| Common Name: | A/C EASYSEAL (4050-06, 4050-01, 4050-02, 4050-10) |
| Manufacturer: | NU-CALGON WHOLESALER |
| SDS Revision Date: | 1/12/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 13D662, 13D663, 13D664 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
NU-CALGON
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER: A/C EASYSEAL (4050-06, 4050-01, 4050-02, 4050-10)
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE: LEAK SEALANT FOR REFRIGERATION AND AC SYSTEMS
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER:
NU-CALGON
2008 ALTOM COURT
ST. LOUIS, MO 63146
US
PHONE: 314-469-7000 / 800-554-5499
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: LIQUEFIED GAS
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
REPRODUCTIVE TOXICITY (THE UNBORN CHILD): CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 RESPIRATORY TRACT IRRITATION
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT
SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. WASH THOROUGHLY AFTER HANDLING. WEAR
PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
AVOID BREATHING MIST/VAPORS/SPRAY. USE ONLY OUTDOORS OR IN A
WELL-VENTILATED AREA.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT
BEFORE REUSE. SPECIFIC TREATMENT (SEE THIS LABEL).
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
STORE IN A WELL-VENTILATED PLACE.
STORE LOCKED UP. KEEP CONTAINER TIGHTLY CLOSED.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NOT APPLICABLE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
BUTANE 106-97-8 15-40
PROPANE 74-98-6 15-40
TRIETHOXY(VINYL)SILANE 78-08-0 10-30
BENZENE, C14-30-ALKYL DERIVITIVES 68855-24-3 5-10
ETHANOL 64-17-5 5-10
TOLUENE 108-88-3 0.1-1
COMPOSITION COMMENTS:
US GHS:
THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS
A TRADE SECRET IN ACCORDANCE WITH PARAGRAPH (I) OF SUBSECTION 1910.1200.
| 4. FIRST AID MEASURES | |
INHALATION:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
SKIN CONTACT:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT
BEFORE REUSE.
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH IF VICTIM
IS UNCONSCIOUS, OR IS CONVULSING. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS SAFETY DATA SHEET TO THE
DOCTOR IN ATTENDANCE. DO NOT PUNCTURE OR INCINERATE CONTAINER. DO NOT STORE
AT TEMPERATURES ABOVE 49 DEG. C. KEEP AWAY FROM SOURCES OF IGNITION. NO
SMOKING.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2). DRY CHEMICAL. FOAM. WATER FOG.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED TO
HEAT OR FLAME. COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL
AFTER FIRE IS OUT. FIREFIGHTERS SHOULD WEAR A SELF-CONTAINED BREATHING
APPARATUS.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE CLOTHING INCLUDING SELF CONTAINED
BREATHING APPARATUS.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. COOL CONTAINERS EXPOSED TO FLAMES WITH WATER UNTIL WELL AFTER THE
FIRE IS OUT. IN THE EVENT OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
GENERAL FIRE HAZARDS: EXTREMELY FLAMMABLE AEROSOL.
HAZARDOUS COMBUSTION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NOT AVAILABLE.
SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP OUT OF LOW AREAS. KEEP PEOPLE AWAY
FROM AND UPWIND OF SPILL/LEAK. ELIMINATE ALL IGNITION SOURCES (NO SMOKING,
FLARES, SPARKS, OR FLAMES IN IMMEDIATE AREA). MANY GASES ARE HEAVIER THAN
AIR AND WILL SPREAD ALONG GROUND AND COLLECT IN LOW OR CONFINED AREAS
(SEWERS, BASEMENTS, TANKS). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
CLOTHING DURING CLEAN-UP. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED
MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID BREATHING
GAS. VENTILATE CLOSED SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES SHOULD
BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL
PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REFER TO ATTACHED SAFETY DATA SHEETS AND/OR INSTRUCTIONS FOR USE.
EXTINGUISH ALL FLAMES IN THE VICINITY. THIS PRODUCT IS MISCIBLE IN WATER.
STOP LEAK IF YOU CAN DO SO WITHOUT RISK. IF POSSIBLE, TURN LEAKING
CONTAINERS SO THAT GAS ESCAPES RATHER THAN LIQUID. ISOLATE AREA UNTIL GAS
HAS DISPERSED. DIKE FAR AHEAD OF SPILL FOR LATER DISPOSAL. USE WATER SPRAY
TO REDUCE VAPORS OR DIVERT VAPOR CLOUD DRIFT. PREVENT ENTRY INTO WATERWAYS,
SEWER, BASEMENTS OR CONFINED AREAS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA
WITH WATER. FOR WASTE DISPOSAL, SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT CONTAMINATE
WATER. AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT HANDLE, STORE OR OPEN
NEAR AN OPEN FLAME, SOURCES OF HEAT OR SOURCES OF IGNITION. PROTECT
MATERIAL FROM DIRECT SUNLIGHT. ALL EQUIPMENT USED WHEN HANDLING THE PRODUCT
MUST BE GROUNDED. USE ONLY WITH ADEQUATE VENTILATION.
AVOID BREATHING MIST OR VAPOR. AVOID CONTACT DURING PREGNANCY/WHILE
NURSING. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
AVOID PROLONGED EXPOSURE. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. WHEN USING, DO NOT EAT,
DRINK OR SMOKE.
WASH THOROUGHLY AFTER HANDLING. USE GOOD INDUSTRIAL HYGIENE PRACTICES IN
HANDLING THIS MATERIAL.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. PROTECT FROM SUNLIGHT. STORE IN A COOL, DRY PLACE OUT OF
DIRECT SUNLIGHT. STORE IN A WELL-VENTILATED PLACE. STORE AWAY FROM
INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS). KEEP OUT OF REACH OF
CHILDREN. KEEP AWAY FROM HEAT, OPEN FLAMES OR OTHER SOURCES OF IGNITION. DO
NOT EXPOSE TO TEMPERATURES EXCEEDING 122 DEG. F (50 DEG. C).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
ETHANOL (CAS 64-17-5) PEL 1900 MG/M3
1000 PPM
PROPANE (CAS 74-98-6) PEL 1800 MG/M3
1000 PPM
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
TOLUENE (CAS 108-88-3) CEILING 300 PPM
TWA 200 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
BUTANE (CAS 106-97-8) STEL 1000 PPM
ETHANOL (CAS 64-17-5) STEL 1000 PPM
TOLUENE (CAS 108-88-3) TWA 20 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
BUTANE (CAS 106-97-8) TWA 1900 MG/M3
800 PPM
ETHANOL (CAS 64-17-5) TWA 1900 MG/M3
1000 PPM
PROPANE (CAS 74-98-6) TWA 1800 MG/M3
1000 PPM
TOLUENE (CAS 108-88-3) STEL 560 MG/M3
150 PPM
TWA 375 MG/M3
100 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
TOLUENE 0.3 MG/G O-CRESOL, WITH CREATININE *
(CAS 108-88-3) HYDROLYSIS IN URINE
0.03 MG/L TOLUENE URINE *
0.02 MG/L TOLUENE BLOOD *
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION: RUBBER GLOVES. CONFIRM WITH A REPUTABLE SUPPLIER FIRST.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. AS REQUIRED BY EMPLOYER CODE.
RESPIRATORY PROTECTION:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA). WHERE
EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AN APPROVED NIOSH
RESPIRATOR.
THERMAL HAZARDS: NOT APPLICABLE.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING, DO NOT EAT, DRINK OR SMOKE. WASH HANDS AND FACE BEFORE BREAKS
AND IMMEDIATELY AFTER HANDLING THE PRODUCT. ALWAYS OBSERVE GOOD PERSONAL
HYGIENE MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE
EATING, DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND
PROTECTIVE EQUIPMENT TO REMOVE CONTAMINANTS. WHEN USING DO NOT EAT OR
DRINK.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COMPRESSED LIQUEFIED GAS.
PHYSICAL STATE: GAS.
FORM: LIQUEFIED GAS. AEROSOL
COLOR: COLORLESS
ODOR: AMINE
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: 143 DEG. F (61.67 DEG. C)
POUR POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: 9.1
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE
FLASH POINT: 132.2 DEG. F (55.7 DEG. C) TAG CLOSED CUP
EVAPORATION RATE: <1
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: 116.63 HPA
VAPOR DENSITY: >1 (AIR=1)
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES): NOT AVAILABLE
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: THIS PRODUCT MAY REACT WITH STRONG OXIDIZING AGENTS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID:
DO NOT MIX WITH OTHER CHEMICALS. CONTACT WITH INCOMPATIBLE MATERIALS.
AEROSOL CONTAINERS ARE UNSTABLE AT TEMPERATURES ABOVE 49 DEG. C
(120.2 DEG. F).
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. NITRATES. FLUORINE. CHLORINE. ACIDS. CAUSTICS.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON.
| 11. TOXICOLOGICAL INFORMATION | |
ROUTES OF EXPOSURE: EYE, SKIN CONTACT, INHALATION, INGESTION.
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
INHALATION:
PROLONGED INHALATION MAY BE HARMFUL. MAY CAUSE IRRITATION TO THE
RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: MAY CAUSE RESPIRATORY IRRITATION.
COMPONENTS SPECIES TEST RESULTS
BENZENE, C14-30-ALKYL DERIVITIVES (CAS 68855-24-3):
ACUTE:
DERMAL:
LD50 RABBIT >7940 MG/KG
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 RAT >15800 MG/KG
BUTANE (CAS 106-97-8):
ACUTE:
INHALATION:
LC50 MOUSE 680 MG/L, 2 HOURS
RAT 276000 PPM, 4 HOURS
658 MG/L/4H
ORAL:
LD50 NOT AVAILABLE
ETHANOL (CAS 64-17-5):
ACUTE:
DERMAL:
LD50 NOT AVAILABLE
INHALATION:
LC50 MOUSE 39 MG/L, 4 HOURS
RAT 31623 PPM, 4 HOURS
20000 PPM, 10 HOURS
ORAL:
LD50 DOG 5500 MG/KG
GUINEA PIG 5600 MG/KG
MOUSE 3450 MG/KG
RAT 7060 MG/KG
PROPANE (CAS 74-98-6):
ACUTE:
INHALATION:
LC50 RAT >1442.8 MG/L, 15 MINUTES
ORAL:
LD50 NOT AVAILABLE
TOLUENE (CAS 108-88-3):
ACUTE:
DERMAL:
LD50 RABBIT 12196 MG/KG
12125 MG/KG
8390 MG/KG
14.1 ML/KG
INHALATION:
LC50 MOUSE 7100 MG/L, 4 HOURS
5320 PPM, 8 HOURS
400 PPM, 24 HOURS
RAT 26700 PPM, 1 HOURS
<=28800 MG/M3, 4 HOURS
12200 PPM, 2 HOURS
8000 PPM, 4 HOURS
12.5 MG/L/4H
ORAL:
LD50 RAT >5580 MG/KG
636 MG/KG
TRIETHOXY(VINYL)SILANE (CAS 78-08-0):
ACUTE:
DERMAL:
LD50 RABBIT 9100 MG/KG
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 NOT AVAILABLE
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
EXPOSURE MINUTES: NOT AVAILABLE.
ERYTHEMA VALUE: NOT AVAILABLE.
OEDEMA VALUE: NOT AVAILABLE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
CORNEAL OPACITY VALUE: NOT AVAILABLE.
IRIS LESION VALUE: NOT AVAILABLE.
CONJUNCTIVAL REDDENING VALUE: NOT AVAILABLE.
CONJUNCTIVAL OEDEMA VALUE: NOT AVAILABLE.
RECOVER DAYS: NOT AVAILABLE.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT AVAILABLE.
SKIN SENSITIZATION: NOT APPLICABLE.
GERM CELL MUTAGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
MUTAGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
CARCINOGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
ACGIH CARCINOGENS:
TOLUENE (CAS 108-88-3):
A4: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
ETHANOL (CAS 64-17-5):
VOLUME 44, VOLUME 96, VOLUME 100E
VOLUME 96, VOLUME 100E
TOLUENE (CAS 108-88-3):
VOLUME 47, VOLUME 71 - 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
REPRODUCTIVE TOXICITY:
POSSIBLE REPRODUCTIVE HAZARD. SUSPECTED OF DAMAGING THE UNBORN CHILD.
TERATOGENICITY:
TOLUENE (BENZENE, METHYL-) HAS CAUSED FETOTOXICITY (REDUCED FETAL WEIGHT),
BEHAVIOURAL EFFECTS (EFFECTS ON LEARNING AND MEMORY) AND HEARING LOSS (IN
MALES). THESE EFFECTS HAVE BEEN OBSERVED IN THE OFFSPRING OF RATS EXPOSED
BY INHALATION TO 1200 OR 1800 PPM TOLUENE. THESE EFFECTS WERE OBSERVED IN
THE ABSENCE OF MATERNAL TOXICITY.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
RESPIRATORY TRACT IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT LIKELY, DUE TO THE FORM OF THE PRODUCT.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
FURTHER INFORMATION: NOT AVAILABLE.
NAME OF TOXICOLOGICALLY SYNERGISTIC PRODUCTS: NOT AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: SEE BELOW
COMPONENTS SPECIES TEST RESULTS
ETHANOL (CAS 64-17-5):
CRUSTACEA EC50 DAPHNIA 11744.5 MG/L, 48 HOURS
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA 7.7 - 11.2 MG/L,
MAGNA) 48 HOURS
FISH LC50 FATHEAD MINNOW >100 MG/L, 96 HOURS
(PIMEPHALES PROMELAS)
TOLUENE (CAS 108-88-3):
ALGAE IC50 ALGAE 433 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 7.645 MG/L, 48 HOURS
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA 5.46 - 9.83 MG/L,
MAGNA) 48 HOURS
FISH LC50 COHO SALMON, SILVER 8.11 MG/L, 96 HOURS
SALMON (ONCORHYNCHUS
KISUTCH)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
MOBILITY IN SOIL: NO DATA AVAILABLE.
MOBILITY IN GENERAL: NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS. CONSULT AUTHORITIES BEFORE DISPOSAL. THIS
MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE. DO NOT
ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO NOT CONTAMINATE
PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED CONTAINER.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
US RCRA HAZARDOUS WASTE U LIST REFERENCE
TOLUENE (CAS 108-88-3) U220
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION (DOT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE, N.O.S.
HAZARD CLASS: LIMITED QUANTITY - US
SPECIAL PROVISIONS: N82
PACKAGING EXCEPTIONS: 306
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS: LIMITED QUANTITY - CANADA
SPECIAL PROVISIONS: 80
IATA/ICAO (AIR):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS: LIMITED QUANTITY - IATA
ERG CODE: 10L
IMDG (MARINE TRANSPORT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS: LIMITED QUANTITY - US
DOT; IMDG; TDG:
LIMITED QUANTITTY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
IATA: LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS AND THE SDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
CANADA DSL CHALLENGE SUBSTANCES LISTED SUBSTANCE
BUTANE (CAS 106-97-8) LISTED.
CANADA NPRI VOCS WITH ADDITIONAL REPORTING MASS REPORTING THRESHOLD/
REQUIREMENTS IDENTIFICATION NUMBER
BUTANE (CAS 106-97-8) 1 TONNES
ETHANOL (CAS 64-17-5) 1 TONNES
PROPANE (CAS 74-98-6) 1 TONNES
TOLUENE (CAS 108-88-3) 1 TONNES
CANADA WHMIS INGREDIENT DISCLOSURE THRESHOLD LIMITS
BUTANE (CAS 106-97-8) 1%
ETHANOL (CAS 64-17-5) 0.1%
TOLUENE (CAS 108-88-3) 1%
WHMIS STATUS: CONTROLLED
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS B - DIVISION 5 - FLAMMABLE AEROSOL
CLASS D - DIVISION 2A, 2B
WHMIS LABELING:
A - COMPRESSED GAS
B - FLAMMABLE AND COMBUSTIBLE MATERIAL
D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
US EPCRA (SARA TITLE III) SECTION 313 - DE MINIMIS CONCENTRATION
TOXIC CHEMICAL
TOLUENE (CAS 108-88-3) 1.0%
US EPCRA (SARA TITLE III) SECTION 313 - LISTED SUBSTANCE
TOXIC CHEMICAL
TOLUENE (CAS 108-88-3) LISTED.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
US CWA SECTION 311 HAZARDOUS SUBSTANCES LISTED SUBSTANCE
TOLUENE (CAS 108-88-3) LISTED.
US CWA SECTION 307(A)(1) TOXIC POLLUTANTS LISTED SUBSTANCE
TOLUENE (CAS 108-88-3) LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
BUTANE (CAS 106-97-8): LISTED.
PROPANE (CAS 74-98-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
US CAA SECTION 111 VOLATILE ORGANIC COMPOUNDS LISTED SUBSTANCE
ETHANOL (CAS 64-17-5) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US CAA SECTION 112(R) ACCIDENTAL RELEASE LISTED SUBSTANCE
PREVENTION - REGULATED FLAMMABLE SUBSTANCE
BUTANE (CAS 106-97-8) REGULATED FLAMMABLE
SUBSTANCE.
PROPANE (CAS 74-98-6) REGULATED FLAMMABLE
SUBSTANCE.
US CAA SECTION 112(R) ACCIDENTAL THRESHOLD QUANTITY
RELEASE PREVENTION
BUTANE (CAS 106-97-8) 10000 LBS
PROPANE (CAS 74-98-6) 10000 LBS
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130):
BUTANE (CAS 106-97-8): LISTED.
PROPANE (CAS 74-98-6): LISTED.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
TOLUENE (CAS 108-88-3): LISTED.
US CAA SECTION 612 SNAP PROGRAM LISTED SUBSTANCE
BUTANE (CAS 106-97-8) LISTED.
PROPANE (CAS 74-98-6) LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: YES
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING): NOT REGULATED.
OTHER FEDERAL REGULATIONS:
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
US STATE REGULATIONS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA HAZARDOUS SUBSTANCES (DIRECTOR'S) LISTED SUBSTANCE
BUTANE (CAS 106-97-8) LISTED.
ETHANOL (CAS 64-17-5) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - CALIFORNIA PROPOSITION 65 - CARCINOGENS LISTED SUBSTANCE
& REPRODUCTIVE TOXICITY (CRT)
ETHANOL (CAS 64-17-5) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - ILLINOIS CHEMICAL SAFETY ACT LISTED SUBSTANCE
BUTANE (CAS 106-97-8) LISTED.
ETHANOL (CAS 64-17-5) LISTED.
PROPANE (CAS 74-98-6) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - LOUISIANA SPILL REPORTING LISTED SUBSTANCE
BUTANE (CAS 106-97-8) LISTED.
ETHANOL (CAS 64-17-5) LISTED.
PROPANE (CAS 74-98-6) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - MICHIGAN CRITICAL MATERIALS REGISTER PARAMETER NUMBER
TOLUENE (CAS 108-88-3) 00108-88-3 LISTED.
US - MINNESOTA HAZ SUBS LISTED SUBSTANCE
BUTANE (CAS 106-97-8) LISTED.
ETHANOL (CAS 64-17-5) LISTED.
PROPANE (CAS 74-98-6) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - NEW JERSEY RTK - SUBSTANCES LISTED SUBSTANCE
BUTANE (CAS 106-97-8) LISTED.
ETHANOL (CAS 64-17-5) LISTED.
PROPANE (CAS 74-98-6) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - NEW YORK RELEASE REPORTING: LISTED SUBSTANCE
HAZARDOUS SUBSTANCES
TOLUENE (CAS 108-88-3) LISTED.
US - NORTH CAROLINA TOXIC AIR POLLUTANTS LISTED SUBSTANCE
TOLUENE (CAS 108-88-3) LISTED.
US - TEXAS EFFECTS SCREENING LEVELS LISTED SUBSTANCE
BENZENE, C14-30-ALKYL DERIVITIVES (CAS 68855-24-3) LISTED.
BUTANE (CAS 106-97-8) LISTED.
ETHANOL (CAS 64-17-5) LISTED.
PROPANE (CAS 74-98-6) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - WASHINGTON CHEMICAL OF HIGH CONCERN LISTED SUBSTANCE
TO CHILDREN
TOLUENE (CAS 108-88-3) LISTED.
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
BUTANE (CAS 106-97-8): LISTED.
ETHANOL (CAS 64-17-5): LISTED.
PROPANE (CAS 74-98-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
US. PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES:
BUTANE (CAS 106-97-8): LISTED.
ETHANOL (CAS 64-17-5): LISTED.
PROPANE (CAS 74-98-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
US. RHODE ISLAND RTK:
BUTANE (CAS 106-97-8): LISTED.
PROPANE (CAS 74-98-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
INVENTORY STATUS:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
HEALTH 2
FLAMMABILITY 4
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA:
2
4
0
LEGEND:
SEVERE: 4
SERIOUS: 3
MODERATE: 2
SLIGHT: 1
MINIMAL: 0
DISCLAIMER:
THE INFORMATION IN THE SHEET WAS WRITTEN BASED ON THE BEST KNOWLEDGE AND
EXPERIENCE CURRENTLY AVAILABLE. INFORMATION CONTAINED HEREIN WAS OBTAINED
FROM SOURCES CONSIDERED TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY
EFFORT HAS BEEN MADE TO ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME
CASES DATA IS NOT AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL
PRODUCT USE ARE BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF
THIS MATERIAL HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL
APPLICABLE LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED
OR IMPLIED, IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES,
INJURIES OR CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR
RELIANCE ON ANY INFORMATION CONTAINED IN THIS DOCUMENT.
ISSUE DATE: 12-JANUARY-2015
EFFECTIVE DATE: 01-JANUARY-2015
EXPIRY DATE: 01-JANUARY-2018
FURTHER INFORMATION:
FOR AN UPDATED SDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED IN THE
BEGINNING OF THIS DOCUMENT.
PREPARED BY: NU-CALGON TECHNICAL SERVICE
PHONE: (314) 469-7000
OTHER INFORMATION:
THIS SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE CURRENT OSHA HAZARD
COMMUNICATION STANDARD (HCS) ADOPTION OF THE GLOBALLY HARMONIZED SYSTEM OF
CLASSIFICATION AND LABELING OF CHEMICALS (GHS).
THIS SDS CONFORMS TO THE ANSI Z400.1/Z129.1-2010 STANDARD.
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