| Common Name: | TOILET BOWL CLEANER - TOUGH STAIN REMOVER |
| Manufacturer: | CLOROX |
| SDS Revision Date: | 1/5/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 20K968 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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THE CLOROX COMPANY
SAFETY DATA SHEET
ISSUING DATE: JANUARY 5, 2015
REVISION DATE: NEW
REVISION NUMBER: 0
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND OF THE COMPANY/UNDERTAKING
PRODUCT IDENTIFIER:
PRODUCT NAME: CLOROX(R*) TOILET BOWL CLEANER - TOUGH STAIN REMOVER
OTHER MEANS OF IDENTIFICATION:
EPA REGISTRATION NUMBER: 5813-87
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: DISINFECTING TOILET BOWL CLEANER
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER ADDRESS:
THE CLOROX COMPANY
1221 BROADWAY
OAKLAND, CA 94612
PHONE: 1-510-271-7000
EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE NUMBERS:
FOR MEDICAL EMERGENCIES CALL: 1-800-446-1014
FOR TRANSPORTATION EMERGENCIES, CALL CHEMTREC: 1-800-424-9300
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
SKIN CORROSION/IRRITATION CATEGORY: 3
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
EMERGENCY OVERVIEW:
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES MILD SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
EXCLAMATION MARK
APPEARANCE: CLEAR, BLUE
PHYSICAL STATE: VISCOUS LIQUID
ODOR: APPLE, FLORAL
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR EYE PROTECTION/FACE PROTECTION SUCH AS SAFETY GLASSES.
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT
LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
PRECAUTIONARY STATEMENTS - STORAGE: NONE
PRECAUTIONARY STATEMENTS - DISPOSAL: NONE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NO INFORMATION AVAILABLE.
UNKNOWN TOXICITY:
3% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
OTHER INFORMATION: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
INTERACTIONS WITH OTHER CHEMICALS:
MAY REACT WITH BLEACH-CONTAINING PRODUCTS OR OTHER HOUSEHOLD CLEANERS TO
PRODUCE HAZARDOUS GASES.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NO. WEIGHT % TRADE SECRET
GLYCOLIC ACID 79-14-1 1 - 5 *
OCTYL DECYL DIMETHYL AMMONIUM 32426-11-2 0.1 - 0.3 *
CHLORIDES
N-ALKYL (40% C12, 50% C14, 68424-85-1 0.1 - 0.3 *
10% C16) DIMETHYL BENZYL
AMMONIUM CHLORIDES
* THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS
A TRADE SECRET
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
CALL A POISON CONTROL CENTER OR DOCTOR IMMEDIATELY FOR TREATMENT ADVICE.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
EYE CONTACT:
HOLD EYE OPEN AND RINSE SLOWLY AND GENTLY WITH WATER FOR 15 - 20 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST 5 MINUTES, THEN CONTINUE
RINSING EYE. CALL A POISON CONTROL CENTER OR DOCTOR FOR TREATMENT ADVICE.
SKIN CONTACT:
TAKE OFF CONTAMINATED CLOTHING. RINSE SKIN IMMEDIATELY WITH PLENTY OF WATER
FOR 15-20 MINUTES. CALL A POISON CONTROL CENTER OR DOCTOR FOR TREATMENT
ADVICE.
INHALATION:
MOVE TO FRESH AIR. IF THE PERSON IS NOT BREATHING, CALL 911 OR AN
AMBULANCE, AND THEN GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH.
CALL A POISON CONTROL CENTER OR DOCTOR IMMEDIATELY FOR TREATMENT ADVICE.
INGESTION:
HAVE PERSON SIP A GLASSFUL OF WATER IF ABLE TO SWALLOW. DO NOT INDUCE
VOMITING UNLESS TOLD TO DO SO BY A POISON CONTROL CENTER OR DOCTOR. DO NOT
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A POISON CONTROL
CENTER OR DOCTOR IMMEDIATELY FOR TREATMENT ADVICE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
MOST IMPORTANT SYMPTOMS/EFFECTS: STINGING AND IRRITATION OF EYES.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
UNSUITABLE EXTINGUISHING MEDIA:
CAUTION: USE OF WATER SPRAY WHEN FIGHTING FIRE MAY BE INEFFICIENT.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NO INFORMATION AVAILABLE
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE
SENSITIVITY TO STATIC DISCHARGE: NONE
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS: AVOID CONTACT WITH SKIN, EYES, AND CLOTHING.
OTHER INFORMATION: REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
SEE SECTION 12 FOR ADDITIONAL ECOLOGICAL INFORMATION
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
ABSORB AND CONTAINERIZE. WASH RESIDUAL DOWN TO SANITARY SEWER. CONTACT THE
SANITARY TREATMENT FACILITY IN ADVANCE TO ASSURE ABILITY TO PROCESS
WASHED-DOWN MATERIAL.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. DO NOT EAT, DRINK, OR SMOKE
WHEN USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL, AND WELL-VENTILATED PLACE.
INCOMPATIBLE PRODUCTS: NONE KNOWN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
GLYCOLIC ACID NONE NONE NONE
79-14-1
N-ALKYL (40% C12, 50% C14, 10% C16) NONE NONE NONE
DIMETHYL BENZYL AMMONIUM CHLORIDE
68424-85-1
OCTYL DECYL DIMETHYL AMMONIUM CHLORIDE NONE NONE NONE
32426-11-2
ACGIH TLV:
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS - THRESHOLD LIMIT
VALUE.
OSHA PEL:
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION - PERMISSIBLE EXPOSURE
LIMITS.
NIOSH IDLH: IMMEDIATELY DANGEROUS TO LIFE OR HEALTH.
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
IF SPLASHES ARE LIKELY TO OCCUR, WEAR SAFETY GLASSES WITH SIDE-SHIELDS.
NONE REQUIRED FOR CONSUMER USE.
SKIN AND BODY PROTECTION: NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED.
RESPIRATORY PROTECTION:
IF EXPOSURE LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, NIOSH/MSHA
APPROVED RESPIRATORY PROTECTION SHOULD BE WORN. POSITIVE-PRESSURE SUPPLIED
AIR RESPIRATORS MAY BE REQUIRED FOR HIGH AIRBORNE CONTAMINANT
CONCENTRATIONS. RESPIRATORY PROTECTION MUST BE PROVIDED IN ACCORDANCE WITH
CURRENT LOCAL REGULATIONS.
HYGIENE MEASURES:
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE RE-USE. AVOID CONTACT WITH
SKIN, EYES, OR CLOTHING. DO NOT EAT, DRINK, OR SMOKE WHEN USING THIS
PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: VISCOUS LIQUID
APPEARANCE: CLEAR
ODOR: APPLE, FLORAL
COLOR: BLUE
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS/ METHOD
PH 3 - 4 NONE KNOWN
MELTING/FREEZING POINT NO DATA AVAILABLE NONE KNOWN
BOILING POINT/RANGE NO DATA AVAILABLE NONE KNOWN
FLASH POINT NO DATA AVAILABLE NONE KNOWN
EVAPORATION RATE NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY (SOLID, GAS) NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO DATA AVAILABLE NONE KNOWN
LOWER FLAMMABILITY LIMIT NO DATA AVAILABLE NONE KNOWN
VAPOR PRESSURE NO DATA AVAILABLE NONE KNOWN
VAPOR DENSITY NO DATA AVAILABLE NONE KNOWN
SPECIFIC GRAVITY APPROX. 1.0 NONE KNOWN
WATER SOLUBILITY SOLUBLE IN WATER. NONE KNOWN
SOLUBILITY IN OTHER SOLVENTS NO DATA AVAILABLE NONE KNOWN
PARTITION COEFFICIENT N-OCTANOL/WATER NO DATA AVAILABLE NONE KNOWN
AUTOIGNITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
DECOMPOSITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
KINEMATIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
DYNAMIC VISCOSITY APPROX. 500 CP NONE KNOWN
EXPLOSIVE PROPERTIES NOT EXPLOSIVE
OXIDIZING PROPERTIES NO DATA AVAILABLE
OTHER INFORMATION:
SOFTENING POINT NO DATA AVAILABLE
VOC CONTENT (%) NO DATA AVAILABLE
PARTICLE SIZE NO DATA AVAILABLE
PARTICLE SIZE DISTRIBUTION NO DATA AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
MAY REACT WITH BLEACH-CONTAINING PRODUCTS OR OTHER HOUSEHOLD CLEANERS TO
PRODUCE HAZARDOUS GASES.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE KNOWN.
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBLE MATERIALS:
PRODUCTS CONTAINING BLEACH AND OTHER HOUSEHOLD CLEANERS.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
INHALATION: EXPOSURE TO VAPOR OR MIST MAY IRRITATE RESPIRATORY TRACT.
EYE CONTACT: MAY CAUSE EYE IRRITATION.
SKIN CONTACT: PROLONGED CONTACT MAY CAUSE IRRITATION.
INGESTION:
INGESTION MAY CAUSE IRRITATION TO MUCOUS MEMBRANES AND GASTROINTESTINAL
IRRITATION, NAUSEA, VOMITING, AND DIARRHEA.
COMPONENT INFORMATION:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
GLYCOLIC ACID 7.7 MG/L (RAT, 4 H)
79-14-1
INFORMATION ON TOXICOLOGICAL EFFECTS:
SYMPTOMS: MAY CAUSE REDNESS AND TEARING OF THE EYES.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE.
CARCINOGENICITY:
THIS PRODUCT DOES NOT CONTAIN ANY INGREDIENTS LISTED AS A CARCINOGEN.
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
CHRONIC TOXICITY: NO KNOWN EFFECT.
TARGET ORGAN EFFECTS: EYES, SKIN, RESPIRATORY SYSTEM
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
NUMERICAL MEASURES OF TOXICITY PRODUCT INFORMATION:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT:
ATEMIX (ORAL): 27 G/KG
ATEMIX (INHALATION-DUST/MIST): 416 MG/L
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC LIFE WITH LONG-LASTING EFFECTS.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
REGULATIONS.
CONTAMINATED PACKAGING:
DO NOT REUSE EMPTY CONTAINERS. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE, AND LOCAL REGULATIONS.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
TDG: NOT REGULATED
ICAO: NOT REGULATED
IATA: NOT REGULATED
IMDG/IMO: NOT REGULATED
| 15. REGULATORY INFORMATION | |
CHEMICAL INVENTORIES:
TSCA:
ALL COMPONENTS OF THIS PRODUCT ARE EITHER ON THE TSCA 8(B) INVENTORY OR
OTHERWISE EXEMPT FROM LISTING.
DSL/NDSL: ALL COMPONENTS ARE ON THE DSL OR NDSL.
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
U.S. FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372.
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
CLEAN WATER ACT:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES THAT ARE REGULATED POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS A
HAZARDOUS SUBSTANCE UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302).
EPA STATEMENT:
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE ENVIRONMENTAL
PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING REQUIREMENTS UNDER
FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM THE CLASSIFICATION
CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY DATA SHEETS AND FOR
WORKPLACE LABELS OF NON-PESTICIDE CHEMICALS. FOLLOWING IS THE HAZARD
INFORMATION AS REQUIRED ON THE PESTICIDE LABEL:
WARNING:
CAUSES SUBSTANTIAL BUT TEMPORARY EYE INJURY. DO NOT GET IN EYES, ON SKIN OR
CLOTHING. WEAR PROTECTIVE EYEWEAR SUCH AS GOGGLES, FACE SHIELD, OR SAFETY
GLASSES. WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING AND BEFORE
EATING, DRINKING, CHEWING GUM, OR USING TOBACCO. REMOVE AND WASH
CONTAMINATED CLOTHING BEFORE REUSE.
U.S. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS.
U.S. STATE RIGHT-TO-KNOW REGULATIONS: NONE KNOWN.
INTERNATIONAL REGULATIONS:
CANADA:
WHMIS HAZARD CLASS:
D2B: TOXIC MATERIALS
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARD 2
FLAMMABILITY 0
INSTABILITY 0
PHYSICAL AND CHEMICAL HAZARDS
HMIS:
HEALTH HAZARD 2
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
PREPARED BY:
PRODUCT STEWARDSHIP
23 BRITISH AMERICAN BLVD.
LATHAM, NY 12110
1-800-572-6501
PREPARATION/REVISION DATE: JANUARY 5, 2015
REVISION DATE: NEW
REVISION NOTE: NEW
REFERENCE: 1055455/52749.003
GENERAL DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION, AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL, AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.