| Common Name: | CAL-BLAST (4132-20) |
| Manufacturer: | NU-CALGON WHOLESALER |
| SDS Revision Date: | 3/23/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 20LP96 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NU-CALGON
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER: CAL-BLAST(TM) (4132-20)
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE: CLEANER RECOMMENDED
RESTRICTIONS: NONE KNOWN.
MANUFACTURER:
NU-CALGON
2008 ALTOM COURT
ST. LOUIS, MO 63146
US
PHONE: 314-469-7000 / 800-554-5499
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: LIQUEFIED GAS
HEALTH HAZARDS:
ACUTE TOXICITY, ORAL: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SENSITIZATION, SKIN: CATEGORY 1
CARCINOGENICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 RESPIRATORY TRACT IRRITATION
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 2
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
HARMFUL IF SWALLOWED.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
SUSPECTED OF CAUSING CANCER.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT
SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. WASH THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. OBTAIN SPECIAL
INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE
BEEN READ AND UNDERSTOOD.
DO NOT BREATHE GAS. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR
PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF SWALLOWED: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL. RINSE MOUTH.
IF ON SKIN:
WASH WITH PLENTY OF WATER. SPECIFIC TREATMENT (SEE THIS LABEL).
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/
122 DEG. F. KEEP CONTAINER TIGHTLY CLOSED. STORE LOCKED UP. STORE IN A
WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION:
0.6% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN ACUTE ORAL
TOXICITY.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
METHYLENE CHLORIDE 75-09-2 60-100
D-LIMONENE 5989-27-5 1-5
COMPOSITION COMMENTS:
US GHS:
THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS A
TRADE SECRET IN ACCORDANCE WITH PARAGRAPH (I) OF SUBSECTION 1910.1200.
| 4. FIRST AID MEASURES | |
INHALATION:
IF SYMPTOMS DEVELOP, MOVE VICTIM TO FRESH AIR. IF SYMPTOMS PERSIST, OBTAIN
MEDICAL ATTENTION. IF BREATHING HAS STOPPED, TRAINED PERSONNEL SHOULD
ADMINISTER CPR IMMEDIATELY.
SKIN CONTACT:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. SPECIFIC TREATMENT (SEE PRODUCT LABEL).
WASH CONTAMINATED CLOTHING BEFORE REUSE.
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
INGESTION:
IF SWALLOWED: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL. RINSE MOUTH.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. DERMATITIS.
RASH. MAY CAUSE REDNESS AND PAIN. PROLONGED EXPOSURE MAY CAUSE CHRONIC
EFFECTS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. IN CASE OF
SHORTNESS OF BREATH, GIVE OXYGEN. KEEP VICTIM WARM. KEEP VICTIM UNDER
OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE. WASH
CONTAMINATED CLOTHING BEFORE REUSE. AVOID CONTACT WITH EYES AND SKIN.
KEEP OUT OF REACH OF CHILDREN. DO NOT PUNCTURE OR INCINERATE CONTAINER.
DO NOT STORE AT TEMPERATURES ABOVE 49 DEG. C. WEAR RUBBER GLOVES AND
CHEMICAL SPLASH GOGGLES.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA: WATER. FOAM. CARBON DIOXIDE. DRY CHEMICAL.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED TO
HEAT OR FLAME. COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL
AFTER FIRE IS OUT. FIREFIGHTERS SHOULD WEAR A SELF-CONTAINED BREATHING
APPARATUS.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE CLOTHING INCLUDING SELF CONTAINED
BREATHING APPARATUS.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. DO NOT MOVE CARGO OR VEHICLE IF CARGO HAS BEEN
EXPOSED TO HEAT. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. USE WATER SPRAY TO COOL UNOPENED CONTAINERS. CONTAINERS SHOULD BE
COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILD UP. COOL CONTAINERS WITH
FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT. FOR MASSIVE FIRE
IN CARGO AREA, USE UNMANNED HOSE HOLDER OR MONITOR NOZZLES, IF POSSIBLE.
IF NOT, WITHDRAW AND LET FIRE BURN OUT.
SPECIFIC METHODS:
COOL CONTAINERS EXPOSED TO FLAMES WITH WATER UNTIL WELL AFTER THE FIRE IS
OUT.
HAZARDOUS COMBUSTION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: CHLORINE GAS. PHOSGENE. OXIDES OF
CARBON.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NOT AVAILABLE.
SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP OUT OF LOW AREAS. KEEP PEOPLE AWAY
FROM AND UPWIND OF SPILL/LEAK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
CLOTHING DURING CLEAN-UP. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED
MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID BREATHING
GAS. ENSURE ADEQUATE VENTILATION. LOCAL AUTHORITIES SHOULD BE ADVISED IF
SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION,
SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REFER TO ATTACHED SAFETY DATA SHEETS AND/OR INSTRUCTIONS FOR USE. ELIMINATE
ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE
AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED
MATERIAL. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. MOVE THE CYLINDER TO A
SAFE AND OPEN AREA IF THE LEAK IS IRREPARABLE. ISOLATE AREA UNTIL GAS HAS
DISPERSED. PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS OR CONFINED
AREAS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER. FOR WASTE
DISPOSAL, SEE SECTION 13 OF THE SDS. PREVENT ENTRY INTO WATERWAYS, SEWERS,
BASEMENTS OR CONFINED AREAS.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. AVOID DISCHARGE INTO
DRAINS, WATER COURSES OR ONTO THE GROUND. DO NOT DISCHARGE INTO LAKES,
STREAMS, PONDS OR PUBLIC WATERS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS
MISSING OR DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER
INCANDESCENT MATERIAL. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE
IS THOROUGHLY DRY. DO NOT CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE
CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. GROUND
AND BOND CONTAINERS WHEN TRANSFERRING MATERIAL. DO NOT RE-USE EMPTY
CONTAINERS. USE ONLY WITH ADEQUATE VENTILATION. DO NOT BREATHE GAS.
DO NOT TASTE OR SWALLOW. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
AVOID PROLONGED EXPOSURE. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. WHEN USING, DO NOT EAT, DRINK OR SMOKE. WASH
THOROUGHLY AFTER HANDLING. AVOID BREATHING VAPORS OR MISTS OF THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. CONTENTS UNDER PRESSURE. DO NOT EXPOSE TO HEAT OR STORE AT
TEMPERATURES ABOVE 120 DEG. F/49 DEG. C AS CAN MAY BURST. DO NOT PUNCTURE,
INCINERATE OR CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR
OTHER SOURCES OF IGNITION. PROTECT FROM SUNLIGHT. STORE IN A COOL, DRY
PLACE OUT OF DIRECT SUNLIGHT. STORE IN A WELL-VENTILATED PLACE. STORE AWAY
FROM INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS). DO NOT STORE AT
TEMPERATURES ABOVE 49 DEG. C (120.2 DEG. F). KEEP AWAY FROM HEAT, OPEN
FLAMES OR OTHER SOURCES OF IGNITION. KEEP OUT OF REACH OF CHILDREN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
COMPONENTS TYPE VALUE
METHYLENE CHLORIDE (CAS 75-09-2) STEL 125 PPM
TWA 25 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
METHYLENE CHLORIDE (CAS 75-09-2) TWA 50 PPM
US. AIHA WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL (WEEL) GUIDES:
COMPONENTS TYPE VALUE
D-LIMONENE (CAS 5989-27-5) TWA 165.5 MG/M3
30 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
METHYLENE CHLORIDE 0.3 MG/L DICHLOROMETHANE URINE *
(CAS 75-09-2)
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO
AN ACCEPTABLE LEVEL.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR CHEMICAL GOGGLES.
SKIN PROTECTION:
HAND PROTECTION: RUBBER GLOVES. CONFIRM WITH A REPUTABLE SUPPLIER FIRST.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. AS REQUIRED BY EMPLOYER CODE.
RESPIRATORY PROTECTION:
WHERE EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AN APPROVED NIOSH
RESPIRATOR. RESPIRATOR SHOULD BE SELECTED BY AND USED UNDER THE DIRECTION
OF A TRAINED HEALTH AND SAFETY PROFESSIONAL FOLLOWING REQUIREMENTS FOUND
IN OSHA'S RESPIRATOR STANDARD (29 CFR 1910.134), CAN/CSA-Z94.4 AND ANSI'S
STANDARD FOR RESPIRATORY PROTECTION (Z88.2).
THERMAL HAZARDS: NOT APPLICABLE.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING, DO NOT EAT, DRINK OR SMOKE. WASH HANDS AND FACE BEFORE BREAKS
AND IMMEDIATELY AFTER HANDLING THE PRODUCT. ALWAYS OBSERVE GOOD PERSONAL
HYGIENE MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE
EATING, DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND
PROTECTIVE EQUIPMENT TO REMOVE CONTAMINANTS. CONTAMINATED WORK CLOTHING
SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR
PHYSICAL STATE: GAS.
FORM: AEROSOL
COLOR: COLORLESS
ODOR: SOLVENT
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
POUR POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.30 - 1.34
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
FLASH POINT: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
FLAME EXTENSION: 0
FLAMMABILITY (FLASH BACK): NO
HEAT OF COMBUSTION: LEVEL 1
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: REACTS VIGOROUSLY WITH ALKALINE MATERIAL OR METALS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID:
DO NOT MIX WITH OTHER CHEMICALS.
AEROSOL CONTAINERS ARE UNSTABLE AT TEMPERATURES ABOVE 49 DEG. C
(120.2 DEG. F).
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS. ACIDS. CAUSTICS.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO:
HYDROGEN CHLORIDE. OXIDES OF CARBON. CHLORINE GAS. PHOSGENE.
| 11. TOXICOLOGICAL INFORMATION | |
ROUTES OF EXPOSURE: EYE, SKIN CONTACT, INHALATION, INGESTION.
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION: HARMFUL IF SWALLOWED.
INHALATION:
PROLONGED INHALATION MAY BE HARMFUL. MAY CAUSE DAMAGE TO ORGANS BY
INHALATION. MAY CAUSE IRRITATION TO THE RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. MAY CAUSE AN ALLERGIC SKIN REACTION. SKIN IRRITATION. MAY CAUSE
REDNESS AND PAIN. DERMATITIS. RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
HARMFUL IF SWALLOWED. MAY CAUSE AN ALLERGIC SKIN REACTION. MAY CAUSE
RESPIRATORY IRRITATION.
COMPONENTS SPECIES TEST RESULTS
D-LIMONENE (CAS 5989-27-5):
ACUTE:
DERMAL:
LD50 RABBIT >5000 MG/KG
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 MOUSE 5600 MG/KG
RAT 4400 MG/KG
METHYLENE CHLORIDE (CAS 75-09-2):
ACUTE:
DERMAL:
LD50 RABBIT 2700 MG/KG
INHALATION:
LC50 GUINEA PIG 11600 PPM, 6 HOURS
40.2 MG/L, 6 HOURS
MOUSE 14400 PPM, 7 HOURS
56.2 MG/L, 7 HOURS
51.5 MG/L, 2 HOURS
49.1 MG/L, 6 HOURS
RAT 76000 MG/L/4H
14250 MG/M3
2000 MG/L, 15 MINUTES
88 MG/L, 900 DAYS
79 MG/L, 2 HOURS
52 MG/L, 6 HOURS
LD50 MOUSE 16000 PPM, 7 HOURS
ORAL:
LD50 RAT 1410 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
EXPOSURE MINUTES: NOT AVAILABLE.
ERYTHEMA VALUE: NOT AVAILABLE.
OEDEMA VALUE: NOT AVAILABLE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
CORNEAL OPACITY VALUE: NOT AVAILABLE.
IRIS LESION VALUE: NOT AVAILABLE.
CONJUNCTIVAL REDDENING VALUE: NOT AVAILABLE.
CONJUNCTIVAL OEDEMA VALUE: NOT AVAILABLE.
RECOVER DAYS: NOT AVAILABLE.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT AVAILABLE.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
MUTAGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
CARCINOGENICITY: SUSPECTED OF CAUSING CANCER.
ACGIH CARCINOGENS:
METHYLENE CHLORIDE (CAS 75-09-2):
A3 CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
D-LIMONENE (CAS 5989-27-5):
VOLUME 73 - 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
METHYLENE CHLORIDE (CAS 75-09-2):
VOLUME 71 - 2B POSSIBLY CARCINOGENIC TO HUMANS.
US - CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/CARCINOGENIC SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) CARCINOGENIC.
US NTP REPORT ON CARCINOGENS ANTICIPATED CARCINOGEN
METHYLENE CHLORIDE (CAS 75-09-2) REASONABLY ANTICIPATED TO BE A HUMAN
CARCINOGEN.
REPRODUCTIVE TOXICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
TERATOGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
RESPIRATORY TRACT IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: NOT LIKELY, DUE TO THE FORM OF THE PRODUCT.
CHRONIC EFFECTS:
PROLONGED INHALATION MAY BE HARMFUL. PROLONGED EXPOSURE MAY CAUSE CHRONIC
EFFECTS. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
FURTHER INFORMATION: NOT AVAILABLE.
NAME OF TOXICOLOGICALLY SYNERGISTIC PRODUCTS: NOT AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: SEE BELOW
COMPONENTS SPECIES TEST RESULTS
D-LIMONENE (CAS 5989-27-5):
AQUATIC:
CRUSTACEA EC50 WATER FLEA 69.6 MG/L, 48 HOURS
(DAPHNIA PULEX)
FISH LC50 FATHEAD MINNOW 0.619 - 0.796 MG/L,
(PIMEPHALES PROMELAS) 96 HOURS
METHYLENE CHLORIDE (CAS 75-09-2):
ALGAE IC50 ALGAE 500 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 1689.5 MG/L, 48 HOURS
AQUATIC:
CRUSTACEA EC50 WATER FLEA 1250 MG/L, 48 HOURS
(DAPHNIA MAGNA)
FISH LC50 FATHEAD MINNOW 140.8 - 277.8 MG/L,
(PIMEPHALES PROMELAS) 96 HOURS
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
MOBILITY IN SOIL: NO DATA AVAILABLE.
MOBILITY IN GENERAL: NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
CONSULT AUTHORITIES BEFORE DISPOSAL. CONTENTS UNDER PRESSURE. DO NOT
PUNCTURE, INCINERATE OR CRUSH. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF AS HAZARDOUS WASTE. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO
SEWERS/WATER SUPPLIES. DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH
CHEMICAL OR USED CONTAINER.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
US RCRA HAZARDOUS WASTE U LIST REFERENCE
METHYLENE CHLORIDE (CAS 75-09-2) U080
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED. DO NOT RE-USE EMPTY
CONTAINERS.
| 14. TRANSPORT INFORMATION | |
GENERAL:
CANADA:
TDG PROOF OF CLASSIFICATION: IN ACCORDANCE WITH PART 2.2.1 (SOR/2014-152)
OF THE TRANSPORTATION OF DANGEROUS GOODS REGULATIONS, WE CERTIFY THAT THE
CLASSIFICATION OF THIS PRODUCT IS CORRECT AS OF THE SDS DATE OF ISSUE.
IF APPLICABLE, THE TECHNICAL NAME AND THE CLASSIFICATION OF THE PRODUCT
WILL APPEAR BELOW.
U.S. DEPARTMENT OF TRANSPORTATION (DOT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME:
AEROSOLS, FLAMMABLE, (EACH NOT EXCEEDING 1 L CAPACITY)
HAZARD CLASS: LIMITED QUANTITY - US
SPECIAL PROVISIONS: N82
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME:
AEROSOLS, FLAMMABLE, CONTAINING SUBSTANCES IN CLASS 6.1, PACKING GROUP III
HAZARD CLASS: LIMITED QUANTITY - CANADA
IATA/ICAO (AIR):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME:
AEROSOLS, FLAMMABLE, CONTAINING SUBSTANCES IN DIVISION 6.1, PACKING
GROUP III
HAZARD CLASS: LIMITED QUANTITY - IATA
IMDG (MARINE TRANSPORT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS: LIMITED QUANTITY - IMDG
DOT; IMDG; TDG:
LIMITED QUANTITTY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
IATA: LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS AND THE SDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
CANADA CEPA SCHEDULE I LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
CANADA NPRI VOCS WITH ADDITIONAL MASS REPORTING THRESHOLD/
REPORTING REQUIREMENTS IDENTIFICATION NUMBER
D-LIMONENE (CAS 5989-27-5) 1 TONNES
CANADA WHMIS INGREDIENT DISCLOSURE THRESHOLD LIMITS
D-LIMONENE (CAS 5989-27-5) 1%
METHYLENE CHLORIDE (CAS 75-09-2) 0.1%
WHMIS STATUS: CONTROLLED
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS, CLASS D - DIVISION 1B, 2A, 2B
WHMIS LABELING:
A - COMPRESSED GAS
D1 - MATERIALS CAUSING IMMEDIATE AND SERIOUS TOXIC EFFECTS
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
US EPCRA (SARA TITLE III) SECTION 313 - DE MINIMIS CONCENTRATION
TOXIC CHEMICAL
METHYLENE CHLORIDE (CAS 75-09-2) 0.1%
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
US CWA SECTION 307(A)(1) TOXIC POLLUTANTS LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
METHYLENE CHLORIDE (CAS 75-09-2): LISTED.
US CAA SECTION 111 VOLATILE ORGANIC COMPOUNDS LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
METHYLENE CHLORIDE (CAS 75-09-2): LISTED.
US CAA SECTION 612 SNAP PROGRAM LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
US CAA VOCS WITH NEGLIGIBLE PHOTOCHEMICAL ACTIVITY LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: NO
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
METHYLENE CHLORIDE 75-09-2 60-100
OTHER FEDERAL REGULATIONS:
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
US STATE REGULATIONS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
US - CALIFORNIA HAZARDOUS SUBSTANCES (DIRECTOR'S) LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
US - CALIFORNIA PROPOSITION 65 - CARCINOGENS & LISTED SUBSTANCE
REPRODUCTIVE TOXICITY (CRT)
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
US - ILLINOIS CHEMICAL SAFETY ACT LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
US - LOUISIANA SPILL REPORTING LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
US - MICHIGAN CRITICAL MATERIALS REGISTER PARAMETER NUMBER
METHYLENE CHLORIDE (CAS 75-09-2) 00075-09-2 LISTED.
US - MINNESOTA HAZ SUBS LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
US - NEW JERSEY RTK - SUBSTANCES LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
US - NEW YORK RELEASE REPORTING: HAZARDOUS SUBSTANCES LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
US - NORTH CAROLINA TOXIC AIR POLLUTANTS LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
US - PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES SPECIAL HAZARD
METHYLENE CHLORIDE (CAS 75-09-2) SPECIAL HAZARD.
US - TEXAS EFFECTS SCREENING LEVELS LISTED SUBSTANCE
D-LIMONENE (CAS 5989-27-5) LISTED.
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
US - WASHINGTON CHEMICAL OF HIGH CONCERN TO CHILDREN LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2) LISTED.
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
METHYLENE CHLORIDE (CAS 75-09-2): LISTED.
US. PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES:
METHYLENE CHLORIDE (CAS 75-09-2): LISTED.
US. RHODE ISLAND RTK:
METHYLENE CHLORIDE (CAS 75-09-2): LISTED.
INVENTORY STATUS:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
HEALTH 3*
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA:
3
1
0
LEGEND:
SEVERE: 4
SERIOUS: 3
MODERATE: 2
SLIGHT: 1
MINIMAL: 0
DISCLAIMER:
THE INFORMATION IN THE SHEET WAS WRITTEN BASED ON THE BEST KNOWLEDGE AND
EXPERIENCE CURRENTLY AVAILABLE. INFORMATION CONTAINED HEREIN WAS OBTAINED
FROM SOURCES CONSIDERED TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY
EFFORT HAS BEEN MADE TO ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME
CASES DATA IS NOT AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL
PRODUCT USE ARE BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF
THIS MATERIAL HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL
APPLICABLE LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED
OR IMPLIED, IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES,
INJURIES OR CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR
RELIANCE ON ANY INFORMATION CONTAINED IN THIS DOCUMENT.
ISSUE DATE: 23-MARCH-2015
EFFECTIVE DATE: 23-MARCH-2015
EXPIRY DATE: 23-MARCH-2018
FURTHER INFORMATION:
FOR AN UPDATED SDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED IN THE
BEGINNING OF THIS DOCUMENT.
PREPARED BY: NU-CALGON TECHNICAL SERVICE
PHONE: (314) 469-7000
OTHER INFORMATION:
THIS SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE CURRENT OSHA HAZARD
COMMUNICATION STANDARD (HCS) ADOPTION OF THE GLOBALLY HARMONIZED SYSTEM OF
CLASSIFICATION AND LABELING OF CHEMICALS (GHS).
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