
CONDITIONS TO AVOID: NO FURTHER RELEVANT INFORMATION AVAILABLE.
INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO DANGEROUS DECOMPOSITION PRODUCTS KNOWN.
| 11 TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRIMARY IRRITANT EFFECT:
ON THE SKIN: NO IRRITANT EFFECT.
ON THE EYE: NO IRRITATING EFFECT.
SENSITIZATION: NO SENSITIZING EFFECTS KNOWN.
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE PRODUCT SHOWS THE FOLLOWING DANGERS ACCORDING TO INTERNALLY APPROVED
CALCULATION METHODS FOR PREPARATIONS: HARMFUL
CARCINOGENIC CATEGORIES:
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
112926-00-8 PRECIPITATED SILICA (SILICA-AMORPHOUS) 3
91-64-5 COUMARIN 3
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS IS LISTED.
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS IS LISTED.
| 12 ECOLOGICAL INFORMATION | |
TOXICITY:
AQUATIC TOXICITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
BEHAVIOR IN ENVIRONMENTAL SYSTEMS:
BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
WATER HAZARD CLASS 2 (SELF-ASSESSMENT): HAZARDOUS FOR WATER
DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER COURSE OR SEWAGE SYSTEM.
DANGER TO DRINKING WATER IF EVEN SMALL QUANTITIES LEAK INTO THE GROUND.
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW
PRODUCT TO REACH SEWAGE SYSTEM.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
RECOMMENDED CLEANSING AGENT: WATER, IF NECESSARY WITH CLEANSING AGENTS.
| 14 TRANSPORT INFORMATION | |
UN-NUMBER:
DOT, IMDG, IATA: UN2811
UN PROPER SHIPPING NAME:
DOT: TOXIC SOLIDS, ORGANIC, N.O.S. (SODIUM DODECYLBENZENESULPHONATE, PURE)
IMDG, IATA:
TOXIC SOLID, ORGANIC, N.O.S. (SODIUM DODECYLBENZENESULPHONATE, PURE)
TRANSPORT HAZARD CLASS(ES):
DOT: CLASS 6.1, TOXIC
CLASS: 6.1 TOXIC SUBSTANCES
LABEL: 6.1
IMDG, IATA: CLASS 6.1 - TOXIC
CLASS: 6.1 TOXIC SUBSTANCES
LABEL: 6.1
PACKING GROUP:
DOT, IMDG, IATA: III
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER:
WARNING: TOXIC SUBSTANCES
DANGER CODE (KEMLER): 60
EMS NUMBER: F-A, S-A
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
DOT:
QUANTITY LIMITATIONS:
ON PASSENGER AIRCRAFT/RAIL: 100 KG
ON CARGO AIRCRAFT ONLY: 200 KG
IMDG:
LIMITED QUANTITIES (LQ): 5 KG
EXCEPTED QUANTITIES (EQ):
CODE: E1
MAXIMUM NET QUANTITY PER INNER PACKAGING: 30 G
MAXIMUM NET QUANTITY PER OUTER PACKAGING: 1000 G
UN "MODEL REGULATION":
UN2811, TOXIC SOLIDS, ORGANIC, N.O.S. (SODIUM DODECYLBENZENESULPHONATE,
PURE), 6.1, III
| 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IS LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
NONE OF THE INGREDIENTS IS LISTED.
TSCA (TOXIC SUBSTANCES CONTROL ACT):
7757-82-6 SODIUM SULPHATE
25155-30-0 SODIUM DODECYLBENZENESULPHONATE, PURE
POLYETHYLENE GLYCOL
78-70-6 LINALOOL
106-24-1 GERANIOL
106-22-9 CITRONELLOL
91-64-5 COUMARIN
5392-40-5 CITRAL
138-86-3 DIPENTENE
PROPOSITION 65:
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS IS LISTED.
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY): NONE OF THE INGREDIENTS IS LISTED.
TLV (THRESHOLD LIMIT VALUE ESTABLISHED BY ACGIH):
NONE OF THE INGREDIENTS IS LISTED.
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS IS LISTED.
PRODUCT RELATED HAZARD INFORMATIONS:
THE PRODUCT HAS BEEN CLASSIFIED AND MARKED IN ACCORDANCE WITH DIRECTIVES
ON HAZARDOUS MATERIALS.
HAZARD SYMBOLS: HARMFUL
HAZARD-DETERMINING COMPONENTS OF LABELING:
SODIUM DODECYLBENZENESULPHONATE, PURE
RISK PHRASES: HARMFUL IF SWALLOWED.
SAFETY PHRASES:
KEEP OUT OF THE REACH OF CHILDREN.
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS.
IF SWALLOWED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THIS CONTAINER OR
LABEL.
DISPOSE OF THIS MATERIAL AND ITS CONTAINER TO HAZARDOUS OR SPECIAL WASTE
COLLECTION POINT.
CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL NOT
ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
DEPARTMENT ISSUING SDS: GRAINGER TECHNICAL SUPPORT
CONTACT: GRAINGER TECHNICAL SUPPORT
DATE OF PREPARATION / LAST REVISION: 11/18/2014 / -
ABBREVIATIONS AND ACRONYMS:
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
ACUTE TOX. 4: ACUTE TOXICITY, HAZARD CATEGORY 4
USA