| Common Name: | COMMERCIAL SOLUTIONS CLEAN-UP DISINFECTANT BLEACH CLEANER |
| Manufacturer: | CLOROX CANADA |
| SDS Revision Date: | 1/5/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 22D029, 22D030 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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THE CLOROX COMPANY
SAFETY DATA SHEET
ISSUING DATE: JANUARY 5, 2015
REVISION DATE: NEW
REVISION NUMBER: 0
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND OF THE COMPANY/UNDERTAKING
PRODUCT IDENTIFIER:
PRODUCT NAME:
CLOROX COMMERCIAL SOLUTIONS(R*) CLOROX(R*) CLEAN-UP(R*) DISINFECTANT BLEACH
CLEANER
OTHER MEANS OF IDENTIFICATION:
DRUG IDENTIFICATION NUMBER: 02319489
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: DISINFECTING BLEACH SPRAY CLEANER
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER ADDRESS:
THE CLOROX COMPANY OF CANADA LTD.
150 BISCAYNE CRESCENT
BRAMPTON, ONTARIO L6W 4V3
PHONE: 1-905-595-8200
EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE NUMBERS:
FOR MEDICAL EMERGENCIES, CALL: 1-800-446-1014
FOR TRANSPORTATION EMERGENCIES, CALL CHEMTREC: 1-800-424-9300
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION: THIS CHEMICAL IS CONSIDERED HAZARDOUS UNDER GHS.
SKIN CORROSION/IRRITATION: CATEGORY 3
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
EMERGENCY OVERVIEW:
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES MILD SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
EXCLAMATION MARK
APPEARANCE: CLEAR, PALE YELLOW
PHYSICAL STATE: LIQUID
ODOUR: CITRUS, HERBACEOUS, BLEACH
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING.
WEAR EYE PROTECTION/FACE PROTECTION SUCH AS SAFETY GLASSES.
PRECAUTIONARY STATEMENTS - RESPONSE:
EYES:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
SKIN:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
PRECAUTIONARY STATEMENTS - STORAGE: NONE
PRECAUTIONARY STATEMENTS - DISPOSAL: NONE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC):
THE FOLLOWING MEDICAL CONDITIONS MAY BE AGGRAVATED BY EXPOSURE TO HIGH
CONCENTRATIONS OF VAPOUR OR MIST:
HEART CONDITIONS OR CHRONIC RESPIRATORY PROBLEMS SUCH AS ASTHMA, EMPHYSEMA,
OR OBSTRUCTIVE LUNG DISEASE.
UNKNOWN TOXICITY:
0.08% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
OTHER INFORMATION: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
INTERACTIONS WITH OTHER CHEMICALS:
REACTS WITH OTHER HOUSEHOLD CHEMICALS SUCH AS PRODUCTS CONTAINING AMMONIA,
TOILET BOWL CLEANERS, RUST REMOVERS, OR ACIDS TO PRODUCE HAZARDOUS GASES,
SUCH AS CHLORINE AND OTHER CHLORINATED COMPOUNDS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO WEIGHT % TRADE SECRET
SODIUM HYPOCHLORITE 7681-52-9 1 - 5 *
SODIUM HYDROXIDE 1310-73-2 0.1 - 1 *
* THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS
A TRADE SECRET.
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE: SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO.
CONTINUE RINSING. KEEP EYE WIDE OPEN WHILE RINSING. DO NOT RUB AFFECTED
AREA. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
SKIN CONTACT:
TAKE OFF CONTAMINATED CLOTHING. RINSE SKIN IMMEDIATELY WITH PLENTY OF WATER
FOR 15-20 MINUTES. IF IRRITATION DEVELOPS, CALL A DOCTOR.
INHALATION: MOVE TO FRESH AIR. IF BREATHING IS AFFECTED, CALL A DOCTOR.
INGESTION:
CALL A POISON CONTROL CENTER OR DOCTOR IMMEDIATELY. HAVE PERSON SIP A
GLASSFUL OF WATER IF ABLE TO SWALLOW. DO NOT INDUCE VOMITING UNLESS TOLD TO
DO SO BY A POISON CONTROL CENTER OR DOCTOR.
PROTECTION OF FIRST-AIDERS:
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. WEAR PERSONAL PROTECTIVE CLOTHING (SEE SECTION 8).
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
MOST IMPORTANT SYMPTOMS AND EFFECTS: STINGING AND IRRITATION OF EYES.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
UNSUITABLE EXTINGUISHING MEDIA:
CAUTION: USE OF WATER SPRAY WHEN FIGHTING FIRE MAY BE INEFFICIENT.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NO INFORMATION AVAILABLE.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: NONE.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED.
OTHER INFORMATION: REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS: SEE SECTION 12 FOR ECOLOGICAL INFORMATION.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
ABSORB AND CONTAINERIZE. WASH RESIDUAL DOWN TO SANITARY SEWER. CONTACT THE
SANITARY TREATMENT FACILITY IN ADVANCE TO ASSURE ABILITY TO PROCESS
WASHED-DOWN MATERIAL.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN
USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
INCOMPATIBLE PRODUCTS:
PRODUCTS CONTAINING AMMONIA, TOILET BOWL CLEANERS, RUST REMOVERS, OR ACIDS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
SODIUM HYDROXIDE CEILING: 2 MG/M3 TWA: 2 MG/M3 IDLH: 10 MG/M3
1310-73-2 CEILING: 2 MG/M3
SODIUM HYPOCHLORITE NONE NONE NONE
7681-52-9
ACGIH TLV:
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS - THRESHOLD LIMIT
VALUE.
OSHA PEL:
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION - PERMISSIBLE EXPOSURE
LIMITS.
NIOSH IDLH: IMMEDIATELY DANGEROUS TO LIFE OR HEALTH.
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
IF SPLASHES ARE LIKELY TO OCCUR:
WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES). NONE REQUIRED FOR
CONSUMER USE.
SKIN AND BODY PROTECTION: WEAR PROTECTIVE GLOVES AND PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
IF EXPOSURE LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, NIOSH/MSHA
APPROVED RESPIRATORY PROTECTION SHOULD BE WORN. POSITIVE-PRESSURE SUPPLIED
AIR RESPIRATORS MAY BE REQUIRED FOR HIGH AIRBORNE CONTAMINANT
CONCENTRATIONS. RESPIRATORY PROTECTION MUST BE PROVIDED IN ACCORDANCE WITH
CURRENT LOCAL REGULATIONS.
HYGIENE MEASURES:
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE RE-USE. AVOID CONTACT WITH
SKIN, EYES OR CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR
COLOUR: PALE YELLOW
ODOUR: CITRUS, HERBACEOUS, BLEACH
ODOUR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS/ METHOD
PH 12.4 - 12.8 NONE KNOWN
MELTING/FREEZING POINT NO DATA AVAILABLE NONE KNOWN
BOILING POINT / BOILING RANGE NO DATA AVAILABLE NONE KNOWN
FLASH POINT NOT FLAMMABLE NONE KNOWN
EVAPOURATION RATE NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY (SOLID, GAS) NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO DATA AVAILABLE NONE KNOWN
LOWER FLAMMABILITY LIMIT NO DATA AVAILABLE NONE KNOWN
VAPOUR PRESSURE NO DATA AVAILABLE NONE KNOWN
VAPOUR DENSITY NO DATA AVAILABLE NONE KNOWN
SPECIFIC GRAVITY APPROX. 1.03 NONE KNOWN
WATER SOLUBILITY SOLUBLE IN WATER NONE KNOWN
SOLUBILITY IN OTHER SOLVENTS NO DATA AVAILABLE NONE KNOWN
PARTITION COEFFICIENT N-OCTANOL/WATER NO DATA AVAILABLE NONE KNOWN
AUTOIGNITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
DECOMPOSITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
KINEMATIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
DYNAMIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
EXPLOSIVE PROPERTIES NOT EXPLOSIVE
OXIDIZING PROPERTIES NO DATA AVAILABLE
OTHER INFORMATION:
SOFTENING POINT NO DATA AVAILABLE
VOC CONTENT (%) NO DATA AVAILABLE
PARTICLE SIZE NO DATA AVAILABLE
PARTICLE SIZE DISTRIBUTION NO DATA AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
REACTS WITH OTHER HOUSEHOLD CHEMICALS SUCH AS PRODUCTS CONTAINING AMMONIA,
TOILET BOWL CLEANERS, RUST REMOVERS, OR ACIDS TO PRODUCE HAZARDOUS GASES,
SUCH AS CHLORINE AND OTHER CHLORINATED COMPOUNDS.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: NONE KNOWN BASED ON INFORMATION SUPPLIED.
INCOMPATIBLE MATERIALS:
PRODUCTS CONTAINING AMMONIA, TOILET BOWL CLEANERS, RUST REMOVERS, VINEGAR,
OR ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
INHALATION: EXPOSURE TO VAPOUR OR MIST MAY IRRITATE RESPIRATORY TRACT.
EYE CONTACT: MAY CAUSE EYE IRRITATION.
SKIN CONTACT: PROLONGED CONTACT MAY CAUSE IRRITATION.
INGESTION:
INGESTION MAY CAUSE IRRITATION TO MUCOUS MEMBRANES AND GASTROINTESTINAL
TRACT, NAUSEA, VOMITING, AND DIARRHEA.
COMPONENT INFORMATION:
CHEMICAL NAME LD50 ORAL LD50 DERMAL LC50 INHALATION
SODIUM HYPOCHLORITE 8200 MG/KG (RAT) >10000 MG/KG
7681-52-9 (RABBIT)
SODIUM HYDROXIDE 1350 MG/KG
1310-73-2 (RABBIT)
INFORMATION ON TOXICOLOGICAL EFFECTS:
SYMPTOMS: MAY CAUSE REDNESS AND TEARING OF THE EYES.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE.
CARCINOGENICITY:
THE TABLE BELOW INDICATES WHETHER EACH AGENCY HAS LISTED ANY INGREDIENT AS
A CARCINOGEN.
CHEMICAL NAME ACGIH IARC NTP OSHA
SODIUM HYPOCHLORITE GROUP 3
7681-52-9
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
GROUP 3 - NOT CLASSIFIABLE AS TO CARCINOGENICITY IN HUMANS
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE.
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
CHRONIC TOXICITY: CARCINOGENIC POTENTIAL IS UNKNOWN.
TARGET ORGAN EFFECTS:
RESPIRATORY SYSTEM, EYES, SKIN, GASTROINTESTINAL TRACT (GI).
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
NUMERICAL MEASURES OF TOXICITY - PRODUCT INFORMATION:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT: NOT APPLICABLE
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, PROVINCIAL, AND LOCAL
REGULATIONS.
CONTAMINATED PACKAGING:
DO NOT REUSE EMPTY CONTAINERS. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, PROVINCIAL, AND LOCAL REGULATIONS.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
TDG:
UN-NO: UN3082
PROPER SHIPPING NAME: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS: 9
PACKING GROUP: III
DESCRIPTION:
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(SODIUM HYPOCHLORITE), 9, III, MARINE POLLUTANT
ICAO:
UN-NO: UN3082
PROPER SHIPPING NAME: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS: 9
PACKING GROUP: III
DESCRIPTION:
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(SODIUM HYPOCHLORITE), 9, III
IATA:
UN-NO: UN3082
PROPER SHIPPING NAME: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS: 9
PACKING GROUP: III
DESCRIPTION:
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(SODIUM HYPOCHLORITE), 9, III
IMDG/IMO:
UN-NO: UN3082
PROPER SHIPPING NAME: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS: 9
PACKING GROUP: III
EMS NO.: F-A, S-F
MARINE POLLUTANT:
PRODUCT IS A MARINE POLLUTANT ACCORDING TO THE CRITERIA SET BY IMDG/IMO
DESCRIPTION:
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(SODIUM HYPOCHLORITE), 9, III, MARINE POLLUTANT
| 15. REGULATORY INFORMATION | |
CHEMICAL INVENTORIES:
TSCA:
ALL COMPONENTS OF THIS PRODUCT ARE EITHER ON THE TSCA 8(B) INVENTORY OR
OTHERWISE EXEMPT FROM LISTING.
DSL/NDSL: ALL COMPONENTS ARE ON THE DSL OR NDSL.
TSCA - UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL - CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
INTERNATIONAL REGULATIONS:
CANADA:
WHMIS HAZARD CLASS:
D2B: TOXIC MATERIALS
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARD 2
FLAMMABILITY 0
INSTABILITY 0
PHYSICAL AND CHEMICAL HAZARDS
HMIS
HEALTH HAZARD 2
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
PREPARED BY:
PRODUCT STEWARDSHIP
23 BRITISH AMERICAN BLVD.
LATHAM, NY 12110
1-800-572-6501
PREPARATION/REVISION DATE: NEW
REVISION NOTE: NEW
REFERENCE: 1076552-A/50546003.004
GENERAL DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.