| Common Name: | SPRAY-N-BOND (4369-75) |
| Manufacturer: | NU-CALGON WHOLESALER |
| SDS Revision Date: | 12/5/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 3CFP5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NU-CALGON
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER: SPRAY-N-BOND (4369-75)
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE: ADHESIVE
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER:
NU-CALGON
2008 ALTOM COURT
ST. LOUIS, MO 63146
US
PHONE: 314-469-7000 / 800-554-5499
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: LIQUEFIED GAS
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
REPRODUCTIVE TOXICITY (THE UNBORN CHILD): CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
SUSPECTED OF DAMAGING THE UNBORN CHILD.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT
SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. WASH THOROUGHLY AFTER HANDLING. WEAR
PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE GAS. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
SPECIFIC TREATMENT (SEE THIS LABEL).
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NOT APPLICABLE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
PROPANE 74-98-6 21-23
ACETONE 67-64-1 19-21
BUTANE 106-97-8 16-18
HEPTANE 142-82-5 11-13
HEPTANE, BRANCHED, CYCLIC 426260-76-6 11-13
AND LINEAR
METHYL ACETATE 79-20-9 4-6
TOLUENE 108-88-3 0.1-1
| 4. FIRST AID MEASURES | |
INHALATION:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
SKIN CONTACT:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
INGESTION:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. SKIN IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. MAY CAUSE
REDNESS AND PAIN. PROLONGED EXPOSURE MAY CAUSE CHRONIC EFFECTS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES.
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. WEAR SUITABLE PROTECTIVE CLOTHING.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
POWDER. ALCOHOL RESISTANT FOAM. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED TO
HEAT OR FLAME.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK. CONTAINERS
SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILD UP. FOR MASSIVE
FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER OR MONITOR NOZZLES, IF
POSSIBLE. IF NOT, WITHDRAW AND LET FIRE BURN OUT.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. IN THE EVENT OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
GENERAL FIRE HAZARDS: EXTREMELY FLAMMABLE AEROSOL.
HAZARDOUS COMBUSTION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NOT AVAILABLE.
SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP OUT OF LOW AREAS. KEEP PEOPLE AWAY
FROM AND UPWIND OF SPILL/LEAK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
CLOTHING DURING CLEAN-UP. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED
MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID BREATHING
GAS. VENTILATE CLOSED SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES
SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR
PERSONAL PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REFER TO ATTACHED SAFETY DATA SHEETS AND/OR INSTRUCTIONS FOR USE. ELIMINATE
ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE
AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED
MATERIAL. THIS MATERIAL IS CLASSIFIED AS A WATER POLLUTANT UNDER THE CLEAN
WATER ACT AND SHOULD BE PREVENTED FROM CONTAMINATING SOIL OR FROM ENTERING
SEWAGE AND DRAINAGE SYSTEMS WHICH LEAD TO WATERWAYS. STOP LEAK IF YOU CAN
DO SO WITHOUT RISK. MOVE THE CYLINDER TO A SAFE AND OPEN AREA IF THE LEAK
IS IRREPARABLE. ISOLATE AREA UNTIL GAS HAS DISPERSED. DIKE FAR AHEAD OF
SPILL FOR LATER DISPOSAL. SCOOP UP USED ABSORBENT INTO DRUMS OR OTHER
APPROPRIATE CONTAINER. PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS OR
CONFINED AREAS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER. FOR
WASTE DISPOSAL, SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT HANDLE, STORE OR OPEN
NEAR AN OPEN FLAME, SOURCES OF HEAT OR SOURCES OF IGNITION. PROTECT
MATERIAL FROM DIRECT SUNLIGHT.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS
MISSING OR DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER
INCANDESCENT MATERIAL. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE IS
THOROUGHLY DRY. DO NOT CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE
CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. DO NOT
BREATHE GAS. AVOID CONTACT DURING PREGNANCY/WHILE NURSING. AVOID CONTACT
WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED EXPOSURE. USE ONLY IN
WELL-VENTILATED AREAS. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. WASH HANDS THOROUGHLY AFTER HANDLING.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT
EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. DO NOT PUNCTURE,
INCINERATE OR CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR
OTHER SOURCES OF IGNITION. STORE AWAY FROM INCOMPATIBLE MATERIALS (SEE
SECTION 10 OF THE SDS). KEEP OUT OF THE REACH OF CHILDREN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) PEL 2400 MG/M3
1000 PPM
HEPTANE (CAS 142-82-5) PEL 2000 MG/M3
500 PPM
METHYL ACETATE (CAS 79-20-9) PEL 610 MG/M3
200 PPM
PROPANE (CAS 74-98-6) PEL 1800 MG/M3
1000 PPM
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
TOLUENE (CAS 108-88-3) CEILING 300 PPM
TWA 200 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) STEL 750 PPM
TWA 500 PPM
BUTANE (CAS 106-97-8) STEL 1000 PPM
HEPTANE (CAS 142-82-5) STEL 500 PPM
TWA 400 PPM
METHYL ACETATE (CAS 79-20-9) STEL 250 PPM
TWA 200 PPM
TOLUENE (CAS 108-88-3) TWA 20 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) TWA 590 MG/M3
250 PPM
BUTANE (CAS 106-97-8) TWA 1900 MG/M3
800 PPM
HEPTANE (CAS 142-82-5) CEILING 1800 MG/M3
440 PPM
TWA 350 MG/M3
85 PPM
METHYL ACETATE (CAS 79-20-9) STEL 760 MG/M3
250 PPM
TWA 610 MG/M3
200 PPM
PROPANE (CAS 74-98-6) TWA 1800 MG/M3
1000 PPM
TOLUENE (CAS 108-88-3) STEL 560 MG/M3
150 PPM
TWA 375 MG/M3
100 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
ACETONE 50 MG/L ACETONE URINE *
(CAS 67-64-1)
TOLUENE 0.3 MG/G O-CRESOL, WITH CREATININE *
(CAS 108-88-3) HYDROLYSIS IN URINE
0.03 MG/L TOLUENE URINE *
0.02 MG/L TOLUENE BLOOD *
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE
AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
OTHER: WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA). IN CASE
OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT.
THERMAL HAZARDS: NOT APPLICABLE.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING, DO NOT EAT, DRINK OR SMOKE. ALWAYS OBSERVE GOOD PERSONAL
HYGIENE MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE
EATING, DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND
PROTECTIVE EQUIPMENT TO REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR
PHYSICAL STATE: GAS.
FORM: AEROSOL
COLOR: LIGHT YELLOW
ODOR: SOLVENT
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
POUR POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: 0.840 (CONCENTRATE)
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
FLASH POINT: <0.0 DEG. F (< -17.8 DEG. C) (CONCENTRATE)
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: 60 PSIG @ 70 DEG. F
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: >20.5 MM2/S
OTHER INFORMATION:
FLAME EXTENSION: >70 CM
FLAMMABILITY (FLASH BACK): YES
HEAT OF COMBUSTION: 40.9 KJ/G
VOC (WEIGHT %): 53.5%
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: DO NOT MIX WITH OTHER CHEMICALS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID: CONTACT WITH INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS. ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON.
| 11. TOXICOLOGICAL INFORMATION | |
ROUTES OF EXPOSURE: INHALATION. INGESTION. SKIN CONTACT. EYE CONTACT.
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
INHALATION: PROLONGED INHALATION MAY BE HARMFUL. NARCOTIC EFFECTS.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT:
CAUSES SERIOUS EYE IRRITATION. DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY
IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. SYMPTOMS OF
OVEREXPOSURE MAY BE HEADACHE, DIZZINESS, TIREDNESS, NAUSEA AND VOMITING.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NARCOTIC EFFECTS.
COMPONENTS SPECIES TEST RESULTS
ACETONE (CAS 67-64-1):
ACUTE:
DERMAL:
LD50 RABBIT 15800 MG/KG
20 ML/KG
INHALATION:
LC50 MOUSE 44000 MG/M3/4H
RAT 76 MG/L, 4 HOURS
50.1 MG/L, 8 HOURS
39 MG/L/4H
ORAL:
LD50 HUMAN 2857 MG/KG
MOUSE 3000 MG/KG
RABBIT 5340 MG/KG
RAT 5800 MG/KG
BUTANE (CAS 106-97-8):
ACUTE:
INHALATION:
LC50 MOUSE 680 MG/L, 2 HOURS
RAT 276000 PPM, 4 HOURS
658 MG/L/4H
ORAL:
LD50 NOT AVAILABLE
HEPTANE (CAS 142-82-5):
ACUTE:
INHALATION:
LC50 RAT 103 MG/L, 4 HOURS
LD50 MOUSE 75 MG/L, 2 HOURS
ORAL:
LD50 RAT 15000 MG/KG
HEPTANE, BRANCHED, CYCLIC AND LINEAR (CAS 426260-76-6):
ACUTE:
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 NOT AVAILABLE
METHYL ACETATE (CAS 79-20-9):
ACUTE:
DERMAL:
LD50 RABBIT >5000 MG/KG
INHALATION:
LC50 RAT >16000 PPM
ORAL:
LD50 RABBIT 3705 MG/KG
RAT >5000 MG/KG
PROPANE (CAS 74-98-6):
ACUTE:
INHALATION:
LC50 RAT >1442.8 MG/L, 15 MINUTES
ORAL:
LD50 NOT AVAILABLE
TOLUENE (CAS 108-88-3):
ACUTE:
DERMAL:
LD50 RABBIT 12196 MG/KG, SIGMA
12125 MG/KG
8390 MG/KG
14.1 ML/KG
INHALATION:
LC50 MOUSE 7100 MG/L, 4 HOURS
5320 PPM, 8 HOURS
400 PPM, 24 HOURS
RAT 26700 PPM, 1 HOURS
<=28800 MG/M3, 4 HOURS,
SIGMA
12200 PPM, 2 HOURS
8000 PPM, 4 HOURS
12.5 MG/L/4H
ORAL:
LD50 RAT >5580 MG/KG, SIGMA
636 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
EXPOSURE MINUTES: NOT AVAILABLE.
ERYTHEMA VALUE: NOT AVAILABLE.
OEDEMA VALUE: NOT AVAILABLE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
CORNEAL OPACITY VALUE: NOT AVAILABLE.
IRIS LESION VALUE: NOT AVAILABLE.
CONJUNCTIVAL REDDENING VALUE: NOT AVAILABLE.
CONJUNCTIVAL OEDEMA VALUE: NOT AVAILABLE.
RECOVER DAYS: NOT AVAILABLE.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT AVAILABLE.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, NTP, OR OSHA.
ACGIH CARCINOGENS:
ACETONE (CAS 67-64-1): A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
TOLUENE (CAS 108-88-3): A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
TOLUENE (CAS 108-88-3):
VOLUME 47, VOLUME 71 - 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
US - CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/CARCINOGENIC SUBSTANCE
BENZENE (CAS 71-43-2) CARCINOGENIC.
BENZENE, ETHYL- (CAS 100-41-4) CARCINOGENIC.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING THE UNBORN CHILD.
TERATOGENICITY:
TOLUENE (BENZENE, METHYL-) HAS CAUSED FETOTOXICITY (REDUCED FETAL WEIGHT),
BEHAVIOURAL EFFECTS (EFFECTS ON LEARNING AND MEMORY) AND HEARING LOSS (IN
MALES). THESE EFFECTS HAVE BEEN OBSERVED IN THE OFFSPRING OF RATS EXPOSED
BY INHALATION TO 1200 OR 1800 PPM TOLUENE. THESE EFFECTS WERE OBSERVED IN
THE ABSENCE OF MATERNAL TOXICITY.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NARCOTIC EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT APPLICABLE.
ASPIRATION HAZARD: NOT APPLICABLE.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
FURTHER INFORMATION: NOT AVAILABLE.
NAME OF TOXICOLOGICALLY SYNERGISTIC PRODUCTS: NOT AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: SEE BELOW
COMPONENTS SPECIES TEST RESULTS
ACETONE (CAS 67-64-1):
CRUSTACEA EC50 DAPHNIA 13999 MG/L, 48 HOURS
AQUATIC:
CRUSTACEA EC50 WATER FLEA 21.6 - 23.9 MG/L, 48 HOURS
(DAPHNIA MAGNA)
FISH LC50 RAINBOW TROUT, 4740 - 6330 MG/L, 96 HOURS
DONALDSON TROUT
(ONCORHYNCHUS
MYKISS)
HEPTANE (CAS 142-82-5):
AQUATIC:
FISH LC50 MOZAMBIQUE 375 MG/L, 96 HOURS
TILAPIA (TILAPIA
MOSSAMBICA)
METHYL ACETATE (CAS 79-20-9):
ALGAE IC50 ALGAE 120 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 1026.7 MG/L, 48 HOURS
AQUATIC:
FISH LC50 FATHEAD MINNOW 295 - 348 MG/L, 96 HOURS
(PIMEPHALES
PROMELAS)
TOLUENE (CAS 108-88-3):
ALGAE IC50 ALGAE 433 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 7.645 MG/L, 48 HOURS
AQUATIC:
CRUSTACEA EC50 WATER FLEA 5.46 - 9.83 MG/L, 48 HOURS
(DAPHNIA MAGNA)
FISH LC50 COHO SALMON, 8.11 MG/L, 96 HOURS
SILVER SALMON
(ONCORHYNCHUS
KISUTCH)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
MOBILITY IN SOIL: NO DATA AVAILABLE.
MOBILITY IN GENERAL: NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR CRUSH. THIS
MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE. DO NOT
ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO NOT CONTAMINATE
PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED CONTAINER. DISPOSE OF
CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL
REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
US RCRA HAZARDOUS WASTE U LIST REFERENCE
ACETONE (CAS 67-64-1) U002
TOLUENE (CAS 108-88-3) U220
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED. DO NOT RE-USE EMPTY
CONTAINERS.
| 14. TRANSPORT INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION (DOT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS: LIMITED QUANTITY - US
SPECIAL PROVISIONS: N82
PACKAGING EXCEPTIONS: 306
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS: LIMITED QUANTITY - CANADA
SPECIAL PROVISIONS: 80
IATA/ICAO (AIR):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS: LIMITED QUANTITY - IATA
IMDG (MARINE TRANSPORT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS: LIMITED QUANTITY - US
DOT; IMDG; TDG:
LIMITED QUANTITTY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
IATA: LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS AND THE SDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
CANADA DSL CHALLENGE SUBSTANCES LISTED SUBSTANCE
BUTANE (CAS 106-97-8) LISTED.
CANADA NPRI VOCS WITH ADDITIONAL MASS REPORTING THRESHOLD/
REPORTING REQUIREMENTS IDENTIFICATION NUMBER
BUTANE (CAS 106-97-8) 1 TONNES
HEPTANE (CAS 142-82-5) 1 TONNES
PROPANE (CAS 74-98-6) 1 TONNES
TOLUENE (CAS 108-88-3) 1 TONNES
CANADA WHMIS INGREDIENT DISCLOSURE THRESHOLD LIMITS
ACETONE (CAS 67-64-1) 1%
BUTANE (CAS 106-97-8) 1%
HEPTANE (CAS 142-82-5) 1%
METHYL ACETATE (CAS 79-20-9) 1%
TOLUENE (CAS 108-88-3) 1%
WHMIS STATUS: CONTROLLED
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS, CLASS B - DIVISION 5 - FLAMMABLE AEROSOL,
CLASS D - DIVISION 2A, 2B
WHMIS LABELING:
A - COMPRESSED GAS
B - FLAMMABLE AND COMBUSTIBLE MATERIAL
D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
US EPCRA (SARA TITLE III) SECTION DE MINIMIS CONCENTRATION
313 - TOXIC CHEMICAL
TOLUENE (CAS 108-88-3) 1.0%
US EPCRA (SARA TITLE III) SECTION LISTED SUBSTANCE
313 - TOXIC CHEMICAL
TOLUENE (CAS 108-88-3) LISTED.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
US CWA SECTION 311 HAZARDOUS SUBSTANCES LISTED SUBSTANCE
TOLUENE (CAS 108-88-3) LISTED.
US CWA SECTION 307(A)(1) TOXIC POLLUTANTS LISTED SUBSTANCE
TOLUENE (CAS 108-88-3) LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
ACETONE (CAS 67-64-1): LISTED.
BUTANE (CAS 106-97-8): LISTED.
HEPTANE (CAS 142-82-5): LISTED.
METHYL ACETATE (CAS 79-20-9): LISTED.
PROPANE (CAS 74-98-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
US CAA SECTION 111 VOLATILE ORGANIC COMPOUNDS LISTED SUBSTANCE
ACETONE (CAS 67-64-1) LISTED.
METHYL ACETATE (CAS 79-20-9) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US CAA SECTION 112(R) ACCIDENTAL RELEASE LISTED SUBSTANCE
PREVENTION - REGULATED FLAMMABLE SUBSTANCE
BUTANE (CAS 106-97-8) REGULATED FLAMMABLE SUBSTANCE.
PROPANE (CAS 74-98-6) REGULATED FLAMMABLE SUBSTANCE.
US CAA SECTION 112(R) ACCIDENTAL RELEASE PREVENTION THRESHOLD QUANTITY
BUTANE (CAS 106-97-8) 10000 LBS
PROPANE (CAS 74-98-6) 10000 LBS
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130):
BUTANE (CAS 106-97-8): LISTED.
PROPANE (CAS 74-98-6): LISTED.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
TOLUENE (CAS 108-88-3): LISTED.
US CAA SECTION 612 SNAP PROGRAM LISTED SUBSTANCE
ACETONE (CAS 67-64-1) LISTED.
BUTANE (CAS 106-97-8) LISTED.
PROPANE (CAS 74-98-6) LISTED.
US CAA VOCS WITH NEGLIGIBLE PHOTOCHEMICAL ACTIVITY LISTED SUBSTANCE
ACETONE (CAS 67-64-1) LISTED.
METHYL ACETATE (CAS 79-20-9) LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING): NOT REGULATED.
OTHER FEDERAL REGULATIONS:
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
US STATE REGULATIONS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA HAZARDOUS SUBSTANCES (DIRECTOR'S) LISTED SUBSTANCE
ACETONE (CAS 67-64-1) LISTED.
BUTANE (CAS 106-97-8) LISTED.
HEPTANE (CAS 142-82-5) LISTED.
METHYL ACETATE (CAS 79-20-9) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - CALIFORNIA PROPOSITION 65 - CARCINOGENS LISTED SUBSTANCE
& REPRODUCTIVE TOXICITY (CRT)
BENZENE (CAS 71-43-2) LISTED.
BENZENE, ETHYL- (CAS 100-41-4) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - ILLINOIS CHEMICAL SAFETY ACT LISTED SUBSTANCE
ACETONE (CAS 67-64-1) LISTED.
BUTANE (CAS 106-97-8) LISTED.
HEPTANE (CAS 142-82-5) LISTED.
METHYL ACETATE (CAS 79-20-9) LISTED.
PROPANE (CAS 74-98-6) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - LOUISIANA SPILL REPORTING LISTED SUBSTANCE
ACETONE (CAS 67-64-1) LISTED.
BUTANE (CAS 106-97-8) LISTED.
HEPTANE (CAS 142-82-5) LISTED.
METHYL ACETATE (CAS 79-20-9) LISTED.
PROPANE (CAS 74-98-6) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - MICHIGAN CRITICAL MATERIALS REGISTER PARAMETER NUMBER
TOLUENE (CAS 108-88-3) 00108-88-3 LISTED.
US - MINNESOTA HAZ SUBS LISTED SUBSTANCE
ACETONE (CAS 67-64-1) LISTED.
BUTANE (CAS 106-97-8) LISTED.
HEPTANE (CAS 142-82-5) LISTED.
METHYL ACETATE (CAS 79-20-9) LISTED.
PROPANE (CAS 74-98-6) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - NEW JERSEY RTK - SUBSTANCES LISTED SUBSTANCE
ACETONE (CAS 67-64-1) LISTED.
BUTANE (CAS 106-97-8) LISTED.
HEPTANE (CAS 142-82-5) LISTED.
METHYL ACETATE (CAS 79-20-9) LISTED.
PROPANE (CAS 74-98-6) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - NEW YORK RELEASE REPORTING: HAZARDOUS SUBSTANCES LISTED SUBSTANCE
ACETONE (CAS 67-64-1) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - NORTH CAROLINA TOXIC AIR POLLUTANTS LISTED SUBSTANCE
TOLUENE (CAS 108-88-3) LISTED.
US - TEXAS EFFECTS SCREENING LEVELS LISTED SUBSTANCE
ACETONE (CAS 67-64-1) LISTED.
BUTANE (CAS 106-97-8) LISTED.
HEPTANE (CAS 142-82-5) LISTED.
METHYL ACETATE (CAS 79-20-9) LISTED.
PROPANE (CAS 74-98-6) LISTED.
TOLUENE (CAS 108-88-3) LISTED.
US - WASHINGTON CHEMICAL OF HIGH CONCERN TO CHILDREN LISTED SUBSTANCE
TOLUENE (CAS 108-88-3) LISTED.
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
ACETONE (CAS 67-64-1): LISTED.
BUTANE (CAS 106-97-8): LISTED.
HEPTANE (CAS 142-82-5): LISTED.
METHYL ACETATE (CAS 79-20-9): LISTED.
PROPANE (CAS 74-98-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
US. PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES:
ACETONE (CAS 67-64-1): LISTED.
BUTANE (CAS 106-97-8): LISTED.
HEPTANE (CAS 142-82-5): LISTED.
METHYL ACETATE (CAS 79-20-9): LISTED.
PROPANE (CAS 74-98-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
US. RHODE ISLAND RTK:
ACETONE (CAS 67-64-1): LISTED.
BUTANE (CAS 106-97-8): LISTED.
PROPANE (CAS 74-98-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
INVENTORY STATUS:
COUNTRY(S) INVENTORY NAME ON INVENTORY
OR REGION (YES/NO)*
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
UNITED STATES TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
& PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
HEALTH 2
FLAMMABILITY 4
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA:
2
4
1
LEGEND:
SEVERE: 4
SERIOUS: 3
MODERATE: 2
SLIGHT: 1
MINIMAL: 0
DISCLAIMER:
THE INFORMATION IN THE SHEET WAS WRITTEN BASED ON THE BEST KNOWLEDGE AND
EXPERIENCE CURRENTLY AVAILABLE. INFORMATION CONTAINED HEREIN WAS OBTAINED
FROM SOURCES CONSIDERED TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY
EFFORT HAS BEEN MADE TO ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME
CASES DATA IS NOT AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL
PRODUCT USE ARE BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF
THIS MATERIAL HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL
APPLICABLE LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED
OR IMPLIED, IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES,
INJURIES OR CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR
RELIANCE ON ANY INFORMATION CONTAINED IN THIS DOCUMENT.
ISSUE DATE: 05-DECEMBER-2014
EFFECTIVE DATE: 01-DECEMBER-2014
EXPIRY DATE: 01-DECEMBER-2017
FURTHER INFORMATION:
FOR AN UPDATED SDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED IN THE
BEGINNING OF THIS DOCUMENT.
PREPARED BY: NU-CALGON TECHNICAL SERVICE
PHONE: (314) 469-7000
OTHER INFORMATION:
THIS SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE CURRENT OSHA HAZARD
COMMUNICATION STANDARD (HCS) ADOPTION OF THE GLOBALLY HARMONIZED SYSTEM OF
CLASSIFICATION AND LABELING OF CHEMICALS (GHS).
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