| Common Name: | NU-BLAST, AEROSOL (4290-75) |
| Manufacturer: | NU-CALGON WHOLESALER |
| SDS Revision Date: | 12/22/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 2RZW5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NU-CALGON
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER: NU-BLAST, AEROSOL (4290-75)
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE: COIL CLEANER/DEGREASER
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER:
NU-CALGON
2008 ALTOM COURT
ST. LOUIS, MO 63146
US
PHONE: 314-469-7000 / 800-554-5499
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS:
GASES UNDER PRESSURE: LIQUEFIED GAS
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SENSITIZATION, SKIN: CATEGORY 1
GERM CELL MUTAGENICITY: CATEGORY 2
CARCINOGENICITY: CATEGORY 1
REPRODUCTIVE TOXICITY: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
SUSPECTED OF CAUSING GENETIC DEFECTS.
MAY CAUSE CANCER.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENT:
PREVENTION:
WASH THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE GLOVES/PROTECTIVE
CLOTHING/EYE PROTECTION/FACE PROTECTION.
AVOID BREATHING MIST OR VAPOR. CONTAMINATED WORK CLOTHING MUST NOT BE
ALLOWED OUT OF THE WORKPLACE.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. SPECIFIC TREATMENT (SEE THIS LABEL).
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE:
PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
KEEP CONTAINER TIGHTLY CLOSED. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION:
3.5% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN ACUTE INHALATION
TOXICITY. 3.5% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN ACUTE
ORAL TOXICITY.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
ETHENE, TRICHLORO- 79-01-6 95 - 98
CARBON DIOXIDE 124-38-9 2 - 5
FRAGRANCE TRADE SECRET 0.1 - 1
| 4. FIRST AID MEASURES | |
INHALATION:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
SKIN CONTACT:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IF SYMPTOMS
OCCUR. NEVER GIVE ANYTHING BY MOUTH IF VICTIM IS UNCONSCIOUS, OR IS
CONVULSING. OBTAIN MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. DERMATITIS.
RASH. VAPORS HAVE A NARCOTIC EFFECT AND MAY CAUSE HEADACHE, FATIGUE,
DIZZINESS AND NAUSEA. MAY CAUSE REDNESS AND PAIN.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE. WASH
CONTAMINATED CLOTHING BEFORE REUSE. WEAR RUBBER GLOVES AND CHEMICAL SPLASH
GOGGLES.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA: TREAT FOR SURROUNDING MATERIAL.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. FIREFIGHTERS SHOULD WEAR A SELF-CONTAINED
BREATHING APPARATUS.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA. FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE CLOTHING
INCLUDING SELF CONTAINED BREATHING APPARATUS.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. DO NOT MOVE CARGO OR VEHICLE IF CARGO HAS BEEN
EXPOSED TO HEAT. IF TANK, RAIL CAR OR TANK TRUCK IS INVOLVED IN A FIRE,
ISOLATE FOR 800 METERS (1/2 MILE) IN ALL DIRECTIONS; ALSO CONSIDER INITIAL
EVACUATION FOR 800 METERS (1/2 MILE) IN ALL DIRECTIONS. ALWAYS STAY AWAY
FROM TANKS ENGULFED IN FLAME. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO
SO WITHOUT RISK. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER
OR MONITOR NOZZLES, IF POSSIBLE. IF NOT, WITHDRAW AND LET FIRE BURN OUT.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS.
HAZARDOUS COMBUSTION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NOT AVAILABLE.
SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP OUT OF LOW AREAS. KEEP PEOPLE AWAY
FROM AND UPWIND OF SPILL/LEAK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
CLOTHING DURING CLEAN-UP. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED
MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID INHALATION
OF VAPORS OR MISTS. ENSURE ADEQUATE VENTILATION. LOCAL AUTHORITIES SHOULD
BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL
PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
THIS MATERIAL IS CLASSIFIED AS A WATER POLLUTANT UNDER THE CLEAN WATER ACT
AND SHOULD BE PREVENTED FROM CONTAMINATING SOIL OR FROM ENTERING SEWAGE
AND DRAINAGE SYSTEMS WHICH LEAD TO WATERWAYS. STOP THE FLOW OF MATERIAL,
IF THIS IS WITHOUT RISK.
LARGE SPILLS:
DIKE THE SPILLED MATERIAL, WHERE THIS IS POSSIBLE. COVER WITH PLASTIC SHEET
TO PREVENT SPREADING. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE
INTO CONTAINERS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. FOR WASTE DISPOSAL, SEE
SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE ONLY WITH ADEQUATE
VENTILATION.
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID CONTACT DURING
PREGNANCY/WHILE NURSING.
AVOID PROLONGED EXPOSURE. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES. WEAR PERSONAL PROTECTIVE
EQUIPMENT. WHEN USING, DO NOT EAT, DRINK OR SMOKE.
WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER TIGHTLY CLOSED.
AVOID BREATHING VAPORS OR MISTS OF THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. STORE IN A COOL, DRY PLACE OUT OF DIRECT SUNLIGHT. STORE
IN A WELL-VENTILATED PLACE. STORE AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10 OF THE SDS). KEEP OUT OF REACH OF CHILDREN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
CARBON DIOXIDE PEL 9000 MG/M3
(CAS 124-38-9) 5000 PPM
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
ETHENE, TRICHLORO- CEILING 200 PPM
(CAS 79-01-6)
TWA 100 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
CARBON DIOXIDE STEL 30000 PPM
(CAS 124-38-9)
TWA 5000 PPM
ETHENE, TRICHLORO- STEL 25 PPM
(CAS 79-01-6)
TWA 10 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
CARBON DIOXIDE STEL 54000 MG/M3
(CAS 124-38-9) 30000 PPM
TWA 9000 MG/M3
5000 PPM
ETHENE, TRICHLORO- TWA 25 PPM
(CAS 79-01-6)
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
ETHENE, TRICHLORO- 15 MG/L TRICHLOROACETIC URINE *
(CAS 79-01-6) ACID
0.5 MG/L TRICHLOROETHANOL, BLOOD *
WITHOUT
HYDROLYSIS
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD
BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR CHEMICAL GOGGLES.
SKIN PROTECTION:
HAND PROTECTION: RUBBER GLOVES. CONFIRM WITH A REPUTABLE SUPPLIER FIRST.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. AS REQUIRED BY EMPLOYER CODE.
RESPIRATORY PROTECTION:
WHERE EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AN APPROVED NIOSH
RESPIRATOR.
THERMAL HAZARDS: NOT APPLICABLE.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING, DO NOT EAT, DRINK OR SMOKE. ALWAYS OBSERVE GOOD PERSONAL
HYGIENE MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE
EATING, DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND
PROTECTIVE EQUIPMENT TO REMOVE CONTAMINANTS. WASH HANDS BEFORE BREAKS AND
IMMEDIATELY AFTER HANDLING THE PRODUCT. CONTAMINATED WORK CLOTHING SHOULD
NOT BE ALLOWED OUT OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR
PHYSICAL STATE: GAS.
FORM: SPRAY
COLOR: COLORLESS
ODOR: SOLVENT
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
POUR POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.46
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
FLASH POINT: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: 50-85 PSIG @ 70 DEG. F
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: <20.5 MM2/S
OTHER INFORMATION:
FLAME PROJECTION: <18 IN
FLAMMABILITY (FLASH BACK): NO
HEAT OF COMBUSTION: 6.95 KJ/G
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: THIS PRODUCT MAY REACT WITH OXIDIZING AGENTS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID: DO NOT MIX WITH OTHER CHEMICALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS. SOFT METALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON. PHOSGENE.
| 11. TOXICOLOGICAL INFORMATION | |
ROUTES OF EXPOSURE: EYE, SKIN CONTACT, INHALATION, INGESTION.
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
INHALATION:
VAPORS HAVE A NARCOTIC EFFECT AND MAY CAUSE HEADACHE, FATIGUE, DIZZINESS
AND NAUSEA. PROLONGED INHALATION MAY BE HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. MAY CAUSE AN ALLERGIC SKIN REACTION. RASH. SKIN IRRITATION. MAY
CAUSE REDNESS AND PAIN. DERMATITIS. SYMPTOMS OF OVEREXPOSURE MAY BE
HEADACHE, DIZZINESS, TIREDNESS, NAUSEA AND VOMITING.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NARCOTIC EFFECTS. MAY CAUSE AN ALLERGIC SKIN REACTION.
COMPONENTS SPECIES TEST RESULTS
CARBON DIOXIDE (CAS 124-38-9):
ACUTE:
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 NOT AVAILABLE
ETHENE, TRICHLORO- (CAS 79-01-6):
ACUTE:
DERMAL:
LD50 RABBIT 20000 MG/KG
INHALATION:
LC50 MOUSE 8450 PPM, 4 HOURS
RAT 8000 MG/L/4H
LD50 MOUSE 49000 PPM, 30 MINUTES
5500 PPM, 10 HOURS
ORAL:
LD50 DOG 5680 MG/KG
MOUSE 2402 MG/KG
RAT 4290 MG/KG
FRAGRANCE (CAS TRADE SECRET):
ACUTE:
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 NOT AVAILABLE
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
EXPOSURE MINUTES: NOT AVAILABLE.
ERYTHEMA VALUE: NOT AVAILABLE.
OEDEMA VALUE: NOT AVAILABLE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
CORNEAL OPACITY VALUE: NOT AVAILABLE.
IRIS LESION VALUE: NOT AVAILABLE.
CONJUNCTIVAL REDDENING VALUE: NOT AVAILABLE.
CONJUNCTIVAL OEDEMA VALUE: NOT AVAILABLE.
RECOVER DAYS: NOT AVAILABLE.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT AVAILABLE.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: SUSPECTED OF CAUSING GENETIC DEFECTS.
MUTAGENICITY: SUSPECTED OF CAUSING GENETIC DEFECTS.
CARCINOGENICITY: MAY CAUSE CANCER.
ACGIH CARCINOGENS:
ETHENE, TRICHLORO- (CAS 79-01-6): A2 SUSPECTED HUMAN CARCINOGEN.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
ETHENE, TRICHLORO- (CAS 79-01-6):
VOLUME 63, VOLUME 106 - 1 CARCINOGENIC TO HUMANS.
US - CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/CARCINOGENIC SUBSTANCE
ETHENE, TRICHLORO- (CAS 79-01-6) CARCINOGENIC.
US NTP REPORT ON CARCINOGENS ANTICIPATED CARCINOGEN
ETHENE, TRICHLORO- (CAS 79-01-6) REASONABLY ANTICIPATED TO BE A HUMAN
CARCINOGEN.
REPRODUCTIVE TOXICITY: MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
TERATOGENICITY: NON-HAZARDOUS BY WHMIS/OSHA CRITERIA.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NARCOTIC EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT AVAILABLE.
CHRONIC EFFECTS:
PROLONGED INHALATION MAY BE HARMFUL. PROLONGED EXPOSURE MAY CAUSE CHRONIC
EFFECTS. CHRONIC EXPOSURE TO TRICHLOROETHYLENE MAY CAUSE LIVER, KIDNEY,
CENTRAL NERVOUS SYSTEM AND PERIPHERAL NERVOUS SYSTEM EFFECTS.
FURTHER INFORMATION: NOT AVAILABLE.
NAME OF TOXICOLOGICALLY SYNERGISTIC PRODUCTS: NOT AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: SEE BELOW
COMPONENTS SPECIES TEST RESULTS
ETHENE, TRICHLORO- (CAS 79-01-6):
CRUSTACEA EC50 DAPHNIA 2.2 MG/L, 48 HOURS
AQUATIC:
FISH LC50 FLAGFISH (JORDANELLA FLORIDAE) 3.1 MG/L, 96 HOURS
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
MOBILITY IN SOIL: NO DATA AVAILABLE.
MOBILITY IN GENERAL: NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
CONSULT AUTHORITIES BEFORE DISPOSAL. THIS MATERIAL AND ITS CONTAINER MUST
BE DISPOSED OF AS HAZARDOUS WASTE. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO
SEWERS/WATER SUPPLIES. DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH
CHEMICAL OR USED CONTAINER. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE
WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
US RCRA HAZARDOUS WASTE U LIST REFERENCE
ETHENE, TRICHLORO- (CAS 79-01-6) U228
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION (DOT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME:
AEROSOLS, POISON, PACKING GROUP III (EACH NOT EXCEEDING 1 L CAPACITY)
HAZARD CLASS: LIMITED QUANTITY - US
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME:
AEROSOLS, NON-FLAMMABLE, CONTAINING SUBSTANCES IN CLASS 6.1, PACKING GROUP
III
HAZARD CLASS: LIMITED QUANTITY - CANADA
SPECIAL PROVISIONS: 80
IATA/ICAO (AIR):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME:
AEROSOLS, NON-FLAMMABLE, CONTAINING SUBSTANCES IN CLASS 6.1, PACKING GROUP
III
HAZARD CLASS: LIMITED QUANTITY - IATA
IMDG (MARINE TRANSPORT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS: LIMITED QUANTITY - US
DOT; IMDG; TDG:
LIMITED QUANTITTY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
IATA: LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE CONTROLLED PRODUCTS REGULATIONS AND THE SDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
CANADA CEPA SCHEDULE I LISTED SUBSTANCE
CARBON DIOXIDE (CAS 124-38-9) LISTED.
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
CANADA WHMIS INGREDIENT DISCLOSURE THRESHOLD LIMITS
CARBON DIOXIDE (CAS 124-38-9) 1%
ETHENE, TRICHLORO- (CAS 79-01-6) 1%
WHMIS STATUS: CONTROLLED
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS, CLASS D - DIVISION 1B, 2A, 2B
WHMIS LABELING:
A - COMPRESSED GAS
D1 - MATERIALS CAUSING IMMEDIATE AND SERIOUS TOXIC EFFECTS
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL DE MINIMIS
CONCENTRATION
ETHENE, TRICHLORO- (CAS 79-01-6) 0.1%
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL LISTED SUBSTANCE
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
US CWA SECTION 311 HAZARDOUS SUBSTANCES LISTED SUBSTANCE
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
US CWA SECTION 307(A)(1) TOXIC POLLUTANTS LISTED SUBSTANCE
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
ETHENE, TRICHLORO- (CAS 79-01-6): LISTED.
US - CAA MANDATORY REPORTING OF GHGS GLOBAL WARMING POTENTIAL (100 YEAR)
CARBON DIOXIDE (CAS 124-38-9) 1
US CAA SECTION 111 VOLATILE ORGANIC COMPOUNDS LISTED SUBSTANCE
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
ETHENE, TRICHLORO- (CAS 79-01-6): LISTED.
US CAA SECTION 612 SNAP PROGRAM LISTED SUBSTANCE
CARBON DIOXIDE (CAS 124-38-9) LISTED.
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
ETHENE, TRICHLORO- 79-01-6 95 - 98
OTHER FEDERAL REGULATIONS:
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
US STATE REGULATIONS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA HAZARDOUS SUBSTANCES (DIRECTOR'S) LISTED SUBSTANCE
CARBON DIOXIDE (CAS 124-38-9) LISTED.
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
US - CALIFORNIA PROPOSITION 65 - CARCINOGENS & LISTED SUBSTANCE
REPRODUCTIVE TOXICITY (CRT)
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
US - ILLINOIS CHEMICAL SAFETY ACT LISTED SUBSTANCE
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
US - LOUISIANA SPILL REPORTING LISTED SUBSTANCE
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
US - MICHIGAN CRITICAL MATERIALS REGISTER PARAMETER NUMBER
ETHENE, TRICHLORO- (CAS 79-01-6) 00079-01-6 LISTED.
US - MINNESOTA HAZ SUBS LISTED SUBSTANCE
CARBON DIOXIDE (CAS 124-38-9) LISTED.
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
US - NEW JERSEY RTK - SUBSTANCES LISTED SUBSTANCE
CARBON DIOXIDE (CAS 124-38-9) LISTED.
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
US - NEW YORK RELEASE REPORTING: HAZARDOUS SUBSTANCES LISTED SUBSTANCE
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
US - NORTH CAROLINA TOXIC AIR POLLUTANTS LISTED SUBSTANCE
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
US - TEXAS EFFECTS SCREENING LEVELS LISTED SUBSTANCE
CARBON DIOXIDE (CAS 124-38-9) LISTED.
ETHENE, TRICHLORO- (CAS 79-01-6) LISTED.
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
CARBON DIOXIDE (CAS 124-38-9): LISTED.
ETHENE, TRICHLORO- (CAS 79-01-6): LISTED.
US. PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES:
CARBON DIOXIDE (CAS 124-38-9): LISTED.
ETHENE, TRICHLORO- (CAS 79-01-6): LISTED.
US. RHODE ISLAND RTK:
ETHENE, TRICHLORO- (CAS 79-01-6): LISTED.
INVENTORY STATUS:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
CANADA DOMESTIC SUBSTANCES LIST (DSL) NO
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT NO
PUERTO RICO (TSCA) INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA:
2
1
0
LEGEND:
SEVERE: 4
SERIOUS: 3
MODERATE: 2
SLIGHT: 1
MINIMAL: 0
DISCLAIMER:
THE INFORMATION IN THE SHEET WAS WRITTEN BASED ON THE BEST KNOWLEDGE AND
EXPERIENCE CURRENTLY AVAILABLE. INFORMATION CONTAINED HEREIN WAS OBTAINED
FROM SOURCES CONSIDERED TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY
EFFORT HAS BEEN MADE TO ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME
CASES DATA IS NOT AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL
PRODUCT USE ARE BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF
THIS MATERIAL HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL
APPLICABLE LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED
OR IMPLIED, IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES,
INJURIES OR CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR
RELIANCE ON ANY INFORMATION CONTAINED IN THIS DOCUMENT.
ISSUE DATE: 22-DECEMBER-2014
EFFECTIVE DATE: 15-DECEMBER-2014
EXPIRY DATE: 15-DECEMBER-2017
FURTHER INFORMATION:
FOR AN UPDATED SDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED IN
THE BEGINNING OF THIS DOCUMENT.
PREPARED BY: NU-CALGON TECHNICAL SERVICE
PHONE: (314) 469-7000
OTHER INFORMATION:
THIS SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE CURRENT OSHA HAZARD
COMMUNICATION STANDARD (HCS) ADOPTION OF THE GLOBALLY HARMONIZED SYSTEM
OF CLASSIFICATION AND LABELING OF CHEMICALS (GHS).
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