| Common Name: | UNVRSL +SSPR 6PK FLAT BLACK, 245198 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 3/16/2015 |
| SDS Format: | ANSI-OSHA |
| Item Number(s): | 40PM65 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DATE PRINTED: 3/16/2015
MATERIAL SAFETY DATA SHEET
RUST-OLEUM CORPORATION
24 HOUR ASSISTANCE:
1-847-367-7700
RUST-OLEUM CORP.
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: UNVRSL +SSPR 6PK FLAT BLACK
PRODUCT NUMBER: 245198
PRODUCT USE/CLASS: TOPCOAT/AEROSOLS
REVISION DATE: 3/16/2015
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARED BY: REGULATORY DEPARTMENT
| 2. HAZARD IDENTIFICATION | |
EMERGENCY OVERVIEW:
EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS MAY CAUSE FLASH FIRE OR
EXPLOSION. HARMFUL IF INHALED. MAY AFFECT THE BRAIN OR NERVOUS SYSTEM
CAUSING DIZZINESS, HEADACHE OR NAUSEA. CONTENTS UNDER PRESSURE. MAY CAUSE
EYE, SKIN, OR RESPIRATORY TRACT IRRITATION. KEEP OUT OF REACH OF CHILDREN.
HARMFUL IF INHALED. HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION. USE
VENTILATION NECESSARY TO KEEP EXPOSURES BELOW RECOMMENDED EXPOSURE LIMITS,
IF ANY. VAPOR HARMFUL. CAUSES EYE, SKIN, NOSE, AND THROAT IRRITATION.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES SERIOUS EYE IRRITATION
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
MAY CAUSE SKIN IRRITATION. ALLERGIC REACTIONS ARE POSSIBLE.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE HARMFUL IF INHALED.
HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND
LUNGS. HARMFUL IF INHALED. AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST.
PROLONGED OR EXCESSIVE INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION.
EFFECTS OF OVEREXPOSURE - INGESTION: HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
IARC LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B).
CONTAINS CARBON BLACK. CHRONIC INFLAMMATION, LUNG FIBROSIS, AND LUNG TUMORS
HAVE BEEN OBSERVED IN SOME RATS EXPERIMENTALLY EXPOSED FOR LONG PERIODS OF
TIME TO EXCESSIVE CONCENTRATIONS OF CARBON BLACK AND SEVERAL INSOLUBLE
FINE DUST PARTICLES. TUMORS HAVE NOT BEEN OBSERVED IN OTHER ANIMAL SPECIES
(I.E., MOUSE AND HAMSTER) UNDER SIMILAR CIRCUMSTANCES AND STUDY CONDITIONS.
EPIDEMIOLOGICAL STUDIES OF NORTH AMERICAN WORKERS SHOW NO EVIDENCE OF
CLINICALLY SIGNIFICANT ADVERSE HEALTH EFFECTS DUE TO OCCUPATIONAL EXPOSURE
TO CARBON BLACK.
CARBON BLACK IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY
IARC AND IS PROPOSED TO BE LISTED AS A4- "NOT CLASSIFIED AS A HUMAN
CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND THE
ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA. MAY CAUSE CENTRAL
NERVOUS SYSTEM DISORDER (E.G., NARCOSIS INVOLVING A LOSS OF COORDINATION,
WEAKNESS, FATIGUE, MENTAL CONFUSION, AND BLURRED VISION) AND/OR DAMAGE.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE
TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. HIGH
CONCENTRATIONS MAY LEAD TO CENTRAL NERVOUS SYSTEM EFFECTS (DROWSINESS,
DIZZINESS, NAUSEA, HEADACHES, PARALYSIS, AND BLURRED VISION) AND/OR DAMAGE.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INHALATION, SKIN ABSORPTION, SKIN CONTACT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
ACETONE 67-64-1 30.0
LIQUEFIED PETROLEUM GAS 68476-86-8 30.0
N-BUTYL ACETATE 123-86-4 15.0
HYDROUS MAGNESIUM SILICATE 14807-96-6 10.0
SOLVENT NAPHTHA, LIGHT AROMATIC 64742-95-6 5.0
1,2,4-TRIMETHYLBENZENE 95-63-6 5.0
CARBON BLACK 1333-86-4 5.0
ETHYLBENZENE 100-41-4 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
ACETONE 500 PPM 750 PPM 1000 PPM N.E.
LIQUEFIED PETROLEUM GAS N.E. N.E. N.E. N.E.
N-BUTYL ACETATE 150 PPM 200 PPM 150 PPM N.E.
HYDROUS MAGNESIUM 2 MG/M3 N.E. 20 MPPCF N.E.
SILICATE (RESPIRABLE (MINERAL
DUST) DUST <1%
QUARTZ)
SOLVENT NAPHTHA, LIGHT N.E. N.E. N.E. N.E.
AROMATIC
1,2,4-TRIMETHYLBENZENE 25 PPM N.E. N.E. N.E.
(NIOSH
REL)
CARBON BLACK 3 MG/M3 N.E. 3.5 MG/M3 N.E.
(INHALABLE
DUST)
ETHYLBENZENE 20 PPM 125 PPM 100 PPM N.E.
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN
ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION. IF SWALLOWED, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
FLASH POINT, DEG. F: -156 (SETAFLASH)
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND, WATER
FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
FLASH POINT IS LESS THAN 20 DEG. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR!
WATER SPRAY MAY BE INEFFECTIVE. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED
TO EXTREME HEAT DUE TO BUILDUP OF STEAM. CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. ISOLATE FROM
HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME. PERFORATION OF THE
PRESSURIZED CONTAINER MAY CAUSE BURSTING OF THE CAN. NO UNUSUAL FIRE OR
EXPLOSION HAZARDS NOTED. KEEP CONTAINERS TIGHTLY CLOSED.
SPECIAL FIREFIGHTING PROCEDURES:
FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS
SHOULD BE USED. EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE. WATER
MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP AND
POSSIBLE AUTOIGNITION OR EXPLOSION. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL. CONTAINERS MAY EXPLODE WHEN HEATED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. ISOLATE THE HAZARD AREA AND DENY ENTRY TO UNNECESSARY AND
UNPROTECTED PERSONNEL. REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND
REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. DISPOSE OF ACCORDING
TO LOCAL, STATE (PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE
CLOSED CONTAINERS. VENTILATE AREA, ISOLATE SPILLED MATERIAL, AND REMOVE
WITH INERT ABSORBENT. DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND
UNUSED CONTENTS IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY WITH ADEQUATE
VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS
EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. CONTENTS UNDER PRESSURE. DO NOT STORE ABOVE
120 DEG. F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR
STORAGE OF NFPA CLASS I FLAMMABLE LIQUIDS. PRODUCT SHOULD BE STORED IN
TIGHTLY SEALED CONTAINERS AND PROTECTED FROM HEAT, MOISTURE, AND FOREIGN
MATERIALS. STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE. KEEP AWAY FROM HEAT, SPARKS, FLAME AND SOURCES OF
IGNITION. AVOID EXCESS HEAT.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
USE EXPLOSION-PROOF VENTILATION EQUIPMENT. PROVIDE GENERAL DILUTION OF
LOCAL EXHAUST VENTILATION IN VOLUME AND PATTERN TO KEEP TLV OF HAZARDOUS
INGREDIENTS BELOW ACCEPTABLE LIMITS. PREVENT BUILD-UP OF VAPORS BY OPENING
ALL DOORS AND WINDOWS TO ACHIEVE CROSS-VENTILATION. USE PROCESS ENCLOSURES,
LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO CONTROL
AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE
LIMITS.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. NITRILE OR NEOPRENE GLOVES
MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE
REGARDING TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
VAPOR DENSITY: HEAVIER THAN AIR
ODOR: SOLVENT LIKE
APPEARANCE: AEROSOLIZED MIST
EVAPORATION RATE: FASTER THAN ETHER
SOLUBILITY IN WATER: SLIGHT
FREEZE POINT: N.D.
SPECIFIC GRAVITY: 0.802
PH: N.A.
PHYSICAL STATE: LIQUID
(SEE SECTION 16 FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 120 DEG. F. AVOID CONTACT WITH STRONG ACID AND
STRONG BASES. AVOID ALL POSSIBLE SOURCES OF IGNITION.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO
DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES. CONTAINS
SOLVENTS WHICH MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND FORMALDEHYDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
CHEMICAL NAME LD50 LC50
ACETONE 5800 MG/KG (RAT) 50100 MG/M3 (RAT, 8HR)
LIQUEFIED PETROLEUM GAS N.E. N.E.
N-BUTYL ACETATE 13100 MG/KG 2000 PPM
(RAT, ORAL) (RAT, INHALATION, 4HR)
HYDROUS MAGNESIUM SILICATE >15,000 MG/KG TCLO: 11 MG/M3 (INHALATION)
(ORAL, RAT)
SOLVENT NAPHTHA, LIGHT 4700 MG/KG 3400 MG/KG
AROMATIC (RAT, ORAL) (RAT, INHALATION, 4 HR)
1,2,4-TRIMETHYLBENZENE 3280 MG/KG 18,000 MG/M3
(ORAL, RAT) (INHALATION, RAT, 4 HR)
CARBON BLACK >8000 MG/KG N.E.
(RAT, ORAL)
ETHYLBENZENE 3500 MG/KG 17.2 MG/KG
(RAT, ORAL) (RAT, INHALATION, 4HR)
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR TDG
(USDOT) (IMDG) (IATA) (CANADA)
UN NUMBER N.A. 1950 1950 N.A.
PROPER SHIPPING PAINT PRODUCTS AEROSOLS AEROSOLS PAINT PRODUCTS
NAME IN LIMITED IN LIMITED
QUANTITIES QUANTITIES
HAZARD CLASS N.A. 2.1 2.1 N.A.
PACKING GROUP N.A. N.A. N.A. N.A.
LIMITED QUANTITY YES YES YES YES
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FIRE HAZARD, PRESSURE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
1,2,4-TRIMETHYLBENZENE 95-63-6
SEC-BUTYL ALCOHOL 78-92-2
XYLENE (MIXED ISOMERS) 1330-20-7
ETHYLBENZENE 100-41-4
ORTHO-XYLENE 95-47-6
PARA-XYLENE 106-42-3
META-XYLENE 108-38-3
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
INTERNATIONAL REGULATIONS:
CANADIAN WHMIS:
THIS SDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
CANADIAN WHMIS CLASS:
AB5
D2A
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 4
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 4
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 538
REASON FOR REVISION: REGULATORY UPDATE
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.