| Common Name: | ACTI-BRITE |
| Manufacturer: | PARKER HANNIFIN |
| SDS Revision Date: | 5/5/2015 |
| SDS Format: | No Format Specified |
| Item Number(s): | 2NTK8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PARKER
PARKER HANNIFIN CORPORATION
SPORLAN DIVISION
206 LANGE DRIVE
WASHINGTON, MO 63090
U.S.A.
ACTI-BRITE
AB-1, AB-5, AB-55
SDS REVISION DATE (MM/DD/YYYY): 05/05/2015
SAFETY DATA SHEET
| SECTION 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER USED ON THE LABEL: ACTI-BRITE
PRODUCT CODE(S): AB-1 (P/N 475096), AB-5 (P/N 475100), AB-55 (P/N 475102)
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
PROFESSIONAL USE ONLY; REFRIGERATION COIL CLEANER.
CHEMICAL FAMILY: MIXTURE
NAME, ADDRESS, AND TELEPHONE NUMBER OF THE SUPPLIER:
PARKER HANNIFIN CORPORATION - SPORLAN DIVISION
206 LANGE DRIVE
WASHINGTON, MO, 63090
U.S.A.
NAME, ADDRESS, AND TELEPHONE NUMBER OF THE MANUFACTURER: REFER TO SUPPLIER
SUPPLIER'S TELEPHONE #: (636) 239-1111
24 HR. EMERGENCY TEL #:
CHEMTREC: 1-800-424-9300 (WITHIN CONTINENTAL U.S.)
CHEMTREC: 703-527-3887 (OUTSIDE U.S.).
| SECTION 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE CHEMICAL:
WHMIS INFORMATION:
THIS PRODUCT IS A WHMIS CONTROLLED PRODUCT. IT MEETS ONE OR MORE OF THE
CRITERIA FOR A CONTROLLED PRODUCT PROVIDED IN PART IV OF THE CANADIAN
CONTROLLED PRODUCTS REGULATIONS (CPR).
WHMIS CLASSIFICATION:
CLASS D1A (MATERIALS CAUSING IMMEDIATE AND SERIOUS TOXIC EFFECTS, VERY
TOXIC MATERIAL)
CLASS D2A (MATERIALS CAUSING OTHER TOXIC EFFECTS, VERY TOXIC MATERIAL)
CLASS E (CORROSIVE MATERIAL).
OSHA:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS
(29 CFR 1910.1200).
HAZARD CLASSIFICATION:
CORROSIVE TO METALS: CATEGORY 1
ACUTE TOXICITY, INHALATION: CATEGORY 3 (VAPOR)
SKIN CORROSION/IRRITATION: CATEGORY 1
EYE DAMAGE/IRRITATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE: CATEGORY 1
LABEL ELEMENTS:
THE FOLLOWING LABEL INFORMATION IS APPLICABLE ONLY TO THE UNITED STATES
ACCORDING TO OSHA REGULATIONS (29 CFR 1910.1200) (HAZCOM 2012):
SIGNAL WORD:
DANGER!
HAZARD STATEMENT(S):
MAY BE CORROSIVE TO METALS.
TOXIC IF INHALED.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
CAUSES DAMAGE TO THE RESPIRATORY SYSTEM BY INHALATION.
PRECAUTIONARY STATEMENT(S):
KEEP ONLY IN ORIGINAL CONTAINER.
WASH THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
DO NOT BREATHE DUST OR MIST.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES/CLOTHING AND EYE/FACE PROTECTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION/ADVICE.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE.
STORE IN CORROSIVE RESISTANT CONTAINER WITH A RESISTANT INNER LINER.
STORE LOCKED UP.
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
SKULLS AND CROSSBONES
CORROSION
HEALTH HAZARD
THE FOLLOWING LABEL INFORMATION IS APPLICABLE ONLY TO CANADA ACCORDING TO
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR/WHMIS):
FOR SKIN CONTACT, IMMEDIATELY REMOVE CONTAMINATED CLOTHING THEN WASH
THOROUGHLY WITH SOAP AND WATER FOR AT LEAST 15 MINUTES.
DANGER!
MAY BE CORROSIVE TO METALS. CORROSIVE TO ALL TISSUES. CAUSES EYE, SKIN AND
DIGESTIVE TRACT BURNS.
POISON!
FATAL IF SWALLOWED, IN CONTACT WITH SKIN OR IF INHALED. SEVERE RESPIRATORY
IRRITANT. PROLONGED EXPOSURE MAY CAUSE SKELETAL FLUORSIS (WEAKEND BONE
STRUCTURE).
USE ONLY IN WELL-VENTILATED AREAS. WEAR SUITABLE PROTECTIVE EQUIPMENT
DURING HANDLING. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT EAT,
DRINK OR SMOKE WHEN USING THIS PRODUCT. DO NOT BREATHE FUMES, MISTS OR
VAPOURS. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER CLOSED WHEN NOT
IN USE.
IF SWALLOWED, CALL A POISON CONTROL CENTRE OR DOCTOR IMMEDIATELY. RINSE
MOUTH WITH WATER. DO NOT INDUCE VOMITING.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IF BREATHING
IS DIFFICULT, GIVE OXYGEN BY QUALIFIED MEDICAL PERSONNEL ONLY. IF BREATHING
STOPPED, BEGIN ARTIFICIAL RESPIRATION. CALL A PHYSICIAN OR POISON CONTROL
CENTRE IMMEDIATELY. FOR EYE CONTACT, IMMEDIATELY FLUSH EYES THOROUGHLY WITH
RUNNING WATER FOR AT LEAST 20 TO 30 MINUTES. CALL A PHYSICIAN OR POISON
CONTROL CENTRE IMMEDIATELY. FOR SKIN CONTACT, FLUSH WITH WATER FOR AT LEAST
15 MINUTES, WHILE REMOVING CONTAMINATED CLOTHING. CALL A PHYSICIAN OR
POISON CONTROL CENTRE IMMEDIATELY.
E - CORROSIVE MATERIAL
D1 - MATERIALS CAUSING IMMEDIATE AND SERIOUS TOXIC EFFECTS
OTHER HAZARDS:
OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
CONTACT WITH MOST METALS WILL GENERATE FLAMMABLE HYDROGEN GAS. CHRONIC SKIN
CONTACT WITH LOW CONCENTRATIONS MAY CAUSE DERMATITIS. IN EXTREME CASES,
TOOTH EROSION COULD RESULT.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS # CONCENTRATION
HYDROFLUORIC ACID 7664-39-3 10.0 - 30.0
PHOSPHORIC ACID 7664-38-2 1.0 - 5.0
SULFONIC N-95 127087-87-0 3.0 - 7.0
| SECTION 4. FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
INGESTION:
DO NOT INDUCE VOMITING. HAVE VICTIM RINSE MOUTH WITH WATER, THEN GIVE ONE
TO TWO GLASSES OF WATER TO DRINK. SEEK IMMEDIATE MEDICAL ATTENTION/ADVICE.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
INHALATION:
IMMEDIATELY REMOVE PERSON TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE
OXYGEN BY QUALIFIED MEDICAL PERSONNEL ONLY. IF BREATHING HAS STOPPED,
GIVE ARTIFICIAL RESPIRATION. SEEK IMMEDIATE MEDICAL ATTENTION/ADVICE.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. FLUSH AFFECTED SKIN WITH GENTLY FLOWING
LUKEWARM WATER FOR AT LEAST 20 MINUTES. COVER WOUND WITH STERILE DRESSING.
DO NOT RUB AREA OF CONTACT. WASH CONTAMINATED CLOTHING BEFORE RE-USE. SEEK
IMMEDIATE MEDICAL ATTENTION/ADVICE. LEATHER AND SHOES THAT HAVE BEEN
CONTAMINATED WITH THE SOLUTION MAY NEED TO BE DESTROYED.
EYE CONTACT:
IMMEDIATELY FLUSH EYES THOROUGHLY WITH RUNNING WATER FOR AT LEAST 20 TO
30 MINUTES. PROTECT UNHARMED EYE. SEEK IMMEDIATE MEDICAL ATTENTION/ADVICE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
IF MISTS ARE FORMED, MAY CAUSE SEVERE IRRITATION TO THE NOSE, THROAT AND
RESPIRATORY TRACT. SYMPTOMS MAY INCLUDE COUGHING, CHOKING AND WHEEZING.
OVEREXPOSURE TO SPRAYS OR MISTS MAY CAUSE CHEMICAL PNEUMONITIS
(INFLAMMATION OF LUNG TISSUE). SYMPTOMS OF PULMONARY EDEMA (CHEST PAIN,
SHORTNESS OF BREATH) MAY BE DELAYED. ABSORBED FLUORIDE CAN CAUSE IRREGULAR
HEARTBEAT, NAUSEA, DIZZINESS, VOMITING AND SEIZURES. CAUSES SEVERE SKIN
IRRITATION. SYMPTOMS MAY INCLUDE REDNESS, BLISTERING, PAIN AND SWELLING.
CAUSES SERIOUS EYE DAMAGE. SYMPTOMS MAY INCLUDE SEVERE PAIN, BLURRED
VISION, REDNESS AND CORROSIVE DAMAGE. COULD CAUSE BLINDNESS. MAY CAUSE
SEVERE IRRITATION AND CORROSIVE DAMAGE IN THE MOUTH, THROAT AND STOMACH.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
IMMEDIATE MEDICAL ATTENTION IS REQUIRED. TREAT SYMPTOMATICALLY. CAUSES
CHEMICAL BURNS.
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE WATER FOG OR FINE SPRAY, FOAMS, CARBON DIOXIDE OR DRY CHEMICAL.
SOME CHEMICAL EXTINGUISHING AGENTS MAY REACT WITH THIS MATERIAL.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A SOLID WATER STREAM AS IT MAY SCATTER AND SPREAD FIRE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE/CONDITIONS OF
FLAMMABILITY:
NOT CONSIDERED FLAMMABLE. CONTACT WITH METALS MAY RELEASE SMALL AMOUNTS OF
FLAMMABLE HYDROGEN GAS. CLOSED CONTAINERS MAY RUPTURE IF EXPOSED TO EXCESS
HEAT OR FLAME DUE TO A BUILD-UP OF INTERNAL PRESSURE. VAPOURS ARE HEAVIER
THAN AIR AND COLLECT IN CONFINED AND LOW-LYING AREAS.
FLAMMABILITY CLASSIFICATION (OSHA 29 CFR 1910.106): NOT FLAMMABLE.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT / STATIC DISCHARGE:
NOT EXPECTED TO BE SENSITIVE TO MECHANICAL IMPACT OR STATIC DISCHARGE.
HAZARDOUS COMBUSTION PRODUCTS:
PHOSPHORUS OXIDES; HYDROGEN FLUORIDE; CARBON OXIDES; FORMALDEHYDE
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIREFIGHTERS SHOULD WEAR AN APPROVED FULL-FACE, SELF-CONTAINED BREATHING
APPARATUS (SCBA) AND IMPERVIOUS CLOTHING.
SPECIAL FIRE-FIGHTING PROCEDURES:
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
BREATHING APPARATUS WITH FULL FACE PIECE OPERATED IN POSITIVE PRESSURE
MODE. MOVE CONTAINERS FROM FIRE AREA IF SAFE TO DO SO. WATER SPRAY MAY BE
USEFUL IN COOLING EQUIPMENT EXPOSED TO HEAT AND FLAME.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
RESTRICT ACCESS TO AREA UNTIL COMPLETION OF CLEAN-UP. ENSURE CLEAN-UP IS
CONDUCTED BY TRAINED PERSONNEL ONLY. INDIVIDUALS INVOLVED IN THE CLEANUP
MUST WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. REFER TO SECTION 8,
EXPOSURE CONTROLS AND PERSONAL PROTECTION, FOR ADDITIONAL INFORMATION ON
ACCEPTABLE PERSONAL PROTECTIVE EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
ENSURE SPILLED PRODUCT DOES NOT ENTER DRAINS, SEWERS, WATERWAYS, OR
CONFINED SPACES. IF NECESSARY, DIKE WELL AHEAD OF THE SPILL TO PREVENT
RUNOFF INTO DRAINS, SEWERS, OR ANY NATURAL WATERWAY OR DRINKING SUPPLY.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA OF RELEASE. STOP THE SPILL
AT SOURCE IF IT IS SAFE TO DO SO. CONTAIN AND ABSORB SPILLED LIQUID WITH
NON-COMBUSTIBLE, INERT ABSORBENT MATERIAL (E.G. SAND), THEN PLACE ABSORBENT
MATERIAL INTO A CONTAINER FOR LATER DISPOSAL (SEE SECTION 13). DO NOT FLUSH
INTO SURFACE WATER OR SANITARY SEWER SYSTEM. NOTIFY THE APPROPRIATE
AUTHORITIES AS REQUIRED.
SPECIAL SPILL RESPONSE PROCEDURES:
IF A SPILL/RELEASE IN EXCESS OF THE EPA REPORTABLE QUANTITY IS MADE INTO
THE ENVIRONMENT, IMMEDIATELY NOTIFY THE NATIONAL RESPONSE CENTER IN THE
UNITED STATES (PHONE: 1-800-424-8802).
US CERCLA REPORTABLE QUANTITY (RQ): SEE SECTION 15.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
USE ONLY IN WELL-VENTILATED AREAS. WEAR PROTECTIVE GLOVES/CLOTHING AND
EYE/FACE PROTECTION. DO NOT BREATHE FUMES OR VAPOURS. AVOID CONTACT WITH
SKIN, EYES AND CLOTHING. DURING PREPARATION OR DILUTION, ALWAYS ADD LIQUID
SLOWLY TO WATER AND WITH CONSTANT STIRRING. WHEN DILUTING, ALWAYS ADD THE
PRODUCT TO WATER. NEVER ADD WATER TO THE PRODUCT. WASH THOROUGHLY AFTER
HANDLING. KEEP AWAY FROM BASES, METALS AND OTHER INCOMPATIBLES. KEEP AWAY
FROM HEAT AND FLAME. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.
CONDITIONS FOR SAFE STORAGE:
STORE IN A COOL, DRY, WELL-VENTILATED AREA. STORE AWAY FROM INCOMPATIBLE
MATERIALS. STORE IN CORROSION-RESISTANT CONTAINERS. CORROSIVE MATERIALS
SHOULD BE STORED IN A SEPARATE SAFETY STORAGE CABINET OR ROOM. STORAGE AREA
SHOULD BE CLEARLY IDENTIFIED, CLEAR OF OBSTRUCTION AND ACCESSIBLE ONLY TO
TRAINED AND AUTHORIZED PERSONNEL. INSPECT PERIODICALLY FOR DAMAGE OR LEAKS.
NO SMOKING IN THE AREA. STORE IN CORROSION-RESISTANT CONTAINERS. STORE
LOCKED UP.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS; METALS; ALKALIES. REDUCING AGENTS.
| SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE LIMITS:
CHEMICAL NAME ACGIH TLV OSHA PEL
TWA STEL PEL STEL
HYDROFLUORIC ACID 0.5 PPM (AS F) N/AV 3 PPM (AS F) N/AV
PHOSPHORIC ACID 1 MG/M3 3 MG/M3 1 MG/M3 N/AV
SULFONIC N-95 N/AV N/AV N/AV N/AV
EXPOSURE CONTROLS:
VENTILATION AND ENGINEERING MEASURES:
USE GENERAL OR LOCAL EXHAUST VENTILATION TO MAINTAIN AIR CONCENTRATIONS
BELOW RECOMMENDED EXPOSURE LIMITS. ENSURE ADEQUATE VENTILATION, ESPECIALLY
IN CONFINED AREAS.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION IS REQUIRED IF THE CONCENTRATIONS EXCEED THE TLV.
NIOSH-APPROVED RESPIRATORS ARE RECOMMENDED. A SELF CONTAINED BREATHING
APPARATUS SHOULD BE USED IN EMERGENCY SITUATIONS OR INSTANCES WHERE
EXPOSURE LEVELS ARE NOT KNOWN. RESPIRATORS SHOULD BE SELECTED BASED ON THE
FORM AND CONCENTRATION OF CONTAMINANTS IN AIR, AND IN ACCORDANCE WITH OSHA
(29 CFR 1910.134) OR CSA Z94.4-02. ADVICE SHOULD BE SOUGHT FROM RESPIRATORY
PROTECTION SPECIALISTS.
SKIN PROTECTION:
IMPERVIOUS GLOVES MUST BE WORN WHEN USING THIS PRODUCT. ADVICE SHOULD BE
SOUGHT FROM GLOVE SUPPLIERS.
EYE / FACE PROTECTION:
CHEMICAL SPLASH GOGGLES MUST BE WORN WHEN HANDLING THIS MATERIAL. A FULL
FACE SHIELD MAY ALSO BE NECESSARY.
OTHER PROTECTIVE EQUIPMENT:
WEAR CHEMICALLY PROTECTIVE GLOVES (IMPERVIOUS), BOOTS, APRONS, AND
GAUNTLETS TO PREVENT PROLONGED OR REPEATED SKIN CONTACT. AN EYEWASH STATION
AND SAFETY SHOWER SHOULD BE MADE AVAILABLE IN THE IMMEDIATE WORKING AREA.
GENERAL HYGIENE CONSIDERATIONS:
AVOID BREATHING VAPOUR OR MIST. AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. UPON COMPLETION OF
WORK, WASH HANDS BEFORE EATING, DRINKING, SMOKING OR USE OF TOILET
FACILITIES. REMOVE SOILED CLOTHING AND WASH IT THOROUGHLY BEFORE REUSE.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
KEEP WORKING CLOTHES SEPARATELY.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: PINK LIQUID.
ODOUR: PUNGENT ODOUR.
ODOUR THRESHOLD: N/AV
PH: <2.0
MELTING/FREEZING POINT: N/AV
INITIAL BOILING POINT AND BOILING RANGE: 100 DEG. C (212 DEG. F)
FLASH POINT: N/AP
FLASHPOINT (METHOD): N/AP
EVAPORATION RATE (BUAE = 1): >1
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
LOWER FLAMMABLE LIMIT (% BY VOL.): N/AP
UPPER FLAMMABLE LIMIT (% BY VOL.): N/AP
OXIDIZING PROPERTIES: NONE.
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
VAPOUR PRESSURE: N/AV
VAPOUR DENSITY: >1
RELATIVE DENSITY / SPECIFIC GRAVITY: 1.15
SOLUBILITY IN WATER: COMPLETE
OTHER SOLUBILITY(IES): NONE KNOWN.
PARTITION COEFFICIENT N-OCTANOL/WATER OR COEFFICIENT OF WATER/OIL
DISTRIBUTION: N/AV
AUTO-IGNITION TEMPERATURE: N/AV
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: N/AV
VOLATILES (% BY WEIGHT): NOT AVAILABLE.
VOLATILE ORGANIC COMPOUNDS (VOC'S): N/AV
ABSOLUTE PRESSURE OF CONTAINER: N/AP
FLAME PROJECTION LENGTH: N/AP
OTHER PHYSICAL/CHEMICAL COMMENTS:
NONE KNOWN OR REPORTED BY THE MANUFACTURER.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NOT NORMALLY REACTIVE. MAY BE CORROSIVE TO METALS. CONTACT WITH METALS
MAY RELEASE SMALL AMOUNTS OF FLAMMABLE HYDROGEN GAS.
CHEMICAL STABILITY:
STABLE UNDER THE RECOMMENDED STORAGE AND HANDLING CONDITIONS PRESCRIBED.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
AVOID HEAT AND OPEN FLAME. AVOID CONTACT WITH INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS; METALS; ALKALIES. REDUCING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NONE KNOWN, REFER TO HAZARDOUS COMBUSTION PRODUCTS IN SECTION 5.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY INHALATION: YES
ROUTES OF ENTRY SKIN & EYE: YES
ROUTES OF ENTRY INGESTION: YES
ROUTES OF EXPOSURE SKIN ABSORPTION: YES
POTENTIAL HEALTH EFFECTS:
SIGNS AND SYMPTOMS OF SHORT-TERM (ACUTE) EXPOSURE:
SIGN AND SYMPTOMS INHALATION:
IF MISTS ARE FORMED, MAY CAUSE SEVERE IRRITATION TO THE NOSE, THROAT AND
RESPIRATORY TRACT. SYMPTOMS MAY INCLUDE COUGHING, CHOKING AND WHEEZING.
EXTREMELY HIGH EXPOSURES MAY LEAD TO INFLAMMATION OF LUNG TISSUE (CHEMICAL
PNEUMONITIS), CHEMICAL BRONCHITIS AND ACCUMULATION OF FLUID IN THE LUNGS
(PULMONARY EDEMA). SYMPTOMS OF PULMONARY EDEMA (CHEST PAIN, SHORTNESS OF
BREATH) MAY BE DELAYED. ABSORBED FLUORIDE CAN CAUSE IRREGULAR HEARTBEAT,
NAUSEA, DIZZINESS, VOMITING AND SEIZURES. COULD ALSO CAUSE CONVULSIONS,
COMA, RESPIRATORY ARREST AND DEATH.
SIGN AND SYMPTOMS INGESTION:
MAY CAUSE SEVERE IRRITATION AND CORROSIVE DAMAGE IN THE MOUTH, THROAT AND
STOMACH. SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, VOMITING, BURNS,
PERFORATIONS, BLEEDING AND EVENTUALLY DEATH.
SIGN AND SYMPTOMS SKIN:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS (29CFR
1910.1200) (HAZCOM 2012).
CLASSIFICATION:
SKIN IRRITATION: CATEGORY 1
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SIGN AND SYMPTOMS EYES:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS (29CFR
1910.1200) (HAZCOM 2012).
CLASSIFICATION EYE DAMAGE/IRRITATION: CATEGORY 1
CAUSES SERIOUS EYE DAMAGE.
POTENTIAL CHRONIC HEALTH EFFECTS:
CHRONIC SKIN CONTACT WITH LOW CONCENTRATIONS MAY CAUSE DERMATITIS. IN
EXTREME CASES, TOOTH EROSION COULD RESULT. PROLONGED EXPOSURE MAY CAUSE
SKELETAL FLUORSIS (WEAKEND BONE STRUCTURE). REPEATED OR PROLONGED EXPOSURE
MAY RESULT IN KIDNEY EFFECTS.
MUTAGENICITY: NOT EXPECTED TO BE MUTAGENIC IN HUMANS.
CARCINOGENICITY:
NO COMPONENTS ARE LISTED AS CARCINOGENS BY ACGIH, IARC, OSHA OR NTP.
REPRODUCTIVE EFFECTS & TERATOGENICITY:
NOT EXPECTED TO HAVE OTHER REPRODUCTIVE EFFECTS.
SENSITIZATION TO MATERIAL:
NOT EXPECTED TO BE A SKIN OR RESPIRATORY SENSITIZER.
SPECIFIC TARGET ORGAN EFFECTS:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS
(29 CFR 1910.1200) (HAZCOM 2012).
CLASSIFICATION:
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE: CATEGORY 1
CAUSES DAMAGE TO THE RESPIRATORY SYSTEM BY INHALATION.
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS SPECIFIC TARGET ORGAN
TOXICANT, REPEATED EXPOSURE.
IRRITANCY: CORROSIVE
MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE:
PRE-EXISTING SKIN, EYE AND RESPIRATORY DISORDERS.
SYNERGISTIC MATERIALS: NOT AVAILABLE.
TOXICOLOGICAL DATA:
ACUTE TOXICITY, INHALATION - CATEGORY 3 (VAPOR)
THE CALCULATED ATE VALUES FOR THIS MIXTURE ARE:
ATE INHALATION (VAPOURS): 6.02 MG/L
CHEMICAL NAME LC50 (4HR) LD50
INH, RAT (ORAL, RAT) (RABBIT, DERMAL)
HYDROFLUORIC ACID 1.83 MG/L N/AV N/AV
PHOSPHORIC ACID N/AV >3500 MG/KG >1260 MG/KG
SULFONIC N-95 N/AV N/AV N/AV
OTHER IMPORTANT TOXICOLOGICAL HAZARDS: NONE KNOWN.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
NO DATA IS AVAILABLE ON THE PRODUCT ITSELF. THE PRODUCT SHOULD NOT BE
ALLOWED TO ENTER DRAINS OR WATER COURSES, OR BE DEPOSITED WHERE IT CAN
AFFECT GROUND OR SURFACE WATERS. SEE THE FOLLOWING TABLES FOR INDIVIDUAL
INGREDIENT ECOTOXICITY DATA.
ECOTOXICITY DATA:
INGREDIENTS CAS NO TOXICITY TO FISH
LC50 / 96H NOEC / 21 DAY M FACTOR
HYDROFLUORIC ACID 7664-39-3 107.5 MG/L N/AV NONE.
(RAINBOW TROUT)
PHOSPHORIC ACID 7664-38-2 75.1 MG/L N/AV NONE.
(JAPANESE
RICEFISH)
INGREDIENTS CAS NO TOXICITY TO DAPHNIA
EC50 48H NOEC / 21 DAY M FACTOR
HYDROFLUORIC ACID 7664-39-3 270 MG/L (WATER N/AV NONE.
FLEA)
PHOSPHORIC ACID 7664-38-2 376 MG/L N/AV NONE.
(DAPHNIA MAGNA)
INGREDIENTS CAS NO TOXICITY TO ALGAE
EC50 96H OR 72H NOEC / 96H OR 72H M FACTOR
HYDROFLUORIC ACID 7664-39-3 N/AV N/AV NONE.
PHOSPHORIC ACID 7664-38-2 32 MG/L/72HR N/AV NONE.
(GREEN ALGAE)
PERSISTENCE AND DEGRADABILITY: NO DATA IS AVAILABLE ON THE PRODUCT ITSELF.
BIOACCUMULATION POTENTIAL: NO DATA IS AVAILABLE ON THE PRODUCT ITSELF.
MOBILITY IN SOIL: NO DATA IS AVAILABLE ON THE PRODUCT ITSELF.
OTHER ADVERSE ENVIRONMENTAL EFFECTS:
NO DATA IS AVAILABLE ON THE PRODUCT ITSELF.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
HANDLING FOR DISPOSAL:
SEE SECTION 7 (HANDLING AND STORAGE) FOR FURTHER DETAILS. EMPTY CONTAINERS
RETAIN RESIDUE (LIQUID AND/OR VAPOUR) AND CAN BE DANGEROUS.
METHODS OF DISPOSAL:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, PROVINCIAL AND
LOCAL REGULATIONS.
RCRA:
IF THIS PRODUCT, AS SUPPLIED, BECOMES A WASTE IN THE UNITED STATES, IT MAY
MEET THE CRITERIA OF A HAZARDOUS WASTE AS DEFINED UNDER RCRA, TITLE 40 CFR
261. IT IS THE RESPONSIBILITY OF THE WASTE GENERATOR TO DETERMINE THE
PROPER WASTE IDENTIFICATION AND DISPOSAL METHOD.
| SECTION 14. TRANSPORTATION INFORMATION | |
REGULATORY UN UN PROPER TRANSPORT PACKING LABEL
INFORMATION NUMBER SHIPPING NAME HAZARD GROUP
CLASS(ES)
TDG UN3264 CORROSIVE LIQUID, 8 II CLASS 8,
ACIDIC, CORROSIVES
INORGANIC, N.O.S.
(HYDROFLUORIC
ACID; PHOSPHORIC
ACID)
TDG WITHIN CANADA, THE LIMITED QUANTITY EXEMPTION MAY APPLY FOR
ADDITIONAL CONTAINERS WHICH HOLD SPECIFIC QUANTITIES OF THE PRODUCT.
INFORMATION UNDER THE TDGR, REFER TO SECTION 1.17 FOR LIMITED QUANTITY
EXEMPTION INFORMATION, IF SHIPPING UNDER THIS EXEMPTION.
49CFR/DOT UN3264 CORROSIVE LIQUID, 8 II CORROSIVE,
ACIDIC, CLASS/
INORGANIC, N.O.S. DIVISION 8
(HYDROFLUORIC
ACID; PHOSPHORIC
ACID)
49CFR/DOT THIS MATERIAL MAY BE SHIPPED AS A LIMITED QUANTITY ACCORDING
ADDITIONAL TO 49CFR SECTION 173.154.
INFORMATION
ICAO/IATA UN3264 CORROSIVE LIQUID, 8 II CLASS 8,
ACIDIC, CORROSIVES
INORGANIC, N.O.S.
(HYDROFLUORIC
ACID; PHOSPHORIC
ACID)
ICAO/IATA REFER TO THE APPROPRIATE PACKING INSTRUCTION, PRIOR TO
ADDITIONAL SHIPPING THIS MATERIAL. REFER TO THE MANUFACTURER FOR SHIPPING
INFORMATION INFORMATION.
SPECIAL PRECAUTIONS FOR USER:
ENVIRONMENTAL HAZARDS: SEE ECOLOGICAL INFORMATION, SECTION 12.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
| SECTION 15. REGULATORY INFORMATION | |
US FEDERAL INFORMATION:
COMPONENTS LISTED BELOW ARE PRESENT ON THE FOLLOWING U.S. FEDERAL CHEMICAL
LISTS:
INGREDIENTS CAS # TSCA INVENTORY CERCLA REPORTABLE
QUANTITY (RQ)
(40 CFR 117.302)
HYDROFLUORIC ACID 7664-39-3 YES 100 LB / 45.4 KG
PHOSPHORIC ACID 7664-38-2 YES (5000 LBS / 2270 KG)
SULFONIC N-95 127087-87-0 YES N/AP
INGREDIENTS SARA TITLE III: SARA TITLE III: SEC. 313, 40 CFR
SEC. 302, 372, SPECIFIC TOXIC CHEMICAL
EXTREMELY TOXIC CHEMICAL DE MINIMUS
HAZARDOUS CONCENTRATION
SUBSTANCE,
40 CFR 355
HYDROFLUORIC ACID 100 LB TPQ YES 1%
PHOSPHORIC ACID NONE. NO N/AP
SULFONIC N-95 N/AV NO N/AP
SARA TITLE III:
SEC. 311 AND 312, MSDS REQUIREMENTS, 40 CFR 370 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD; CHRONIC HEALTH HAZARD. UNDER SARA SECTIONS
311 AND 312, THE EPA HAS ESTABLISHED THRESHOLD QUANTITIES FOR THE REPORTING
OF HAZARDOUS CHEMICALS. THE CURRENT THRESHOLDS ARE 500 POUNDS FOR THE
THRESHOLD PLANNING QUANTITY (TPQ), WHICHEVER IS LOWER, FOR EXTREMELY
HAZARDOUS SUBSTANCES AND 10,000 POUNDS FOR ALL OTHER HAZARDOUS CHEMICALS.
US STATE RIGHT TO KNOW LAWS:
THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES:
INGREDIENTS CAS # CALIFORNIA STATE "RIGHT TO KNOW" LISTS
PROPOSITION 65 CA MA MN NJ PA RI
LISTED TYPE OF
TOXICITY
HYDROFLUORIC 7664-39-3 NO N/AP YES YES YES YES YES YES
ACID
PHOSPHORIC 7664-38-2 NO N/AP NO YES YES YES YES YES
ACID
SULFONIC 127087-87-0 NO N/AP NO NO NO NO NO NO
N-95
CANADIAN INFORMATION:
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) INFORMATION:
ALL INGREDIENTS LISTED APPEAR ON THE DOMESTIC SUBSTANCES LIST (DSL).
REFER TO SECTION 2 FOR A WHMIS CLASSIFICATION FOR THIS PRODUCT.
INTERNATIONAL INFORMATION:
COMPONENTS LISTED BELOW ARE PRESENT ON THE FOLLOWING INTERNATIONAL
INVENTORY LIST:
INGREDIENTS CAS # EUROPEAN AUSTRALIA PHILIPPINES
EINECS AICS PICCS
HYDROFLUORIC ACID 7664-39-3 231-634-8 PRESENT PRESENT
PHOSPHORIC ACID 7664-38-2 PRESENT PRESENT PRESENT
SULFONIC N-95 127087-87-0 N/AV PRESENT PRESENT
INGREDIENTS JAPAN ENCS KOREA CHINA NEWZEALAND
KECI/KECL IECSC IOC
HYDROFLUORIC ACID (1)-306 KE-20198 PRESENT HSR001537,
HSR001568,
HSR001569,
HSR001570,
HSR001589
(DILUTION)
PHOSPHORIC ACID PRESENT PRESENT PRESENT PRESENT
SULFONIC N-95 NO INFORMATION NO INFORMATION PRESENT NO INFORMATION
AVAILABLE. AVAILABLE. AVAILABLE.
| SECTION 16. OTHER INFORMATION | |
LEGEND:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
CA: CALIFORNIA
CAS: CHEMICAL ABSTRACT SERVICES
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT OF
1980
CFR: CODE OF FEDERAL REGULATIONS
CSA CANADIAN STANDARDS ASSOCIATION
DOT: DEPARTMENT OF TRANSPORTATION
EPA: ENVIRONMENTAL PROTECTION AGENCY
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
HSDB: HAZARDOUS SUBSTANCES DATA BANK
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
INH: INHALATION
MA: MASSACHUSETTS
MN: MINNESOTA
MSHA: MINE SAFETY AND HEALTH ADMINISTRATION
N/AP: NOT APPLICABLE
N/AV: NOT AVAILABLE
NFPA NATIONAL FIRE PROTECTION ASSOCIATION
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
NJ: NEW JERSEY
NTP: NATIONAL TOXICOLOGY PROGRAM
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PA: PENNSYLVANIA
PEL: PERMISSIBLE EXPOSURE LIMIT
RCRA: RESOURCE CONSERVATION AND RECOVERY ACT
RI: RHODE ISLAND
RTECS: REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
STEL: SHORT TERM EXPOSURE LIMIT
TDG: CANADIAN TRANSPORTATION OF DANGEROUS GOODS ACT & REGULATIONS
TLV: THRESHOLD LIMIT VALUES
TWA: TIME WEIGHTED AVERAGE
WHMIS: WORKPLACE HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
REFERENCES:
CANADIAN CENTRE FOR OCCUPATIONAL HEALTH AND SAFETY, CCINFOWEB DATABASES,
2015 (CHEMPENDIUM, RTECS, HSDB, INCHEM).
EUROPEAN CHEMICALS AGENCY, CLASSIFICATION LEGISLATION, 2015
OECD:
THE GLOBAL PORTAL TO INFORMATION ON CHEMICAL SUBSTANCES - ECHEMPORTAL, 2015
MATERIAL SAFETY DATA SHEET FROM MANUFACTURER
PREPARATION DATE (MM/DD/YYYY): 08/27/2010
REVIEWED DATE SDS (DD/MM/YYYY): 05/05/2015
REVISION NO.: 4
REVISION INFORMATION: ALL (FORMAT CHANGE)
OTHER SPECIAL CONSIDERATIONS FOR HANDLING:
HMIS RATING:
HEALTH 4*
FLAMMABILITY 0
REACTIVITY 1
* - CHRONIC HAZARD
0 - MINIMAL
1 - SLIGHT
2 - MODERATE
3 - SERIOUS
4 - SEVERE
NFPA RATING:
HEALTH 4
FLAMMABILITY 0
INSTABILITY 1
SPECIAL HAZARDS NONE
0 - MINIMAL
1 - SLIGHT
2 - MODERATE
3 - SERIOUS
4 - SEVERE
PREPARED FOR:
PARKER HANNIFIN CORPORATION - SPORLAN DIVISION
206 LANGE DRIVE
WASHINGTON, MO 63090
USA
(636) 239-1111
DIRECT ALL ENQUIRIES TO: PARKER HANNIFIN CORP. - SPORLAN DIVISION.
PARKER
PREPARED BY:
ICC THE COMPLIANCE CENTER INC.
TELEPHONE:
(888) 442-9628 (U.S.)
(888) 977-4834 (CANADA)
HTTP://WWW.THECOMPLIANCECENTER.COM
ICC
COMPLIANCE CENTER
DISCLAIMER:
THIS MATERIAL SAFETY DATA SHEET WAS PREPARED BY ICC THE COMPLIANCE CENTER
INC. USING INFORMATION PROVIDED BY / OBTAINED FROM PARKER HANNIFIN CORP AND
CCOHS' WEB INFORMATION SERVICE. THE INFORMATION IN THE MATERIAL SAFETY DATA
SHEET IS OFFERED FOR YOUR CONSIDERATION AND GUIDANCE WHEN EXPOSED TO THIS
PRODUCT. ICC THE COMPLIANCE CENTER INC AND PARKER HANNIFIN CORP EXPRESSLY
DISCLAIM ALL EXPRESSED OR IMPLIED WARRANTIES AND ASSUME NO RESPONSIBILITIES
FOR THE ACCURACY OR COMPLETENESS OF THE DATA CONTAINED HEREIN. THE DATA IN
THIS MSDS DOES NOT APPLY TO USE WITH ANY OTHER PRODUCT OR IN ANY OTHER
PROCESS.
THIS MATERIAL SAFETY DATA SHEET MAY NOT BE CHANGED, OR ALTERED IN ANY WAY
WITHOUT THE EXPRESSED KNOWLEDGE AND PERMISSION OF ICC THE COMPLIANCE CENTER
INC. AND PARKER HANNIFIN CORP.