Grainger SDS Lookup

COMPANY:
ARKEMA INC.
900 FIRST AVENUE
KING OF PRUSSIA, PENNSYLVANIA 19406

FLUOROCHEMICALS

CUSTOMER SERVICE TELEPHONE NUMBER: (800) 245-5858
(MONDAY THROUGH FRIDAY, 8:00 AM TO 5:00 PM EST)

EMERGENCY INFORMATION:

TRANSPORTATION:
CHEMTREC: (800) 424-9300
(24 HRS., 7 DAYS A WEEK)

MEDICAL:
ROCKY MOUNTAIN POISON CENTER: (866) 767-5089
(24 HRS., 7 DAYS A WEEK)

PRODUCT INFORMATION:

PRODUCT NAME: FORANE(R*) 134A

SYNONYMS: HFC 134A, R 134A

MOLECULAR FORMULA: CH2FCF3

CHEMICAL FAMILY: HYDROFLUOROCARBON

MOLECULAR WEIGHT: 102.03 G/MOL

PRODUCT USE: REFRIGERANT, FOAM BLOWING AGENT, AEROSOL PROPELLANTS

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW:

COLOR: CLEAR - COLOURLESS

PHYSICAL STATE: GASEOUS

FORM: LIQUEFIED GAS

ODOR: SLIGHTLY ETHER-LIKE

*CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GASES UNDER PRESSURE, LIQUEFIED GAS, H280

*FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.

GHS-LABELING:

HAZARD PICTOGRAMS: GAS CYLINDER

SIGNAL WORD: WARNING

HAZARD STATEMENTS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.

SUPPLEMENTAL HAZARD STATEMENTS:
OVERHEATING OR OVER PRESSURIZING MAY CAUSE GAS RELEASE OR VIOLENT CYLINDER
BURSTING. MAY DECOMPOSE ON CONTACT WITH FLAMES OR EXTREMELY HOT METAL
SURFACES TO PRODUCE TOXIC AND CORROSIVE PRODUCTS. MAY CAUSE FROSTBITE. MAY
CAUSE HEADACHE, NAUSEA, DIZZINESS, DROWSINESS, LOSS OF CONSCIOUSNESS. MAY
CAUSE CARDIAC SENSITIZATION/CARDIAC ARRHYTHMIA. MAY DISPLACE OXYGEN AND
CAUSE RAPID SUFFOCATION.

PRECAUTIONARY STATEMENTS:

STORAGE:
P403: STORE IN A WELL-VENTILATED PLACE.
P410: PROTECT FROM SUNLIGHT.

SUPPLEMENTAL INFORMATION:

POTENTIAL HEALTH EFFECTS:

LIQUID:
CONTACT WITH LIQUID OR REFRIGERATED GAS CAN CAUSE COLD BURNS AND FROSTBITE.
VAPOR: VAPOR IS HEAVIER THAN AIR AND CAN CAUSE SUFFOCATION BY REDUCING
OXYGEN AVAILABLE FOR BREATHING.

IF INHALED:

CENTRAL NERVOUS SYSTEM EFFECTS:
HEADACHE, NAUSEA, DIZZINESS, DROWSINESS, LOSS OF CONSCIOUSNESS.

STRESS INDUCED HEART EFFECTS:
INHALATION MAY CAUSE AN INCREASE IN THE SENSITIVITY OF THE HEART TO
ADRENALINE, WHICH COULD RESULT IN IRREGULAR OR RAPID HEARTBEATS AND REDUCED
HEART FUNCTION.

MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE:
HEART DISEASE OR COMPROMISED HEART FUNCTION.

3. COMPOSITION/INFORMATION ON INGREDIENTS

CHEMICAL NAME CAS-NO. WT/WT GHS CLASSIFICATION**

ETHANE, 1,1,1,2-TETRAFLUORO- 811-97-2 >99% H280

**FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.

4. FIRST AID MEASURES

INHALATION:
IF INHALED, REMOVE VICTIM TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.

SKIN:
IF ON SKIN, FLUSH EXPOSED SKIN WITH LUKEWARM WATER (NOT HOT), OR USE OTHER
MEANS TO WARM SKIN SLOWLY. GET MEDICAL ATTENTION IF FROSTBITTEN BY LIQUID
OR IF IRRITATION OCCURS. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH
CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.

EYES: IMMEDIATELY FLUSH EYE(S) WITH PLENTY OF WATER.

INGESTION:
INGESTION IS NOT APPLICABLE - PRODUCT IS A GAS AT AMBIENT TEMPERATURES.

NOTES TO PHYSICIAN: DO NOT GIVE DRUGS FROM ADRENALINE-EPHEDRINE GROUP.

5. FIREFIGHTING MEASURES

EXTINGUISHING MEDIA (SUITABLE):
USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS.

PROTECTIVE EQUIPMENT:
FIRE FIGHTERS AND OTHERS WHO MAY BE EXPOSED TO PRODUCTS OF COMBUSTION
SHOULD WEAR FULL FIRE FIGHTING TURN OUT GEAR (FULL BUNKER GEAR) AND
SELF-CONTAINED BREATHING APPARATUS (PRESSURE DEMAND / NIOSH APPROVED OR
EQUIVALENT).

FURTHER FIREFIGHTING ADVICE:

FIGHT FIRE WITH LARGE AMOUNTS OF WATER FROM A SAFE DISTANCE.

STOP THE FLOW OF GAS IF POSSIBLE.

WATER MIST SHOULD BE USED TO REDUCE VAPOR CONCENTRATIONS IN AIR.

COOL CLOSED CONTAINERS EXPOSED TO FIRE WITH WATER SPRAY.

CLOSED CONTAINERS OF THIS MATERIAL MAY EXPLODE WHEN SUBJECTED TO HEAT FROM
SURROUNDING FIRE.

AFTER A FIRE, WAIT UNTIL THE MATERIAL HAS COOLED TO ROOM TEMPERATURE BEFORE
INITIATING CLEAN-UP ACTIVITIES.

FIRE FIGHTING EQUIPMENT SHOULD BE THOROUGHLY DECONTAMINATED AFTER USE.

FIRE AND EXPLOSION HAZARDS:

MAY DECOMPOSE ON CONTACT WITH FLAMES OR EXTREMELY HOT METAL SURFACES TO
PRODUCE TOXIC AND CORROSIVE PRODUCTS.

LIQUID AND GAS UNDER PRESSURE, OVERHEATING OR OVER PRESSURIZING MAY CAUSE
GAS RELEASE AND/OR VIOLENT CYLINDER BURSTING.

CONTAINER MAY EXPLODE IF HEATED DUE TO RESULTING PRESSURE RISE.

SOME MIXTURES OF HCFCS AND/OR HFCS, AND AIR OR OXYGEN MAY BE COMBUSTIBLE IF
PRESSURIZED AND EXPOSED TO EXTREME HEAT OR FLAME.

WHEN BURNED, THE FOLLOWING HAZARDOUS PRODUCTS OF COMBUSTION CAN OCCUR:

CARBON OXIDES
HYDROGEN FLUORIDE
CARBONYL HALIDES

6. ACCIDENTAL RELEASE MEASURES

IN CASE OF SPILL OR LEAK:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF YOU CAN DO SO WITHOUT RISK. EVACUATE
AREA OF ALL UNNECESSARY PERSONNEL. ELIMINATE ALL IGNITION SOURCES. USE
HALOGEN LEAK DETECTOR OR OTHER SUITABLE MEANS TO LOCATE LEAKS OR CHECK
ATMOSPHERE. KEEP UPWIND. EVACUATE ENCLOSED SPACES AND DISPERSE GAS WITH
FLOOR-LEVEL FORCED-AIR VENTILATION. AVOID BREATHING LEAKED MATERIAL.
CONSULT A REGULATORY SPECIALIST TO DETERMINE APPROPRIATE STATE OR LOCAL
REPORTING REQUIREMENTS, FOR ASSISTANCE IN WASTE CHARACTERIZATION AND/OR
HAZARDOUS WASTE DISPOSAL AND OTHER REQUIREMENTS LISTED IN PERTINENT
ENVIRONMENTAL PERMITS.

7. HANDLING AND STORAGE

HANDLING:

GENERAL INFORMATION ON HANDLING:

AVOID BREATHING GAS.

AVOID CONTACT WITH THE SKIN, EYES AND CLOTHING.

KEEP AWAY FROM HEAT, SPARKS AND FLAMES.

WEAR COLD-INSULATING GLOVES/FACE SHIELD/EYE PROTECTION.

KEEP CONTAINER CLOSED.

USE ONLY WITH ADEQUATE VENTILATION.

USE EQUIPMENT RATED FOR CYLINDER PRESSURE.

USE A BACKFLOW PREVENTATIVE DEVICE IN PIPING.

WASH THOROUGHLY AFTER HANDLING.

DO NOT CHANGE OR FORCE FIT CONNECTIONS.

CLOSE VALVE AFTER EACH USE AND WHEN EMPTY.

DO NOT ENTER CONFINED SPACES UNLESS ADEQUATELY VENTILATED.

DO NOT CUT, DRILL, GRIND, OR WELD ON OR NEAR THIS CONTAINER.

EMPTIED CONTAINER RETAINS PRODUCT RESIDUE.

OBSERVE ALL LABELED SAFEGUARDS UNTIL CONTAINER IS CLEANED, RECONDITIONED OR
DESTROYED.

STORAGE:

GENERAL INFORMATION ON STORAGE CONDITIONS:
KEEP AWAY FROM DIRECT SUNLIGHT. KEEP CYLINDERS RESTRAINED. STORE IN COOL,
DRY, WELL VENTILATED AREA AWAY FROM SOURCES OF IGNITION SUCH AS FLAME,
SPARKS AND STATIC ELECTRICITY.

STORAGE STABILITY - REMARKS:
DO NOT APPLY DIRECT FLAME TO CYLINDER. DO NOT STORE CYLINDER IN DIRECT SUN
OR EXPOSE IT TO HEAT ABOVE 120 F (48.9 C.). DO NOT DROP OR REFILL THIS
CYLINDER.

STORAGE INCOMPATIBILITY - GENERAL:
STORE SEPARATE FROM: ALKALINE EARTH METALS
FINELY DIVIDED METALS (ALUMINIUM, MAGNESIUM, ZINC...)
STRONG OXIDIZING AGENTS
ALKALI METALS
STRONG BASES

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

AIRBORNE EXPOSURE GUIDELINES:

ETHANE, 1,1,1,2-TETRAFLUORO- (811-97-2):

US. OARS. WEELS WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL GUIDE:
TIME WEIGHTED AVERAGE: 1,000 PPM (4,240 MG/M3)

REMARKS: LISTED

ONLY THOSE COMPONENTS WITH EXPOSURE LIMITS ARE PRINTED IN THIS SECTION.
LIMITS WITH SKIN CONTACT DESIGNATION ABOVE HAVE SKIN CONTACT EFFECT. AIR
SAMPLING ALONE IS INSUFFICIENT TO ACCURATELY QUANTITATE EXPOSURE. MEASURES
TO PREVENT SIGNIFICANT CUTANEOUS ABSORPTION MAY BE REQUIRED. LIMITS WITH A
SENSITIZER DESIGNATION ABOVE MEAN THAT EXPOSURE TO THIS MATERIAL MAY CAUSE
ALLERGIC REACTIONS.

ENGINEERING CONTROLS:

INVESTIGATE ENGINEERING TECHNIQUES TO REDUCE EXPOSURES BELOW AIRBORNE
EXPOSURE LIMITS OR TO OTHERWISE REDUCE EXPOSURES. PROVIDE VENTILATION IF
NECESSARY TO MINIMIZE EXPOSURES OR TO CONTROL EXPOSURE LEVELS TO BELOW
AIRBORNE EXPOSURE LIMITS (IF APPLICABLE SEE ABOVE).IF PRACTICAL, USE LOCAL
MECHANICAL EXHAUST VENTILATION AT SOURCES OF AIR CONTAMINATION SUCH AS OPEN
PROCESS EQUIPMENT.

MONITOR CARBON MONOXIDE AND OXYGEN LEVELS IN TANKS AND ENCLOSED SPACES.
CONSULT ACGIH VENTILATION MANUAL, NFPA STANDARD 91 AND NFPA STANDARD 654
FOR DESIGN OF EXHAUST SYSTEM AND SAFE HANDLING.

RESPIRATORY PROTECTION:
AVOID BREATHING GAS. WHERE AIRBORNE EXPOSURE IS LIKELY OR AIRBORNE EXPOSURE
LIMITS ARE EXCEEDED (IF APPLICABLE, SEE ABOVE), USE NIOSH APPROVED
RESPIRATORY PROTECTION EQUIPMENT APPROPRIATE TO THE MATERIAL AND/OR ITS
COMPONENTS (FULL FACEPIECE RECOMMENDED). CONSULT RESPIRATOR MANUFACTURER TO
DETERMINE APPROPRIATE TYPE EQUIPMENT FOR A GIVEN APPLICATION. OBSERVE
RESPIRATOR USE LIMITATIONS SPECIFIED BY NIOSH OR THE MANUFACTURER. FOR
EMERGENCY AND OTHER CONDITIONS WHERE THERE MAY BE A POTENTIAL FOR
SIGNIFICANT EXPOSURE OR WHERE EXPOSURE LIMIT MAY BE SIGNIFICANTLY EXCEEDED,
USE AN APPROVED FULL FACE POSITIVE-PRESSURE, SELF-CONTAINED BREATHING
APPARATUS OR POSITIVE-PRESSURE AIRLINE WITH AUXILIARY SELF-CONTAINED AIR
SUPPLY. RESPIRATORY PROTECTION PROGRAMS MUST COMPLY WITH 29 CFR SUBSECTION
1910.134.

SKIN PROTECTION:
WEAR APPROPRIATE CHEMICAL RESISTANT PROTECTIVE CLOTHING AND CHEMICAL
RESISTANT GLOVES TO PREVENT SKIN CONTACT. CONSULT GLOVE MANUFACTURER TO
DETERMINE APPROPRIATE TYPE GLOVE MATERIAL FOR GIVEN APPLICATION. RINSE
IMMEDIATELY IF SKIN IS CONTAMINATED. WASH CONTAMINATED CLOTHING AND CLEAN
PROTECTIVE EQUIPMENT BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING.

EYE PROTECTION: USE GOOD INDUSTRIAL PRACTICE TO AVOID EYE CONTACT.

9. PHYSICAL AND CHEMICAL PROPERTIES

COLOR: CLEAR - COLOURLESS

PHYSICAL STATE: GASEOUS

FORM: LIQUEFIED GAS

ODOR: SLIGHTLY ETHER-LIKE

ODOR THRESHOLD: NO DATA AVAILABLE

FLASH POINT: NOT APPLICABLE

AUTO-IGNITION TEMPERATURE: 1,369 DEG. F (743 DEG. C)

LOWER FLAMMABLE LIMIT (LFL): NONE.
UPPER FLAMMABLE LIMIT (UFL): NONE.

PH: NOT APPLICABLE

DENSITY: NOT DETERMINED

SPECIFIC GRAVITY (RELATIVE DENSITY): 1.21 (77 DEG. F(25 DEG. C))

VAPOR PRESSURE: 4,432.000 MMHg (70.0 DEG. F (21.1 DEG. C))

RELATIVE VAPOR DENSITY: 3.54 (AIR = 1.0)

VAPOR DENSITY: 3.54 KG/M3

BOILING POINT/BOILING RANGE: -15.5 DEG. F (-26.4 DEG. C)

FREEZING POINT: -150 DEG. F (-101 DEG. C)

MELTING POINT/RANGE: NO DATA AVAILABLE

EVAPORATION RATE: NO DATA AVAILABLE

SOLUBILITY IN WATER: 0.9 G/L 77 DEG. F (25 DEG. C)

MOLECULAR WEIGHT: 102.03 G/MOL

OIL/WATER PARTITION COEFFICIENT: NOT APPLICABLE

THERMAL DECOMPOSITION: >698 DEG. F (>370 DEG. C)

CRITICAL POINT:
CRITICAL PRESSURE: 30,528 MMHg
CRITICAL TEMPERATURE: 214 DEG. F (101 DEG. C)

HENRY'S CONSTANT: 10.2E+03 PA.M3/MOL 77 DEG. F (25 DEG. C)

FLAMMABILITY: SEE GHS CLASSIFICATION IN SECTION 2

10. STABILITY AND REACTIVITY

STABILITY:
THIS MATERIAL IS CHEMICALLY STABLE UNDER NORMAL AND ANTICIPATED STORAGE,
HANDLING AND PROCESSING CONDITIONS.

MATERIALS TO AVOID:
ALKALINE EARTH METALS
FINELY DIVIDED METALS (ALUMINIUM, MAGNESIUM, ZINC...)
STRONG OXIDIZING AGENTS
ALKALI METALS
STRONG BASES

CONDITIONS / HAZARDS TO AVOID: HEAT

HAZARDOUS DECOMPOSITION PRODUCTS:

THERMAL DECOMPOSITION GIVING TOXIC AND CORROSIVE PRODUCTS:
HYDROGEN FLUORIDE
CARBONYL HALIDES
CARBON OXIDES

11. TOXICOLOGICAL INFORMATION

DATA FOR FORANE(R*) 134A

ACUTE TOXICITY:

INHALATION:

PRACTICALLY NONTOXIC. (RAT) 4 H LC50 APPROXIMATELY 567000 PPM.

SIGNS/EFFECTS REPORTED AFTER ACUTE EXPOSURE (MOUSE, DOG, CAT, MONKEY)
SIGNS: ANESTHETIC EFFECTS

SKIN IRRITATION:
PRACTICALLY NON-IRRITATING. (RABBIT) IRRITATION INDEX: <1 / 8. (24 H)
(OCCLUDED EXPOSURE)

EYE IRRITATION: CAUSES MILD EYE IRRITATION. (RABBIT) (VAPOR)

SENSITIZATION:
CAUSES CARDIAC SENSITIZATION. INHALATION. (DOG) STRESS INDUCED HEART
EFFECTS: SIGNS: IRREGULAR HEART BEAT, RAPID HEART BEAT, IN SOME CASES,
SUDDEN DEATH (REACTION MAY OCCUR IN RESPONSE TO STRESS (NATURAL ADRENALINE
RELEASE) OR ADMINISTRATION OF EPINEPHRINE.)

SKIN SENSITIZATION:
NOT A SENSITIZER. GUINEA PIG MAXIMIZATION TEST. NO SKIN ALLERGY WAS
OBSERVED

REPEATED DOSE TOXICITY:
CHRONIC INHALATION ADMINISTRATION TO RAT / NO ADVERSE SYSTEMIC EFFECTS
REPORTED.

CARCINOGENICITY:

CHRONIC INHALATION ADMINISTRATION TO MALE RAT / AFFECTED ORGAN(S):
TESTES / SIGNS: TUMORS WERE BENIGN., INCREASE IN TUMOR INCIDENCE WAS
REPORTED.

CHRONIC INHALATION ADMINISTRATION TO FEMALE RAT / SIGNS:
NO INCREASE IN TUMOR INCIDENCE WAS REPORTED.

CHRONIC INHALATION ADMINISTRATION TO MOUSE / SIGNS:
NO INCREASE IN TUMOR INCIDENCE WAS REPORTED.

1 YEAR ORAL GAVAGE ADMINISTRATION TO RAT / SIGNS:
NO INCREASE IN TUMOR INCIDENCE WAS REPORTED.

GENOTOXICITY:

ASSESSMENT IN VITRO:
NO GENETIC CHANGES WERE OBSERVED IN LABORATORY TESTS USING: BACTERIA,
ANIMAL CELLS, YEAST, HUMAN CELLS

ASSESSMENT IN VIVO:
NO GENETIC CHANGES WERE OBSERVED IN LABORATORY TESTS USING: RATS, MICE

DEVELOPMENTAL TOXICITY:

EXPOSURE DURING PREGNANCY. INHALATION (RAT) / NO BIRTH DEFECTS WERE
OBSERVED. (DELAYS IN DEVELOPMENT, AT DOSES THAT PRODUCE EFFECTS IN MOTHERS)

EXPOSURE DURING PREGNANCY. INHALATION (RABBIT) / NO BIRTH DEFECTS WERE
OBSERVED.

REPRODUCTIVE EFFECTS:
TWO-GENERATION STUDY. INHALATION (RAT) / NO TOXICITY TO REPRODUCTION.

12. ECOLOGICAL INFORMATION

CHEMICAL FATE AND PATHWAY:
DATA ON THIS MATERIAL AND/OR ITS COMPONENTS ARE SUMMARIZED BELOW.

DATA FOR FORANE(R*) 134A

BIODEGRADATION: NOT READILY BIODEGRADABLE. (28 D) BIODEGRADATION 3%

OCTANOL WATER PARTITION COEFFICIENT: LOG POW = 1.06

PHOTODEGRADATION:
DEGRADATION IN THE ATMOSPHERE HALF-LIFE DIRECT PHOTOLYSIS: 9.6 - 16.7 Y

GLOBAL WARMING POTENTIAL:

GWP 0.3 (HALOCARBON GLOBAL WARMING POTENTIAL.)

GWP 1,320 (GLOBAL WARMING POTENTIAL WITH RESPECT TO CO2 (TIME HORIZON 100
YEARS))

OZONE DEPLETION POTENTIAL: ODP 0

ECOTOXICOLOGY:
DATA ON THIS MATERIAL AND/OR ITS COMPONENTS ARE SUMMARIZED BELOW.

DATA FOR FORANE(R*) 134A

AQUATIC TOXICITY DATA:
PRACTICALLY NONTOXIC. ONCORHYNCHUS MYKISS (RAINBOW TROUT) 96 H LC50 = 450
MG/L

AQUATIC INVERTEBRATES:
PRACTICALLY NONTOXIC. DAPHNIA MAGNA (WATER FLEA) 48 H EC50 = 930 MG/L

MICROORGANISMS:
PRACTICALLY NONTOXIC. PSEUDOMONAS PUTIDA 16 H EC10 >730 MG/L

13. DISPOSAL CONSIDERATIONS

WASTE DISPOSAL:
DO NOT VENT THE CONTAINER CONTENTS, OR PRODUCT RESIDUALS, TO THE
ATMOSPHERE. RECOVER AND RECLAIM UNUSED CONTENTS OR RESIDUALS AS
APPROPRIATE. RECOVERED/RECLAIMED PRODUCT CAN BE RETURNED TO AN APPROVED
CERTIFIED RECLAIMER OR BACK TO THE SELLER DEPENDING ON THE MATERIAL.
COMPLETELY EMPTIED DISPOSABLE CONTAINERS CAN BE DISPOSED OF AS RECYCLABLE
STEEL. RETURNABLE CYLINDERS MUST BE RETURNED TO SELLER. DISPOSE OF IN
ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. CONSULT A REGULATORY
SPECIALIST TO DETERMINE APPROPRIATE STATE OR LOCAL REPORTING REQUIREMENTS,
FOR ASSISTANCE IN WASTE CHARACTERIZATION AND/OR HAZARDOUS WASTE DISPOSAL
AND OTHER REQUIREMENTS LISTED IN PERTINENT ENVIRONMENTAL PERMITS.

NOTE:
CHEMICAL ADDITIONS TO, PROCESSING OF, OR OTHERWISE ALTERING THIS MATERIAL
MAY MAKE THIS WASTE MANAGEMENT INFORMATION INCOMPLETE, INACCURATE, OR
OTHERWISE INAPPROPRIATE. FURTHERMORE, STATE AND LOCAL WASTE DISPOSAL
REQUIREMENTS MAY BE MORE RESTRICTIVE OR OTHERWISE DIFFERENT FROM FEDERAL
LAWS AND REGULATIONS.

14. TRANSPORT INFORMATION

US DEPARTMENT OF TRANSPORTATION (DOT):
UN NUMBER: 3159
PROPER SHIPPING NAME: 1,1,1,2-TETRAFLUOROETHANE(REFRIGERANT GAS R 134A)
CLASS: 2.2
MARINE POLLUTANT: NO

INTERNATIONAL MARITIME DANGEROUS GOODS CODE (IMDG):
UN NUMBER: 3159
PROPER SHIPPING NAME: 1,1,1,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 134A)
CLASS: 2.2
MARINE POLLUTANT: NO

15. REGULATORY INFORMATION

CHEMICAL INVENTORY STATUS:

EU. EINECS                      EINECS      CONFORMS TO

UNITED STATES TSCA INVENTORY    TSCA        THE COMPONENTS OF THIS PRODUCT
                                            ARE ALL ON THE TSCA INVENTORY.

CANADIAN DOMESTIC SUBSTANCES    DSL         ALL COMPONENTS OF THIS PRODUCT
LIST (DSL)                                  ARE ON THE CANADIAN DSL.

CHINA. INVENTORY OF EXISTING    IECSC (CN)  CONFORMS TO
CHEMICAL SUBSTANCES IN CHINA
(IECSC)

JAPAN. ENCS - EXISTING AND NEW  ENCS (JP)   DOES NOT CONFORM
CHEMICAL SUBSTANCES INVENTORY

JAPAN. ISHL - INVENTORY OF      ISHL (JP)   DOES NOT CONFORM
CHEMICAL SUBSTANCES

KOREA. KOREAN EXISTING          KECI (KR)   CONFORMS TO
CHEMICALS INVENTORY (KECI)

PHILIPPINES INVENTORY OF        PICCS (PH)  CONFORMS TO
CHEMICALS AND CHEMICAL
SUBSTANCES (PICCS)

AUSTRALIA INVENTORY OF          AICS        CONFORMS TO
CHEMICAL SUBSTANCES (AICS)

UNITED STATES - FEDERAL REGULATIONS:

SARA TITLE III - SECTION 302 EXTREMELY HAZARDOUS CHEMICALS:
THE COMPONENTS IN THIS PRODUCT ARE EITHER NOT SARA SECTION 302 REGULATED OR
REGULATED BUT PRESENT IN NEGLIGIBLE CONCENTRATIONS.

SARA TITLE III - SECTION 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD, SUDDEN RELEASE OF PRESSURE HAZARD

SARA TITLE III - SECTION 313 TOXIC CHEMICALS:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.

COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
(CERCLA) - REPORTABLE QUANTITY (RQ):
THE COMPONENTS IN THIS PRODUCT ARE EITHER NOT CERCLA REGULATED, REGULATED
BUT PRESENT IN NEGLIGIBLE CONCENTRATIONS, OR REGULATED WITH NO ASSIGNED
REPORTABLE QUANTITY.

UNITED STATES - STATE REGULATIONS:

NEW JERSEY RIGHT TO KNOW:
NO COMPONENTS ARE SUBJECT TO THE NEW JERSEY RIGHT TO KNOW ACT.

PENNSYLVANIA RIGHT TO KNOW:

CHEMICAL NAME                  CAS-NO.

ETHANE, 1,1,1,2-TETRAFLUORO-   811-97-2

CALIFORNIA PROP. 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS, OR ANY OTHER REPRODUCTIVE
DEFECTS.

16. OTHER INFORMATION

FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.

MISCELLANEOUS:

OTHER INFORMATION:
THIS MSDS COVERS THE FOLLOWING GRADES: HIGH PURITY.

LATEST REVISION(S):

REFERENCE NUMBER: 000000033838

DATE OF REVISION: 05/09/2015

DATE PRINTED: 05/09/2015

FORANE(R*) IS A REGISTERED TRADEMARK OF ARKEMA INC.

ARKEMA INC. BELIEVES THAT THE INFORMATION AND RECOMMENDATIONS CONTAINED
HEREIN (INCLUDING DATA AND STATEMENTS) ARE ACCURATE AS OF THE DATE HEREOF.
NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF
MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE
CONCERNING THE INFORMATION PROVIDED HEREIN. THE INFORMATION PROVIDED HEREIN
RELATES ONLY TO THE SPECIFIC PRODUCT DESIGNATED AND MAY NOT BE VALID WHERE
SUCH PRODUCT IS USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS. FURTHER, SINCE THE CONDITIONS AND METHODS OF USE ARE BEYOND THE
CONTROL OF ARKEMA INC., ARKEMA INC. EXPRESSLY DISCLAIMS ANY AND ALL
LIABILITY AS TO ANY RESULTS OBTAINED OR ARISING FROM ANY USE OF THE PRODUCT
OR RELIANCE ON SUCH INFORMATION.

PRODUCT CODE: 04134

VERSION: 4.0

ISSUED ON: 05/09/2015

QUICK-FDS [17298-32564-27858-014719] - 2015-05-11 - 09:02:44