| Common Name: | DYKEM OPAQUE STAIN - ALL COLORS |
| Manufacturer: | ITW PROFESSIONAL BRANDS |
| SDS Revision Date: | 5/1/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 2GKW6, 2GKW7, 2GKW8, 2GKW9, 2GKX4, 2GKX5, 2GKX6, 2GKX7, 2GKX8, 2GKX9, 2GKY1, 2GKY2, 2GKY3, 2GKY4, 2GKY5, 30E903, 38GG49 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ITW PROFESSIONAL BRANDS
SAFETY DATA SHEET
ISSUING DATE: 01-MAY-2014
REVISION DATE: 01-MAY-2014
REVISION NUMBER: 0
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND THE COMPANY/UNDERTAKING
GHS PRODUCT IDENTIFIER:
PRODUCT NAME: DYKEM OPAQUE STAIN - ALL COLORS
OTHER MEANS OF IDENTIFICATION:
PART NUMBER:
BLACK (81724), DARK BLUE (81478, 81778), LIGHT BLUE (81725), DARK GREEN
(81706, 81806), LIGHT GREEN (81708), ORANGE (81413, 81713), PINK (81760),
PURPLE (81763), RED (81491, 81791), WHITE (81427, 81727, 81827), YELLOW
(81405, 81705)
FORMULA CODE:
BLACK (8718D1), DARK BLUE (8719D1), LIGHT BLUE (8720D1), DARK GREEN (8939),
LIGHT GREEN (8940), ORANGE (8941), PINK (8726D2), PURPLE (8732D2), RED
(8727D2), WHITE (8728D1), YELLOW (8938)
UN-NUMBER: UN1263
SYNONYMS: DYKEM OPAQUE STAINING COLORS
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: STAINING COLORS
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER'S DETAILS:
SUPPLIER ADDRESS:
ITW PROFESSIONAL BRANDS
805 E. OLD 56 HIGHWAY
OLATHE, KS 66061
TEL: 1-800-443-9536
EMERGENCY TELEPHONE NUMBER:
EMERGENCY TELEPHONE NUMBER: 800-535-5053 INFOTRAC
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS ACCORDING TO THE OSHA HAZARD
COMMUNICATION STANDARD 2012 (29 CFR 1910.1200)
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE): CATEGORY 3
FLAMMABLE LIQUIDS: CATEGORY 2
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
EMERGENCY OVERVIEW:
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE DAMAGE
MAY CAUSE RESPIRATORY IRRITATION
MAY CAUSE DROWSINESS OR DIZZINESS
HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXCLAMATION MARK
CORROSION
FLAME
APPEARANCE:
COLOR: VARIES, THIN VISCOSITY
PHYSICAL STATE: LIQUID.
ODOR: SWEET, SOLVENT
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES - NO SMOKING
KEEP CONTAINER TIGHTLY CLOSED
KEEP COOL
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT
USE ONLY NON-SPARKING TOOLS
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
GENERAL ADVICE:
SPECIFIC TREATMENT (SEE SUPPLEMENTAL FIRST AID INSTRUCTIONS ON THIS LABEL)
EYES:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
SKIN:
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
INHALATION:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
FIRE:
IN CASE OF FIRE: USE CO2, DRY CHEMICAL, OR FOAM FOR EXTINCTION.
STORAGE:
STORE LOCKED UP
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
HAZARD NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER INFORMATION:
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SYNONYMS: DYKEM OPAQUE STAINING COLORS
CHEMICAL NAME CAS-NO WEIGHT % TRADE SECRET
N-BUTYL ACETATE 123-86-4 30-60 *
ETHANOL 64-17-5 10-30 *
N-BUTYL ALCOHOL 71-36-3 10-30 *
ETHYL ACETATE 141-78-6 7-13 *
TITANIUM DIOXIDE 13463-67-7 7-13 *
CARBON BLACK 1333-86-4 3-7 *
ISOPROPYL ALCOHOL 67-63-0 1-5 *
BENZOIC ACID, 15782-06-6 1-5 *
2-[(2-HYDROXY-3,6-
DISULFO-1-NAPHTHALENYL)
AZO]-, BARIUM SALT (2:3)
N-PROPYL ACETATE 109-60-4 1-5 *
*THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS A
TRADE SECRET.
| 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST-AID MEASURES:
GENERAL ADVICE:
IMMEDIATE MEDICAL ATTENTION IS REQUIRED. SHOW THIS SAFETY DATA SHEET TO THE
DOCTOR IN ATTENDANCE. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER. AFTER INITIAL FLUSHING, REMOVE ANY
CONTACT LENSES AND CONTINUE FLUSHING FOR AT LEAST 15 MINUTES. KEEP EYE WIDE
OPEN WHILE RINSING. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHES AND SHOES. IF SKIN IRRITATION PERSISTS, CALL A
PHYSICIAN.
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SYMPTOMS
PERSIST, CALL A PHYSICIAN.
INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. DRINK PLENTY OF WATER. IF SYMPTOMS PERSIST, CALL A
PHYSICIAN.
PROTECTION OF FIRST-AIDERS:
USE PERSONAL PROTECTIVE EQUIPMENT. REMOVE ALL SOURCES OF IGNITION.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MOST IMPORTANT SYMPTOMS/EFFECTS: NO INFORMATION AVAILABLE.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA: CARBON DIOXIDE (CO2). FOAM. DRY CHEMICAL.
UNSUITABLE EXTINGUISHING MEDIA:
CAUTION: USE OF WATER SPRAY WHEN FIGHTING FIRE MAY BE INEFFICIENT.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
MOST VAPORS ARE HEAVIER THAN AIR. THEY WILL SPREAD ALONG GROUND AND COLLECT
IN LOW OR CONFINED AREAS (SEWERS, BASEMENTS, TANKS). MOST VAPORS ARE
HEAVIER THAN AIR. VAPORS MAY SPREAD ALONG GROUND AND COLLECT IN LOW OR
CONFINED AREAS (SEWERS, BASEMENTS, TANKS).
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: YES.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE PERSONNEL TO SAFE AREAS. USE
PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
ENSURE ADEQUATE VENTILATION. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. PREVENT PRODUCT FROM
ENTERING DRAINS. DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
SMALL SPILLAGE:
TAKE UP WITH SAND OR OTHER NONCOMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO
CONTAINERS FOR LATER DISPOSAL.
LARGE SPILLAGE:
PUMP OR VACUUM TRANSFER SPILLED PRODUCT TO CLEAN CONTAINERS FOR RECOVERY.
ABSORB UNRECOVERABLE PRODUCT.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. USE ONLY IN AN AREA
CONTAINING FLAME PROOF EQUIPMENT. DO NOT BREATHE VAPORS OR SPRAY MIST.
ENSURE ADEQUATE VENTILATION. TO AVOID IGNITION OF VAPORS BY STATIC
ELECTRICITY DISCHARGE, ALL METAL PARTS OF THE EQUIPMENT MUST BE GROUNDED.
USE ONLY IN AREA PROVIDED WITH APPROPRIATE EXHAUST VENTILATION. DO NOT EAT,
DRINK OR SMOKE WHEN USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
KEEP IN PROPERLY LABELED CONTAINERS. KEEP AWAY FROM HEAT AND SOURCES OF
IGNITION. KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED
PLACE. KEEP PRODUCT AND EMPTY CONTAINER AWAY FROM HEAT AND SOURCES OF
IGNITION KEEP AWAY FROM INCOMPATIBLE MATERIALS.
INCOMPATIBLE PRODUCTS:
STRONG OXIDIZING AGENTS. STRONG ACIDS. STRONG REDUCING AGENTS. STRONG
ALKALIS.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
N-BUTYL ACETATE STEL: 200 PPM TWA: 150 PPM IDLH: 1700 PPM
123-86-4 TWA: 150 PPM TWA: 710 MG/M3 TWA: 150 PPM
(VACATED) TWA: 150 PPM TWA: 710 MG/M3
(VACATED) TWA: 710 MG/M3 STEL: 200 PPM
(VACATED) STEL: 200 PPM STEL: 950 MG/M3
(VACATED) STEL:
950 MG/M3
ETHANOL STEL: TWA: 1000 PPM IDLH:
64-17-5 1000 PPM TWA: 1900 MG/M3 3300 PPM 10% LEL
(VACATED) TWA: 1000 PPM TWA: 1000 PPM
(VACATED) TWA: TWA: 1900 MG/M3
1900 MG/M3
N-BUTYL ALCOHOL TWA: 20 PPM TWA: 100 PPM IDLH: 1400 PPM
71-36-3 TWA: 300 MG/M3 CEILING: 50 PPM
(VACATED) S* CEILING:
(VACATED) CEILING: 50 PPM 150 MG/M3
(VACATED) CEILING:
150 MG/M3
ETHYL ACETATE TWA: 400 PPM TWA: 400 PPM IDLH: 2000 PPM
141-78-6 TWA: 1400 MG/M3 TWA: 400 PPM
(VACATED) TWA: 400 PPM TWA: 1400 MG/M3
(VACATED) TWA: 1400 MG/M3
TITANIUM TWA: 10 MG/M3 TWA: 15 MG/M3 TOTAL DUST IDLH: 5000 MG/M3
DIOXIDE (VACATED) TWA:
13463-67-7 10 MG/M3 TOTAL DUST
CARBON BLACK TWA: TWA: 3.5 MG/M3 IDLH: 1750 MG/M3
1333-86-4 3.5 MG/M3 (VACATED) TWA: 3.5 MG/M3 TWA: 3.5 MG/M3
TWA:
0.1 MG/M3 CARBON
BLACK IN
PRESENCE OF
POLYCYCLIC
AROMATIC
HYDROCARBONS PAH
ISOPROPYL STEL: 400 PPM TWA: 400 PPM IDLH:
ALCOHOL TWA: 200 PPM TWA: 980 MG/M3 2000 PPM 10% LEL
67-63-0 (VACATED) TWA: 400 PPM TWA: 980 MG/M3
(VACATED) TWA: 980 MG/M3 TWA: 400 PPM
(VACATED) STEL: 500 PPM STEL: 500 PPM
(VACATED) STEL: STEL: 1225 MG/M3
1225 MG/M3
BENZOIC ACID, TWA: TWA: 0.5 MG/M3 Ba TWA:
2-[(2-HYDROXY- 0.5 MG/M3 Ba (VACATED) TWA: 0.5 MG/M3 EXCEPT
3,6-DISULFO-1- 0.5 MG/M3 Ba BARIUM SULFATE
NAPHTHALENYL)AZ Ba
O]-, BARIUM
SALT (2:3)
15782-06-6
N-PROPYL STEL: 250 PPM TWA: 200 PPM IDLH: 1700 PPM
ACETATE TWA: 200 PPM TWA: 840 MG/M3 TWA: 200 PPM
109-60-4 (VACATED) TWA: 200 PPM TWA: 840 MG/M3
(VACATED) TWA: 840 MG/M3 STEL: 250 PPM
(VACATED) STEL: 250 PPM STEL: 1050 MG/M3
(VACATED) STEL:
1050 MG/M3
TRIPHENYL TWA: 3 MG/M3 TWA: 3 MG/M3 IDLH: 1000 MG/M3
PHOSPHATE (VACATED) TWA: 3 MG/M3 TWA: 3 MG/M3
115-86-6
PROPYLENE STEL: 150 PPM (VACATED) TWA: 100 PPM TWA: 100 PPM
GLYCOL TWA: 100 PPM (VACATED) TWA: 360 MG/M3 TWA: 360 MG/M3
MONOMETHYL (VACATED) STEL: 150 PPM STEL: 150 PPM
ETHER (VACATED) STEL: 540 MG/M3 STEL: 540 MG/M3
107-98-2
DIACETONE TWA: 50 PPM TWA: 50 PPM IDLH: 1800 PPM
ALCOHOL TWA: 240 MG/M3 TWA: 50 PPM
123-42-2 (VACATED) TWA: 50 PPM TWA: 240 MG/M3
(VACATED) TWA: 240 MG/M3
XANTHYLIUM,9- (VACATED) CEILING: IDLH:
(2-CARBOXY- 0.1 MG/M3 15 MG/M3 Cr(VI)
PHENYL)-3,6-
BIS(DIETHYL CEILING: TWA:
AMINO)-, 0.1 MG/M3 CrO3 APPLIES 0.001 MG/M3 Cr
HYDROGENBIS TO ANY OPERATIONS OR
[3-[(4,5- SECTORS FOR WHICH THE
DIHYDRO-3- HEXAVALENT CHROMIUM
METHYL-5... STANDARD [29 CFR
84962-27-6 1910.1026] IS STAYED OR
IS OTHERWISE NOT IN
EFFECT
IMMEDIATELY DANGEROUS TO LIFE OR HEALTH.
ACGIH TLV:
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS - THRESHOLD LIMIT
VALUE.
OSHA PEL:
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION - PERMISSIBLE EXPOSURE
LIMITS.
NIOSH IDLH:
OTHER EXPOSURE GUIDELINES:
VACATED LIMITS REVOKED BY THE COURT OF APPEALS DECISION IN AFL-CIO V. OSHA,
965 F.2D 962 (11TH CIR., 1992).
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
IF SPLASHES ARE LIKELY TO OCCUR, WEAR: CHEMICAL SPLASH GOGGLES.
SKIN AND BODY PROTECTION: IMPERVIOUS CLOTHING. CHEMICAL RESISTANT GLOVES
RESPIRATORY PROTECTION:
NO PROTECTIVE EQUIPMENT IS NEEDED UNDER NORMAL USE CONDITIONS. IF EXPOSURE
LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, NIOSH/MSHA APPROVED
RESPIRATORY PROTECTION SHOULD BE WORN.
HYGIENE MEASURES:
WHEN USING, DO NOT EAT, DRINK OR SMOKE. PROVIDE REGULAR CLEANING OF
EQUIPMENT, WORK AREA AND CLOTHING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE:
COLOR: VARIES THIN VISCOSITY
ODOR: SWEET, SOLVENT
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS/ - METHOD
PH NO DATA AVAILABLE NONE KNOWN
MELTING POINT/RANGE NO DATA AVAILABLE NONE KNOWN
BOILING POINT/BOILING RANGE 76.667-125 DEG. C / NONE KNOWN
170-257 DEG. F
FLASH POINT -4.444 DEG. C / 24 DEG. F NONE KNOWN
EVAPORATION RATE <1 (BUAC = 1) NONE KNOWN
FLAMMABILITY (SOLID, GAS) NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO DATA AVAILABLE
LOWER FLAMMABILITY LIMIT NO DATA AVAILABLE
VAPOR PRESSURE NO DATA AVAILABLE NONE KNOWN
VAPOR DENSITY >1 (AIR = 1) NONE KNOWN
SPECIFIC GRAVITY NO DATA AVAILABLE. NONE KNOWN
WATER SOLUBILITY NEGLIGIBLE NONE KNOWN
SOLUBILITY IN OTHER NO DATA AVAILABLE NONE KNOWN
SOLVENTS
PARTITION COEFFICIENT NO DATA AVAILABLE NONE KNOWN
N-OCTANOL/WATER
AUTOIGNITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
DECOMPOSITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
VISCOSITY NO DATA AVAILABLE NONE KNOWN
FLAMMABLE PROPERTIES HIGHLY FLAMMABLE:
WILL BE EASILY IGNITED BY HEAT, SPARKS OR
FLAMES.
EXPLOSIVE PROPERTIES NO DATA AVAILABLE
OXIDIZING PROPERTIES NO DATA AVAILABLE
OTHER INFORMATION:
VOC CONTENT (%):
8718D1 BLACK 87.44%
8719D1 DK BLUE 83.54%
8720D1 LT BLUE 81.85%
8939 DK GREEN 87.49%
8940 LT GREEN 86.57%
8941 ORANGE 84.96%
8726D2 PINK 80.21%
8732D2 PURPLE 84.36%
8727D2 RED 87.95%
8728D1 WHITE 80.24%
8938 YELLOW 86.36%
VOC (G/L):
8718D1 BLACK 772 G/L
8719D1 DK BLUE 765 G/L
8720D1 LT BLUE 766 G/L
8939 DK GREEN 777 G/L
8940 LT GREEN 775 G/L
8941 ORANGE 761 G/L
8726D2 PINK 798 G/L
8732D2 PURPLE 773 G/L
8727D2 RED 780 G/L
8728D1 WHITE 754 G/L
8938 YELLOW 771 G/L
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS POLYMERIZATION: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS. INCOMPATIBLE PRODUCTS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. STRONG ACIDS. STRONG REDUCING AGENTS. STRONG
ALKALIS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NITROGEN OXIDES (NOX). CARBON MONOXIDE, CARBON DIOXIDE AND UNBURNED
HYDROCARBONS (SMOKE). SMOKE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
INHALATION:
MAY CAUSE IRRITATION OF RESPIRATORY TRACT. MAY CAUSE DROWSINESS AND
DIZZINESS.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED. INGESTION MAY CAUSE NAUSEA AND VOMITING.
CHEMICAL NAME LD50 ORAL LD50 DERMAL LC50 INHALATION
N-BUTYL ACETATE =10768 MG/KG >17600 MG/KG =391 PPM
(RAT) (RABBIT) (RAT) 4 H
ETHANOL =7060 MG/KG =124.7 MG/L
(RAT) (RAT) 4 H
N-BUTYL ALCOHOL =790 MG/KG =3400 MG/KG =8000 PPM
(RAT) (RABBIT) (RAT) 4 H
ETHYL ACETATE =5620 MG/KG >20 ML/KG
(RAT) (RABBIT)
>18000 MG/KG
(RABBIT)
TITANIUM DIOXIDE >10000 MG/KG
(RAT)
CARBON BLACK >15400 MG/KG >3 G/KG
(RAT) (RABBIT)
ISOPROPYL ALCOHOL =4396 MG/KG 12800 MG/KG 72.6 MG/L (RAT)
(RAT) (RAT) 4 H
12870 MG/KG
(RABBIT)
N-PROPYL ACETATE =9370 MG/KG >17760 MG/KG
(RAT) (RABBIT)
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE.
CARCINOGENICITY:
ETHANOL HAS BEEN SHOWN TO BE CARCINOGENIC IN LONG-TERM STUDIES ONLY WHEN
CONSUMED AND ABUSED AS AN ALCOHOLIC BEVERAGE. THIS PRODUCT CONTAINS
TITANIUM DIOXIDE IN A NON-RESPIRABLE FORM. INHALATION OF TITANIUM DIOXIDE
IS UNLIKELY TO OCCUR FROM EXPOSURE TO THIS PRODUCT. THIS PRODUCT CONTAINS
CARBON BLACK IN A NON-RESPIRABLE FORM. INHALATION OF CARBON BLACK IS
UNLIKELY TO OCCUR FROM EXPOSURE TO THIS PRODUCT.
CHEMICAL NAME ACGIH IARC NTP OSHA
ETHANOL A3 GROUP 1 KNOWN X
TITANIUM DIOXIDE GROUP 2B
CARBON BLACK A3 GROUP 2B X
ISOPROPYL ALCOHOL GROUP 3 X
ACGIH: (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
A3 - ANIMAL CARCINOGEN
IARC: (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
GROUP 1 - CARCINOGENIC TO HUMANS
GROUP 2B - POSSIBLY CARCINOGENIC TO HUMANS
GROUP 3: NOT CLASSIFIABLE AS TO ITS CARCINOGENICITY TO HUMANS
NTP: (NATIONAL TOXICITY PROGRAM)
KNOWN - KNOWN CARCINOGEN
OSHA: (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION)
X - PRESENT
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE.
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
CHRONIC TOXICITY:
AVOID REPEATED EXPOSURE. MAY CAUSE ADVERSE LIVER EFFECTS. ETHANOL HAS
BEEN SHOWN TO BE A REPRODUCTIVE TOXIN ONLY WHEN CONSUMED AS AN ALCOHOLIC
BEVERAGE. ETHANOL HAS BEEN SHOWN TO BE CARCINOGENIC IN LONG-TERM STUDIES
ONLY WHEN CONSUMED AS ALCOHOLIC BEVERAGE. MAY CAUSE ADVERSE EFFECTS ON THE
BONE MARROW AND BLOOD-FORMING SYSTEM. THIS PRODUCT CONTAINS TITANIUM
DIOXIDE IN A NON-RESPIRABLE FORM. INHALATION OF TITANIUM DIOXIDE IS
UNLIKELY TO OCCUR FROM EXPOSURE TO THIS PRODUCT. THIS PRODUCT CONTAINS
CARBON BLACK IN A NON-RESPIRABLE FORM. INHALATION OF CARBON BLACK IS
UNLIKELY TO OCCUR FROM EXPOSURE TO THIS PRODUCT.
TARGET ORGAN EFFECTS:
RESPIRATORY SYSTEM. EYES. SKIN. CENTRAL NERVOUS SYSTEM (CNS). PERIPHERAL
NERVOUS SYSTEM (PNS)
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
NUMERICAL MEASURES OF TOXICITY - PRODUCT:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT:
LD50 ORAL: 2158 MG/KG
LD50 DERMAL: 13697 MG/KG
DUST/MIST: 18.2 MG/L
VAPOR: 134.2 MG/L
| 12. ECOLOGICAL INFORMATION | |
THIS PRODUCT CONTAINS A CHEMICAL WHICH IS LISTED AS A SEVERE MARINE
POLLUTANT ACCORDING TO DOT.
ECOTOXICITY:
THE ENVIRONMENTAL IMPACT OF THIS PRODUCT HAS NOT BEEN FULLY INVESTIGATED.
CHEMICAL NAME TOXICITY TO ALGAE TOXICITY TO FISH
N-BUTYL ACETATE EC50 72 H: LC50 96 H:
123-86-4 =674.7 MG/L (DESMODESMUS 17 - 19 MG/L FLOW-THROUGH
SUBSPICATUS) (PIMEPHALES PROMELAS)
LC50 96 H:
=100 MG/L STATIC (LEPOMIS
MACROCHIRUS)
LC50 96 H:
=62 MG/L STATIC
(LEUCISCUS IDUS)
ETHANOL LC50 96 H:
64-17-5 12.0 - 16.0 ML/L STATIC
(ONCORHYNCHUS MYKISS)
LC50 96 H:
>100 MG/L STATIC
(PIMEPHALES PROMELAS)
LC50 96 H:
13400 - 15100 MG/L
FLOW-THROUGH (PIMEPHALES
PROMELAS)
N-BUTYL ALCOHOL EC50 96 H: LC50 96 H:
71-36-3 >500 MG/L (DESMODESMUS 1730 - 1910 MG/L STATIC
SUBSPICATUS) (PIMEPHALES PROMELAS)
EC50 72 H: LC50 96 H:
>500 MG/L (DESMODESMUS =1740 MG/L FLOW-THROUGH
SUBSPICATUS) (PIMEPHALES PROMELAS)
LC50 96 H:
100000 - 500000 (MICRO)G/L
STATIC (LEPOMIS
MACROCHIRUS)
LC50 96 H:
=1910000 (MICRO)G/L
STATIC (PIMEPHALES
PROMELAS)
ETHYL ACETATE EC50 48 H: LC50 96 H:
141-78-6 =3300 MG/L (DESMODESMUS 220 - 250 MG/L FLOW-
SUBSPICATUS) THROUGH (PIMEPHALES
PROMELAS)
LC50 96 H:
=484 MG/L FLOW-THROUGH
(ONCORHYNCHUS MYKISS)
LC50 96 H:
352 - 500 MG/L SEMI-STATIC
(ONCORHYNCHUS MYKISS)
CARBON BLACK
1333-86-4
ISOPROPYL ALCOHOL EC50 96 H: LC50 96 H:
67-63-0 >1000 MG/L (DESMODESMUS =11130 MG/L STATIC
SUBSPICATUS) (PIMEPHALES PROMELAS)
EC50 72 H: LC50 96 H:
>1000 MG/L (DESMODESMUS =9640 MG/L FLOW-THROUGH
SUBSPICATUS) (PIMEPHALES PROMELAS)
LC50 96 H:
>1400000 (MICRO)G/L
(LEPOMIS MACROCHIRUS)
N-PROPYL ACETATE LC50 96 H:
109-60-4 56-64 MG/L FLOW-THROUGH
(PIMEPHALES PROMELAS)
LC50 96 H:
56-64 MG/L STATIC
(PIMEPHALES PROMELAS)
CHEMICAL NAME TOXICITY TO DAPHNIA MAGNA (WATER
MICROORGANISMS FLEA)
N-BUTYL ACETATE EC50: 70.0 MG/L 5 MIN EC50 24 H:
EC50: 82.2 MG/L 15 MIN =72.8 MG/L (DAPHNIA
EC50: 959 MG/L 18 H MAGNA)
EC50: 98.9 MG/L 30 MIN
ETHANOL EC50: 34634 MG/L 30 MIN LC50 48 H:
EC50: 35470 MG/L 5 MIN 9268 - 14221 MG/L (DAPHNIA
MAGNA)
EC50 24 H:
=10800 MG/L (DAPHNIA
MAGNA)
EC50 48 H:
=2 MG/L STATIC (DAPHNIA
MAGNA)
N-BUTYL ALCOHOL EC50: 2041.4 MG/L 5 MIN EC50 48 H:
EC50: 2186 MG/L 30 MIN =1983 MG/L (DAPHNIA
EC50: 3980 MG/L 24 H MAGNA)
EC50: 4400 MG/L 17 H
EC50 48 H:
1897 - 2072 MG/L STATIC
(DAPHNIA MAGNA)
ETHYL ACETATE EC50: 1180 MG/L 5 MIN EC50 48 H:
EC50: 1500 MG/L 15 MIN =560 MG/L STATIC (DAPHNIA
EC50: 5870 MG/L 15 MIN MAGNA)
EC50: 7400 MG/L 2 H
CARBON BLACK EC50 24 H:
>5600 MG/L (DAPHNIA MAGNA)
ISOPROPYL ALCOHOL EC50 48 H:
=13299 MG/L (DAPHNIA
MAGNA)
N-PROPYL ACETATE EC50 24 H:
=318 MG/L (DAPHNIA MAGNA)
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION:
CHEMICAL NAME LOG POW
N-BUTYL ACETATE 1.81
ETHANOL -0.32
N-BUTYL ALCOHOL 0.785
ETHYL ACETATE 0.6
ISOPROPYL ALCOHOL 0.05
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHODS:
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS
CONTAMINATED PACKAGING: DO NOT RE-USE EMPTY CONTAINERS.
US EPA WASTE NUMBER:
D001
U031
CHEMICAL NAME RCRA RCRA - BASIS FOR RCRA - D SERIES RCRA - U SERIES
LISTING WASTES WASTES
N-BUTYL INCLUDED IN WASTE U031
ALCOHOL - STREAM: F039
71-36-3
ETHYL ACETATE INCLUDED IN WASTE U112
- 141-78-6 STREAM: F039
THIS PRODUCT CONTAINS ONE OR MORE SUBSTANCES THAT ARE LISTED WITH THE STATE
OF CALIFORNIA AS A HAZARDOUS WASTE.
CHEMICAL NAME CALIFORNIA HAZARDOUS WASTE
N-BUTYL ACETATE TOXIC
ETHANOL TOXIC
IGNITABLE
N-BUTYL ALCOHOL TOXIC
ETHYL ACETATE TOXIC
IGNITABLE
ISOPROPYL ALCOHOL TOXIC
IGNITABLE
N-PROPYL ACETATE TOXIC
IGNITABLE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
REPORTABLE QUANTITY (RQ):
N-BUTYL ACETATE:
RQ KG: 5141.85
ETHYL ACETATE:
RQ KG: 21597.45
1-BUTANOL:
RQ KG: 14073.64
MARINE POLLUTANT:
THIS PRODUCT CONTAINS A CHEMICAL WHICH IS LISTED AS A SEVERE MARINE
POLLUTANT ACCORDING TO DOT.
DESCRIPTION: UN1263, PAINT, 3, II, RQ
EMERGENCY RESPONSE GUIDE NUMBER: 128
TDG:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
MARINE POLLUTANT:
THIS PRODUCT CONTAINS A CHEMICAL WHICH IS LISTED AS A SEVERE MARINE
POLLUTANT ACCORDING TO TDG.
DESCRIPTION: UN1263, PAINT, 3, II
MEX:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
DESCRIPTION: UN1263, PAINT, 3, II
ICAO:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
DESCRIPTION: UN1263, PAINT, 3, II
IATA:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
ERG CODE: 3L
DESCRIPTION: UN1263, PAINT, 3, II
IMDG/IMO:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
EMS NO.: F-E, S-E
DESCRIPTION: UN1263, PAINT, 3, II, (-4.444 DEG. C C.C.)
RID:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
CLASSIFICATION CODE: F1
DESCRIPTION: UN1263, PAINT, 3, II
ADR:
UN-NUMBER: UN1263
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
CLASSIFICATION CODE: F1
TUNNEL RESTRICTION CODE: (D/E)
DESCRIPTION: UN1263, PAINT, 3, II, (D/E)
ADR/RID-LABELS: 3
ADN:
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
PACKING GROUP: II
CLASSIFICATION CODE: F1
SPECIAL PROVISIONS: 163, 640C, 650
DESCRIPTION: UN1263, PAINT, 3, II
LIMITED QUANTITY: 5 L
VENTILATION: VE01
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: COMPLIES
IECSC:
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
U.S. FEDERAL REGULATIONS:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT CONTAINS A CHEMICAL OR CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372:
CHEMICAL NAME CAS-NO WEIGHT % SARA 313 - THRESHOLD
VALUES %
N-BUTYL ALCOHOL 71-36-3 10-30 10
ISOPROPYL ALCOHOL 67-63-0 1-5 1.0
BENZOIC ACID, 15782-06-6 1-5 1.0
2-[(2-HYDROXY-3,6-
DISULFO-1-NAPHTHALENYL)
AZO]-, BARIUM SALT (2:3)
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: YES
SUDDEN RELEASE OF PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
CLEAN WATER ACT:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES WHICH ARE REGULATED
POLLUTANTS PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR
122.42):
CHEMICAL NAME CWA - REPORTABLE CWA - TOXIC CWA - PRIORITY CWA -
QUANTITIES POLLUTANTS POLLUTANTS HAZARDOUS
SUBSTANCES
N-BUTYL 5000 LB X
ACETATE
CERCLA:
THIS MATERIAL, AS SUPPLIED, CONTAINS ONE OR MORE SUBSTANCES REGULATED AS A
HAZARDOUS SUBSTANCE UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302):
CHEMICAL NAME HAZARDOUS SUBSTANCES EXTREMELY HAZARDOUS RQ
RQS SUBSTANCES RQS
N-BUTYL 5000 LB RQ:
ACETATE 5000 LB FINAL RQ
RQ:
2270 KG FINAL RQ
N-BUTYL 5000 LB RQ:
ALCOHOL 5000 LB FINAL RQ
RQ:
2270 KG FINAL RQ
ETHYL ACETATE 5000 LB RQ:
5000 LB FINAL RQ
RQ:
2270 KG FINAL RQ
U.S. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS THE FOLLOWING PROPOSITION 65 CHEMICALS:
ETHYL ALCOHOL IS ONLY CONSIDERED A PROPOSITION 65 DEVELOPMENTAL HAZARD WHEN
IT IS INGESTED AS AN ALCOHOLIC BEVERAGE.
CHEMICAL NAME CAS-NO CALIFORNIA PROP. 65
ETHANOL 64-17-5 DEVELOPMENTAL
TITANIUM DIOXIDE 13463-67-7 CARCINOGEN
CARBON BLACK 1333-86-4 CARCINOGEN
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA ILLINOIS RHODE
ISLAND
N-BUTYL ACETATE X X X X
ETHANOL X X X
N-BUTYL ALCOHOL X X X X
ETHYL ACETATE X X X X
TITANIUM DIOXIDE X X
NITROCELLULOSE X X X X
CARBON BLACK X X X X X
ISOPROPYL X X X X
ALCOHOL
N-PROPYL ACETATE X X X X
TRIPHENYL X X X X
PHOSPHATE
PROPYLENE GLYCOL X X X X
MONOMETHYL ETHER
U.S. EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: NOT APPLICABLE
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARD 2
FLAMMABILITY 3
INSTABILITY 0
PHYSICAL AND CHEMICAL HAZARDS
HMIS:
HEALTH HAZARD 2
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
PREPARED BY:
PRODUCT STEWARDSHIP
23 BRITISH AMERICAN BLVD.
LATHAM, NY 12110
1-800-572-6501
ISSUING DATE: 01-MAY-2014
REVISION DATE: 01-MAY-2014
REVISION NOTE: INITIAL RELEASE.
GENERAL DISCLAIMER:
THE INFORMATION PROVIDED ON THIS SDS IS CORRECT TO THE BEST OF OUR
KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION. THE
INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT TO BE
CONSIDERED AS A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION RELATES
ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH
MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS,
UNLESS SPECIFIED IN THE TEXT.
WPS-ITW-029 - DYKEM OPAQUE STAIN - ALL COLORS