| Common Name: | PHASE III ACID TEST KIT (S) (4320S), PHASE III REFRIGERATION OIL TEST KIT (L)(43 |
| Manufacturer: | NU-CALGON WHOLESALER |
| SDS Revision Date: | 8/7/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 22NV34 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
NU-CALGON
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PHASE III ACID TEST KIT (S) (4320S)
(PART OF 4320-W8 TO BE USED IN CONJUNCTION WITH PHASE III REFRIGERATION OIL
TEST REAGENT (L)(4320L)
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE: ACID TEST KIT
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER:
COMPANY NAME: NU-CALGON
ADDRESS:
2008 ALTOM COURT
ST. LOUIS, MO 63146
UNITED STATES
TELEPHONE: 314-469-7000 / 800-554-5499
E-MAIL: INFO@NUCALGON.COM
EMERGENCY PHONE NUMBER: 1-800-424-9300 (CHEMTREC)
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS: NOT CLASSIFIED.
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
HAZARD SYMBOL: NONE.
SIGNAL WORD: NONE.
HAZARD STATEMENT:
THE MIXTURE DOES NOT MEET THE CRITERIA FOR CLASSIFICATION.
PRECAUTIONARY STATEMENT:
PREVENTION: OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES.
RESPONSE: WASH HANDS AFTER HANDLING.
STORAGE: STORE AWAY FROM INCOMPATIBLE MATERIALS.
DISPOSAL:
DISPOSE OF WASTE AND RESIDUES IN ACCORDANCE WITH LOCAL AUTHORITY
REQUIREMENTS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NOT APPLICABLE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
INGREDIENTS NOT IDENTIFIED ARE PROPRIETARY OR NON-HAZARDOUS BY GHS
CRITERIA.
| 4. FIRST AID MEASURES | |
INHALATION:
IF SYMPTOMS DEVELOP MOVE VICTIM TO FRESH AIR. IF SYMPTOMS PERSIST, OBTAIN
MEDICAL ATTENTION.
SKIN CONTACT:
FLUSH WITH COOL WATER. WASH WITH SOAP AND WATER. OBTAIN MEDICAL ATTENTION
IF IRRITATION PERSISTS.
EYE CONTACT:
FLUSH WITH COOL WATER. REMOVE CONTACT LENSES, IF APPLICABLE, AND CONTINUE
FLUSHING. OBTAIN MEDICAL ATTENTION IF IRRITATION PERSISTS.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. IF VOMITING OCCURS
NATURALLY, HAVE VICTIM LEAN FORWARD TO REDUCE RISK OF ASPIRATION. NEVER
GIVE ANYTHING BY MOUTH IF VICTIM IS UNCONSCIOUS, OR IS CONVULSING.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
TREAT SYMPTOMATICALLY.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA: TREAT FOR SURROUNDING MATERIAL.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS.
GENERAL FIRE HAZARDS: NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP OUT OF LOW AREAS. KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY
FROM AND UPWIND OF SPILL/LEAK. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED
MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. FOR PERSONAL
PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK.
LARGE SPILLS:
DIKE THE SPILLED MATERIAL, WHERE THIS IS POSSIBLE. COVER WITH PLASTIC SHEET
TO PREVENT SPREADING. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE
INTO CONTAINERS. PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS OR CONFINED
AREAS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
USE GOOD INDUSTRIAL HYGIENE PRACTICES IN HANDLING THIS MATERIAL.
KEEP OUT OF REACH OF CHILDREN. STORE IN A CLOSED CONTAINER AWAY FROM
INCOMPATIBLE MATERIALS.
WHEN USING, DO NOT EAT, DRINK OR SMOKE.
AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ORIGINAL TIGHTLY CLOSED CONTAINER. STORE AWAY FROM INCOMPATIBLE
MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS: NO EXPOSURE LIMITS NOTED FOR INGREDIENT(S).
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION:
HAND PROTECTION:
FOLLOW STANDARD INDUSTRIAL HYGIENE PRACTICES.
RUBBER GLOVES. CONFIRM WITH A REPUTABLE SUPPLIER FIRST.
OTHER: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR
PHYSICAL STATE: LIQUID.
FORM: LIQUID.
COLOR: COLORLESS
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NOT AVAILABLE.
PH: 10.9 (CONCENTRATE)
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
POUR POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: 0.9048
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE
FLASH POINT: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES): COMPLETE
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
BULK DENSITY: 7.54 LB/GAL
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: THIS PRODUCT MAY REACT WITH STRONG OXIDIZING AGENTS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID:
AVOID TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO:
OXIDES OF CARBON WHEN HEATED TO DECOMPOSITION.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION: MAY CAUSE STOMACH DISTRESS, NAUSEA OR VOMITING.
INHALATION: NO ADVERSE EFFECTS DUE TO INHALATION ARE EXPECTED.
SKIN CONTACT: NO ADVERSE EFFECTS DUE TO SKIN CONTACT ARE EXPECTED.
EYE CONTACT: DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS: DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT AVAILABLE.
SKIN CORROSION/IRRITATION:
PROLONGED SKIN CONTACT MAY CAUSE TEMPORARY IRRITATION.
EXPOSURE MINUTES: NOT AVAILABLE.
ERYTHEMA VALUE: NOT AVAILABLE.
OEDEMA VALUE: NOT AVAILABLE.
SERIOUS EYE DAMAGE/EYE IRRITATION:
DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
CORNEAL OPACITY VALUE: NOT AVAILABLE.
IRIS LESION VALUE: NOT AVAILABLE.
CONJUNCTIVAL REDDENING VALUE: NOT AVAILABLE.
CONJUNCTIVAL OEDEMA VALUE: NOT AVAILABLE.
RECOVER DAYS: NOT AVAILABLE.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT AVAILABLE.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT AVAILABLE.
CHRONIC EFFECTS:
THE FINISHED PRODUCT IS NOT EXPECTED TO HAVE CHRONIC HEALTH EFFECTS.
FURTHER INFORMATION:
THIS PRODUCT HAS NO KNOWN ADVERSE EFFECT ON HUMAN HEALTH.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: THIS PRODUCT HAS NOT BEEN TESTED.
PERSISTENCE AND DEGRADABILITY: THIS PRODUCT HAS NOT BEEN TESTED.
BIOACCUMULATIVE POTENTIAL: NOT DETERMINED
MOBILITY IN SOIL: NOT AVAILABLE.
MOBILITY IN GENERAL: NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION (DOT): NOT REGULATED AS DANGEROUS GOODS.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: NO
DELAYED HAZARD: NO
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING): NOT REGULATED.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
US STATE REGULATIONS:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65):
THIS MATERIAL IS NOT KNOWN TO CONTAIN ANY CHEMICALS CURRENTLY LISTED AS
CARCINOGENS OR REPRODUCTIVE TOXINS.
US - CALIFORNIA PROPOSITION 65 - CARCINOGENS & REPRODUCTIVE TOXICITY (CRT):
LISTED SUBSTANCE
NOT LISTED.
US. MASSACHUSETTS RTK - SUBSTANCE LIST: NOT REGULATED.
US. PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES: NOT REGULATED.
US. RHODE ISLAND RTK: NOT REGULATED.
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION (YES/NO)*
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THIS PRODUCT COMPLIES WITH THE INVENTORY REQUIREMENTS
ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
LEGEND:
SEVERE 4
SERIOUS 3
MODERATE 2
SLIGHT 1
MINIMAL 0
HEALTH / 1
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA:
0
1
0
DISCLAIMER:
INFORMATION CONTAINED HEREIN WAS OBTAINED FROM SOURCES CONSIDERED
TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY EFFORT HAS BEEN MADE TO
ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME CASES DATA IS NOT
AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL PRODUCT USE ARE
BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF THIS MATERIAL
HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL APPLICABLE
LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED OR IMPLIED,
IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES, INJURIES OR
CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR RELIANCE ON ANY
INFORMATION CONTAINED IN THIS DOCUMENT.
ISSUE DATE: 07-AUGUST-2014
FURTHER INFORMATION:
FOR AN UPDATED SDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED IN THE
BEGINNING OF THIS DOCUMENT.
OTHER INFORMATION:
THIS SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE CURRENT OSHA HAZARD
COMMUNICATION STANDARD (HCS) ADOPTION OF THE GLOBALLY HARMONIZED SYSTEM OF
CLASSIFICATION AND LABELING OF CHEMICALS (GHS).
PREPARED BY:
NU-CALGON TECHNICAL SERVICE PHONE: (314) 469-7000
#25042
NU-CALGON
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT IDENTIFIER: PHASE III REFRIGERATION OIL TEST KIT (L)(4320L) - GHS
(PART OF 4320-W8 TO BE USED IN CONJUNCTION WITH PHASE III ACID TEST REAGENT
(S)(4320S)
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE: REFRIGERATION OIL TEST KIT
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER:
COMPANY NAME: NU-CALGON
ADDRESS:
2008 ALTOM COURT
ST. LOUIS, MO 63146
UNITED STATES
TELEPHONE: 314-469-7000 / 800-554-5499
E-MAIL: INFO@NUCALGON.COM
EMERGENCY PHONE NUMBER: 1-800-424-9300 (CHEMTREC)
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE LIQUIDS: CATEGORY 1
HEALTH HAZARDS:
ACUTE TOXICITY, ORAL: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
GERM CELL MUTAGENICITY: CATEGORY 2
CARCINOGENICITY: CATEGORY 1B
REPRODUCTIVE TOXICITY (FERTILITY, THE UNBORN CHILD): CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 2
ASPIRATION HAZARD: CATEGORY 1
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE LIQUID AND VAPOR. HARMFUL IF SWALLOWED. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE
IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. SUSPECTED OF CAUSING GENETIC
DEFECTS. MAY CAUSE CANCER. SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN
CHILD. CAUSES DAMAGE TO ORGANS. MAY CAUSE DAMAGE TO ORGANS THROUGH
PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. KEEP
CONTAINER TIGHTLY CLOSED. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT. USE ONLY
NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
WASH THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE MIST OR VAPOR. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
IN CASE OF FIRE: USE APPROPRIATE MEDIA TO EXTINGUISH.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. RINSE MOUTH. DO NOT INDUCE
VOMITING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
SPECIFIC TREATMENT (SEE THIS LABEL).
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. KEEP COOL.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NOT APPLICABLE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
TOLUENE 108-88-3 43.65
METHANOL 67-56-1 32.14
ISOPROPANOL 67-63-0 22.82
PHENOLPHTHALEIN 77-09-8 1.39
| 4. FIRST AID MEASURES | |
INHALATION:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
SKIN CONTACT:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
INGESTION:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING. RINSE
MOUTH.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. SKIN IRRITATION. VAPORS HAVE A NARCOTIC EFFECT AND MAY CAUSE
HEADACHE, FATIGUE, DIZZINESS AND NAUSEA. PROLONGED EXPOSURE MAY CAUSE
CHRONIC EFFECTS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. IN CASE OF
SHORTNESS OF BREATH, GIVE OXYGEN. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. IF EXPOSED OR CONCERNED: GET
MEDICAL ADVICE/ATTENTION. TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING
AND WASH IT BEFORE REUSE.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE. ALCOHOL FOAM. WATER SPRAY. DRY CHEMICAL. FOG.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS MAY TRAVEL CONSIDERABLE
DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. DURING FIRE, GASES
HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES. MOVE CONTAINERS FROM
FIRE AREA IF YOU CAN DO SO WITHOUT RISK.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS.
GENERAL FIRE HAZARDS: EXTREMELY FLAMMABLE LIQUID AND VAPOR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP OUT OF LOW AREAS. KEEP PEOPLE AWAY
FROM AND UPWIND OF SPILL/LEAK. ELIMINATE ALL IGNITION SOURCES (NO SMOKING,
FLARES, SPARKS, OR FLAMES IN IMMEDIATE AREA). WEAR APPROPRIATE PROTECTIVE
EQUIPMENT AND CLOTHING DURING CLEAN-UP. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID
INHALATION OF VAPORS OR MISTS. VENTILATE CLOSED SPACES BEFORE ENTERING
THEM. LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT
BE CONTAINED. FOR PERSONAL PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. USE
ONLY NON-SPARKING TOOLS. KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY
FROM SPILLED MATERIAL. THIS PRODUCT IS MISCIBLE IN WATER. STOP THE FLOW OF
MATERIAL, IF THIS IS WITHOUT RISK.
LARGE SPILLS:
DIKE THE SPILLED MATERIAL, WHERE THIS IS POSSIBLE. COVER WITH PLASTIC SHEET
TO PREVENT SPREADING. USE A NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND
OR EARTH TO SOAK UP THE PRODUCT AND PLACE INTO A CONTAINER FOR LATER
DISPOSAL. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE INTO
CONTAINERS. PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS OR CONFINED
AREAS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. VAPORS MAY FORM EXPLOSIVE
MIXTURES WITH AIR. DO NOT HANDLE, STORE OR OPEN NEAR AN OPEN FLAME, SOURCES
OF HEAT OR SOURCES OF IGNITION. PROTECT MATERIAL FROM DIRECT SUNLIGHT. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. ALL EQUIPMENT USED WHEN
HANDLING THE PRODUCT MUST BE GROUNDED. USE NON-SPARKING TOOLS AND
EXPLOSION-PROOF EQUIPMENT. DO NOT BREATHE MIST OR VAPOR. DO NOT TASTE OR
SWALLOW. AVOID CONTACT DURING PREGNANCY/WHILE NURSING. AVOID CONTACT WITH
EYES, SKIN AND CLOTHING. AVOID PROLONGED EXPOSURE. PROVIDE ADEQUATE
VENTILATION. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. OBSERVE GOOD
INDUSTRIAL HYGIENE PRACTICES. USE PERSONAL PROTECTIVE EQUIPMENT AS
REQUIRED. WHEN USING, DO NOT EAT, DRINK OR SMOKE. WASH HANDS THOROUGHLY
AFTER HANDLING.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. KEEP
CONTAINER TIGHTLY CLOSED. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT. USE ONLY
NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
STORE LOCKED UP. STORE IN A COOL, DRY PLACE OUT OF DIRECT SUNLIGHT. STORE
IN A WELL-VENTILATED PLACE. STORE IN COOL PLACE. STORE AWAY FROM
INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS). KEEP OUT OF THE REACH
OF CHILDREN. KEEP IN AN AREA EQUIPPED WITH SPRINKLERS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
ISOPROPANOL (CAS 67-63-0) PEL 980 MG/M3
400 PPM
METHANOL (CAS 67-56-1) PEL 260 MG/M3
200 PPM
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
TOLUENE (CAS 108-88-3) CEILING 300 PPM
TWA 200 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
ISOPROPANOL (CAS 67-63-0) STEL 400 PPM
TWA 200 PPM
METHANOL (CAS 67-56-1) STEL 250 PPM
TWA 200 PPM
TOLUENE (CAS 108-88-3) TWA 20 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
ISOPROPANOL (CAS 67-63-0) STEL 1225 MG/M3
500 PPM
TWA 980 MG/M3
400 PPM
METHANOL (CAS 67-56-1) STEL 325 MG/M3
250 PPM
TWA 260 MG/M3
200 PPM
TOLUENE (CAS 108-88-3) STEL 560 MG/M3
150 PPM
TWA 375 MG/M3
100 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING
TIME
ISOPROPANOL (CAS 67-63-0) 40 MG/L ACETONE URINE *
METHANOL (CAS 67-56-1) 15 MG/L METHANOL URINE *
TOLUENE (CAS 108-88-3) 0.3 MG/G O-CRESOL, WITH CREATININE *
HYDROLYSIS IN URINE
0.03 MG/L TOLUENE URINE *
0.02 MG/L TOLUENE BLOOD *
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US ACGIH THRESHOLD LIMIT VALUES: SKIN DESIGNATION
METHANOL (CAS 67-56-1) CAN BE ABSORBED THROUGH THE SKIN.
US. CALIFORNIA CODE OF REGULATIONS, TITLE 8, SECTION 5155. AIRBORNE
CONTAMINANTS:
METHYL ALCOHOL; METHANOL (CAS 67-56-1) CAN BE ABSORBED THROUGH THE SKIN.
TOLUENE; TOLUOL (CAS 108-88-3) CAN BE ABSORBED THROUGH THE SKIN.
US. MINNESOTA HAZARDOUS SUBSTANCES LIST (MINN. RULES 5206.0400).:
METHANOL (CAS 67-56-1) SKIN DESIGNATION APPLIES.
TOLUENE (CAS 108-88-3) SKIN DESIGNATION APPLIES.
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
METHANOL (CAS 67-56-1) CAN BE ABSORBED THROUGH THE SKIN.
US. TENNESSEE. OELS. OCCUPATIONAL EXPOSURE LIMITS, TABLE Z1A:
METHANOL (CAS 67-56-1) CAN BE ABSORBED THROUGH THE SKIN.
APPROPRIATE ENGINEERING CONTROLS:
EXPLOSION-PROOF GENERAL AND LOCAL EXHAUST VENTILATION. GOOD GENERAL
VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION
RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO
MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE
LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE
LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE AVAILABLE WHEN
HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
OTHER: WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW
RECOMMENDED EXPOSURE LIMITS (WHERE APPLICABLE) OR TO AN ACCEPTABLE LEVEL
(IN COUNTRIES WHERE EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED), AN APPROVED
RESPIRATOR MUST BE WORN. WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS (SCBA). IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE
RESPIRATORY EQUIPMENT.
THERMAL HAZARDS: NOT APPLICABLE.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING, DO NOT EAT, DRINK OR SMOKE. ALWAYS OBSERVE GOOD PERSONAL
HYGIENE MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE
EATING, DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND
PROTECTIVE EQUIPMENT TO REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR
PHYSICAL STATE: LIQUID.
FORM: LIQUID.
COLOR: COLORLESS
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: <212 DEG. F (<100 DEG. C)
POUR POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: 0.9168
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
FLASH POINT: <55.4 DEG. F (<13.0 DEG. C)
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES): COMPLETE
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
BULK DENSITY: 7.64 LBS/GALLON
FLASH POINT CLASS: FLAMMABLE IB
VOC (WEIGHT %): 100%
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: THIS PRODUCT MAY REACT WITH OXIDIZING AGENTS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. AVOID
TEMPERATURES EXCEEDING THE FLASH POINT. DO NOT MIX WITH OTHER CHEMICALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS. ACIDS. CAUSTICS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
INHALATION:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. VAPORS HAVE A NARCOTIC EFFECT
AND MAY CAUSE HEADACHE, FATIGUE, DIZZINESS AND NAUSEA. PROLONGED INHALATION
MAY BE HARMFUL. MAY CAUSE DAMAGE TO ORGANS BY INHALATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. SYMPTOMS OF
OVEREXPOSURE MAY BE HEADACHE, DIZZINESS, TIREDNESS, NAUSEA AND VOMITING.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. NARCOTIC EFFECTS.
COMPONENTS SPECIES TEST RESULTS
ISOPROPANOL (CAS 67-63-0)
ACUTE:
DERMAL:
LD50 RABBIT 12800 MG/KG
INHALATION:
LC50 RAT 16970 MG/L/4H
ORAL:
LD50 DOG 4797 MG/KG
MOUSE 3600 MG/KG
RABBIT 5030 MG/KG
RAT 4396 MG/KG
METHANOL (CAS 67-56-1)
ACUTE:
DERMAL:
LD50 RABBIT 15800 - 20000 MG/KG
RAT >450000 MG/KG
INHALATION:
LC50 CAT 85.4 MG/L/4H
43.7 MG/L, 6 HOURS
RAT 64000 PPM, 4 HOURS
87.5 MG/L, 6 HOURS
83.2 - 128.8 MG/L/4H
ORAL:
LD50 DOG 8000 MG/KG
HUMAN 143 - 300 MG/KG
MONKEY 3000 MG/KG
2000 MG/KG
MOUSE 7300 MG/KG
RABBIT 14200 - 14400 MG/KG
RAT 790 - 13000 MG/KG
PHENOLPHTHALEIN (CAS 77-09-8)
ACUTE:
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 RAT 1000 MG/KG
TOLUENE (CAS 108-88-3)
ACUTE:
DERMAL:
LD50 RABBIT 12125 MG/KG
8390 MG/KG
14.1 ML/KG
INHALATION:
LC50 MOUSE 7100 MG/L, 4 HOURS
5320 PPM, 8 HOURS
400 PPM, 24 HOURS
RAT 26700 PPM, 1 HOURS
12200 PPM, 2 HOURS
8000 PPM, 4 HOURS
12.5 MG/L/4H
ORAL:
LD50 RAT 636 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
EXPOSURE MINUTES: NOT AVAILABLE.
ERYTHEMA VALUE: NOT AVAILABLE.
OEDEMA VALUE: NOT AVAILABLE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
CORNEAL OPACITY: VALUE NOT AVAILABLE.
IRIS LESION VALUE: NOT AVAILABLE.
CONJUNCTIVAL REDDENING VALUE: NOT AVAILABLE.
CONJUNCTIVAL OEDEMA VALUE: NOT AVAILABLE.
RECOVER DAYS: NOT AVAILABLE.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT AVAILABLE.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY: SUSPECTED OF CAUSING GENETIC DEFECTS.
CARCINOGENICITY: MAY CAUSE CANCER.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
PHENOLPHTHALEIN (CAS 77-09-8) 2B POSSIBLY CARCINOGENIC TO HUMANS.
TOLUENE (CAS 108-88-3) 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY
TO HUMANS.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS:
PHENOLPHTHALEIN (CAS 77-09-8) REASONABLY ANTICIPATED TO BE A HUMAN
CARCINOGEN.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS. NARCOTIC EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CHRONIC EFFECTS:
PROLONGED INHALATION MAY BE HARMFUL. MAY CAUSE DAMAGE TO ORGANS THROUGH
PROLONGED OR REPEATED EXPOSURE.
FURTHER INFORMATION: NOT AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: SEE BELOW
COMPONENTS SPECIES TEST RESULTS
ISOPROPANOL (CAS 67-63-0)
ALGAE IC50 ALGAE 1000 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 13299 MG/L, 48 HOURS
AQUATIC:
FISH LC50 BLUEGILL (LEPOMIS MACROCHIRUS) >1400 MG/L, 96 HOURS
METHANOL (CAS 67-56-1)
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) >10000 MG/L, 48 HOURS
FISH LC50 FATHEAD MINNOW (PIMEPHALES >100 MG/L, 96 HOURS
PROMELAS)
TOLUENE (CAS 108-88-3)
ALGAE IC50 ALGAE 433 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 7.645 MG/L, 48 HOURS
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 5.46 - 9.83 MG/L, 48 HOURS
FISH LC50 COHO SALMON, SILVER SALMON 8.11 MG/L, 96 HOURS
(ONCORHYNCHUS KISUTCH)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
ISOPROPANOL 0.05
METHANOL -0.77
PHENOLPHTHALEIN 2.41
TOLUENE 2.73
MOBILITY IN SOIL: NO DATA AVAILABLE.
MOBILITY IN GENERAL: NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS
HAZARDOUS WASTE. INCINERATE THE MATERIAL UNDER CONTROLLED CONDITIONS IN AN
APPROVED INCINERATOR. DO NOT INCINERATE SEALED CONTAINERS. DO NOT ALLOW
THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO NOT CONTAMINATE
PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED CONTAINER. IF DISCARDED,
THIS PRODUCT IS CONSIDERED A RCRA IGNITABLE WASTE, D001. DISPOSE OF
CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL
REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
D001: WASTE FLAMMABLE MATERIAL WITH A FLASH POINT <140 F
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
US RCRA HAZARDOUS WASTE U LIST: REFERENCE
METHANOL (CAS 67-56-1) U154
TOLUENE (CAS 108-88-3) U220
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION (DOT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1993
PROPER SHIPPING NAME: FLAMMABLE LIQUIDS, N.O.S. (TOLUENE, METHANOL)
HAZARD CLASS: LIMITED QUANTITY - US
PACKING GROUP: II
SPECIAL PROVISIONS: IB2, T7, TP1, TP8, TP28
PACKAGING EXCEPTIONS: <0.3 G -LIMITED QUANTITY
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1993
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (TOLUENE, METHANOL)
HAZARD CLASS: LIMITED QUANTITY - CANADA
PACKING GROUP: II
SPECIAL PROVISIONS: 16
PACKAGING EXCEPTIONS: <1L - LIMITED QUANTITY
DOT; TDG: LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
ISOPROPANOL (CAS 67-63-0) LISTED.
METHANOL (CAS 67-56-1) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: YES
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
TOLUENE 108-88-3 43.65
METHANOL 67-56-1 32.14
ISOPROPANOL 67-63-0 22.82
PHENOLPHTHALEIN 77-09-8 1.39
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
METHANOL (CAS 67-56-1)
TOLUENE (CAS 108-88-3)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): NOT REGULATED.
CLEAN WATER ACT (CWA) SECTION 112(R) (40 CFR 68.130):
HAZARDOUS SUBSTANCE
PRIORITY POLLUTANT
TOXIC POLLUTANT
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 2, ESSENTIAL CHEMICALS (21 CFR
1310.02(B) AND 1310.04(F)(2) AND CHEMICAL CODE NUMBER:
TOLUENE (CAS 108-88-3) 6594
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 1 & 2 EXEMPT CHEMICAL MIXTURES
(21 CFR 1310.12(C)):
TOLUENE (CAS 108-88-3) 35%WV
DEA EXEMPT CHEMICAL MIXTURES CODE NUMBER:
TOLUENE (CAS 108-88-3) 594
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
US STATE REGULATIONS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA HAZARDOUS SUBSTANCES (DIRECTOR'S): LISTED SUBSTANCE
ISOPROPANOL (CAS 67-63-0) LISTED.
METHANOL (CAS 67-56-1) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - CALIFORNIA PROPOSITION 65 - CARCINOGENS & REPRODUCTIVE TOXICITY (CRT):
LISTED SUBSTANCE
METHANOL (CAS 67-56-1) LISTED.
PHENOLPHTHALEIN (CAS 77-09-8) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - ILLINOIS CHEMICAL SAFETY ACT: LISTED SUBSTANCE
ISOPROPANOL (CAS 67-63-0) LISTED.
METHANOL (CAS 67-56-1) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - LOUISIANA SPILL REPORTING: LISTED SUBSTANCE
ISOPROPANOL (CAS 67-63-0) LISTED.
METHANOL (CAS 67-56-1) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - MICHIGAN CRITICAL MATERIALS REGISTER: PARAMETER NUMBER
TOLUENE (CAS 108-88-3) 00108-88-3 LISTED.
US - MINNESOTA HAZ SUBS: LISTED SUBSTANCE
ISOPROPANOL (CAS 67-63-0) LISTED.
METHANOL (CAS 67-56-1) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - NEW JERSEY RTK - SUBSTANCES: LISTED SUBSTANCE
ISOPROPANOL (CAS 67-63-0) LISTED.
METHANOL (CAS 67-56-1) LISTED.
PHENOLPHTHALEIN (CAS 77-09-8) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - NEW YORK RELEASE REPORTING: HAZARDOUS SUBSTANCES: LISTED SUBSTANCE
METHANOL (CAS 67-56-1) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - NORTH CAROLINA TOXIC AIR POLLUTANTS: LISTED SUBSTANCE
TOLUENE (CAS 108-88-3) LISTED.
US - WASHINGTON CHEMICAL OF HIGH CONCERN TO CHILDREN: LISTED SUBSTANCE
TOLUENE (CAS 108-88-3) LISTED.
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
ISOPROPANOL (CAS 67-63-0) LISTED.
METHANOL (CAS 67-56-1) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US. PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES:
ISOPROPANOL (CAS 67-63-0) LISTED.
METHANOL (CAS 67-56-1) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US. RHODE ISLAND RTK:
ISOPROPANOL (CAS 67-63-0) LISTED.
METHANOL (CAS 67-56-1) LISTED.
PHENOLPHTHALEIN (CAS 77-09-8) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION (YES/NO)*
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THIS PRODUCT COMPLIES WITH THE INVENTORY REQUIREMENTS
ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
HEALTH 2*
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA:
2
3
0
LEGEND:
SEVERE 4
SERIOUS 3
MODERATE 2
SLIGHT 1
MINIMAL 0
DISCLAIMER:
THE INFORMATION IN THE SHEET WAS WRITTEN BASED ON THE BEST KNOWLEDGE AND
EXPERIENCE CURRENTLY AVAILABLE. INFORMATION CONTAINED HEREIN WAS OBTAINED
FROM SOURCES CONSIDERED TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY
EFFORT HAS BEEN MADE TO ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME
CASES DATA IS NOT AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL
PRODUCT USE ARE BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF
THIS MATERIAL HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL
APPLICABLE LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED
OR IMPLIED, IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES,
INJURIES OR CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR
RELIANCE ON ANY INFORMATION CONTAINED IN THIS DOCUMENT.
ISSUE DATE: 07-AUGUST-2014
FURTHER INFORMATION:
FOR AN UPDATED SDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED IN THE
BEGINNING OF THIS DOCUMENT.
OTHER INFORMATION:
THIS SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE CURRENT OSHA HAZARD
COMMUNICATION STANDARD (HCS) ADOPTION OF THE GLOBALLY HARMONIZED SYSTEM OF
CLASSIFICATION AND LABELING OF CHEMICALS (GHS).
PREPARED BY: NU-CALGON TECHNICAL SERVICE
PHONE: (314) 469-7000
#25043